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Kettnerite

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Barbora adit, Knöttel (Knötel; Knödel) area, Krupka (Graupen), Krušné Hory Mts (Erzgebirge), Ústí Region, Bohemia (Böhmen; Boehmen), Czech Republic

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Formula:
CaBiCO
 
3
OF
System:Orthorhombic
Name:In honour of Radim Kettner (1891–1968), Professor of Geology, Charles University, Czech Republic.


A rare secondary Ca-Bi carbonate visually indistinguishable from bismutite and beyerite.

Classification of Kettnerite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:5/C.09-30
Strunz 9th edition ID:5.BE.
Nickel-Strunz 10th (pending) edition ID:5.BE.30

5 : CARBONATES (NITRATES)
B : Carbonates with additional anions, without H2O
E : With Pb, Bi
Dana 8th edition ID:16a.3.7.1

16a : ANHYDROUS CARBONATES CONTAINING HYDROXYL OR HALOGEN
3 : (AB)2(XO3)Zq
Hey's CIM Ref.:12.1.26

12 : Carbonates with other anions
1 : Carbonates with halides
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Type Occurrence of Kettnerite

Type Locality:Barbora adit, Knöttel (Knötel; Knödel) area, Krupka (Graupen), Krušné Hory Mts (Erzgebirge), Ústí Region, Bohemia (Böhmen; Boehmen), Czech Republic
Year of Discovery:1956

Crystallography of Kettnerite

Crystal System:Orthorhombic
Class (H-M):mmm (2/m 2/m 2/m) - Dipyramidal
Cell Parameters:a = 5.3641Å, c = 13.5771Å
Ratio:a:c = 1 : 2.531
Unit Cell Volume:V 0.00 ų (Calculated from Unit Cell)
Z:4
Twinning:Twinned via [001].
Comment:Pseudotetragonal, twinned. Subcell with a = 3.798 and c = 13.569 also known.
X-Ray Powder Diffraction:
d-spacingIntensity
2.89 (10)
2.104 (7)
1.893 (8)
1.732 (9)
1.589 (9)
1.278 (6)
1.200 (8)

Chemical Properties of Kettnerite

Formula:
CaBiCO
 
3
OF
Essential elements:Bi, C, Ca, F, O
All elements listed in formula:Bi, C, Ca, F, O

Relationship of Kettnerite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
5.BE.05Shannonite
Pb
 
2
OCO
 
3
5.BE.10Hydrocerussite
Pb
 
3
(CO
 
3
)
 
2
(OH)
 
2
5.BE.15Plumbonacrite
Pb
 
5
O(OH)
 
2
(CO
 
3
)
 
3
5.BE.20Phosgenite
Pb
 
2
CO
 
3
Cl
 
2
5.BE.25Bismutite
(BiO)
 
2
CO
 
3
5.BE.35Beyerite
Ca(BiO)
 
2
(CO
 
3
)
 
2
Related Minerals - Hey's Index Grouping:

- +
12.1.1Northupite
Na
 
3
Mg(CO
 
3
)
 
2
Cl
12.1.2Barentsite
Na
 
7
AlH
 
2
(CO
 
3
)
 
4
F
 
4
12.1.3Rouvilleite
Na
 
3
(Ca,Mn,Fe)
 
2
(CO
 
3
)
 
3
F
12.1.4Chlormagaluminite
(Mg,Fe
2+
 
)
 
4
Al
 
2
(Cl
 
2
,CO
 
3
)(OH)
 
12
 · 2H
 
2
O
12.1.5Defernite
Ca
 
6
(CO
 
3
)
 
2-x
(SiO
 
4
)
 
x
(OH)
 
7
(Cl,OH)
 
1-2x
 (x=0.5)
12.1.6Brenkite
Ca
 
2
(CO
 
3
)F
 
2
12.1.7Stenonite
(Sr,Ba,Na)
 
2
Al(CO
 
3
)F
 
5
12.1.8Bastnäsite-(Ce)
(Ce,La)(CO
 
3
)F
12.1.9Bastnäsite-(La)
(La,Ce)(CO
 
3
)F
12.1.10Bastnäsite-(Y)
(Y,Ce)(CO
 
3
)F
12.1.11Parisite-(Ce)
Ca(Ce,La)
 
2
(CO
 
3
)
 
3
F
 
2
12.1.12Parisite-(Nd)
Ca(Nd,Ce,La)
 
2
(CO
 
3
)
 
3
F
 
2
12.1.13Synchysite-(Ce)
Ca(Ce,La)(CO
 
3
)
 
2
F
12.1.14Synchysite-(Y)
Ca(Y,Ce)(CO
 
3
)
 
2
F
12.1.15Synchysite-(Nd)
Ca(Nd,Y,Gd)(CO
 
3
)
 
2
F
12.1.16Röntgenite-(Ce)
Ca
 
2
(Ce,La)
 
3
(CO
 
3
)
 
5
F
 
3
12.1.17Cordylite-(Ce)
NaBaCe
 
2
(CO
 
3
)
 
4
F
12.1.19Huanghoite-(Ce)
BaCe(CO
 
3
)
 
2
F
12.1.20Zhonghuacerite-(Ce)
Ba
 
2
Ce(CO
 
3
)
 
3
F
12.1.21Cebaite-(Ce)
Ba
 
3
Ce
 
2
(CO
 
3
)
 
5
F
 
2
12.1.22Thorbastnäsite
Th(Ca,Ce)(CO
 
3
)
 
2
F
 
2
 · 3H
 
2
O
12.1.23Phosgenite
Pb
 
2
CO
 
3
Cl
 
2
12.1.24Barstowite
Pb
 
4
Cl
 
6
(CO
 
3
) · H
 
2
O
12.1.25Albrechtschraufite
Ca
 
4
Mg(UO
 
2
)
 
2
(CO
 
3
)
 
6
F
 
2
 · 17 H
 
2
O

Other Names for Kettnerite

Other Languages:
German:Kettnerit
Russian:Кеттнерит
Spanish:Kettnerita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Kettnerite

Reference List:

- +
American Mineralogist (1957): 42:121.

American Mineralogist (1958): 43: 385.

Grice, J. D., Cooper, M. A. & Hawthorne, F. C. (1999): Crystal-structure determination of twinned kettnerite. Canadian Mineralogist, 37, 923-927.

Hybler, J. & Dušek, M. (2007): Revision of the crystal structure of kettnerite CaBi[OFCO3]. European Journal of Mineralogy, 19, 411-418.

Hybler, J. & Durovic, S. (2009): The OD interpretation of the crystal structure of kettnerite CaBiOFCO3. Acta Crystallogr. A65, 501-511.


Internet Links for Kettnerite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Kettnerite details from Handbook of Mineralogy (PDF)
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    • Localities for Kettnerite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Argentina
     
    • Córdoba
      • Punilla Department
        • Tanti
    		Colombo, F. y Lira, R. (2006) Geología y mineralogía de algunas pegmatitas del borde oriental del distrito Punilla, Córdoba. Revista de la Asociación Geológica Argentina 61:
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Karlovy Vary Region
        • Krušné Hory Mts (Erzgebirge)
          • Jáchymov (St Joachimsthal) District
            • Jáchymov (St Joachimsthal)
    		Lapis 2002(7/8), 46
    Lapis 2002(7/8), 46
      • Ústí Region
        • Krušné Hory Mts (Erzgebirge)
          • Krupka (Graupen)
            • Knöttel (Knötel; Knödel) area
    		Lapis 23(4), 18-34 (1998)
            • Steinknochen (Lux vein) area
    		Lapis 23(4), 18-34 (1998)
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Wolfach
          • Oberwolfach
            • Rankach valley
    		Walenta, K. (1992): Die Mineralien des Schwarzwaldes. Chr. Weise Verlag, München, 336 pp. (in German); WALENTA, K. (1993): Neue Mineralfunde von der Grube Clara (5. Folge). - Lapis 18 (1), 16-23.
    • Saxony
      • Erzgebirge
        • Marienberg District
          • Lauta
    		Hajek, W. (2010): Kristallwelten Marienberg. Weise Verlag, München.
        • Schlema-Hartenstein District
          • Schlema
            • Niederschlema
    		http://www.mineralienatlas.de/lexikon/index.php/Deutschland/Sachsen/Chemnitz%2C%20Direktionsbezirk/Erzgebirgskreis/Schlema-Alberoda-Hartenstein/Schacht%20382
    X-ray diffraction analysis, Thomas Witzke
        • Schneeberg District
          • Neustädtel
    		Lapis 30(7/8):41-70 (2005)
    Lapis 30(7/8):41-70 (2005)
    Lapis 30(7/8):41-70 (2005)
    Greece
     
    • Attikí (Attica; Attika) Prefecture
      • Lavrion (Laurion; Laurium) District
        • Lavrion District Mines
          • Agios Konstantinos [St Constantine] (Kamariza)
            • Kamariza Mines (Kamareza Mines)
              • Hilarion area
    		No reference listed
    USA
     
    • Arizona
      • Cochise Co.
        • Bowie area
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 209, 267.
        • Mule Mts
          • Warren District
    		[MinRec 24:421]
    Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 259, 267; Graeme, R. (1993), Bisbee revisited, Min.Rec.: 24: 421-436.
      • Graham Co.
        • Bowie [Cochise Co.] area
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 139.
      • La Paz Co.
        • Granite Wash Mts
          • Ellsworth District
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 139, 267.
    • California
      • Inyo Co.
        • Darwin District
          • Darwin
    		[Margerum, W. (2004) The Darwin Tungsten Area Part II: Mines and Mineralogy in the Bulletin of the Mineralogical Society of Southern California Vol. 74 No.5]
        • Inyo Mts (Inyo Range)
          • Manzanar Station area
    		Adams, Paul (2010) The Brown Monster and Reward Mines Inyo County, California. Mineralogical Record 41:175-193.
      • San Bernardino Co.
        • Baker
    		"The Blue Bell Claims San Bernardino County, California" Maynard, M, et al. pg. 40; Mills, S. J., Kampf, A. R., Kolitsch, U., Housley, R. M. & Raudsepp, M. (2010) The crystal chemistry and crystal structure of kuksite, Pb3Zn3Te6+P2O14, and a note on the crystal structure of yafsoanite, (Ca,Pb)3Zn(TeO6)2. American Mineralogist, 95(7), 933–938.
    • New Mexico
      • Hidalgo Co.
        • Apache No. 2 District
    		Min News 20:10 p 8
      • Luna Co.
    		Northrop, Minerals of New Mexico, 3rd rev. ed., 1996
    • Utah
      • Juab Co.
        • East Tintic Mts
          • Tintic District
    		Collected by and in the collection of Brent Thorne.
    Tony Nikischer specimen and analysis
      • Tooele Co.
        • Deep Creek Mts
          • Gold Hill District (Clifton District)
            • Gold Hill
              • Gold Hill Mine (Western Utah Mine)
    		collected by Brent Thorne
      • Utah Co.
        • Tintic District
          • Eureka
    		No reference listed
    • Wisconsin
      • Jefferson Co.
        • Waterloo
    		Buchholz, T.W., Falster, A.U., and Simmons, WmB. (2007) 34th Rochester Mineralogical Symposium, Contributed Papers.
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    Copyright © Jolyon Ralph and Ida Chau 1993-2011. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them. Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. Mindat does not offer minerals for sale. If you would like to add information to improve the quality of our database, then click here to register.
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