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Clinozoisite-(Sr)

Formula:
CaSrAl
 
3
(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
System:MonoclinicColour:pale grey to yellowish ...
Hardness:5 - 5½
Name:Originally named for Niigata prefecture, where the type locality is.


Epidote Group. Originally known as niigataite; renamed by the Epidote Subcommittee of the CNMMN in 2006.

Classification of Clinozoisite-(Sr)

IMA status:Approved 2001
Strunz 8th edition ID:8/C.23-35
Nickel-Strunz 10th (pending) edition ID:9.BG.05

9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
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Type Occurrence of Clinozoisite-(Sr)

Type Locality:Miyabana beach, Ohmi, Itoigawa, Niigata Prefecture, Chubu Region, Honshu Island, Japan
General Appearance of Type Material:Micro anhedral grains to 0.5 mm across, intimately intergrown with clinozoisite, diaspore and chlorite.
Place of Conservation of Type Material:Fossa Magna Museum
Geological Setting of type material:Prehnite-rich rodingite block derived from serpentinite melange. Unlike the other Sr-bearing silicates from this district, niigataite has not been found in the jadeitite boulders.
Associated Minerals at type locality:
PrehniteDiasporeClinozoisiteChlorite Group

Physical Properties of Clinozoisite-(Sr)

Lustre:Vitreous
Diaphaneity (Transparency):Translucent
Colour:pale grey to yellowish green
Streak:white
Hardness (Mohs):5 - 5½
Hardness Data:Measured
Tenacity:Brittle
Cleavage:Perfect
on {001}
Density (calculated):3.63 g/cm3

Crystallography of Clinozoisite-(Sr)

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Cell Parameters:a = 8.89Å, b = 5.588Å, c = 10.21Å
β = 115.12°
Ratio:a:b:c = 1.591 : 1 : 1.827
Unit Cell Volume:V 459.23 ų (Calculated from Unit Cell)
Morphology:anhedral grains
X-Ray Powder Diffraction:
d-spacingIntensity
2.90 (100)
2.79 (50)

Chemical Properties of Clinozoisite-(Sr)

Formula:
CaSrAl
 
3
(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
Essential elements:
All elements listed in formula:Al, Ca, H, O, Si, Sr
Empirical Formula:
(Ca
 
1.28
Sr
 
0.72
)
 
2.00
(Al
 
2.48
Fe
 
0.45
Ti
 
0.05
Mn
 
0.02
Mg
 
0.01
)
 
3.01
[HSi
 
3
O
 
13
]
Common Impurities:Fe

Relationship of Clinozoisite-(Sr) to other Species

Related to:
  • Epidote Group
  • Related Minerals - Nickel-Strunz Grouping):
    9.BG.05Allanite-(Ce)
    {CaCe}{Al
     
    2
    Fe
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Allanite-(La)
    {CaLa}{Al
     
    2
    Fe
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Allanite-(Y)
    {CaY}{Al
     
    2
    Fe
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Clinozoisite
    {Ca
     
    2
    }{Al
     
    3
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Dissakisite-(Ce)
    {CaCe}{Al
     
    2
    Mg}[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Dollaseite-(Ce)
    {CaCe}{MgAlMg}[F|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Epidote
    {Ca
     
    2
    }{Al
     
    2
    Fe
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Epidote-(Pb)
    {CaPb}{Al
     
    3
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Khristovite-(Ce)
    {CaCe}{MgAlMn
    2+
     
    }[F|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Mukhinite
    {Ca
     
    2
    }{Al
     
    2
    V
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Piemontite
    {Ca
     
    2
    }{Al
     
    2
    Mn
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Piemontite-(Sr)
    {CaSr}{Al
     
    2
    Mn
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Manganiandrosite-(La)
    {LaMn
    2+
     
    }{Mn
    3+
     
    AlMn
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Tawmawite
    Ca
     
    2
    (Al,Fe
    3+
     
    ,Cr)
     
    3
    [O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Manganipiemontite-(Sr)
    {CaSr}{Mn
    3+
     
    AlMn
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Ferriallanite-(Ce)
    {CaCe}{Fe
    3+
     
    AlFe
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Ferriepidote
    9.BG.05Manganiandrosite-(Ce)
    (Mn
    2+
     
    ,Ca)(Ce,REE)AlMn
    3+
     
    Mn
    2+
     
    (Si
     
    2
    O
     
    7
    )(SiO
     
    4
    )O(OH)
    9.BG.05Dissakisite-(La)
    {CaLa}{Al
     
    2
    Mg}[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Vanadoandrosite-(Ce)
    {Mn
    2+
     
    Ce}{V
    3+
     
    AlMn
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Androsite-(La)
    9.BG.05Uedaite-(Ce)
    {Mn
    2+
     
    Ce}{Al
     
    2
    Fe
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05IMA2006-055
    CaSrAl
     
    2
    Fe
    3+
     
    (Si
     
    2
    O
     
    7
    )(SiO
     
    4
    )O(OH)
    9.BG.10Zoisite
    {Ca
     
    2
    }{Al
     
    3
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.15Macfallite
    Ca
     
    2
    (Mn
    3+
     
    ,Al)
     
    3
    [(OH)
     
    3
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.15Sursassite
    Mn
     
    2
    Al
     
    3
    [(OH)
     
    3
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.20Julgoldite-(Fe2+)
    Ca
     
    2
    (Fe
    2+
     
    ,Mg)(Fe
    3+
     
    ,Al)
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Okhotskite
    Ca
     
    8
    (Mn,Mg)
     
    4
    (Mn,Al,Fe)
     
    8
    Si
     
    12
    O
     
    56-n
    (OH)
     
    n
    9.BG.20Pumpellyite-(Fe2+)
    Ca
     
    2
    Fe
    2+
     
    Al
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Pumpellyite-(Fe3+)
    Ca
     
    2
    (Fe
    3+
     
    ,Mg,Fe
    2+
     
    )(Al,Fe
    3+
     
    )
     
    2
    [(OH,O)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Pumpellyite-(Mg)
    Ca
     
    2
    MgAl
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Pumpellyite-(Mn2+)
    Ca
     
    2
    (Mn
    2+
     
    ,Mg)(Al,Mn
    3+
     
    ,Fe
    3+
     
    )
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Shuiskite
    Ca
     
    2
    (Mg,Al)(Cr,Al)
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · 2H
     
    2
    O
    9.BG.20Julgoldite-(Fe3+)
    Ca
     
    2
    (Fe
    3+
     
    ,Mg)(Fe
    3+
     
    ,Al)
     
    2
    [(OH,O)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Pumpellyite-(Al)
    Ca
     
    2
    (Al,Fe
    2+
     
    ,Mg)Al
     
    2
    [(OH,O)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Poppiite
    Ca
     
    2
    (V
    3+
     
    ,Fe
    3+
     
    ,Mg)(V
    3+
     
    ,Al)
     
    2
    [(OH,O)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Julgoldite-(Mg)
    Ca
     
    2
    (Mg,Fe
    2+
     
    )(Fe
    3+
     
    ,Al)
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.25Ganomalite
    Pb
     
    9
    Ca
     
    5
    Mn[O|SiO
     
    4
    |(Si
     
    2
    O
     
    7
    )
     
    4
    ]
    9.BG.30Rustumite
    Ca
     
    10
    (Si
     
    2
    O
     
    7
    )
     
    2
    (SiO
     
    4
    )Cl
     
    2
    (OH)
     
    2
    9.BG.35Vesuvianite
    Ca
     
    10
    (Mg,Fe)
     
    2
    Al
     
    4
    Si
     
    9
    O
     
    34
    (OH)
     
    4
    9.BG.35Wiluite
    Ca
     
    19
    (Al,Mg,Fe,Ti)
     
    13
    (B,Al,[ ])
     
    5
    Si
     
    18
    O
     
    68
    (O,OH)
     
    10
    9.BG.35Manganvesuvianite
    Ca
     
    19
    Mn(Al,Mn,Fe)
     
    19
    (Mg,Mn)
     
    2
    Si
     
    18
    O
     
    69
    (OH)
     
    9
    9.BG.35Fluorvesuvianite
    Ca
     
    19
    (Al,Mg,Fe
    2+
     
    )
     
    13
    [(F,OH,O)
     
    10
    |(SiO
     
    4
    )
     
    10
    |(Si
     
    2
    O
     
    7
    )
     
    4
    ]
    9.BG.40Vyuntspakhkite-(Y)
    Y
     
    4
    Al
     
    3
    Si
     
    5
    O
     
    18
    (OH)
     
    5
    9.BG.45Dellaite
    Ca
     
    6
    Si
     
    3
    O
     
    11
    (OH)
     
    2
    9.BG.50Gatelite-(Ce)
    CaCe
     
    3
    Al
     
    2
    (Al,Mg)(Mg,Fe
    2+
     
    ,Al)[(O,F)|(OH,O)
     
    2
    |(SiO
     
    4
    )
     
    3
    |Si
     
    2
    O
     
    7
    ]
    9.BG.55Västmanlandite-(Ce)
    Ca(Ce,La)
     
    3
    Al
     
    2
    Mg
     
    2
    [F|(OH)
     
    2
    |(SiO
     
    4
    )
     
    3
    |Si
     
    2
    O
     
    7
    ]

    Other Names for Clinozoisite-(Sr)

    Synonyms:
    IMA2001-055Niigataite
    German names:
    Niigatait
    Japanese names:
    新潟石
    Russian names:
    Клиноцоизит-(Sr)
    Spanish names:
    Niigataita

    Other Information

    Fluorescence in UV light:none
    Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

    References for Clinozoisite-(Sr)

    Reference List:H. Miyajima, S. Matsubara, R. Miyawaki, K. Hirokawa (2003): Niigataite, CaSrAl3(Si2O7)(SiO4)O(OH): Sr-analogue of clinozoisite, a new member of the epidote group from the Itoigawa-Ohmi district, Niigata Prefecture, central Japan. Journal of Mineralogy and Petrology Science, 98, 118-129.

    American Mineralogist (2004): 89: 469. [Abstract].

    www2.ocn.ne.jp/~miyajima/niigataite
    www.city.itoigawa.niigata.jp/fmm.

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    Localities for Clinozoisite-(Sr)

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Japan
     
    • Honshu Island
      • Chubu Region
        • Niigata Prefecture
    www-jm.eps.s.u-tokyo.ac.jp/2002cd-rom/pdf/j038/j038-003_e.pdf.
            • Ohmi
    Miyajima et al. (2003) Journal of Mineralogical and Petrological Sciences, 98, 118-129.
    Mineral and/or Locality
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