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Earlandite

Formula:
Ca
 
3
[CH
 
2
(COO)-CHOH(COO)-CH
 
2
(COO)]
 
2
· 4H
 
2
O
System:MonoclinicColour:White, pale yellow
Name:For Arthur Earland (1866-1958), British oceanographer.


Chemically identical to calcium citrate tetrahydrate - a citric acid salt.

Occurs in unconsolidated ocean floor sediment at 2,580 meters in depth.

Classification of Earlandite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:9/A.02-30
Nickel-Strunz 10th (pending) edition ID:10.AC.10

10 : ORGANIC COMPOUNDS
A : Salts of organic acids
C : Benzine Salts
Dana 8th edition ID:50.2.2.1

50 : ORGANIC COMPOUNDS
2 : Mellitates, Citrates, Cyanates, Acetates and Formates
Hey's CIM Ref.:31.2.1

31 : Oxalates, Citrates, Mellitates and Acetates
2 : Citrates
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Type Occurrence of Earlandite

Type Locality:71°22'S; 16°34'W, Weddell Sea, Western Antarctica, Antarctica
General Appearance of Type Material:Warty,fine-grained nodules.
Place of Conservation of Type Material:The Natural History Museum, London, England: #1936,978, 1936,979. Harvard University, Cambridge, Massachusetts, USA: #134573.U.S. National Museum of Natural History, Washington, D.C., USA: #105859, 162618.
Year of Discovery:1936
Geological Setting of type material:Unconsolidated ocean sediments.
Associated Minerals at type locality:
Quartz

Physical Properties of Earlandite

Diaphaneity (Transparency):Translucent
Colour:White, pale yellow
Comment:Hardness not determined.
Density (measured):1.80 - 1.95 g/cm3
Density (calculated):1.96 g/cm3

Crystallography of Earlandite

Crystal System:Monoclinic
Cell Parameters:a = 30.94Å, b = 5.93Å, c = 10.56Å
β = 93.74°
Ratio:a:b:c = 5.218 : 1 : 1.781
Unit Cell Volume:V 1,933.36 ų (Calculated from Unit Cell)
Z:4
Morphology:Veruginous, fine-grained nodules.
Comment:Crystal System determination based on observations on synthetic material. Class and Space Group not determined.

Optical Data of Earlandite

Type:Biaxial (+)
RI values: nα = 1.515 nβ = 1.530 nγ = 1.580
2V:Measured: 60° , Calculated: 50°
Maximum Birefringence:δ = 0.065

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low
Dispersion:r > v

Chemical Properties of Earlandite

Formula:
Ca
 
3
[CH
 
2
(COO)-CHOH(COO)-CH
 
2
(COO)]
 
2
· 4H
 
2
O
Essential elements:C, Ca, H, O
All elements listed in formula:C, Ca, H, O

Relationship of Earlandite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
10.AC.05Mellite
Al
 
2
[C
 
6
(COO)
 
6
] · 16H
 
2
O
10.AC.05Pigotite
Al
 
4
C
 
6
H
 
5
O
 
10
·13H
 
2
O (?)

Other Names for Earlandite

Other Languages:
German:Earlandit
Spanish:Earlandita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Earlandite

Reference List:Bannister (1936) Discovery Reports: 13: 67.

American Mineralogist (1937): 22: 71.

Palache, Charles, Harry Berman & Clifford Frondel (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 1105–1106.

Pogainis, E.M. and E.H. Shaw (1957) The unit cell dimensions of tricalcium citrate tetrahydrate. Proc. South Dakota Academy of Science, 36, 56–59.

Articles/Blogs about Earlandite

Internet Links for Earlandite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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    Localities for Earlandite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Antarctica
     
    • Western Antarctica
      • Weddell Sea
    Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1106.
    Mineral and/or Locality
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