Mindat Logo

Harshaw District, Patagonia Mts, Santa Cruz Co., Arizona, USA

‡Ref.: The Resources of Arizona - A Reliable Manual of Information Concerning the Territory, compiled by Patrick Hamilton (1881), Prescott, Arizona: 42.

Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 245-279.

Kartchner, W.E. (1944) The geology and ore deposits of a portion of the Harshaw district, Patagonia Mountains, Arizona: Tucson, University of Arizona, Ph.D. dissertation, 100 p.

Havens, R., et al (1954), Benefication of oxide manganese and manganese-silver ores from southern Arizona, U.S. Bureau of Mines Report of Investigation 5024.

Moores, R.C., III (1972) The geology and ore deposits of a portion of the Harshaw district, Santa Cruz County, Arizona: Tucson, University of Arizona, M.S. thesis, 98 p.

Simons, F.S. (1974) Geologic map and sections of the Nogales and Lochiel quadrangles, Santa Cruz County, Arizona: U.S. Geological Survey Miscellaneous Investigations Series Map I-762, 9 p., 1 sheet, scale 1:48,000.

Davis, S.R. (1975), The Hardshell silver deposit, Harshaw Mining District, Santa Cruz County, Arizona (abstract), Symposium of the New Mexico Geological Society and Arizona Geological Society Abstract with Programs: 6.

Keith, Stanton B. (1975), Arizona Bureau of mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 55.

Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 145, 195.

Arizona Bureau of Mines file data.

A Zn-Pb-Ag-Cu-Au-Mn (F-Ba-alunite) mining area located in T.22-23S., R.15-16E, in the northeastern Patagonia Mountains, about 70 miles SE of Tucson. This district adjoins the Wrightson District and Redrock District on the south. It is about 5 miles wide and extends from Sonoita Creek at Patagonia 9 miles southeastward to a point 3 miles beyond Harshaw. Harshaw Creek marks the northeast boundary, Meadow Valley Flat the east boundary, and east-west line passing just south of the American Mine the south boundary, separating it from the Patagonia District, and the main ridge of the Patagonia Mountains to the west of Alum and Flux Gulches the west boundary, separating it from the Patagonia District.

The topography is rough and much of it in the western part, which lies in the Patagonia Mountains, and rises to elevations of more than 6,000 feet, is rugged.

The bedrock of the district comprises five or more formations, which, named in ascending order, are the Paleozoic limestones, quartz diorite, granite porphyry, rhyolite, and andesite. The most important of the formations with reference to the mineral deposits are the diorite, granite porphyry, and rhyolite.

The Paleozoic limestones occupy only a small east-west belt along the middle part of the southern border of the district, but this belt is part of the limestone area around Mowry on the south.

The quartz diorite and granite porphyry belong with the group of Mesozoic intrusive rocks and the rhyolite and andesite with the Tertiary volcanic rocks.

The quartz diorite occupies an irregular belt about ¾ mile wide and nearly 3 miles long, extending from a point about 1 mile SE of Harshaw northwestward to the World's Fair ine and Alum Canyon.

The granite porphyry occupies a belt about ½ mile wide along the western border of the district, where it seems to underlie the rhyolite. This belt is but the eastern part of the much larger area in the Palmetto District, on the west.

The most extensive formation is the rhyolite, which, besides occurring in a north-south belt near the west border of the district, occupies a belt 2 miles wide extending across the north-central part and includes practically the whole of Red Mountain. It is coarsely porphyritic, tridymite-bearing rock profusely impregnated with pyrite, chalcopyrite, and chalcocite disseminated in crystals and grains and at a number of places contains promising copper prospects. The oxidation of the iron content of these minerals colors the entire mountain a brilliant red. In Alum Canyon, on the southwest, the weathered surface of the rock and the alluvial gravels derived from it are coated with efflorescences and incrustations of alum, some of whose constituents seem to be derived from the pyritic content of the rock through oxidation.

The next most abundant rock is the andesite, which occurs in flows and tuffs filling chiefly the valleys and low places. It overlies the rhyolite and other older rocks. Besides occupying an irregular circular area about 2½ miles in diameter in the south-central part of the district, north of Harshaw. It also occurs in a belt about 1 mile wide extending northward along the Patagonia road for about 3 miles.

Some syenitic rocks occur locally in the western part of Alum Canyon.

Quaternary gravels occupy two belts, each about 1½ miles in width, across the northeast and southwest ends of the district and more or less deeply cover the bedrock formations.

Mineralization is varied: (1) Irregular and lensing lodes and veins of argentiferous lead minerals with varying zinc, copper and minor gold along fault fissures and in breccia zones in Jurassic-Triassic, Cretaceous, and Laramide andesitic and rhyolite volcanics, probably intruded below by a Laramide granitic body. Some replacement of interbedded limestone in the volcanics. Silver enrichment near the surface; (2) Disseminations and fracture fillings of copper mineralization, with varying lead and zinc, in brecciated zones in Cretaceous andesite; (3) Irregular mantos, lenses and pods of manganese-silver ore as replacements in silicified, altered and brecciated Paleozoic limestone and Jurassic-Triassic volcanics and agglomerate; and, (4) Small, spotty, and generally low grade gold placer deposits.

Workings include shaft, tunnel, adit and open pit operations. Developed and mined from about the 1850's to the middle 1960's. Total production would be some 1,300,000 tons of ore containing about 86,000 tons of zinc, 72,000 tons of lead, 9,200,000 oz. of silver, 3,100 tons of copper and 4,300 oz. of gold. An estimated 10,000 long tons of manganese ores of variable grade were also produced, much of it as argentiferous smelter flux. Placer gold output is unknown but probably minor.




Mineral list contains entries from the region specified including sub-localities


Mineral List:
  • Acanthite
    Ag
     
    2
    S
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 101; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, AZ, USGS Bull. 582: 262; Schrader, F.C. (1917), The geologic distribution and genesis of the metals in the Santa Rite-Patagonia Mountains, AZ, Econ.Geol.: 12: 237-269; Galbraith, F.W. (1947), Minerals of AZ, AZ Bur. Mines Bull. 153: 15.]
  • Alabandite
    Mn
    2+
     
    S
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 104.]
  • 'Alum Group'
    XAl(SO
     
    4
    )
     
    2
    ·12H
     
    2
    O
    Description: A weathering product on outcroppings.
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 258.]
  • Alunite
    KAl
     
    3
    [(OH)
     
    3
    |SO
     
    4
    ]
     
    2
    Reference: [MRDS database Dep. ID file #10048351, MRDS ID #M899941]
  • Andalusite
    Al
     
    2
    [O|SiO
     
    4
    ]
    Reference: [Singer, D.A., Berger, V.I., and Moring, B.C. (2008): US Geological Survey Open-File Report 2008-1155.]
  • Anglesite
    PbSO
     
    4
    Habit: Crystals up to 1 cm long
    Colour: Yellow
    Description: Occurs as clear crystals in goethite vugs.
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 112.]
  • Aurichalcite
    (Zn,Cu)
     
    5
    [(OH)
     
    3
    |CO
     
    3
    ]
     
    2
    Habit: Thick acicular crystals aggregated into clots
    Colour: Light blue
    Description: Occurs on limonite.
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 123, 248.]
  • Azurite
    Cu
     
    3
    [OH|CO
     
    3
    ]
     
    2
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 276.]
  • Baryte
    BaSO
     
    4
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 57 (Table 4); Schrader (1915): 276-277; Arizona Bureau of Mines file data.]
  • Biotite
    Reference: [MRDS database Dep. ID #10048342, MRDS ID #M899929.]
  • Bisbeeite ?
    (Cu,Mg)SiO
     
    3
    ·nH
     
    2
    O
    Habit: Fibrous; crystals orthorhombic
    Colour: Blue
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 137-138.]
  • Bornite
    Cu
     
    5
    FeS
     
    4
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 56 (Table 4); Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 264; Arizona Bureau of Mines file data.]
  • Braunite
    Mn
    2+
     
    Mn
    3+
    6
    [O
     
    8
    |SiO
     
    4
    ]
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 145; Havens, R., et al (1954), Benefication of oxide manganese and manganese-silver ores from southern AZ, US Bur. Mines Rept. Inv. 5024.]
  • Calcite
    CaCO
     
    3
    Description: Occurs in moderate amounts as a gangue mineral.
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 307.]
  • Cerussite
    PbCO
     
    3
    Habit: Jackstrawed sheaves of needle-like & pencil-like crystal aggregates
    Colour: White
    Fluorescence: Whitish (SW).
    Description: From the roof in the inner part of the south tunnel and adjacent parts of the crosscuts hang great masses of closely spaced, acicular or filiform (jackstrawed), silky, white cerussite about a foot in length, for which this mine is famous.
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 58 (Table 4); Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 159; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, AZ, USGS Bull. 582: 258-263; Kartchner (1944); Arizona Bureau of Mines file data; Kunz, G.F. (1885), On remarkable copper minerals from AZ, Annals N.Y. Acad. Sci.: 3: 275-278; Shannon, D.M. (1981), What's new in minerals, Min.Rec.: 12: 117-118; Univ. AZ Bull. 41 (1916-17), Mineralogy of Useful Minerals in AZ: 26; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 262; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 28, 50; Dana 6:1094.]
    Site Photo
    Flux Mine (Goshen Mine), Flux Gulch, Alum Gulch, Harshaw District, Patagonia Mts, Santa Cruz Co., Arizona, USA
    © Rob Lavinsky
  • Cerussite
    var: Argentiferous Cerussite
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 58 (Table 4); Wilson, E.D. & G.M. Butler (1930), Manganese ore deposits in AZ, AZ Bur. Mines Bull. 127: 91-94; Arizona Bureau of Mines file data.]
  • Chalcanthite
    CuSO
     
    4
    ·5H
     
    2
    O
    Description: A weathering product on outcroppings.
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 258.]
    Site Photo
    Aztec Mine (Aztec group of claims; Aztec Mine group; Andes group), Aztec Gulch, Alum Gulch, Harshaw District, Patagonia Mts, Santa Cruz Co., Arizona, USA
    © Michael C. Roarke
  • Chalcocite
    Cu
     
    2
    S
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 56 (Table 4); Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 264; Arizona Bureau of Mines file data.]
  • Chalcopyrite
    CuFeS
     
    2
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 58 (Table 4); Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 262; Kartchner (1944); Arizona Bureau of Mines file data;]
  • Chenevixite
    Cu
     
    2
    Fe
    3+
    2
    [(OH)
     
    2
    |AsO
     
    4
    ]
     
    2
    Habit: Micro-crystals
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 168.]
    Site Photo
    Unnamed prospect, Humboldt Mine area, Harshaw District, Patagonia Mts, Santa Cruz Co., Arizona, USA
    © 2009 ROM
  • Chlorargyrite
    AgCl
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 58 (Table 4); Arizona Bureau of Mines file data; Rocks & Min.:64:145.]
  • Chlorargyrite
    var: Bromian Chlorargyrite
    Ag(Cl,Br)
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 340; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 272; Galbraith, F.W. (1947), Minerals of AZ, AZ Bur. of Mines Bull. 153: 26; Galbraith, F.W. & Brennan (1959), Minerals of AZ: 44.]
  • 'Chlorite Group'
    Description: In altered wall rocks.
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 58 (Table 4); Schrader (1915): 258-263; Kartchner (1944); Arizona Bureau of Mines file data;]
  • Chrysocolla
    (Cu,Al)
     
    2
    H
     
    2
    Si
     
    2
    O
     
    5
    (OH)
     
    4
    ·nH
     
    2
    O
    Reference: [MRDS database Dep. ID file #1048344, MRDS ID #M899931.]
  • Cornubite
    Cu
     
    5
    [(OH)
     
    2
    |AsO
     
    4
    ]
     
    2
    Colour: Pistachio-green
    Description: Lovely crystals assoc. with luetheite & chenevixite.
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 187.]
    Site Photo
    Hardshell Mine (Manto Mine; Eagle-Picher properties), Hardshell Gulch, Harshaw, Harshaw District, Patagonia Mts, Santa Cruz Co., Arizona, USA
    © Bruce Murphy 2007
  • Cryptomelane
    K(Mn
    4+
     
    ,Mn
    2+
     
    )
     
    8
    O
     
    16
    Description: Plentiful argentiferous material.
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 195; Davis, S.R. (1975), The Hardshell silver deposit, Harshaw mining district, Santa Cruz Co., AZ (abs.), Sympos. New Mexico Geol. Soc. and AZ Geol. Soc. Abs. with Progs: 6.]
  • Cuprite
    Cu
     
    2
    O
    Reference: [MRDS database Dep. ID file #10048356, MRDS ID #M899944.]
  • Descloizite
    Pb(Zn,Cu)[OH|VO
     
    4
    ]
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 299.]
  • Diaspore
    AlO(OH)
    Reference: [Singer, D.A., Berger, V.I., and Moring, B.C. (2008): US Geological Survey Open-File Report 2008-1155.]
  • Diopside
    CaMg[Si
     
    2
    O
     
    6
    ]
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 229.]
  • Enargite
    Cu
     
    3
    AsS
     
    4
    Description: Rare vein mineral with pyrite under a chalcocite enrichment blanket.
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 213.]
  • Epidote
    {Ca
     
    2
    }{Al
     
    2
    Fe
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    Reference: [MRDS database Dep. ID file #1048344, MRDS ID #M899931.]
  • Epsomite
    MgSO
     
    4
    ·7H
     
    2
    O
    Reference: [MRDS database Dep. ID file #10048353, MRDS ID #M899940.]
  • 'Feldspar Group'
    Reference: [MRDS database Dep. ID file #10048354, MRDS ID #M899945.]
  • Fluorite
    CaF
     
    2
    Colour: Reddish.
    Description: As a gangue mineral.
    Reference: [The Resources of Arizona - A Reliable Manual of Information Concerning the Territory, compiled by Patrick Hamilton (1881), Prescott, AZ: 42; Ref.: Keith, Stanton B. (1975), Arizona Bureau of mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 56; Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 340; Schrader (1915): 271-272; Schrader, F.C. (1917), The geologic distribution and genesis of the metals in the Santa Rita-Patagonia Mts, AZ, Econ.Geol.: 12: 237-269; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mts, AZ, USGS Bull.430: 154-163; Galbraith, F.W. (1947), Minerals of AZ, AZ Bur. of Mines Bull. 153: 26; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 272; Galbraith, F.W. & Brennan (1959), Minerals of AZ: 44; Arizona Bureau of Mines file data.]
  • Freibergite
    (Ag
     
    4+2x
    Cu
     
    2-2x
    )[(Cu, Ag)
     
    4
    (Fe, Zn)
     
    2
    ]Sb
     
    4
    S
     
    12
    S
     
    1-x
    (0 < x < 1)
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 60 (Table 4); Schrader (1915): 248-251; Arizona Bureau of Mines file data.]
  • Galena
    PbS
    Habit: Excellent cubo-octahedral crystals
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 58 (Table 4); Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 229; ; Kartchner (1944); Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, AZ, USGS Bull. 582: 258-263; Galbraith, F.W. (1947), Minerals of AZ, AZ Bur. Mines Bull. 153: 18; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 262; Arizona Bureau of Mines file data;]
  • Galena
    var: Argentiferous Galena
    Reference: [The Resources of Arizona - A Reliable Manual of Information Concerning the Territory, compiled by Patrick Hamilton (1881), Prescott, AZ: 42; Ref.: Keith, Stanton B. (1975), Arizona Bureau of mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 56; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 272; Arizona Bureau of Mines file data.]
  • Goethite
    α-Fe
    3+
     
    O(OH)
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 112.]
  • Gold
    Au
    Reference: [MRDS database Dep. ID file #10103551, MRDS ID #M030387.]
  • Gypsum
    Ca[SO
     
    4
    ] · 2H
     
    2
    O
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 275.]
  • Gypsum
    var: Selenite
    Reference: [www.johnbetts-fineminerals.com]
  • Halite
    NaCl
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 243.]
  • Hausmannite
    MnMn
     
    2
    O
     
    4
    Description: A constituent of the mnaganese ores.
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 244.]
  • Hematite
    Fe
     
    2
    O
     
    3
    Reference: [MRDS database Dep. ID file #1048344, MRDS ID #M899931.]
  • Hematite
    var: Specularite
    Reference: [The Resources of Arizona - A Reliable Manual of Information Concerning the Territory, compiled by Patrick Hamilton (1881), Prescott, AZ: 42; Ref.: Keith, Stanton B. (1975), Arizona Bureau of mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 56; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 272; Arizona Bureau of Mines file data.]
  • Hemimorphite
    Zn
     
    4
    [(OH)
     
    2
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 123, 248.]
  • 'Hornblende'
    Reference: [MRDS database Dep. ID file #1048344, MRDS ID #M899931.]
  • Hydrozincite
    Zn
     
    5
    [(OH)
     
    3
    |CO
     
    3
    ]
     
    2
    Reference: [MRDS database Dep. ID file #10103551, MRDS ID #M030387.]
  • Illite
    K
     
    0.65
    A
     
    2.0
    [][Al
     
    0.65
    Si,
     
    3.35
    O
     
    10
    ](OH)
     
    2
    Reference: [Singer, D.A., Berger, V.I., and Moring, B.C. (2008): US Geological Survey Open-File Report 2008-1155.]
  • Iodargyrite
    AgI
    Habit: Small, isolated
    Description: Globules & specks in "contour boxwork" limonite deposits.
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 259; Blanchard, R. & P.F. Boswell (1930), Limonite types derived from bornite and tetrahedrite, Econ.Geol. 25: 557-580;]
  • Jarosite
    KFe
    3+
     
     
    3
    [(OH)
     
    3
    |SO
     
    4
    ]
     
    2
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 262.]
  • Kaolinite
    Al
     
    2
    Si
     
    2
    O
     
    5
    (OH)
     
    4
    Description: In altered wall rocks.
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 58 (Table 4); Schrader (1915): 258-263; Kartchner (1944); Arizona Bureau of Mines file data;]
  • 'K Feldspar'
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 276.]
  • Lead
    Pb
    Description: As native lead in a gold placer deposit.
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 59 (Table 4); Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mts, AZ, USGS Bull. 582: 279.]
  • Limonite
    FeO(OH)·nH
     
    2
    O
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 262; Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 123, 248.]
  • Luetheite
    Cu
     
    2
    Al
     
    2
    [(OH)
     
    2
    |AsO
     
    4
    ]
     
    2
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 187.]
  • Magnetite
    Fe
    2+
     
    Fe
    3+
    2
    O
     
    4
    Reference: [Singer, D.A., Berger, V.I., and Moring, B.C. (2008): US Geological Survey Open-File Report 2008-1155.]
  • Malachite
    Cu
     
    2
    [(OH)
     
    2
    |CO
     
    3
    ]
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 272.]
  • Manganite
    Mn
    3+
     
    O(OH)
    Reference: [MRDS database Dep. ID file #10103551, MRDS ID #M030387.]
  • Massicot
    PbO
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 291; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 28; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, AZ, USGS Bull. 582: 258-263.]
  • Mimetite
    Pb
     
    5
    [Cl|(AsO
     
    4
    )
     
    3
    ]
    Habit: Micro-crystals
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 299.]
    Site Photo
    Hardshell Mine (Manto Mine; Eagle-Picher properties), Hardshell Gulch, Harshaw, Harshaw District, Patagonia Mts, Santa Cruz Co., Arizona, USA
    © 2002 John H. Betts
  • Minium
    Pb
     
    3
    O
     
    4
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 300; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, AZ, USGS Bull. 582: 258-263.]
  • Molybdenite
    MoS
     
    2
    Description: Occurs as stains only.
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, AZ, USGS Bull. 582: 274.]
  • Muscovite
    KAl
     
    2
    [(OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    Description: As rims surrounding ore minerals or as masses enclosing the ore minerals.
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 264.]
  • Nsutite
    (Mn
    4+
     
    ,Mn
    2+
     
    )(O,OH)
     
    2
    Description: Occurs with several other manganese oxides.
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 315; Koutz, F. (1984), The Hardshell silver, base-metal, Mn-oxide deposit, in Wilkins, J. (editor), AZ Geol. Soc. Digest: 15: 199.]
  • Pearceite
    [(Ag,Cu)
     
    6
    (As,Sb)
     
    2
    S
     
    7
    ][Ag
     
    9
    CuS
     
    4
    ]
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 323.]
  • Phosphohedyphane
    Pb
     
    3
    Ca
     
    2
    [Cl|(PO
     
    4
    )
     
    3
    ]
    Reference: [Am.Min. 91, 1909-1917(2006)]
  • 'Psilomelane'
    Reference: [Wilson, E.D. & G.M. Butler (1930), Manganese ore deposits in AZ, AZ Bur. Mines Bull. 127: 91-92; Jones, E.L., Jr. & F.L. Ransome (1920), Deposits of manganese ore in Arizona, USGS Bull. 710-D: 176.]
  • Pyrargyrite
    Ag
     
    3
    SbS
     
    3
    Description: Occurs in deeper levels as a 4 inch wide oreshoot.
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 340; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 272; Galbraith, F.W. (1947), Minerals of AZ, AZ Bur. of Mines Bull. 153: 26; Galbraith, F.W. & Brennan (1959), Minerals of AZ: 44;]
  • Pyrite
    FeS
     
    2
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 58 (Table 4); Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 262; Kartchner (1944); Arizona Bureau of Mines file data;]
  • Pyrite
    var: Cupriferous Pyrite
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 257.]
  • Pyrolusite
    MnO
     
    2
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 343; Jones, E.L., Jr. & F.L. Ransome (1920), Deposits of manganese ore in Arizona, USGS Bull. 710-D: 176; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 31; Schrader, F.C. (1917), The geologic distribution and genesis of the metals in the Santa Rita-Patagonia Mountains, AZ, Econ.Geol.: 12: 237-269; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, AZ, USGS Bull. 582: 265-271; Wilson, E.D. & G.M. Butler (1930), Manganese ore deposits in AZ, AZ Bur. Mines Bull. 127: 91-94.]
  • Pyromorphite
    Pb
     
    5
    [Cl|(PO
     
    4
    )
     
    3
    ]
    Reference: [Bruce Murphy Collection]
    Site Photo
    Hardshell Mine (Manto Mine; Eagle-Picher properties), Hardshell Gulch, Harshaw, Harshaw District, Patagonia Mts, Santa Cruz Co., Arizona, USA
    © Bruce Murphy 2007
  • Pyrophyllite
    Al
     
    2
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    Reference: [MRDS database Dep. ID file #10048351, MRDS ID #M899941]
  • Quartz
    SiO
     
    2
    Reference: [Rocks & Min.:64:145.]
  • Rhodochrosite
    MnCO
     
    3
    Description: As a gangue mineral.
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 57 (Table 4); Schrader (1915): 278-279; Arizona Bureau of Mines file data.]
  • Rhodonite
    MnSiO
     
    3
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 104.]
  • Saponite
    Ca
     
    0.25
    (Mg,Fe)
     
    3
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    2
    ·nH
     
    2
    O
    Description: Occurs in the open pit operation.
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 361.]
  • 'Sericite'
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 261.]
  • Siderite
    FeCO
     
    3
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 371; Schrader, F.C. (1917), The geologic distribution and genesis of the metals in the Santa Rita-Patagonia Mountains, AZ, Econ.Geol.: 12: 237-269.]
  • Silver
    Ag
    Description: Occurs with tetrahedrite.
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 60 (Table 4); Schrader (1915): 248-251; Arizona Bureau of Mines file data; Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 373; Galbraith, F.W. (1947), Minerals of AZ, AZ Bur. of Mines Bull. 153:9.]
  • 'Smectite Group'
    A
     
    0.3
    D
     
    2-3
    [T
     
    4
    O
     
    10
    ]Z
     
    2
    ·nH
     
    2
    O
    Reference: [Singer, D.A., Berger, V.I., and Moring, B.C. (2008): US Geological Survey Open-File Report 2008-1155.]
  • Smithsonite
    ZnCO
     
    3
    Reference: [MRDS database Dep. ID file #10103551, MRDS ID #M030387.]
  • Sphalerite
    (Zn,Fe
    2+
     
    )S
    Description: Considerable in the sulphide orebody.
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 58 (Table 4); Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 262; Kartchner (1944); Arizona Bureau of Mines file data;]
  • Stephanite
    Ag
     
    5
    SbS
     
    4
    Reference: [Galbraith, F.W. (1947), Minerals of AZ, AZ Bur. Mines Bull. 153: 26; Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 381; Schrader, F.C. (1917), The geologic distribution and genesis of the metals in the Santa Rita-Patagonia Mountains, AZ, Econ.Geol.: 12: 237-269.]
  • Sulphur
    S
     
    8
    Description: A weathering product on outcroppings.
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 258.]
  • Tennantite
    (Cu,Ag,Fe,Zn)
     
    12
    As
     
    4
    S
     
    13
    Reference: [Singer, D.A., Berger, V.I., and Moring, B.C. (2008): US Geological Survey Open-File Report 2008-1155.]
  • Tenorite
    CuO
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 258; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 27.]
  • Tetrahedrite
    (Cu,Fe,Ag,Zn)
     
    12
    Sb
     
    4
    S
     
    13
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 393; Mineralogy of Useful Minerals in AZ, Univ. of AZ Bull. 41 (1916-17): 58.]
  • Tetrahedrite
    var: Argentian Tetrahedrite
    Reference: [Keith, Stanton B. (1975), Arizona Bureau of Mines Bull. 191, Index of Mining Properties in Santa Cruz County Arizona: 60 (Table 4); Schrader (1915): 248-251; Arizona Bureau of Mines file data; Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 373, 393; Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 251; Galbraith, F.W. (1947), Minerals of AZ, AZ Bur. of Mines Bull. 153:9.]
  • 'Tourmaline'
    AD
     
    3
    G
     
    6
    (BO
     
    3
    )
     
    3
    [T
     
    6
    O
     
    18
    ]Y
     
    3
    Z
    Reference: [MRDS database Dep. ID file #10048351, MRDS ID #M899941]
  • Tridymite
    SiO
     
    2
    Description: Microscopic component of ore.
    Reference: [Schrader, F.C. & J.M. Hill (1915), Mineral deposits of the Santa Rita and Patagonia Mountains, Arizona, USGS Bull. 582: 264.]
  • Vanadinite
    Pb
     
    5
    [Cl|(VO
     
    4
    )
     
    3
    ]
    Reference: [Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 411.]
  • 'Wad'
    Reference: [MRDS database Dep. ID file #10048355, MRDS ID #M899943.]
  • Wulfenite
    Pb[MoO
     
    4
    ]
    Reference: [MRDS database Dep. ID file #10103551, MRDS ID #M030387.]
  • Zunyite
    Al
     
    13
    Si
     
    5
    O
     
    20
    (OH,F)
     
    18
    Cl
    Reference: [Singer, D.A., Berger, V.I., and Moring, B.C. (2008): US Geological Survey Open-File Report 2008-1155.]


    97 entries listed. 77 valid minerals.

    Localities in this Region:
    USA
     
    • Arizona
      • Santa Cruz Co.
        • Patagonia Mts
          • Harshaw District
              • Aztec Gulch
              • Flux Gulch
            • American Peak
              • Hardshell Gulch
              • Hardshell Mine area
            • Patagonia

    The above list contains all mineral locality references listed on mindat.org. This does not claim to be a complete list. If you know of more minerals from this site, please register so you can add to our database!
    This page is currently not sponsored. Click here to find out how you can sponsor this page.


    Mineral and/or Locality
    Google
     
    www.mindat.org Web
    Copyright © Jolyon Ralph and Ida Chau 1993-2009. Jobs in Arizona, USA Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 30th Nov 2009 06:05:33