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Structure of the new mineral sarrabusite, Pb5CuCl4(SeO3)4

Posted by Uwe Kolitsch

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Uwe Kolitsch

Structure of the new mineral sarrabusite, Pb5CuCl4(SeO3)4
January 18, 2012 11:40AM

Registered: 7 years ago
Posts: 11,005

M. Gemmi, I. Campostrini, F. Demartin, T. E. Gorelik and C. M. Gramaccioli (2012): Structure of the new mineral sarrabusite, Pb5CuCl4(SeO3)4, solved by manual electron-diffraction tomography. Acta Crystallogr. B68, 15-23.

Synopsis: The crystal structure of the new mineral sarrabusite Pb5CuCl4(SeO3)4 has been solved using a manual and an automated version of the new electron-diffraction tomography technique combined with the precession of the electron beam.

Space group C2/c.
_cell_length_a 24.917(3)
_cell_length_b 5.5060(10)
_cell_length_c 14.242(2)
_cell_angle_beta 101.770(10)
_cell_volume 1912.8(5)

_cell_formula_units_Z 4

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Uwe Kolitsch

Re: Structure of the new mineral sarrabusite, Pb5CuCl4(SeO3)4
January 18, 2012 02:37PM

Registered: 7 years ago
Posts: 11,005

Possibly identical to Pb4CuCl3(OH)(SeO3)3 ? (Despite the not completely identical stoichiometry.)
(UM1999-29-SeO:ClCuHPb, [www.mindat.org])

Edited 1 time(s). Last edit at 01/18/2012 02:41PM by Uwe Kolitsch.

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Marco E. Ciriotti

Re: Structure of the new mineral sarrabusite, Pb5CuCl4(SeO3)4
January 18, 2012 04:12PM

Registered: 7 years ago
Posts: 4,441

Yes Uwe, it is the same phase.

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