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Tapiolite-(Mn)

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Formula:
(Mn,Fe)(Ta,Nb)
 
2
O
 
6
System:TetragonalColour:Dark brown
Hardness:6 - 6½
Name:Named manganotapiolite in 1983 for its compositional relationship to ferrotapiolite.
Isostructural with:Tapiolite-(Fe)

Classification of Tapiolite-(Mn)

IMA status:Approved
Strunz 8th edition ID:4/D.04-20
Nickel-Strunz 10th (pending) edition ID:4.DB.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
B : With medium-sized cations; chains of edge-sharing octahedra
Dana 8th edition ID:8.3.1.2

8 : MULTIPLE OXIDES CONTAINING NIOBIUM,TANTALUM OR TITANIUM
3 : AB2O6
Hey's CIM Ref.:18.1.38

18 : Niobates and Tantalates
1 : Niobates and tantalates containing neither rare earths nor U
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Type Occurrence of Tapiolite-(Mn)

Type Locality:Tiainen pegmatite, Eräjärvi area, Orivesi, Western and Inner Finland Region, Finland
Year of Discovery:1983
Geological Setting of type material:Granite pegmatite.
Associated Minerals at type locality:
Tapiolite-(Fe)

Occurrences of Tapiolite-(Mn)

Geological Setting:Granite pegmatite.

Physical Properties of Tapiolite-(Mn)

Lustre:Sub-Adamantine, Metallic, Sub-Metallic
Diaphaneity (Transparency):Opaque
Colour:Dark brown
Streak:Dark brown
Hardness (Mohs):6 - 6½
Hardness (Vickers):VHN100=711 kg/mm2
Tenacity:Brittle
Cleavage:None Observed
Fracture:Irregular/Uneven, Splintery
Density (calculated):7.72 g/cm3

Crystallography of Tapiolite-(Mn)

Crystal System:Tetragonal
Class (H-M):4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Space Group:P42/mnm {P42/m 21/n 2/m}
Cell Parameters:a = 4.762Å, c = 9.272Å
Ratio:a:c = 1 : 1.947
Unit Cell Volume:V 210.26 ų (Calculated from Unit Cell)
Z:2
Morphology:Nearly equant to short prismatic.
Twinning:Twinning is not mentioned in the original description, but may be present.
X-Ray Powder Diffraction:
d-spacingIntensity
4.24 (40)
3.37 (100)
2.59 (90)
2.38 (60)
1.75 (90)
1.68 (60)
1.50 (40)
1.41 (40)
Comments:ICDD 35-626

Optical Data of Tapiolite-(Mn)

Type:Uniaxial
Type:Anisotropic
Anisotropism:Weak
Optical Extinction:Parallel
Colour in reflected light:Gray
Internal Reflections:strong red-brown

Chemical Properties of Tapiolite-(Mn)

Formula:
(Mn,Fe)(Ta,Nb)
 
2
O
 
6
Essential elements:Mn, O, Ta
All elements listed in formula:Fe, Mn, Nb, O, Ta
Analytical Data:Compositions with Mn>Fe = 59:32 not yet reported.

Relationship of Tapiolite-(Mn) to other Species

Series:Forms a series with Tapiolite-(Fe) (see here)
Related Minerals - Nickel-Strunz Grouping):

- +
4.DB.05Argutite
GeO
 
2
4.DB.05Cassiterite
SnO
 
2
4.DB.05Plattnerite
PbO
 
2
4.DB.05Pyrolusite
MnO
 
2
4.DB.05Rutile
TiO
 
2
4.DB.05Tripuhyite
Fe
3+
 
Sb
5+
 
O
 
4
4.DB.05Tugarinovite
MoO
 
2
4.DB.05Varlamoffite
(Sn,Fe)(O,OH)
 
2
4.DB.10Byströmite
MgSb
 
2
O
 
6
4.DB.10Tapiolite-(Fe)
(Fe,Mn)(Ta,Nb)
 
2
O
 
6
4.DB.10Ordoñezite
ZnSb
 
2
O
 
6
4.DB.15bAkhtenskite
ε-Mn
4+
 
O
 
2
4.DB.15cNsutite
(Mn
4+
 
,Mn
2+
 
)(O,OH)
 
2
4.DB.15aParamontroseite
V
4+
 
O
 
2
4.DB.15aRamsdellite
Mn
4+
 
O
 
2
4.DB.20Scrutinyite
alpha-PbO
 
2
4.DB.25Ishikawaite
U
4+
 
Fe
2+
 
Nb
 
2
O
 
8
4.DB.25Ixiolite
(Ta,Nb,Sn,Fe,Mn)
 
4
O
 
8
4.DB.25Samarskite-(Y)
(Y,Fe
3+
 
,Fe
2+
 
,U,Th,Ca)
 
2
(Nb,Ta)
 
2
O
 
8
4.DB.25Srilankite
Ti
 
2
ZrO
 
6
4.DB.25Yttrocolumbite-(Y)
Y(U
4+
 
,Fe
2+
 
)Nb
 
2
O
 
8
4.DB.25Calciosamarskite
(Ca,Fe
3+
 
,Y)
 
2
(Nb,Ta,Ti)
 
2
O
 
8
4.DB.25Samarskite-(Yb)
(Yb,Fe
3+
 
)
 
2
(Nb,Ta)
 
2
O
 
8
4.DB.30Ferberite
FeWO
 
4
4.DB.30Hübnerite
MnWO
 
4
4.DB.30Sanmartinite
(Zn,Fe)WO
 
4
4.DB.30Krasnoselskite
CoWO
 
4
4.DB.30Heftetjernite
ScTaO
 
4
4.DB.30Huanzalaite
MgWO
 
4
4.DB.35Columbite-(Fe)
FeNb
 
2
O
 
6
4.DB.35Tantalite-(Fe)
FeTa
 
2
O
 
6
4.DB.35Columbite-(Mn)
(Mn,Fe)(Nb,Ta)
 
2
O
 
6
4.DB.35Tantalite-(Mn)
MnTa
 
2
O
 
6
4.DB.35Columbite-(Mg)
(Mg,Fe,Mn)(Nb,Ta)
 
2
O
 
6
4.DB.35Qitianlingite
(Fe,Mn)
 
2
(Nb,Ta)
 
2
WO
 
10
4.DB.35Magnocolumbite
4.DB.35Tantalite-(Mg)
(Mg,Fe
2+
 
)(Ta,Nb)
 
2
O
 
6
4.DB.40Ferrowodginite
FeSnTa
 
2
O
 
8
4.DB.40Lithiotantite
Li(Ta,Nb)
 
3
O
 
8
4.DB.40Lithiowodginite
LiTa
 
3
O
 
8
4.DB.40Titanowodginite
MnTiTa
 
2
O
 
8
4.DB.40Wodginite
Mn(Sn,Ta)Ta
 
2
O
 
8
4.DB.40Ferrotitanowodginite
Fe
2+
 
TiTa
 
2
O
 
8
4.DB.40Wolframowodginite
Mn(Mn,Sn,Fe,Ta)(W,Ta,Nb)
 
2
O
 
8
4.DB.45Tivanite
V
3+
 
TiO
 
3
(OH)
4.DB.50Carmichaelite
(Ti,Cr,Fe)[O
 
2-x
(OH)
 
x
]
4.DB.55Alumotantite
AlTaO
 
4
4.DB.60Biehlite
((Sb,As)O)
 
2
[MoO
 
4
]
Related Minerals - Hey's Index Grouping:

- +
18.1.1Lithiotantite
Li(Ta,Nb)
 
3
O
 
8
18.1.2Lueshite
NaNbO
 
3
18.1.3Natroniobite
NaNbO
 
3
18.1.4Franconite
Na
 
2
Nb
 
4
O
 
11
· 9H
 
2
O
18.1.5Natrotantite
Na
 
2
Ta
 
4
O
 
11
18.1.6Irtyshite
Na
 
2
(Ta,Nb)
 
4
O
 
11
18.1.7Rankamaite
(Na,K,Pb,Li)
 
3
(Ta,Nb,Al)
 
11
(O,OH)
 
30
18.1.8Hydropyrochlore
(H
 
2
O,□)
 
2
Nb
 
2
(O,OH)
 
6
(H
 
2
O)
18.1.9Calciotantite
CaTa
 
4
O
 
11
18.1.10Rynersonite
Ca(Ta,Nb)
 
2
O
 
6
18.1.11Microlite Group
18.1.12Belyankinite
Ca
 
1-2
(Ti,Nb)
 
5
O
 
12
· 9H
 
2
O (?)
18.1.13Latrappite
(Ca,Na)(Nb,Ti,Fe)O
 
3
18.1.14Hochelagaite
(Ca,Na,Sr)(Nb,Ti,Si,Al)
 
4
O
 
11
· 8H
 
2
O
18.1.15Bariomicrolite (of Hogarth 1977)
18.1.16Parabariomicrolite
BaTa
 
4
O
 
10
(OH)
 
2
· 2H
 
2
O
18.1.17Bariopyrochlore (of Hogarth 1977)
18.1.18Alumotantite
AlTaO
 
4
18.1.19Simpsonite
Al
 
4
(Ta,Nb)
 
3
O
 
13
(OH,F)
18.1.20Sosedkoite
(K,Na)
 
5
Al
 
2
(Ta,Nb)
 
22
O
 
60
18.1.21Thoreaulite
SnTa
 
2
O
 
6
18.1.22Stannomicrolite (of Hogarth 1977)
18.1.23Foordite
(Sn,Pb)(Nb,Ta)
 
2
O
 
6
18.1.24Changbaiite
PbNb
 
2
O
 
6
18.1.25Plumbopyrochlore (of Skorobogatova et al)
18.1.26Plumbomicrolite (of Hogarth 1977)
18.1.27Stibiocolumbite
Sb(Nb,Ta)O
 
4
18.1.28Stibiotantalite
Sb(Ta,Nb)O
 
4
18.1.29Natrobistantite
18.1.30Cesplumtantite
(Cs,Na)
 
2
(Pb,Sb
3+
 
)
 
3
Ta
 
8
O
 
24
18.1.31Stibiomicrolite (of Groat et al)
18.1.32Cesstibtantite
18.1.34Bismutotantalite
Bi(Ta,Nb)O
 
4
18.1.35Bismutomicrolite (of Hogarth 1977)
18.1.36Tantalite-(Mn)
MnTa
 
2
O
 
6
18.1.37Gerasimovskite
(Mn,Ca)(Nb,Ti)
 
5
O
 
12
· 9H
 
2
O
18.1.39Columbite-(Mn)
(Mn,Fe)(Nb,Ta)
 
2
O
 
6
18.1.40Wodginite
Mn(Sn,Ta)Ta
 
2
O
 
8
18.1.41Ixiolite
(Ta,Nb,Sn,Fe,Mn)
 
4
O
 
8
18.1.42Columbite-(Fe)
FeNb
 
2
O
 
6
18.1.43Tantalite-(Fe)
FeTa
 
2
O
 
6
18.1.44Columbite
(Fe,Mn)(Nb,Ta)
 
2
O
 
6
18.1.45Tantalite
(Fe,Mn)(Ta,Nb)
 
2
O
 
6
18.1.46Tapiolite
(Fe,Mn)(Ta,Nb)
 
2
O
 
6
18.1.47Tapiolite-(Fe)
(Fe,Mn)(Ta,Nb)
 
2
O
 
6
18.1.48Columbite-(Mg)
(Mg,Fe,Mn)(Nb,Ta)
 
2
O
 
6
18.1.50Strüverite
(Ti,Ta,Fe)O
 
2
18.1.51 Staringite
(Fe,Mn)
 
x
(Ta,Nb)
 
2x
Sn
 
6-3x
O
 
12

Other Names for Tapiolite-(Mn)

Synonyms:
IMA1983-005Manganotapiolite
Other Languages:
German:Manganotapiolit
Russian:Манганотапиолит
Spanish:Manganotapiolita

Other Information

Fluorescence in UV light:Not fluorescent.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Industrial Uses:Known in only a very few specimens. Compositionally zoned.

References for Tapiolite-(Mn)

Reference List:

- +
- Lahti, S.I., Johanson, B. & Virkkunen, M. (1983): Contribution to the chemistry of tapiolite – manganotapiolite, a new mineral. Bulletin of the Geological Society of Finland. 55, 101-109.
American Mineralogist (1985): 70: 217.
Mineralogical Record 39:132
Canadian Mineralogist (1996): 34: 631-647.

Internet Links for Tapiolite-(Mn)

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  • Localities for Tapiolite-(Mn)

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Finland
     
    • Western and Inner Finland Region
      • Orivesi
        • Eräjärvi area
    Lahti, S.I., Johanson, B. & Virkkunen, M. (1983): Contribution to the chemistry of tapiolite – manganotapiolite, a new mineral. Bulletin of the Geological Society of Finland. 55, 101-109.
    USA
     
    • Maine
      • Franklin Co.
        • D Township
    King, V. and Foord, E., 1994, Mineralogy of Maine, volume 1.
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