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Despujolsite

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Formula:
Ca
 
3
Mn
4+
 
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
System:HexagonalHardness:
Member of:Fleischerite Group
Name:In honour of Pierre Despujols (1888–?), founder of the Moroccan Geologic Survey.

Classification of Despujolsite

IMA status:Approved
Strunz 8th edition ID:6/D.11-10
Nickel-Strunz 10th (pending) edition ID:7.DF.25

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
F : With large and medium-sized cations
Dana 8th edition ID:31.7.6.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
7 : (AB)2(XO4)Zq·xH2O
Hey's CIM Ref.:25.9.6

25 : Sulphates
9 : Sulphates of Mn
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Type Occurrence of Despujolsite

Type Locality:Tachgagalt Mine, Ouarzazate Province, Souss-Massa-Draâ Region, Morocco
Year of Discovery:1968

Physical Properties of Despujolsite

Hardness (Mohs):

Crystallography of Despujolsite

Crystal System:Hexagonal
Class (H-M):6 m2 - Ditrigonal Dipyramidal
Space Group:P62c
Cell Parameters:a = 8.5405(5) Å, c = 10.8094(9) Å
Ratio:a:c = 1 : 1.266
Unit Cell Volume:V 682.81 ų
Z:2

Optical Data of Despujolsite

Type:Uniaxial (+)
RI values: nω = 1.656 nε = 1.682
Maximum Birefringence:δ = 0.026

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Despujolsite

Formula:
Ca
 
3
Mn
4+
 
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
Essential elements:Ca, H, Mn, O, S
All elements listed in formula:Ca, H, Mn, O, S

Relationship of Despujolsite to other Species

Member of:Fleischerite Group
Other Members of Group:

- +
Fleischerite
Pb
 
3
Ge(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
Mallestigite
Pb
 
3
Sb
5+
 
(SO
 
4
)(AsO
 
4
)(OH)
 
6
· 3H
 
2
O
Schaurteite
Ca
 
3
Ge(SO
 
4
)
 
2
(OH)
 
6
· 4H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
7.DF.05Uklonskovite
NaMg(SO
 
4
)F · 2H
 
2
O
7.DF.10Kainite
KMg(SO
 
4
)Cl · 3H
 
2
O
7.DF.15Natrochalcite
NaCu
 
2
(SO
 
4
)
 
2
(OH) · 2H
 
2
O
7.DF.20Metasideronatrite
Na
 
4
Fe
 
2
(SO
 
4
)
 
4
(OH)
 
2
· 2H
 
2
O
7.DF.20Sideronatrite
Na
 
2
Fe(SO
 
4
)
 
2
(OH) · 3H
 
2
O
7.DF.25Fleischerite
Pb
 
3
Ge(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
7.DF.25Schaurteite
Ca
 
3
Ge(SO
 
4
)
 
2
(OH)
 
6
· 4H
 
2
O
7.DF.25Mallestigite
Pb
 
3
Sb
5+
 
(SO
 
4
)(AsO
 
4
)(OH)
 
6
· 3H
 
2
O
7.DF.30Slavíkite
(H
 
3
O
+
 
)
 
3
Mg
 
6
Fe
 
15
(SO
 
4
)
 
21
(OH)
 
18
· 99H
 
2
O
7.DF.35Metavoltine
Na
 
6
K
 
2
FeFe
 
6
(SO
 
4
)
 
12
O
 
2
· 18H
 
2
O
7.DF.40Lannonite
HCa
 
4
Mg
 
2
Al
 
4
(SO
 
4
)
 
8
F
 
9
· 32H
 
2
O
7.DF.40Vlodavetsite
AlCa
 
2
(SO
 
4
)
 
2
F
 
2
Cl · 4H
 
2
O
7.DF.45Peretaite
Ca(SbO)
 
4
(SO
 
4
)
 
2
(OH)
 
2
· 2H
 
2
O
7.DF.50Gordaite
NaZn
 
4
(SO
 
4
)(OH)
 
6
Cl · 6H
 
2
O
7.DF.55Clairite
(NH
 
4
)
 
2
Fe
 
3
(SO
 
4
)
 
4
(OH)
 
3
· 3H
 
2
O
7.DF.60Arzrunite
Cu
 
4
Pb
 
2
(SO
 
4
)(OH)
 
4
Cl
 
6
· 2H
 
2
O (?)
7.DF.65Elyite
Pb
 
4
Cu(SO
 
4
)O
 
2
(OH)
 
4
· H
 
2
O
7.DF.70Yecoraite
Fe
3+
3
Bi
 
5
(Te
6+
 
O
 
4
)
 
2
(Te
4+
 
O
 
3
)O
 
9
· 9H
 
2
O
7.DF.75Riomarinaite
Bi(SO
 
4
)(OH) · H
 
2
O
7.DF.80Dukeite
Bi
3+
24
Cr
6+
8
O
 
57
(OH)
 
6
· 3H
 
2
O
7.DF.85Xocolatlite
Ca
 
2
Mn
4+
2
(Te
6+
 
O
 
6
)
 
2
· H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
25.9.1Szmikite
MnSO
 
4
· H
 
2
O
25.9.2Jôkokuite
MnSO
 
4
· 5H
 
2
O
25.9.3Mallardite
MnSO
 
4
· 7H
 
2
O
25.9.4Manganolangbeinite
K
 
2
Mn
 
2
(SO
 
4
)
 
3
25.9.5Chvaleticeite
(Mn,Mg)SO
 
4
· 6H
 
2
O
25.9.7Apjohnite
Mn
2+
 
Al
 
2
(SO
 
4
)
 
4
· 22H
 
2
O
25.9.8Shigaite
Al
 
4
Mn
 
7
(SO
 
4
)
 
2
(OH)
 
22
· 8H
 
2
O
25.9.9Ilesite
(Mn,Zn,Fe)SO
 
4
· 4H
 
2
O
25.9.10Mooreite
(Mg,Zn,Mn
2+
 
)
 
15
(SO
 
4
)
 
2
(OH)
 
26
· 8H
 
2
O
25.9.11Torreyite
(Mg,Mn
2+
 
)
 
9
Zn
 
4
(SO
 
4
)
 
2
(OH)
 
22
· 8H
 
2
O
25.9.12Lawsonbauerite
(Mn
2+
 
,Mg)
 
9
Zn
 
4
(SO
 
4
)
 
2
(OH)
 
22
· 8H
 
2
O
25.9.13Dietrichite
(Zn,Fe
2+
 
,Mn
2+
 
)Al
 
2
(SO
 
4
)
 
4
· 22H
 
2
O

Other Names for Despujolsite

Synonyms:
IMA1967-039
Other Languages:
German:Despujolsit
Russian:Деспужолсит
Spanish:Despujolsita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Despujolsite

Reference List:

- +
American Mineralogist: 54: 326.

Acta Crystallographica: B50: 481-510.

Barkley, M. C., Yang, H., Evans, S. H., Downs, R. T. and Origlieri, M. J. (2011): Redetermination of despujolsite, Ca3Mn4+(SO4)2(OH)6•3H2O. Acta Crystallogr. E67, i47-i48.

Internet Links for Despujolsite

Search Engines:
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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Despujolsite details from Handbook of Mineralogy (PDF)
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  • Localities for Despujolsite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Bolivia
     
    • Potosí Department
      • Tomás Frías Province
    Econ Geol (1997) 92:623-632; Dill, H.G. (1998): Mineralium Deposita 33, 359-378.
    Morocco
     
    • Souss-Massa-Draâ Region
      • Ouarzazate Province
    Bull.Soc.fr.Min.Crist.(1968) 91, 43-50
    South Africa
     
    • Northern Cape Province
      • Kalahari manganese fields
        • Kuruman
          • N'Chwaning Mines
    Rob Lavinsky (specimens analyzed by Dr. Robert Downs - University of Arizona)
    USA
     
    • New Mexico
      • Socorro Co.
        • Ojo Caliente No. 2 District
    NMBGMR Open-file Report - 535
    Mineral and/or Locality
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    Copyright © Jolyon Ralph and Ida Chau 1993-2011. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them. Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. Mindat does not offer minerals for sale. If you would like to add information to improve the quality of our database, then click here to register.
    Current server date and time: 9th Sep 2011 20:59:26
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