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Clinotyrolite

Big Photo

Lovelock Mine, Bolivia, Cottonwood Canyon, Table Mountain District, Churchill Co., Nevada, USA
© R.D.Green

Show Clinotyrolite Photos (29)
Formula:
Ca
 
2
Cu
 
9
[(OH,O)
 
10
|(AsO
 
4
,SO
 
4
)
 
4
] · 10H
 
2
O
System:Monoclinic
Name:For the relation to tyrolite (considered to be orthorhombic at that time)


"Clinotyrolite has been published without CNMMN approval. It might well be a separate phase." (Ernst Burke - 21/06/2004).

Since it is well-known that also carbonate-free varieties of tyrolite exist, "tyrolite" may actually represent two or more minerals/polytypes. At least two monoclinic polytypes of tyrolite are known (Krivovichev et al., 2006); one of them seems to be identical to "clinotyrolite".

Clinotyrolite was originally described from Lanniping Mine, Dongchuan Cu ore field, Dongchuan District, Kunming Prefecture, Yunnan Province, China and Tangdan Mine, Dongchuan Cu ore field, Dongchuan District, Kunming Prefecture, Yunnan Province, China.

Classification of Clinotyrolite

IMA status:Published without Approval
Strunz 8th edition ID:7/D.54-30
Nickel-Strunz 10th (pending) edition ID:8.DM.10

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
M : With large and medium-sized cations, (OH, etc.):RO4 > 2:1
Dana 8th edition ID:42.4.4.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
4 : (AB)5(XO4)2Zq·xH2O
Hey's CIM Ref.:22.3.4

22 : Phosphates, Arsenates or Vanadates with other Anions
3 : Phosphates, arsenates or vanadates with sulphates
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Crystallography of Clinotyrolite

Crystal System:Monoclinic
Cell Parameters:a = 10.51Å, b = 5.56Å, c = 27.61Å
β = 94°
Ratio:a:b:c = 1.89 : 1 : 4.966
Unit Cell Volume:V 1,609.48 ų (Calculated from Unit Cell)

Optical Data of Clinotyrolite

Type:Biaxial (-)
RI values: nα = 1.666 nβ = 1.686 nγ = 1.694
2V:Measured: 65° to 66°, Calculated: 62°
Maximum Birefringence:δ = 0.028

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:r > v or r < v

Chemical Properties of Clinotyrolite

Formula:
Ca
 
2
Cu
 
9
[(OH,O)
 
10
|(AsO
 
4
,SO
 
4
)
 
4
] · 10H
 
2
O
Essential elements:As, Ca, Cu, H, O
All elements listed in formula:As, Ca, Cu, H, O, S

Relationship of Clinotyrolite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
8.DM.05Morinite
Na
 
2
Ca
 
4
Al
 
4
[(F,OH)
 
5
|(PO
 
4
)
 
2
]
 
2
 · 3H
 
2
O
8.DM.05Esperanzaite
NaCa
 
2
Al
 
2
[F
 
4
|OH|(AsO
 
4
)
 
2
] · 2H
 
2
O
8.DM.10Tyrolite
Ca
 
2
Cu
 
9
[(OH)
 
4
|(H
 
2
O)
 
11
|CO
 
3
|(AsO
 
4
)
 
4
] · 0-1H
 
2
O
8.DM.15Betpakdalite
{Mg(H
 
2
O)
 
6
}Ca
 
2
(H
 
2
O)
 
13
[Mo
6+
8
As
5+
2
Fe
3+
3
O
 
36
(OH)](H
 
2
O)
 
4
8.DM.15Melkovite
CaFeH
 
6
(MoO
 
4
)
 
4
PO
 
4
·6H
 
2
O or near·
8.DM.15Natrobetpakdalite
(Na
 
2
,Ca)Fe
 
2
(As
 
2
Mo
 
6
O
 
28
)·15H
 
2
O
8.DM.20Phosphovanadylite
(Ba,Ca,K,Na)x[(V,Al)4P2(O,OH)16]·12(H2O) x~0.66
8.DM.25Yukonite
Ca
 
3
Fe
3+
 
[(OH)
 
3
|(AsO
 
4
)
 
2
] · 5H
 
2
O
8.DM.30Uduminelite
Ca
 
3
Al
 
8
(PO
 
4
)
 
2
O
 
12
·2H
 
2
O
8.DM.35Delvauxite
CaFe
 
4
(PO
 
4
,SO
 
4
)
 
2
(OH)
 
8
·4-6H
 
2
O not confirmed·
8.DM.40Santafeite
(Ca,Sr,Na)
 
12
(Mn
2+
 
,Fe
3+
 
,Al,Mg)
 
8
Mn
4+
8
(VO
 
4
)
 
16
(OH,O)
 
20
 · 8H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
22.3.1Parnauite
Cu
 
9
[(OH)
 
10
|SO
 
4
|(AsO
 
4
)
 
2
] · 7H
 
2
O
22.3.2Ardealite
Ca
 
2
[HPO
 
4
|SO
 
4
] · 4H
 
2
O
22.3.3Machatschkiite
(Ca,Na)
 
6
AsO
 
4
(AsO
 
3
OH)
 
3
(PO
 
4
,SO
 
4
)·15H
 
2
O
22.3.5Peisleyite
Na
 
3
Al
 
16
[SO
 
4
|(PO
 
4
)
 
5
]
 
2
 · 20H
 
2
O
22.3.6Chalcophyllite
Cu
 
18
Al
 
2
[(OH)
 
9
|SO
 
4
|AsO
 
4
]
 
3
 · 33H
 
2
O
22.3.7Woodhouseite
CaAl
 
3
[(OH)
 
6
|SO
 
4
|PO
 
4
]
22.3.8Schlossmacherite
(H
 
3
O,Ca)Al
 
3
[(OH)
 
6
|(SO
 
4
,AsO
 
4
)
 
2
]
22.3.9Svanbergite
SrAl
 
3
[(OH)
 
6
|SO
 
4
|PO
 
4
]
22.3.10Kemmlitzite
(Sr,Ce)Al
 
3
[(OH)
 
6
|SO
 
4
|AsO
 
4
]
22.3.11Sanjuanite
Al
 
2
[OH|SO
 
4
|PO
 
4
] · 9H
 
2
O
22.3.12Kribergite
Al
 
5
[(OH)
 
4
|SO
 
4
|(PO
 
4
)
 
3
] · 4H
 
2
O
22.3.13Hotsonite
Al
 
11
[(OH)
 
21
|(SO
 
4
)
 
3
|(PO
 
4
)
 
2
] · 16H
 
2
O
22.3.14Weilerite
22.3.15Tsumebite
Pb
 
2
Cu[OH|SO
 
4
|PO
 
4
]
22.3.16Arsentsumebite
Pb
 
2
Cu[OH|SO
 
4
|AsO
 
4
]
22.3.17Hinsdalite
PbAl
 
3
[(OH)
 
6
|SO
 
4
|PO
 
4
]
22.3.18Hidalgoite
PbAl
 
3
[(OH)
 
6
|SO
 
4
|AsO
 
4
]
22.3.19Orpheite
PbAl
 
3
[(OH)
 
6
|(PO
 
4
,SO
 
4
)
 
2
] (?)
22.3.20Coconinoite
Fe
3+
2
Al
 
2
(UO
 
2
)
 
2
[(OH)
 
2
|SO
 
4
|(PO
 
4
)
 
4
] · 20H
 
2
O
22.3.21Sasaite
(Al,Fe
3+
 
)
 
14
[(OH)
 
7
|SO
 
4
|(PO
 
4
)
 
11
] · 83H
 
2
O
22.3.22Tristramite
(Ca,U,Fe)(PO
 
4
,SO
 
4
)·2H
 
2
O
22.3.23Corkite
PbFe
 
3
[(OH)
 
6
|SO
 
4
|PO
 
4
]
22.3.24Beudantite
PbFe
 
3
[(OH)
 
6
|SO
 
4
|AsO
 
4
]
22.3.25Diadochite
Fe
3+
2
(PO
 
4
)(SO
 
4
)(OH)·5H
 
2
O
22.3.26Sarmientite
Fe
3+
2
[OH|SO
 
4
|AsO
 
4
] · 5H
 
2
O
22.3.27Bukovskýite
Fe
3+
2
[OH|SO
 
4
|AsO
 
4
] · 7H
 
2
O
22.3.28Zýkaite
Fe
3+
4
[OH|SO
 
4
|(AsO
 
4
)
 
3
] · 15H
 
2
O
22.3.29Tooeleite
Fe
3+
6
(AsO
 
3
)
 
4
(SO
 
4
)(OH)
 
4
· 4H
 
2
O
22.3.30Pitticite
[Fe, SO
 
4
, AsO
 
4
, H
 
2
O] ?
22.3.31Xiangjiangite
(Fe
3+
 
,Al)(UO
 
2
)
 
4
[OH|(SO
 
4
)
 
2
|(PO
 
4
)
 
2
] · 22H
 
2
O

Other Names for Clinotyrolite

Other Languages:
German:Clinotyrolit
Klinotirolit
Klinotyrolit
Spanish:Clinotyrolita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Clinotyrolite

Reference List:Ma Zhesheng, Qian Rongyao, and Peng Zhizhong (1980): Clinotyrolite: A new mineral of the hydrous copper arsenate discovered in Dongchuan, Yunnan. Acta Geologica Sinica 54(2), 134-143 (in Chinese with English abstract). - Mineralogical Abstracts 80, 4909 (abstract).

"Clinotyrolite has been published without CNMMN approval. It might well be a separate phase." (Ernst Burke - 21/06/2004).

Krivovichev, S. V., Chernyshov, D. Yu., Döbelin, N., Kahlenberg, V., Tessadri, R., Armbruster, T. and Kaltenhauser, G. (2005): The crystal structure of tyrolite, Ca2Cu9(AsO4)4(CO3)(OH)8(H2O)10: synchrotron X-ray diffraction study. Mitt. Österr. Mineral. Ges. 151, 74. (Poster abstract)

Krivovichev, S.V., Chernyshov, D. Yu., Dobelin, N., Armbruster, Th., Kahlenberg, V., Kaindl, R., Ferraris, G., Tessadri, R., Kaltenhauser, G. (2006). Crystal chemistry and polytypism of tyrolite. American Mineralogist, 91, 1378-1384.

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    Localities for Clinotyrolite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Austria
     
    • Carinthia
      • Karawanken Mts
        • Bad Eisenkappel (Bad Eisenkappl)
          • Rijavitzagraben (Jeravitzagraben; Remscheniggraben)
    		G. Niedermayr: Carinthia II 191./111.:97-102 (2001)
    • Salzburg
      • Saalfelden
        • Leogang
          • Hütten
            • Schwarzleograben
              • Schwarzleo District
    		Poeverlein, R. (2008): Euchroit und seine Begleiter vom prähistorischen Bergbau, Leogang, Österreich. Lapis, 33 (5), 13-22.
    • Styria
      • Knittelfeld
        • Flatschach
          • Cu deposit
    		Gröbner, J. (2000): Neue Mineralienfunde aus Österreich (2). Mineralien-Welt, 11 (5), 49-51.
    • Tyrol
      • North Tyrol
        • Inn valley
          • Brixlegg - Schwaz area
            • Brixlegg - Rattenberg
              • Geyer - Silberberg District
                • Silberberg Mt.
    		Schnorrer, G. and Poeverlein, R. (2002) Schwaz-Brixlegg-Fundstellen: 2. Die Minerale des Stockerstollens bei Brixlegg in Tirol. Aufschluss, 53, 209-228.
                  • West slope ("Am Geyer")
    		R. Poeverlein and J. Gröbner (2007): "Der Bergbau Geyer bei Rattenberg in Tirol und seine Mineralien", Lapis 32(2), 34-38.
    Schnorrer, G. & Poeverlein, R. (2008): Schwaz-Brixlegger Fundstellen. 6. Die Minerale des Gratlspitz bei Brixlegg in Tirol. Aufschluss 59, 7-28.
    Schnorrer, G. & Poeverlein, R. (2005): Schwaz-Brixlegger-Fundstellen: 3. Die Minerale vom Bergbau Maukenötz bei Brixlegg, Tirol. Der Aufschluss, 56, 223-234.
              • St Gertraudi
                • Großkogel Mt.
    		Putz, H. & Poeverlein, R. (2007): Die Mineralien des Gertraudstollens und seiner Halde in St. Gertraudi, Tirol. Lapis 32 (6), 58-63.
            • Schwaz
              • Falkenstein District
    		Lapis 19(7/8):13-78 (1994)
    Chile
     
    • Tarapacá Region
      • Iquique Province
        • Santa Rosa-Huantajaya District
    		Rob Lavinky samples; analysed by XRD methods in USA
    China
     
    • Yunnan Province
      • Kunming Prefecture
        • Dongchuan District
          • Dongchuan Cu ore field
    		Ma Zhesheng, Qian Rongyao, and Peng Zhizhong (1980): Acta Geologica Sinica 54(2), 134-143.
    Ma Zhesheng, Qian Rongyao, and Peng Zhizhong (1980): Acta Geologica Sinica 54(2), 134-143.
    France
     
    • Provence-Alpes-Côte d'Azur
      • Alpes-Maritimes
        • Guillaumes
          • Daluis
    		Mari G., Sarp H., Dalia A. (1997), Le gîte cuprifère de l'Hubac de Jourdan (Daluis et la Croix-sur-Roudoule, Alpes-Maritimes, France), Le Règne Minéral, n° 13, pp: 30-37
    Sarp, H. and Cerny R., 2001, Theoparacelsite, Cu3(OH)2As2O7, a new mineral: its description and crystal structure: Archs Sci. Geneve, 54:7-14.
    • Rhône-Alpes
      • Rhône
        • Monsols
    		Favreau G., Legris J-R., Dardillac M. (1996), La Verrière (Rhône): Histoire et Minéralogie, Le Cahier des Micromonteurs, n°3, pp:3-28
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Wolfach
          • Oberwolfach
            • Rankach valley
    		Blaß, G. & Graf, H. W. (2000): Neufunde von bekannten Fundorten im Schwarzwald. Mineralien-Welt, 11 (4), 57-60. (in German)
    • Hesse
      • North Hesse
        • Richelsdorf District
          • Süss
            • Richelsdorf Smelter
    		S. Weiß: "Mineralfundstellen, Deutschland West", Weise (Munich), 1992
    • Lower Saxony
      • Harz Mts
        • Bad Lauterberg
    		Schnorrer, G. & Tetzer, G. (2006): Clinotyrolite, cupro-allophane, chrysokolla, partzite and claraite from the former fluorite mine Flossberg in greater Andreas valley in Bad Lauterberg in the Southern Harz Mountains. Aufschluss 57, 39-42. (in German)
    Ireland
     
    • Co. Galway
      • Killimor
    		Sarp et al (1987) Arch. Sci. Geneve, 40, p.47-50.
    Italy
     
    • Veneto
      • Vicenza Province
        • Torrebelvicino
          • Mercanti Valley
            • Zuccanti Valley
    		Saccardo D., Benincasa E., Malferrari D., Medici L., 2002. I minerali di Monte Cengio (Torrebelvicino, Vicenza). Riv. Miner. Ital., 1: 42-47.
        • Valli del Pasubio
    		Rivista Mineralogica Italiana, (2), 109-113.
    Morocco
     
    • Souss-Massa-Draâ Region
      • Ouarzazate Province
        • Tazenakht
          • Bou Azzer District
            • Ightem
    		Favreau, G. and Dietrich, J. E. (2006). Die Mineralien von Bou Azzer. Lapis 31(7/8), 27-68
            • Khder
    		Favreau, G. and Dietrich, J. E. (2006). Die Mineralien von Bou Azzer. Lapis 31(7/8), 27-68
    Poland
     
    • Lower Silesia (Dolnośląskie)
      • Rudawy Janowickie Mts
        • Czarnów
          • Rędziny
    		Domańska, J.: Rędziny. Otoczak, nr. 29, p. 38-52; Gołębiowska B., A. Pieczka, & W. Franus: "Olivenite-adamite solid solution from oxidation zone in Redziny (West Sudetes, Poland)": Mineralogia Polonica 37 (2006) 101-111.
    Spain
     
    • Andalusia
      • Almería
        • Huercal-Overa
    		J. Gröbner and M. A. Fernández Périz (2006): Minerals of the Copper-Cobalt Deposits Molvizar and Cerro Minado in Andalusia. Mineralup February 2006, 48-56.
      • Granada
        • Molvizar
    		J. Gröbner and M. A. Fernández Périz (2006): Minerals of the Copper-Cobalt Deposits Molvizar and Cerro Minado in Andalusia. Mineralup February 2006, 48-56.
    • Valencian Community
      • Castellón
        • Vall de Almonacid
          • Fuente Huerpita
    		Juan Miguel Casanova
        • Villahermosa del Rio
          • Cueva de la Guerra Antigua
    		Casanova Honrubia, Juan Miguel & Canseco Caballé, Manuel, 2002, Minerales de la Comunidad Valenciana : 237 p. Ed. Caja de Ahorros del Mediterráneo. Alicante
    Collection and photos of Adrian Pesudo
    USA
     
    • Nevada
      • Churchill Co.
        • Table Mountain District
          • Cottonwood Canyon
            • Bolivia
    		[R.Tayler Minerals catalogue 70 p.2]
    Self collected by Brent Thorne
    Mineral and/or Locality
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