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Pitiglianoite

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Big Photo

Mt Cavalluccio, Campagnano di Roma, Sacrofano Caldera, Rome Province, Latium, Italy
© Elmar Lackner

Show Pitiglianoite Photos (14)



Formula:
Na
 
6
K
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
) · 2H
 
2
O
System:HexagonalColour:colourless
Hardness:5
Member of:Cancrinite Group


Cancrinite Group.

Classification of Pitiglianoite

IMA status:Approved 1990
Strunz 8th edition ID:8/J.09-65
Nickel-Strunz 10th (pending) edition ID:9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
Dana 8th edition ID:76.2.5.11

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
Hey's CIM Ref.:17.10.2

17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate
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Type Occurrence of Pitiglianoite

Type Locality:Case Collina (Toscopomici quarry), Pitigliano, Grosseto Province, Tuscany, Italy

Physical Properties of Pitiglianoite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent
Colour:colourless
Streak:white
Hardness (Mohs):5
Cleavage:Poor/Indistinct

Crystallography of Pitiglianoite

Crystal System:Hexagonal

Optical Data of Pitiglianoite

Type:Uniaxial (-)
RI values: nω = 1.508 nε = 1.506
Maximum Birefringence:δ = 0.002

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low

Chemical Properties of Pitiglianoite

Formula:
Na
 
6
K
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
) · 2H
 
2
O
Essential elements:Al, H, K, Na, O, S, Si
All elements listed in formula:Al, H, K, Na, O, S, Si

Relationship of Pitiglianoite to other Species

Member of:Cancrinite Group
Other Members of Group:

- +
Afghanite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(Cl
 
2
,SO
 
4
,CO
 
3
)
 
3
 · 0.5H
 
2
O
Alloriite
(Na,Ca,K)
 
26
Ca
 
4
(Al
 
6
Si
 
6
O
 
24
)
 
4
(SO
 
4
)
 
6
Cl
 
6
Biachellaite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
(OH)
 
0.5
 · H
 
2
O
Bystrite
(Na,K)
 
7
Ca(Al
 
6
Si
 
6
O
 
24
)(S
 
3
)
 
1.5
 · H
 
2
O
Cancrinite
(Na,Ca,☐)
 
8
(Al
 
6
Si
 
6
O
 
24
)(CO
 
3
,SO
 
4
)
 
2
 · 2H
 
2
O
Cancrisilite
Na
 
7
(Al
 
5
Si
 
7
O
 
24
)(CO
 
3
) · 3H
 
2
O
Davyne
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(Cl
 
2
,SO
 
4
)
 
2
Depmeierite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(PO
 
4
,CO
 
3
)
 
1-x
 · 3H
 
2
O (x<0.5)
Franzinite
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
 · 0.5H
 
2
O
Giuseppettite
(Na,K,Ca)
 
7-8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,Cl)
 
1-2
Hydroxycancrinite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(OH)
 
2
 · 2H
 
2
O
Kircherite
Na
 
5
Ca
 
2
K(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
 · 0.33H
 
2
O
Kyanoxalite
Na
 
7
(Al
 
6-x
Si
 
6+x
O
 
24
)(C
 
2
O
 
4
)
 
0.5+x
 · 5H
 
2
O (0 < x < 0.5)
Liottite
(Na,K)
 
16
Ca
 
8
(Al
 
6
Si
 
6
O
 
24
)
 
3
(SO
 
4
)
 
5
Cl
 
4
Marinellite
(Na,K)
 
42
Ca
 
6
(Al
 
6
Si
 
6
O
 
24
)
 
6
(SO
 
4
)
 
8
Cl
 
2
 · 3H
 
2
O
Microsommite
Na
 
4
K
 
2
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)Cl
 
2
Quadridavyne
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)Cl
 
4
Sacrofanite
(Na,K)
 
98
Ca
 
20
(Al
 
6
Si
 
6
O
 
24
)
 
14
(SO
 
4
)
 
26
Cl
 
2
 · 8H
 
2
O
Tounkite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
Cl · H
 
2
O
Vishnevite
(Na,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,CO
 
3
) · 2H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
9.FB.05Afghanite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(Cl
 
2
,SO
 
4
,CO
 
3
)
 
3
 · 0.5H
 
2
O
9.FB.05Bystrite
(Na,K)
 
7
Ca(Al
 
6
Si
 
6
O
 
24
)(S
 
3
)
 
1.5
 · H
 
2
O
9.FB.05Cancrinite
(Na,Ca,☐)
 
8
(Al
 
6
Si
 
6
O
 
24
)(CO
 
3
,SO
 
4
)
 
2
 · 2H
 
2
O
9.FB.05Cancrisilite
Na
 
7
(Al
 
5
Si
 
7
O
 
24
)(CO
 
3
) · 3H
 
2
O
9.FB.05Davyne
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(Cl
 
2
,SO
 
4
)
 
2
9.FB.05Franzinite
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
 · 0.5H
 
2
O
9.FB.05Giuseppettite
(Na,K,Ca)
 
7-8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,Cl)
 
1-2
9.FB.05Hydroxycancrinite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(OH)
 
2
 · 2H
 
2
O
9.FB.05Liottite
(Na,K)
 
16
Ca
 
8
(Al
 
6
Si
 
6
O
 
24
)
 
3
(SO
 
4
)
 
5
Cl
 
4
9.FB.05Microsommite
Na
 
4
K
 
2
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)Cl
 
2
9.FB.05Quadridavyne
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)Cl
 
4
9.FB.05Sacrofanite
(Na,K)
 
98
Ca
 
20
(Al
 
6
Si
 
6
O
 
24
)
 
14
(SO
 
4
)
 
26
Cl
 
2
 · 8H
 
2
O
9.FB.05Tounkite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
Cl · H
 
2
O
9.FB.05Vishnevite
(Na,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,CO
 
3
) · 2H
 
2
O
9.FB.05Marinellite
(Na,K)
 
42
Ca
 
6
(Al
 
6
Si
 
6
O
 
24
)
 
6
(SO
 
4
)
 
8
Cl
 
2
 · 3H
 
2
O
9.FB.05Farneseite
(Na,Ca,K)
 
56
(Al
 
6
Si
 
6
O
 
24
)
 
7
(SO
 
4
)
 
12
 · 6H
 
2
O
9.FB.05Alloriite
(Na,Ca,K)
 
26
Ca
 
4
(Al
 
6
Si
 
6
O
 
24
)
 
4
(SO
 
4
)
 
6
Cl
 
6
9.FB.05Fantappièite
[Na
 
82.5
Ca
 
33
K
 
16.5
](Si
 
99
Al
 
99
O
 
396
)(SO
 
4
)
 
33
 · 4H
 
2
O
9.FB.05Kyanoxalite
Na
 
7
(Al
 
6-x
Si
 
6+x
O
 
24
)(C
 
2
O
 
4
)
 
0.5+x
 · 5H
 
2
O (0 < x < 0.5)
9.FB.05Balliranoite
(Na,K)
 
6
Ca
 
2
(Si
 
6
Al
 
6
O
 
24
)Cl
 
2
(CO
 
3
)
9.FB.05Carbobystrite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(CO
 
3
) · 3.5H
 
2
O
9.FB.05Depmeierite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(PO
 
4
,CO
 
3
)
 
1-x
 · 3H
 
2
O (x<0.5)
9.FB.05Kircherite
Na
 
5
Ca
 
2
K(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
 · 0.33H
 
2
O
9.FB.10Bicchulite
Ca
 
2
(Al
 
2
SiO
 
6
)(OH)
 
2
9.FB.10Danalite
Fe
2+
4
(Be
 
3
Si
 
3
O
 
12
)S
9.FB.10Genthelvite
Zn
 
4
(Be
 
3
Si
 
3
O
 
12
)S
9.FB.10Haüyne
(Na,Ca)
 
4-8
(Al
 
6
Si
 
6
(O,S)
 
24
)(SO
 
4
,Cl)
 
1-2
9.FB.10Helvite
Mn
2+
4
(Be
 
3
Si
 
3
O
 
12
)S
9.FB.10Kamaishilite
Ca
 
2
(Al
 
2
SiO
 
6
)(OH)
 
2
9.FB.10Lazurite
(Na,Ca)
 
8
(Al
 
6
Si
 
6
O
 
24
)(S,SO
 
4
,Cl
 
2
)
9.FB.10Nosean
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
9.FB.10Sodalite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)Cl
 
2
9.FB.10Tsaregorodtsevite
(N(CH
 
3
)
 
4
)(AlSi
 
5
O
 
12
)
9.FB.10Tugtupite
Na
 
4
(AlBeSi
 
4
O
 
12
)Cl
9.FB.10Helvine
9.FB.15Marialite
Na
 
4
Al
 
3
Si
 
9
O
 
24
Cl
9.FB.15Meionite
Ca
 
4
Al
 
6
Si
 
6
O
 
24
CO
 
3
9.FB.15Silvialite
(Ca,Na)
 
4
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,CO
 
3
)
Related Minerals - Hey's Index Grouping:

- +
17.10.1Nosean
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
17.10.3Vishnevite
(Na,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,CO
 
3
) · 2H
 
2
O
17.10.4Haüyne
(Na,Ca)
 
4-8
(Al
 
6
Si
 
6
(O,S)
 
24
)(SO
 
4
,Cl)
 
1-2
17.10.5Liottite
(Na,K)
 
16
Ca
 
8
(Al
 
6
Si
 
6
O
 
24
)
 
3
(SO
 
4
)
 
5
Cl
 
4
17.10.6Latiumite
K
 
2
Ca
 
6
(Si,Al)
 
11
O
 
25
(SO
 
4
,CO
 
3
)
17.10.7Tuscanite
(K(Ca,Na)
 
6
(Si,Al)
 
10
O
 
22
[SO
 
4
,CO
 
3
,(OH)
 
2
] · H
 
2
O
17.10.8Microsommite
Na
 
4
K
 
2
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)Cl
 
2
17.10.9Delhayelite
(Na,K)
 
10
Ca
 
5
Al
 
6
Si
 
32
O
 
80
(Cl
 
2
,F
 
2
,SO
 
4
)
 
3
 · 18H
 
2
O
17.10.10Hydrodelhayelite
KCa
 
2
AlSi
 
7
O
 
17
(OH)
 
2
 · 6H
 
2
O
17.10.11Davyne
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(Cl
 
2
,SO
 
4
)
 
2
17.10.12Afghanite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(Cl
 
2
,SO
 
4
,CO
 
3
)
 
3
 · 0.5H
 
2
O
17.10.13Franzinite
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
 · 0.5H
 
2
O
17.10.14Giuseppettite
(Na,K,Ca)
 
7-8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,Cl)
 
1-2
17.10.15Sacrofanite
(Na,K)
 
98
Ca
 
20
(Al
 
6
Si
 
6
O
 
24
)
 
14
(SO
 
4
)
 
26
Cl
 
2
 · 8H
 
2
O
17.10.16Chessexite
(Na,K)
 
4
Ca
 
2
(Mg,Zn)
 
3
Al
 
8
(SO
 
4
)
 
10
(SiO
 
4
)
 
2
 · 40H
 
2
O
17.10.17Innelite
Na
 
2
CaBa
 
4
Ti
 
3
(Si
 
2
O
 
7
)
 
2
(SO
 
4
)
 
2
O
 
4
17.10.18Thaumasite
Ca
 
3
(SO
 
4
)[Si(OH)
 
6
](CO
 
3
) · 12H
 
2
O
17.10.19Ellestadite
17.10.20Ellestadite-(Cl)
Ca
 
10
(SiO
 
4
)
 
3
(SO
 
4
)
 
3
Cl
 
2
17.10.21Hydroxylellestadite
Ca
 
5
(SiO
 
4
)
 
1.5
(SO
 
4
)
 
1.5
(OH)
17.10.22Fluorellestadite
Ca
 
5
(SiO
 
4
)
 
1.5
(SO
 
4
)
 
1.5
F
17.10.23Mattheddleite
Pb
 
5
(SiO
 
4
)
 
1.5
(SO
 
4
)
 
1.5
(Cl,OH)
17.10.24Queitite
Pb
 
4
Zn
 
2
(SO
 
4
)(SiO
 
4
)(Si
 
2
O
 
7
)
17.10.25Roeblingite
Pb
 
2
Ca
 
6
Mn
2+
 
(Si
 
3
O
 
9
)
 
2
(SO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
17.10.26Yoshimuraite
Ba
 
2
Mn
 
2
Ti(Si
 
2
O
 
7
)(PO
 
4
)O(OH)
17.10.27Kegelite
Pb
 
8
Al
 
4
(Si
 
8
O
 
20
)(SO
 
4
)
 
2
(CO
 
3
)
 
4
(OH)
 
8
17.10.28Wenkite
(Ba,K)
 
4
(Ca,Na)
 
6
[(SO
 
4
)
 
3
|(Si,Al)
 
20
O
 
39
(OH)
 
2
] · 0.5H
 
2
O
17.10.29Macquartite
Pb
 
3
Cu(CrO
 
4
)(SiO
 
3
)(OH)
 
4
 · 2H
 
2
O
17.10.30Welinite
Mn
2+
6
(W
6+
 
,Mg)
 
2
(SiO
 
4
)
 
2
(O,OH)
 
6

Other Names for Pitiglianoite

Synonyms:
IMA1990-012
Other Languages:
German:Pitiglianoit
Russian:Питильяноит
Spanish:Pitiglianoita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Pitiglianoite

Reference List:

- +
Merlino S., Mellini M., Bonaccorsi E., Pasero M., Leoni L., Orlandi P.(1991): Pitiglianoite, a new feldspathoid from southern Tuscany, Italy: chemical composition and crystal structure. American Mineralogist: 76: 2003-2008.

New Minerals (1997), New Minerals 1990-1994.

Internet Links for Pitiglianoite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Pitiglianoite details from Handbook of Mineralogy (PDF)
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    • Localities for Pitiglianoite

    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Italy
     
    • Latium
      • Rome Province
        • Sacrofano Caldera
          • Campagnano di Roma
    		 Della Ventura, G., Bellatreccia, F., Bonaccorsi, E. (2005): CO2 in minerals of the cancrinite-sodalite group: pitiglianoite. European Journal of Mineralogy, 17, 847-851.
      • Viterbo Province
        • Farnese
    		Sandro Maggia collection
        • Valentano
    		Luigi Mattei Collection
    • Tuscany
      • Grosseto Province
        • Pitigliano
    		Merlino S., Mellini M., Bonaccorsi E., Pasero M., Leoni L., Orlandi P.(1991): Pitiglianoite, a new feldspathoid from southern Tuscany, Italy: chemical composition and crystal structure. Am. Mineral., 76, 2003-2008.
    Mineral and/or Locality
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