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Defernite

Formula:
Ca
 
6
(CO
 
3
)
 
2-x
(SiO
 
4
)
 
x
(OH)
 
7
(Cl,OH)
 
1-2x
(x=0.5)
System:OrthorhombicColour:Colourless, red, ...
Lustre:VitreousHardness:3
This page provides mineralogical data about Defernite.

Classification of Defernite

IMA status:Approved 1978
Strunz 8th edition ID:5/0.0-30
Nickel-Strunz 10th (pending) edition ID:5.BA.25

5 : CARBONATES (NITRATES)
B : Carbonates with additional anions, without H2O
A : With Cu, Co, Ni, Zn, Mg, Mn
Dana 8th edition ID:16b.4.2.1

16b : HYDRATED CARBONATES CONTAINING HYDROXYL OR HALOGEN
4 : AmBn(XO3)pZqxH2O & with (m+n):p = 3:1
Hey's CIM Ref.:12.1.5

12 : Carbonates with other anions
1 : Carbonates with halides
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Type Occurrence of Defernite

Type Locality:Güneyce-Ikizdere, Rize Province, Black Sea Region, Turkey
Year of Discovery:1980

Physical Properties of Defernite

Lustre:Vitreous
Colour:Colourless, red, rose-brown
Hardness (Mohs):3

Crystallography of Defernite

Crystal System:Orthorhombic
Cell Parameters:a = 17.86Å, b = 22.77Å, c = 3.65Å
Ratio:a:b:c = 0.784 : 1 : 0.16
Unit Cell Volume:V 1,484.35 ų (Calculated from Unit Cell)

Optical Data of Defernite

Type:Biaxial (-)
RI values: nα = 1.546 nβ = 1.572 nγ = 1.576
2V:Measured: 42° , Calculated: 42°
Maximum Birefringence:δ = 0.030

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low
Dispersion:none

Chemical Properties of Defernite

Formula:
Ca
 
6
(CO
 
3
)
 
2-x
(SiO
 
4
)
 
x
(OH)
 
7
(Cl,OH)
 
1-2x
(x=0.5)
Essential elements:C, Ca, H, O
All elements listed in formula:C, Ca, Cl, H, O, Si
Common Impurities:Fe,Mn,Mg

Relationship of Defernite to other Species

Related Minerals - Nickel-Strunz Grouping):
5.BA.05Azurite
Cu
 
3
[OH|CO
 
3
]
 
2
5.BA.10Georgeite
Cu
 
2
[(OH)
 
2
|CO
 
3
] · 6H
 
2
O
5.BA.10Glaukosphaerite
(Cu,Ni)
 
2
[(OH)
 
2
|CO
 
3
]
5.BA.10Kolwezite
(Cu,Co)
 
2
[(OH)
 
2
|CO
 
3
]
5.BA.10Malachite
Cu
 
2
[(OH)
 
2
|CO
 
3
]
5.BA.10Mcguinnessite
(Mg,Cu)
 
2
[(OH)
 
2
|CO
 
3
]
5.BA.10Nullaginite
Ni
 
2
[(OH)
 
2
|CO
 
3
]
5.BA.10Pokrovskite
Mg
 
2
[(OH)
 
2
|CO
 
3
]
5.BA.10Rosasite
(Cu,Zn)
 
2
[(OH)
 
2
|CO
 
3
]
5.BA.10Zincrosasite
(Zn,Cu)
 
2
[(OH)
 
2
|CO
 
3
]
5.BA.10Chukanovite
Fe
2+
2
[(OH)
 
2
|CO
 
3
]
5.BA.15Aurichalcite
(Zn,Cu)
 
5
[(OH)
 
3
|CO
 
3
]
 
2
5.BA.15Hydrozincite
Zn
 
5
[(OH)
 
3
|CO
 
3
]
 
2
5.BA.20Holdawayite
Mn
 
6
(CO
 
3
)
 
2
(OH)
 
7
(Cl,OH)
5.BA.30Loseyite
(Zn,Mn
2+
 
)
 
7
[(OH)
 
5
|CO
 
3
]
 
2
5.BA.30Sclarite
(Zn,Mg,Mn
2+
 
)
 
4
Zn
 
3
[(OH)
 
5
|CO
 
3
]
 
2
Related Minerals - Hey's Index Grouping:
12.1.1Northupite
Na
 
3
Mg(CO
 
3
)
 
2
Cl
12.1.2Barentsite
Na
 
7
AlH
 
2
(CO
 
3
)
 
4
F
 
4
12.1.3Rouvilleite
Na
 
3
(Ca,Mn,Fe)
 
2
(CO
 
3
)
 
3
F
12.1.4Chlormagaluminite
(Mg,Fe
2+
 
)
 
4
Al
 
2
[(OH)
 
12
|(Cl
 
2
,CO
 
3
)] · 2H
 
2
O
12.1.6Brenkite
Ca
 
2
[F
 
2
|CO
 
3
]
12.1.7Stenonite
(Sr,Ba,Na)
 
2
AlCO
 
3
F
 
5
12.1.8Bastnäsite-(Ce)
(Ce,La)[F|CO
 
3
]
12.1.9Bastnäsite-(La)
(La,Ce)[F|CO
 
3
]
12.1.10Bastnäsite-(Y)
(Y,Ce)[F|CO
 
3
]
12.1.11Parisite-(Ce)
Ca(Ce,La)
 
2
[F
 
2
|(CO
 
3
)
 
3
]
12.1.12Parisite-(Nd)
Ca(Nd,Ce,La)
 
2
[F
 
2
|(CO
 
3
)
 
3
]
12.1.13Synchysite-(Ce)
Ca(Ce,La)[F|(CO
 
3
)
 
2
]
12.1.14Synchysite-(Y)
Ca(Y,Ce)[F|(CO
 
3
)
 
2
]
12.1.15Synchysite-(Nd)
Ca(Nd,Y,Gd)[F|(CO
 
3
)
 
2
]
12.1.16Röntgenite-(Ce)
Ca
 
2
(Ce,La)
 
3
[F
 
3
|(CO
 
3
)
 
5
]
12.1.17Cordylite-(Ce)
(Na,Ca)BaCe
 
2
(CO
 
3
)
 
4
F
12.1.19Huanghoite-(Ce)
BaCe[F|(CO
 
3
)
 
2
]
12.1.20Zhonghuacerite-(Ce)
Ba
 
2
Ce[F|(CO
 
3
)
 
3
]
12.1.21Cebaite-(Ce)
Ba
 
3
Ce
 
2
[F
 
2
|(CO
 
3
)
 
5
]
12.1.22Thorbastnäsite
Th(Ca,Ce)(CO
 
3
)
 
2
F
 
2
·3H
 
2
O
12.1.23Phosgenite
Pb
 
2
[Cl
 
2
|CO
 
3
]
12.1.24Barstowite
Pb
 
4
[Cl
 
6
|CO
 
3
] · H
 
2
O
12.1.25Albrechtschraufite
Ca
 
4
Mg(UO
 
2
)
 
2
[F
 
2
|(CO
 
3
)
 
6
] · 17 H
 
2
O
12.1.26Kettnerite
(BiO)Ca[F|CO
 
3
]

Other Names for Defernite

Synonyms:
IMA1978-057
German names:
Defernit
Russian names:
Дефернит
Spanish names:
Defernita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Defernite

Reference List:American Mineralogist: 65: 1066.

Schweizerische mineralogische und petrographische Mitteilungen: 65: 153-158.

American Mineralogist: 73: 888-893.

Internet Links for Defernite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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  • Defernite details from Handbook of Mineralogy (PDF)
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    Localities for Defernite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Namibia
     
    • Otjozondjupa Region
      • Grootfontein District
        • Kombat
    Mineralogical Record: 22: 421.
    Turkey
     
    • Black Sea Region
      • Rize Province
    Bull.Soc.fr.Min.Crist.(1980) 103, 185-189
    Mineral and/or Locality
    Google
     
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