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Shirozulite

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Bikkulovskoe deposit, Southern Urals, Urals Region, Russia




Formula:
K(Mn
2+
 
,Mg)
 
3
(AlSi
 
3
O
 
10
)(OH)
 
2
System:MonoclinicColour:dark reddish brown
Hardness:3
Member of:Mica Group
Name:Honouring Professor Haruo Shirozu, University of Kyushu, for his contributions to the crystal chemistry of layered silicates.


Mica Group.
The manganese analogue of Phlogopite.

Classification of Shirozulite

IMA status:Approved 2001
Strunz 8th edition ID:8/H.11-102
Nickel-Strunz 10th (pending) edition ID:9.EC.20

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
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Type Occurrence of Shirozulite

Type Locality:Taguchi mine, Shidara-cho, Kita-Shidara-gun, Aichi Prefecture, Chubu Region, Honshu Island, Japan
General Appearance of Type Material:grains to 0.5 mm across
Geological Setting of type material:contact of barium-rich K feldspars to metamorphosed manganese ores
Associated Minerals at type locality:
TephroiteRhodoniteRhodochrositePyroxmangiteK Feldspar
Hausmannite

Physical Properties of Shirozulite

Lustre:Pearly
Diaphaneity (Transparency):Transparent
Colour:dark reddish brown
Hardness (Mohs):3
Tenacity:Elastic
Cleavage:Perfect
on (001)
Fracture:Micaceous
Density (measured):3.2 g/cm3

Crystallography of Shirozulite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m {B1 1 2/m} {C2/m} {C1 2/m 1}
Cell Parameters:a = 5.3791Å, b = 9.319Å, c = 10.2918Å
α = 90°, β = 100.18°, γ = 90°
Ratio:a:b:c = 0.577 : 1 : 1.104
Unit Cell Volume:V 507.78 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
d-spacingIntensity
10.16 (100)
3.38 (50)
2.65 (95)

Chemical Properties of Shirozulite

Formula:
K(Mn
2+
 
,Mg)
 
3
(AlSi
 
3
O
 
10
)(OH)
 
2
Essential elements:Al, H, K, Mn, O, Si
All elements listed in formula:Al, H, K, Mg, Mn, O, Si

Relationship of Shirozulite to other Species

Member of:Mica Group
Other Members of Group:

- +
Aluminoceladonite
K(Mg,Fe
2+
 
)Al(Si
 
4
O
 
10
)(OH)
 
2
Anandite
(Ba,K)(Fe
2+
 
,Mg)
 
3
((Si,Al,Fe)
 
4
O
 
10
)(S,OH)
 
2
Aspidolite
NaMg
 
3
(AlSi
 
3
O
 
10
)(OH)
 
2
Biotite
Bityite
LiCaAl
 
2
(AlBeSi
 
2
O
 
10
)(OH)
 
2
Boromuscovite
KAl
 
2
(BSi
 
3
O
 
10
)(OH)
 
2
Celadonite
K(Mg,Fe
2+
 
)Fe
3+
 
(Si
 
4
O
 
10
)(OH)
 
2
Chernykhite
(Ba,Na)(V
3+
 
,Al,Mg)
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
Chromceladonite
K(Mg,Fe
2+
 
)(Cr,Al)(Si
 
4
O
 
10
)(OH)
 
2
Chromphyllite
K(Cr,Al)
 
2
(AlSi
 
3
O
 
10
)(OH,F)
 
2
Clintonite
Ca(Mg,Al)
 
3
(Al
 
3
SiO
 
10
)(OH)
 
2
Ephesite
LiNaAl
 
2
(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
Ferro-aluminoceladonite
K(Fe
2+
 
,Mg)(Al,Fe
3+
 
)(Si
 
4
O
 
10
)(OH)
 
2
Ferroceladonite
K(Fe
2+
 
,Mg)(Fe
3+
 
,Al)(Si
 
4
O
 
10
)(OH)
 
2
Ferrokinoshitalite
(Ba,K)(Fe
2+
 
,Mg)
 
3
(Al
 
2
Si
 
2
O
 
10
)(OH,F)
 
2
Ganterite
(Ba,Na,K)(Al,Mg)
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
Glauconite
(K,Na)(Fe
3+
 
,Al,Mg)
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
Hendricksite
K(Zn,Mg,Mn
2+
 
)
 
3
(AlSi
 
3
O
 
10
)(OH)
 
2
Illite
K
 
0.65
Al
 
2.0
[ ][Al
 
0.65
Si
 
3.35
O
 
10
](OH)
 
2
Kinoshitalite
(Ba,K)(Mg,Mn
2+
 
,Al)
 
3
(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
Lepidolite
Margarite
CaAl
 
2
(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
Masutomilite
(K,Rb)(Li,Mn
3+
 
,Al)
 
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
Montdorite
(K,Na)
 
2
(Fe
2+
 
,Mn
2+
 
,Mg)
 
5
(Si
 
4
O
 
10
)
 
2
(OH,F)
 
4
Muscovite
KAl
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
Nanpingite
CsAl
 
2
(AlSi
 
3
O
 
10
)(OH,F)
 
2
Norrishite
KLiMn
2+
2
(Si
 
4
O
 
10
)(OH)
 
2
Oxykinoshitalite
(Ba,K)(Mg,Ti,Fe
3+
 
,Fe
2+
 
)
 
3
((Si,Al)
 
4
O
 
10
)(O,OH,F)
 
2
Oxyphlogopite
KMg
 
2
Ti(AlSi
 
3
O
 
10
)O
 
2
Phengite
Polylithionite
KLi
 
2
Al(Si
 
4
O
 
10
)(F,OH)
 
2
Preiswerkite
NaMg
 
2
Al(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
Roscoelite
K(V
3+
 
,Al)
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
Shirokshinite
KNaMg
 
2
(Si
 
4
O
 
10
)F
 
2
Sokolovaite
CsLi
 
2
Al(Si
 
4
O
 
10
)F
 
2
Suhailite
(NH
 
4
)Fe
2+
3
(AlSi
 
3
O
 
10
)(OH)
 
2
Tainiolite
KLiMg
 
2
(Si
 
4
O
 
10
)F
 
2
Tetraferriphlogopite
KMg
 
3
(Fe
3+
 
Si
 
3
O
 
10
)(OH,F)
 
2
Tobelite
(NH
 
4
,K)Al
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
Trilithionite
K(Li,Al)
 
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
Voloshinite
Rb(LiAl
 
1.5
□
 
1.5
)(Al
 
0.5
Si
 
3.5
)O
 
10
F
 
2
Yangzhumingite
KMg
 
2.5
(Si
 
4
O
 
10
)F
 
2
Zinnwaldite
KLiFe
2+
 
Al(AlSi
 
3
O
 
10
)(F,OH)
 
2
Related Minerals - Nickel-Strunz Grouping):

- +
9.EC.05Minnesotaite
(Fe,Mg)
 
3
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.05Talc
Mg
 
3
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.05Willemseite
(Ni,Mg)
 
3
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.10Ferripyrophyllite
Fe
3+
2
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.10Pyrophyllite
Al
 
2
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Boromuscovite
KAl
 
2
(BSi
 
3
O
 
10
)(OH)
 
2
9.EC.15Celadonite
K(Mg,Fe
2+
 
)Fe
3+
 
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Chernykhite
(Ba,Na)(V
3+
 
,Al,Mg)
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
9.EC.15Montdorite
(K,Na)
 
2
(Fe
2+
 
,Mn
2+
 
,Mg)
 
5
(Si
 
4
O
 
10
)
 
2
(OH,F)
 
4
9.EC.15Muscovite
KAl
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.15Nanpingite
CsAl
 
2
(AlSi
 
3
O
 
10
)(OH,F)
 
2
9.EC.15Paragonite
NaAl
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.15Roscoelite
K(V
3+
 
,Al)
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.15Tobelite
(NH
 
4
,K)Al
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.15Aluminoceladonite
K(Mg,Fe
2+
 
)Al(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Chromphyllite
K(Cr,Al)
 
2
(AlSi
 
3
O
 
10
)(OH,F)
 
2
9.EC.15Ferro-aluminoceladonite
K(Fe
2+
 
,Mg)(Al,Fe
3+
 
)(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Ferroceladonite
K(Fe
2+
 
,Mg)(Fe
3+
 
,Al)(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Chromceladonite
K(Mg,Fe
2+
 
)(Cr,Al)(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Tainiolite
KLiMg
 
2
(Si
 
4
O
 
10
)F
 
2
9.EC.15Ganterite
(Ba,Na,K)(Al,Mg)
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20Annite
KFe
2+
3
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20Ephesite
LiNaAl
 
2
(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.20Hendricksite
K(Zn,Mg,Mn
2+
 
)
 
3
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20Masutomilite
(K,Rb)(Li,Mn
3+
 
,Al)
 
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
9.EC.20Norrishite
KLiMn
2+
2
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.20Phlogopite
KMg
 
3
(AlSi
 
3
O
 
10
)(OH,F)
 
2
9.EC.20Polylithionite
KLi
 
2
Al(Si
 
4
O
 
10
)(F,OH)
 
2
9.EC.20Preiswerkite
NaMg
 
2
Al(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.20Siderophyllite
KFe
2+
2
Al(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.20Tetraferriphlogopite
KMg
 
3
(Fe
3+
 
Si
 
3
O
 
10
)(OH,F)
 
2
9.EC.20Fluorotetraferriphlogopite
KMg
 
3
(Fe
3+
 
Si
 
3
O
 
10
)F
 
2
9.EC.20Wonesite
(Na,K)(Mg,Fe,Al)
 
6
((Al,Si)
 
4
O
 
10
)
 
2
(OH,F)
 
4
9.EC.20Eastonite
KMg
 
2
Al(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.20Tetraferriannite
KFe
2+
3
((Fe
3+
 
,Al)Si
 
3
O
 
10
)(OH)
 
2
9.EC.20Trilithionite
K(Li,Al)
 
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
9.EC.20Fluorannite
KFe
2+
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
9.EC.20Shirokshinite
KNaMg
 
2
(Si
 
4
O
 
10
)F
 
2
9.EC.20Sokolovaite
CsLi
 
2
Al(Si
 
4
O
 
10
)F
 
2
9.EC.20Aspidolite
NaMg
 
3
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20Fluorophlogopite
KMg
 
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
9.EC.20UM2004-49-SiO:AlCsFHKLi
(Cs,K)(Al,Li)
 
2.6
((Si,Al)
 
4
O
 
10
)(F,OH)
 
2
9.EC.20Suhailite
(NH
 
4
)Fe
2+
3
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20Yangzhumingite
KMg
 
2.5
(Si
 
4
O
 
10
)F
 
2
9.EC.20IMA2009-006
KLi
 
2
Ti(Si
 
4
O
 
10
)OF
9.EC.25Brammallite
(Na,H
 
3
O)(Al,Mg,Fe)
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
9.EC.30Margarite
CaAl
 
2
(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.35Anandite
(Ba,K)(Fe
2+
 
,Mg)
 
3
((Si,Al,Fe)
 
4
O
 
10
)(S,OH)
 
2
9.EC.35Bityite
LiCaAl
 
2
(AlBeSi
 
2
O
 
10
)(OH)
 
2
9.EC.35Clintonite
Ca(Mg,Al)
 
3
(Al
 
3
SiO
 
10
)(OH)
 
2
9.EC.35Kinoshitalite
(Ba,K)(Mg,Mn
2+
 
,Al)
 
3
(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.35Ferrokinoshitalite
(Ba,K)(Fe
2+
 
,Mg)
 
3
(Al
 
2
Si
 
2
O
 
10
)(OH,F)
 
2
9.EC.35Oxykinoshitalite
(Ba,K)(Mg,Ti,Fe
3+
 
,Fe
2+
 
)
 
3
((Si,Al)
 
4
O
 
10
)(O,OH,F)
 
2
9.EC.35Fluorokinoshitalite
BaMg
 
3
(Al
 
2
Si
 
2
O
 
10
)F
 
2
9.EC.40Beidellite
(Na,Ca
 
0.5
)
 
0.3
Al
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · nH
 
2
O
9.EC.40Kurumsakite
(Zn,Ni,Cu)
 
8
Al
 
8
V
5+
2
Si
 
5
O
 
35
 · 27H
 
2
O (?)
9.EC.40Montmorillonite
(Na,Ca)
 
0.33
(Al,Mg)
 
2
(Si
 
4
O
 
10
)(OH)
 
2
 · nH
 
2
O
9.EC.40Nontronite
Na
 
0.3
Fe
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · nH
 
2
O
9.EC.40Volkonskoite
Ca
 
0.3
(Cr,Mg,Fe)
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · 4H
 
2
O
9.EC.40Yakhontovite
(Ca,Na)
 
0.5
(Cu,Fe,Mg)
 
2
(Si
 
4
O
 
10
)(OH)
 
2
 · 3H
 
2
O
9.EC.45Hectorite
Na
 
0.3
(Mg,Li)
 
3
(Si
 
4
O
 
10
)(F,OH)
 
2
9.EC.45Saponite
Ca
 
0.25
(Mg,Fe)
 
3
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · nH
 
2
O
9.EC.45Sauconite
Na
 
0.3
Zn
 
3
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · 4H
 
2
O
9.EC.45Spadaite
MgSiO
 
2
(OH)
 
2
 · H
 
2
O (?)
9.EC.45Stevensite
(Ca,Na)
 
x
Mg
 
3-x
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.45Swinefordite
Li(Al,Li,Mg)
 
4
((Si,Al)
 
4
O
 
10
)
 
2
(OH,F)
 
4
 · nH
 
2
O
9.EC.45Zincsilite
Zn
 
3
(Si
 
4
O
 
10
)(OH)
 
2
 · 4H
 
2
O
9.EC.45Ferrosaponite
Ca
 
0.3
(Fe
2+
 
,Mg,Fe
3+
 
)
 
3
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · 4H
 
2
O
9.EC.50Vermiculite
(Mg,Fe,Al)
 
3
((Al,Si)
 
4
O
 
10
)(OH)
 
2
 · 4H
 
2
O
9.EC.55Baileychlore
(Zn,Fe,Al,Mg)
 
6
((Si,Al)
 
4
O
 
10
)(OH)
 
8
9.EC.55Chamosite
(Fe
2+
 
,Mg)
 
5
Al(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Clinochlore
(Mg,Fe
2+
 
)
 
5
Al(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Cookeite
LiAl
 
4
(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Franklinfurnaceite
Ca
 
2
Fe
3+
 
Mn
2+
3
Mn
3+
 
(Zn
 
2
Si
 
2
O
 
10
)(OH)
 
8
9.EC.55Gonyerite
(Mn
2+
 
,Mg)
 
5
Fe
3+
 
(Fe
3+
 
Si
 
3
O
 
10
)(OH)
 
8
9.EC.55Nimite
(Ni,Mg,Al)
 
6
((Si,Al)
 
4
O
 
10
)(OH)
 
8
9.EC.55Orthochamosite
(Fe
2+
 
,Mg,Fe
3+
 
)
 
5
Al(AlSi
 
3
O
 
10
)(OH,O)
 
8
9.EC.55Pennantite
Mn
2+
5
Al(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Sudoite
(Mg,Fe
2+
 
)
 
2
Al
 
3
(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Donbassite
Al
 
4.33
(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Glagolevite
Na(Mg,Al)
 
6
(AlSi
 
3
O
 
10
)(OH,O)
 
8
9.EC.55Borocookeite
Li
 
1+3x
Al
 
4-x
(BSi
 
3
O
 
10
)(OH)
 
8
9.EC.60Aliettite
Ca
 
0.2
Mg
 
6
((Si,Al)
 
8
O
 
20
)(OH)
 
4
 · 4H
 
2
O
9.EC.60Corrensite
(Mg,Fe)
 
9
((Si,Al)
 
8
O
 
20
)(OH)
 
10
 · nH
 
2
O
9.EC.60Dozyite
Mg
 
7
Al
 
2
(Al
 
2
Si
 
4
O
 
15
)(OH)
 
12
9.EC.60Hydrobiotite
K(Mg,Fe
2+
 
)
 
6
((Si,Al)
 
8
O
 
20
)(OH)
 
4
 · nH
 
2
O
9.EC.60Karpinskite
(Ni,Mg)
 
2
Si
 
2
O
 
5
(OH)
 
2
 (?)
9.EC.60Kulkeite
Mg
 
8
Al(AlSi
 
7
O
 
20
)(OH)
 
10
9.EC.60Lunijianlaite
Li
 
0.7
Al
 
6.2
(AlSi
 
7
lO
 
20
)(OH,O)
 
10
9.EC.60Rectorite
(Na,Ca)Al
 
4
((Si,Al)
 
8
O
 
20
)(OH)
 
4
 · 2H
 
2
O
9.EC.60Saliotite
(Li,Na)Al
 
3
(AlSi
 
3
O
 
10
)(OH)
 
5
9.EC.60Tosudite
Na
 
0.5
(Al,Mg)
 
6
((Si,Al)
 
8
O
 
18
)(OH)
 
12
 · 5H
 
2
O
9.EC.60Brinrobertsite
Na
 
0.3
Al
 
4
(Si
 
4
O
 
10
)
 
2
(OH)
 
4
 · 3.5 H
 
2
O
9.EC.65Macaulayite
(Fe,Al)
 
24
Si
 
4
O
 
43
(OH)
 
2
9.EC.70Burckhardtite
Pb
 
2
(Fe
3+
 
,Mn
3+
 
)Te
4+
 
(AlSi
 
3
O
 
10
)O
 
2
(OH)
 
2
 · H
 
2
O
9.EC.75Ferrisurite
(Pb,Ca)
 
2.4
Fe
3+
2
(Si
 
4
O
 
10
)(CO
 
3
)
 
1.7
(OH)
 
3
 · nH
 
2
O
9.EC.75Surite
(Pb,Ca)
 
3
(Al,Fe
2+
 
,Mg)
 
2
((Si,Al)
 
4
O
 
10
)(CO
 
3
)
 
2
(OH)
 
2
9.EC.75Niksergievite
(Ba,Ca)
 
2
Al
 
3
(AlSi
 
3
O
 
10
)(CO
 
3
)(OH)
 
6
 · nH
 
2
O
9.EC.80Kegelite
Pb
 
8
Al
 
4
(Si
 
8
O
 
20
)(SO
 
4
)
 
2
(CO
 
3
)
 
4
(OH)
 
8

Other Names for Shirozulite

Synonyms:
IMA2001-045
Other Languages:
German:Shirozulith
Japanese:白水雲母
Russian:Широцулит
Spanish:Shirozulita

Other Information

Fluorescence in UV light:none
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Shirozulite

Reference List:

- +
Kiyotaka Ishida, Frank C. Hawthorne and Fumitoshi Hirotawari (2004): Shirozulite, KMn3(Si3Al)O10(OH,F)2, a new manganese dominant trioctahedral mica: Description and crystal structure. American Mineralogist 89, 232-238.

Internet Links for Shirozulite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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    • Localities for Shirozulite

    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Japan
     
    • Honshu Island
      • Chubu Region
        • Aichi Prefecture
          • Kita-Shidara-gun
            • Shidara-cho
    		Am Min (2004) 89, (1), 232-247
    Russia
     
    • Urals Region
      • Southern Urals
    		brown microfoliated aggregates - Marco Ciriotti post on Mindat
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