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Chloritoid

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Hualien Co., Taiwan Province, Taiwan

Show Chloritoid Photos (8)
Formula:
(Fe
2+
 
,Mg,Mn
2+
 
)Al
 
2
[O|(OH)
 
2
|SiO
 
4
]
System:MonoclinicColour:dark green to green-gray ...
Hardness:6½


Chloritoid Group. Carboirite-Chloritoid Series.

Classification of Chloritoid

IMA status:Approved
Strunz 8th edition ID:8/B.24-20
Nickel-Strunz 10th (pending) edition ID:9.AF.85

9 : SILICATES (Germanates)
A : Nesosilicates
F : Nesosilicates with additional anions; cations in [4], [5] and/or only [6] coordination
Dana 8th edition ID:52.3.3.1

52 : NESOSILICATES Insular SiO4 Groups and O,OH,F,H2O
3 : Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] coordination only
Hey's CIM Ref.:16.19.6

16 : Silicates Containing Aluminum and other Metals
19 : Aluminosilicates of Fe and Mg
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Type Occurrence of Chloritoid

Type Locality:Kosoi Brod Village, Ekaterinburg (Sverdlovsk), Ekaterinburgskaya (Sverdlovskaya) Oblast', Middle Urals, Urals Region, Russia

Physical Properties of Chloritoid

Lustre:Vitreous, Pearly
Diaphaneity (Transparency):Translucent
Colour:dark green to green-gray or nearly black.
Hardness (Mohs):6½
Cleavage:Perfect
{001} perfect, {110} good.
Density (measured):3.4 - 3.8 g/cm3

Crystallography of Chloritoid

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/b {B1 1 2/b} {C2/c} {C1 2/c 1}
Cell Parameters:a = 9.48Å, b = 5.48Å, c = 18.18Å
Ratio:a:b:c = 1.73 : 1 : 3.318
Unit Cell Volume:V 0.00 ų (Calculated from Unit Cell)
Z:8
Morphology:Thin to thick foliated plates or as massive aggremates. Seldom as pseudohexagonal tabular crystals.

Also triclinic.
Twinning:Often twinned.

Optical Data of Chloritoid

Type:Biaxial (+)
RI values: nα = 1.713 - 1.730 nβ = 1.719 - 1.734 nγ = 1.723 - 1.740
2V:Measured: 36° to 89°, Calculated: 78° to 80°
Maximum Birefringence:δ = 0.010

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:r > v

Chemical Properties of Chloritoid

Formula:
(Fe
2+
 
,Mg,Mn
2+
 
)Al
 
2
[O|(OH)
 
2
|SiO
 
4
]
Essential elements:Al, Fe, H, O, Si
All elements listed in formula:Al, Fe, H, Mg, Mn, O, Si

Relationship of Chloritoid to other Species

Series:Forms a series with Carboirite (see here)
Member of Group:
Chloritoid Group:
Related Minerals - Nickel-Strunz Grouping):

- +
9.AF.05Sillimanite
Al
 
2
[O|SiO
 
4
]
9.AF.10Andalusite
Al
 
2
[O|SiO
 
4
]
9.AF.10Kanonaite
Mn
3+
 
Al[O|SiO
 
4
]
9.AF.15Kyanite
Al
 
2
[O|SiO
 
4
]
9.AF.20Mullite
Al
 
8
[(O,OH,F)|(Si,Al)O
 
4
]
 
4
9.AF.20Krieselite
(Al,Ga)
 
2
[(OH)
 
2
|GeO
 
4
]
9.AF.23Boromullite
Al
 
9
Si
 
2
BO
 
19
9.AF.25Yoderite
Mg(Al,Fe
3+
 
)
 
3
[O|OH|(SiO
 
4
)
 
2
]
9.AF.30Magnesiostaurolite
(Mg,Li,Fe
2+
 
)
 
1.5-2
Al
 
9
[O
 
6
|(OH)
 
2
|(SiO
 
4
)
 
4
]
9.AF.30Staurolite
(Fe
2+
 
,Mg,Zn)
 
1.5-2
Al
 
9
[O
 
6
|(OH,O)
 
2
|(SiO
 
4
)
 
4
]
9.AF.30Zincostaurolite
(Zn,Li,Fe
2+
 
,Mg)
 
<2
Al
 
9
[O
 
6
|(OH)
 
2
|(SiO
 
4
)
 
4
]
9.AF.35Topaz
Al
 
2
[(F,OH)
 
2
|SiO
 
4
]
9.AF.40Norbergite
Mg
 
3
[(F,OH)
 
2
|SiO
 
4
]
9.AF.45Alleghanyite
Mn
2+
5
[(OH)
 
2
|(SiO
 
4
)
 
2
]
9.AF.45Chondrodite
(Mg,Fe
2+
 
)
 
5
[(F,OH)
 
2
|(SiO
 
4
)
 
2
]
9.AF.45Reinhardbraunsite
Ca
 
5
[(OH,F)
 
2
|(SiO
 
4
)
 
2
]
9.AF.45Kumtyubeite
Ca
 
5
(SiO
 
4
)
 
2
F
 
2
9.AF.50Humite
(Mg,Fe
2+
 
)
 
7
[(F,OH)
 
2
|(SiO
 
4
)
 
3
]
9.AF.50Manganhumite
(Mn
2+
 
,Mg)
 
7
[(OH)
 
2
|(SiO
 
4
)
 
3
]
9.AF.50Unnamed (Ca-analogue of humite)
Ca
 
7
(SiO
 
4
)
 
3
(OH)
 
2
9.AF.55Clinohumite
(Mg,Fe
2+
 
)
 
9
[(F,OH)
 
2
|(SiO
 
4
)
 
4
]
9.AF.55Sonolite
Mn
2+
9
[(OH,F)
 
2
|(SiO
 
4
)
 
4
]
9.AF.55Hydroxylclinohumite
Mg
 
9
[(OH,F)
 
2
|(SiO
 
4
)
 
4
]
9.AF.60Leucophoenicite
Mn
2+
7
[(OH)
 
2
|(SiO
 
4
)
 
3
]
9.AF.65Ribbeite
(Mn
2+
 
,Mg)
 
5
[(OH)
 
2
|(SiO
 
4
)
 
2
]
9.AF.70Jerrygibbsite
Mn
2+
9
[(OH)
 
2
|(SiO
 
4
)
 
4
]
9.AF.75Franciscanite
Mn
2+
6
(V
5+
 
,[])
 
2
[(O,OH)
 
3
|SiO
 
4
]
 
2
9.AF.75Örebroite
Mn
2+
3
(Fe
3+
 
,Sb
5+
 
)[(O,OH)
 
3
|SiO
 
4
]
9.AF.75Welinite
Mn
2+
6
(W
6+
 
,Mg)
 
2
[(O,OH)
 
3
|SiO
 
4
]
 
2
9.AF.80Ellenbergerite
Mg
 
6
Al
 
6
Ti[(OH)
 
6
|(HSiO
 
4
)
 
4
|(SiO
 
4
)
 
4
]
9.AF.85Magnesiochloritoid
MgAl
 
2
[O|(OH)
 
2
|SiO
 
4
]
9.AF.85Ottrélite
(Mn
2+
 
,Fe
2+
 
,Mg)Al
 
2
[O|(OH)
 
2
|SiO
 
4
]
9.AF.90Poldervaartite
CaCa[SiO
 
3
OH](OH)
9.AF.90Olmiite
CaMn
2+
 
[SiO
 
3
(OH)](OH)
Related Minerals - Hey's Index Grouping:

- +
16.19.1Indialite
Mg
 
2
Al
 
4
Si
 
5
O
 
18
16.19.2Cordierite
(Mg,Fe)
 
2
Al
 
4
Si
 
5
O
 
18
16.19.3Sekaninaite
(Fe,Mg)
 
2
Al
 
4
Si
 
5
O
 
18
16.19.4Ferrogedrite
☐[Fe
2+
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
16.19.5Staurolite
(Fe
2+
 
,Mg,Zn)
 
1.5-2
Al
 
9
[O
 
6
|(OH,O)
 
2
|(SiO
 
4
)
 
4
]
16.19.7Amesite
Mg
 
2
Al[(OH)
 
4
|AlSiO
 
5
]
16.19.8Corundophilite
(Mg,Fe,Al)
 
6
(Si,Al)
 
4
O
 
10
(OH)
 
8
16.19.9Yoderite
Mg(Al,Fe
3+
 
)
 
3
[O|OH|(SiO
 
4
)
 
2
]
16.19.10Delessite
(Mg,Fe,Fe,Al)(Si,Al)
 
4
O
 
10
(O,OH)
 
8
16.19.11Ferrocarpholite
(Fe
2+
 
,Mg)Al
 
2
[(OH)
 
4
|Si
 
2
O
 
6
]
16.19.12Magnesiocarpholite
(Mg,Fe
2+
 
)Al
 
2
[(OH)
 
4
|Si
 
2
O
 
6
]
16.19.13Chamosite
(Fe
2+
 
,Mg)
 
5
Al[(OH)
 
8
|AlSi
 
3
O
 
10
]
16.19.14Orthochamosite
(Fe,Mg,Fe)
 
5
Al(Si
 
3
Al)O
 
10
(OH,O)
 
8
16.19.15Berthierine
(Fe,Fe,Mg)
 
2-3
(Si,Al)
 
2
O
 
5
(OH)
 
4
16.19.16Odinite
(Fe,Mg,Al,Fe,Ti,Mn)
 
2.4
(Si,Al)
 
2
O
 
5
(OH)
 
4
16.19.17Clinochlore
(Mg,Fe
2+
 
)
 
5
Al[(OH)
 
8
|AlSi
 
3
O
 
10
]
16.19.18Gedrite
☐[Mg
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
16.19.19Magnesiogedrite
16.19.20Diabantite
(Mg,Fe,Al)
 
6
(Si,Al)
 
4
O
 
10
(OH)
 
8
16.19.21Sudoite
(Mg,Fe
2+
 
)
 
2
Al
 
3
[(OH)
 
8
|AlSi
 
3
O
 
10
]
16.19.22Vermiculite
(Mg,Fe,Al)
 
3
(Al,Si)
 
4
O
 
10
(OH)
 
2
·4H
 
2
O
16.19.23Corrensite
(Mg,Fe)
 
9
(Si,Al)
 
8
O
 
20
(OH)
 
10
·nH
 
2
O

Other Names for Chloritoid

Synonyms:
BarytophylliteBliabergiteBliabergsiteChlorite sparChloritoidite
SismondineSismonditeStrüverite (of Brezina)
Other Languages:
German:Barytophyllit
Bliabergit
Bliabergsit
Chloritoidit
Chloritspat
Sismondit
Russian:Хлоритоид
Spanish:Barytophyllita
Bliabergita
Bliabergsita
Chloritoidita
Sismondita
Varieties:
Masonite

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Chloritoid

Reference List:Acta Crystallographica: B31: 780.

American Mineralogist (1980): 65: 534-539.

Theye, T., Seidel, E., and Vidal, O. (1992) Carpholite, sudoite, chloritoid in low-grade high-pressure metapelites from Crete and the Peloponnese, Greece. European Journal of Mineralogy: 4: 487-507.

Theye, T. (2000) New experimental high pressure data on chloritoid and carpholite. Beiheft No. 1, European Journal of Mineralogy: 12: 212.

Internet Links for Chloritoid

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    Localities for Chloritoid

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