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About crystal-chemical formula of chromdravite

Posted by Uwe Kolitsch  
About crystal-chemical formula of chromdravite
January 20, 2012 02:26PM
    
Rozhdestvenskaya, I. V.; Vereshchagin, O. S.; Frank-Kamenetskaya, O. V.; Zolotarev, A. A.; Pekov, I. V. (2011): About crystal-chemical formula of chromdravite - mineral species from the tourmaline group. Zapiski Rossiiskogo Mineralogicheskogo Obshchestva (Proceedings of the Russian Mineralogical Society) 140, 93-99 (in Russian).

The crystal structure of tourmaline with high chromium content (~32 wt % of Cr2O3) from micaceous metasomatites of Onega flexure (a = 16.154, c = 7.427 Å, sp. gr. R3m, R = 0.040, Rw = 0.043) has been refined. The disorder distribution of Cr3+ and Mg2+ cations over Y- and Z-octahedral sites described by the ideal formula Na(Cr2Mg)(Cr4Mg2)(BO3)3(Si6O18)(OH)4 was revealed. The proximity of the common element composition of tourmaline examined to the composition of original chromdravite from the same deposit necessitates the revision of the ideal formula of this mineral species approved before by the commission of IMA.

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Edited 2 time(s). Last edit at 01/21/2012 04:31PM by Uwe Kolitsch.
avatar Re: About crystal-chemical formula of chromdravite
January 20, 2012 07:40PM
The correct name of the mineral is chromium-dravite.
Re: About crystal-chemical formula of chromdravite
January 20, 2012 11:34PM
An interesting consequence of this disorder is that the distinction between chromium-dravite and hypothetical "chromium-schorl" is lost, since both have Cr3+ as the dominant cation on both types of octahedral site.
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