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Clinotobermorite

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Formula:
[Ca
 
4
Si
 
6
O
 
17
· 2H
 
2
O]·(Ca·3H
 
2
O)
System:MonoclinicHardness:
Member of:Tobermorite Group
Name:Redefined in by IMA in 2014, according to new nomenclature for the Tobermorite Group.


Structurally closely related to Tobermorite.

Classification of Clinotobermorite

IMA status:Redefined Approved 2014
Strunz 8th edition ID:8/F.19-25
Nickel-Strunz 10th (pending) edition ID:9.DG.10

9 : SILICATES (Germanates)
D : Inosilicates
G : Inosilicates with 3-periodic single and multiple chains
Dana 8th edition ID:72.3.2.2

72 : PHYLLOSILICATES Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings
3 : Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings with 3-, 4-, or 5-membered rings and 8-membered rings
Hey's CIM Ref.:14.5.24

14 : Silicates not Containing Aluminum
5 : Silicates of Ca
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Type Occurrence of Clinotobermorite

Type Locality:Fuka mine, Fuka, Bicchu-cho (Bitchu-cho), Takahashi City, Okayama Prefecture, Chugoku Region, Honshu Island, Japan
Year of Discovery:1989

Physical Properties of Clinotobermorite

Hardness (Mohs):

Crystallography of Clinotobermorite

Crystal System:Monoclinic
Cell Parameters:a = 11.33Å, b = 7.35Å, c = 22.67Å
β = 96.59°
Ratio:a:b:c = 1.541 : 1 : 3.084
Unit Cell Volume:V 1,875.38 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
d-spacingIntensity
11.25 (100)
3.304 (51)
3.068 (45)
3.034 (60)
3.012 (37)
2.811 (41)
2.794 (60)

Optical Data of Clinotobermorite

Type:Biaxial (+/-)
RI values: nα = 1.575 nβ = 1.580 nγ = 1.585
2V:Measured: 89° , Calculated: 88°
Maximum Birefringence:δ = 0.010

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:very weak

Chemical Properties of Clinotobermorite

Formula:
[Ca
 
4
Si
 
6
O
 
17
· 2H
 
2
O]·(Ca·3H
 
2
O)
Simplified for copy/paste:[Ca4Si6O17·2H2O]·(Ca·3H2O)
Essential elements:Ca, H, O, Si
All elements listed in formula:Ca, H, O, Si
Common Impurities:Ti,B,Al,Fe,Mn,Mg,Na,K,F

Relationship of Clinotobermorite to other Species

Member of:Tobermorite Group
Other Members of Group:

- +
Kenotobermorite
[Ca
 
4
Si
 
6
O
 
15
(OH)
 
2
·2H
 
2
O]·3H
 
2
O
Plombièrite
[Ca
 
4
Si
 
6
O
 
16
(OH)
 
2
· 2H
 
2
O]·(Ca·5H
 
2
O)
Riversideite
Ca
 
5
(HSi
 
3
O
 
9
)
 
2
· 2H
 
2
O
Tobermorite
[Ca
 
4
Si
 
6
O
 
17
) · 2H
 
2
O]·(Ca·3H
 
2
O)
Related Minerals - Nickel-Strunz Grouping):

- +
9.DG.05Bustamite
CaMn
2+
 
(Si
 
2
O
 
6
)
9.DG.05Ferrobustamite
Ca(Fe
2+
 
,Ca,Mn
2+
 
)(Si
 
2
O
 
6
)
9.DG.05Pectolite
NaCa
 
2
(HSi
 
3
O
 
9
)
9.DG.05Sérandite
Na(Mn
2+
 
,Ca)
 
2
(HSi
 
3
O
 
9
)
9.DG.05Wollastonite
CaSiO
 
3
9.DG.05Wollastonite-1A
CaSiO
 
3
9.DG.07Cascandite
Ca(Sc,Fe
3+
 
)(HSi
 
3
O
 
9
)
9.DG.08Plombièrite
[Ca
 
4
Si
 
6
O
 
16
(OH)
 
2
· 2H
 
2
O]·(Ca·5H
 
2
O)
9.DG.10Riversideite
Ca
 
5
(HSi
 
3
O
 
9
)
 
2
· 2H
 
2
O
9.DG.10Tobermorite
[Ca
 
4
Si
 
6
O
 
17
) · 2H
 
2
O]·(Ca·3H
 
2
O)
9.DG.15Foshagite
Ca
 
4
(Si
 
3
O
 
9
)(OH)
 
2
9.DG.20Jennite
Ca
 
9
(Si
 
3
O
 
9
)
 
2
(OH)
 
8
· 8H
 
2
O
9.DG.25Paraumbite
K
 
3
Zr
 
2
H(Si
 
3
O
 
9
)
 
2
· nH
 
2
O
9.DG.25Umbite
K
 
2
(Zr,Ti)Si
 
3
O
 
9
· H
 
2
O
9.DG.30Sørensenite
Na
 
4
SnBe
 
2
Si
 
6
O
 
16
(OH)
 
4
9.DG.35Xonotlite
Ca
 
6
(Si
 
6
O
 
17
)(OH)
 
2
9.DG.40Hillebrandite
Ca
 
2
(SiO
 
3
)(OH)
 
2
9.DG.45Zorite
Na
 
8
(Ti,Nb)
 
5
(Si
 
6
O
 
17
)
 
2
(OH,O)
 
5
· 14H
 
2
O
9.DG.45Chivruaiite
Ca
 
4
(Ti,Nb)
 
5
(Si
 
6
O
 
17
)
 
2
(OH,O)
 
5
· 13-14H
 
2
O
9.DG.50Haineaultite
(Na,Ca)
 
5
Ca(Ti,Nb)
 
5
(Si
 
6
O
 
17
)
 
2
(OH,F)
 
8
· 5H
 
2
O
9.DG.55Epididymite
Na
 
2
Be
 
2
Si
 
6
O
 
15
· H
 
2
O
9.DG.60Eudidymite
Na
 
2
Be
 
2
Si
 
6
O
 
15
· H
 
2
O
9.DG.65Elpidite
Na
 
2
ZrSi
 
6
O
 
15
· 3H
 
2
O
9.DG.70Fenaksite
(K,Na)
 
4
(Fe,Mn)
 
2
(Si
 
4
O
 
10
)
 
2
(OH,F)
9.DG.70Litidionite
CuNaKSi
 
4
O
 
10
9.DG.70Manaksite
KNaMnSi
 
4
O
 
10
9.DG.75Tinaksite
K
 
2
Na(Ca,Mn
2+
 
)
 
2
Ti[O|Si
 
7
O
 
18
(OH)]
9.DG.75Tokkoite
K
 
2
Ca
 
4
Si
 
7
O
 
17
(O,OH,F)
 
4
9.DG.75Senkevichite
CsKNaCa
 
2
Ti[O|Si
 
7
O
 
18
(OH)]
9.DG.80Canasite
K
 
2
Na
 
4
Ca
 
5
(Si
 
12
O
 
30
(OH,F)
 
4
9.DG.80Fluorcanasite
K
 
3
Na
 
3
Ca
 
5
Si
 
12
O
 
30
F
 
4
· H
 
2
O
9.DG.85Miserite
K(Ca,Ce)
 
4
Si
 
5
O
 
13
(OH)
 
3
9.DG.90Frankamenite
K
 
3
Na
 
3
Ca
 
5
(Si
 
12
O
 
30
)(F,OH)
 
4
· H
 
2
O
9.DG.92Charoite
(K,Sr)
 
15-16
(Ca,Na)
 
32
[Si
 
6
O
 
11
(O,OH)
 
6
]
 
2
[Si
 
12
O
 
18
(O,OH)
 
12
]
 
2
[Si
 
17
O
 
25
(O,OH)
 
18
]
 
2
(OH,F)
 
4
· ~3H
 
2
O
9.DG.95Yuksporite
(K,Ba)NaCa
 
2
(Si,Ti)
 
4
O
 
11
(F,OH) · H
 
2
O
9.DG.97Eveslogite
(Na,K,Ca,Sr,Ba)
 
48
[(Ti,Nb,Mn,Fe
2+
 
)
 
12
Si
 
48
O
 
144
(OH)
 
12
](F,OH,Cl)
 
14
Related Minerals - Hey's Index Grouping:

- +
14.5.1Wollastonite
CaSiO
 
3
14.5.2Wollastonite-7T
14.5.3Wollastonite-2M
CaSiO
 
3
14.5.4Rankinite
Ca
 
3
Si
 
2
O
 
7
14.5.5Kilchoanite
Ca
 
6
(SiO
 
4
)(Si
 
3
O
 
10
)
14.5.6Larnite
Ca
 
2
SiO
 
4
14.5.7Bredigite
Ca
 
7
Mg(SiO
 
4
)
 
4
14.5.8Hatrurite
Ca
 
3
(SiO
 
4
)O
14.5.9Rosenhahnite
HCa
 
3
[Si
 
3
O
 
9
(OH)]
14.5.10Dellaite
Ca
 
6
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
14.5.11Afwillite
Ca
 
3
(HSiO
 
4
)
 
2
· 2H
 
2
O
14.5.12Xonotlite
Ca
 
6
(Si
 
6
O
 
17
)(OH)
 
2
14.5.13Foshagite
Ca
 
4
(Si
 
3
O
 
9
)(OH)
 
2
14.5.14Hillebrandite
Ca
 
2
(SiO
 
3
)(OH)
 
2
14.5.15Jaffeite
Ca
 
6
(Si
 
2
O
 
7
)(OH)
 
6
14.5.16Suolunite
Ca
 
2
(H
 
2
Si
 
2
O
 
7
) · H
 
2
O
14.5.17Killalaite
Ca
 
6.4
(H
 
0.6
Si
 
2
O
 
7
)
 
2
(OH)
 
2
14.5.18Okenite
CaSi
 
2
O
 
5
· 2H
 
2
O
14.5.19Riversideite
Ca
 
5
(HSi
 
3
O
 
9
)
 
2
· 2H
 
2
O
14.5.20Trabzonite
Ca
 
4
(Si
 
3
O
 
10
) · 2H
 
2
O
14.5.21Gyrolite
NaCa
 
16
Si
 
23
AlO
 
60
(OH)
 
8
· 14H
 
2
O
14.5.22Foshallasite
Ca
 
3
[Si
 
2
O
 
7
] · 3H
 
2
O(?)
14.5.23Tobermorite
[Ca
 
4
Si
 
6
O
 
17
) · 2H
 
2
O]·(Ca·3H
 
2
O)
14.5.25Nekoite
Ca
 
3
Si
 
6
O
 
15
·7H
 
2
O
14.5.26Plombièrite
[Ca
 
4
Si
 
6
O
 
16
(OH)
 
2
· 2H
 
2
O]·(Ca·5H
 
2
O)
14.5.27Jennite
Ca
 
9
(Si
 
3
O
 
9
)
 
2
(OH)
 
8
· 8H
 
2
O

Other Names for Clinotobermorite

Synonyms:
IMA1990-005
Other Languages:
German:Clinotobermorit
Klinotobermorit
Russian:Клинотоберморит
Spanish:Clinotobermorita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Clinotobermorite

Reference List:

- +
New Minerals (1997), New Minerals 1990-1994.

Mineralogical Magazine: 56: 353-358.

Hoffmann, C. & Armbruster, T. (1997): Clinotobermorite, Ca5[Si3O8(OH)]2.4H2O - Ca5[Si6O17].5H2O, a natural C-S-H(I) type cement mineral. Determination of the substructure. Zeitschrift für Kristallographie 212, 864-873.

Merlino, S., Bonaccorsi, E., and Armbruster, T. (2001): The real structure of tobermorite-11Å: normal and anomalous forms, OD character and polytypic modifications. European Journal of Mineralogy 13(3), 577-590.

Internet Links for Clinotobermorite

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  • Localities for Clinotobermorite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Italy
     
    • Veneto
      • Vicenza Province
        • Cornedo Vicentino
          • Spagnago
    Boscardin M.,Daleffe A.,Rocchetti I., Zordan A. (2011) " Minerali del Vicentino - Aggiornamenti, località e nuove determinazioni " Museo di Archeologia e Scienze Naturali “G. Zannato” – Montecchio Maggiore (Vicenza), pp.183; Boscardin M.,Daleffe A.,Rocchetti I., Zordan A. (2011): Minerali del Vicentino - Aggiornamenti, località e nuove determinazioni. Museo di Archeologia e Scienze Naturali “G. Zannato” – Montecchio Maggiore (Vicenza), pp.183
        • Gambellara
          • S.Marco hill
    Boscardin M.,Daleffe A.,Rocchetti I., Zordan A. (2011) " Minerali del Vicentino - Aggiornamenti, località e nuove determinazioni " Museo di Archeologia e Scienze Naturali “G. Zannato” – Montecchio Maggiore (Vicenza), pp.183
        • San Vito di Leguzzano-Schio
    Boscardin M., Daleffe A., Rocchetti I., Zordan A. “I minerali nel Vicentino”, Museo “G. Zannato”, Montecchio Maggiore (Vicenza), 2011.
    Japan
     
    • Honshu Island
      • Chugoku Region
        • Okayama Prefecture
          • Takahashi City
            • Bicchu-cho (Bitchu-cho)
              • Fuka
    Henmi, C., & Kusachi, I. (1992). Clinotobermorite, Ca5Si6(O,OH)18.5H2O, a new mineral from Fuka, Okayama Prefecture, Japan. Mineralogical Magazine, 56, 353-358.
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