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Enstatite

Formula:
Mg
 
2
[SiO
 
3
]
 
2
System:OrthorhombicColour:White, yellowish green, ...
Lustre:Vitreous, PearlyHardness:5 - 6
Name:From the Greek enstates - "opponent" for refractory nature under blowpipe flame.
Dimorph of:Clinoenstatite


Enstatite Group. Enstatite-Ferrosilite Series.

Classification of Enstatite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:8/F.02-10
Nickel-Strunz 10th (pending) edition ID:9.DA.05

9 : SILICATES (Germanates)
D : Inosilicates
A : Inosilicates with 2-periodic single chains, Si2O6; pyroxene family
Dana 8th edition ID:65.1.2.1

65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
1 : Single-Width Unbranched Chains, W=1 with chains P=2
Hey's CIM Ref.:14.4.2

14 : Silicates not Containing Aluminum
4 : Silicates of Mg
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Occurrences of Enstatite

Geological Setting:Magmatic mafic rocks

Physical Properties of Enstatite

Lustre:Vitreous, Pearly
Diaphaneity (Transparency):Translucent, Opaque
Comment:Pearly on cleavage
Colour:White, yellowish green, brown, greenish white or grey, olive-green
Streak:Grey to white
Hardness (Mohs):5 - 6
Tenacity:Brittle
Cleavage:Distinct/Good
Good on {210}
Parting:on {100} and {010}
Fracture:Irregular/Uneven
Density (measured):3.2 - 3.9 g/cm3
Density (calculated):3.189 g/cm3

Crystallography of Enstatite

Crystal System:Orthorhombic
Class (H-M):mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:Pbca (P21/b 21/c 21/a)
Cell Parameters:a = 18.23Å, b = 8.84Å, c = 5.19Å
Ratio:a:b:c = 2.062 : 1 : 0.587
Unit Cell Volume:V 836.39 ų (Calculated from Unit Cell)
Z:8
Morphology:Prismatic crystals
Twinning:Simple and lamellar on {100}
Crystal Atlas:
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Enstatite no.12 - Goldschmidt (1913-1926)
Enstatite no.67 - Goldschmidt (1913-1926)

About Crystal Atlas

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X-Ray Powder Diffraction:
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Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data: Peaks:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Enstatite

Type:Biaxial (+)
RI values: nα = 1.650 - 1.668 nβ = 1.652 - 1.673 nγ = 1.659 - 1.679
2V:Measured: 54° to 90°, Calculated: 58° to 86°
Maximum Birefringence:δ = 0.009 - 0.011

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r < v weak

Chemical Properties of Enstatite

Formula:
Mg
 
2
[SiO
 
3
]
 
2
Essential elements:Mg, O, Si
All elements listed in formula:Mg, O, Si
Common Impurities:Fe,Ca,Al,Co,Ni,Mn,Ti,Cr,Na,K

Relationship of Enstatite to other Species

Series:Forms a series with Ferrosilite (see here)
Related Minerals - Nickel-Strunz Grouping):
9.DA.05Donpeacorite
(Mn
2+
 
,Mg)Mg[SiO
 
3
]
 
2
9.DA.05Ferrosilite
Fe
 
2
[SiO
 
3
]
 
2
9.DA.05Akimotoite
(Mg,Fe
2+
 
)SiO
 
3
9.DA.10Clinoenstatite
Mg
 
2
[Si
 
2
O
 
6
]
9.DA.10Clinoferrosilite
Fe
2+
 
(Fe
2+
 
,Mg)[Si
 
2
O
 
6
]
9.DA.10Kanoite
Mn
2+
 
(Mg,Mn
2+
 
)[Si
 
2
O
 
6
]
9.DA.10Pigeonite
(Mg,Fe
2+
 
,Ca)(Mg,Fe
2+
 
)[Si
 
2
O
 
6
]
9.DA.15Augite
(Ca,Na)(Mg,Fe
2+
 
,Al,Fe
3+
 
,Ti)[(Si,Al)
 
2
O
 
6
]
9.DA.15Diopside
CaMg[Si
 
2
O
 
6
]
9.DA.15Esseneite
CaFe
3+
 
[AlSiO
 
6
]
9.DA.15Hedenbergite
CaFe
2+
 
[Si
 
2
O
 
6
]
9.DA.15Johannsenite
CaMn
2+
 
[Si
 
2
O
 
6
]
9.DA.15Petedunnite
Ca(Zn,Mn
2+
 
,Mg,Fe
2+
 
)[Si
 
2
O
 
6
]
9.DA.20Aegirine-augite
(Na,Ca)(Fe,Fe,Mg,Al)Si
 
2
O
 
6
9.DA.20Omphacite
(Ca,Na)(Mg,Al)[Si
 
2
O
 
6
]
9.DA.25Aegirine
NaFe
3+
 
[Si
 
2
O
 
6
]
9.DA.25Jadeite
Na(Al,Fe
3+
 
)[Si
 
2
O
 
6
]
9.DA.25Jervisite
(Na,Ca,Fe
2+
 
)(Sc,Mg,Fe
2+
 
)[Si
 
2
O
 
6
]
9.DA.25Kosmochlor
NaCr[Si
 
2
O
 
6
]
9.DA.25Namansilite
NaMn
3+
 
[Si
 
2
O
 
6
]
9.DA.25Natalyite
Na(V
3+
 
,Cr)[Si
 
2
O
 
6
]
9.DA.30Spodumene
LiAl[Si
 
2
O
 
6
]
Related Minerals - Hey's Index Grouping:
14.4.1Forsterite
Mg
 
2
[SiO
 
4
]
14.4.3Clinoenstatite
Mg
 
2
[Si
 
2
O
 
6
]
14.4.4Chrysotile
Mg
 
3
Si
 
2
O
 
5
(OH)
 
4
14.4.5Clinochrysotile
14.4.6Orthochrysotile
14.4.7Parachrysotile
14.4.8Lizardite
Mg
 
3
[(OH)
 
4
|Si
 
2
O
 
5
]
14.4.9Talc
Mg
 
3
Si
 
4
O
 
10
(OH)
 
2
14.4.10Spadaite
MgSiO
 
2
(OH)
 
2
·H
 
2
O
14.4.11Sepiolite
Mg
 
4
Si
 
6
O
 
15
(OH)
 
2
·6H
 
2
O
14.4.12Loughlinite
Na
 
2
Mg
 
3
Si
 
6
O
 
16
·8H
 
2
O
14.4.13Eifelite
KNa
 
3
Mg
 
4
Si
 
12
O
 
30
14.4.14Stevensite
(Ca,Na)
 
x
Mg
 
3
Si
 
4
O
 
10
(OH)
 
2
14.4.15Antigorite
(Mg,Fe
2+
 
)
 
3
[(OH)
 
4
|Si
 
2
O
 
5
]
14.4.16 Magnesio-anthophyllite

Other Names for Enstatite

Synonyms:
AmblystegiteChladniteEnstaditeFiciniteO-enstatite
OrthobronziteOrthoenstatitePaulitePeckhamiteProtobastite
SheparditeShepardite (of Rose)Victorite
German names:
AmblystegitChladnitCladnitEnstaditEnstatit
FicinitO-enstatitOrthobronzitOrthoenstatitPaulit
PeckhamitProtobastitSheparditVictorit
Russian names:
Энстатит
Spanish names:
AmblystegitaChladnitaEnstaditaEnstatitaFicinita
OrthobronzitaOrthoenstatitaPaulitaPeckhamitaProtobastita
SheparditaVictorita
Varieties:
BronziteLime-BronziteVanadinbronzite

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Enstatite

Reference List:Morimoto, N. and Koto, K. (1969) The crystal structure of orthoenstatite. Zeitschrift für Kristallographie: 129: 65-83.

Anastasiou, P. and Seifert, F. (1972) Solid solubility of Al2O3 in enstatite at high temperatures and 1-5 kb water pressure. Contributions to Mineralogy and Petrology: 34: 272-287.

Arima, M. and Onuma, K. (1977) The solubility of alumina in enstatite and the phase equilibria in the join MgSiO3-MgAl2SiO6 at 10-25 kbar. Contributions to Mineralogy and Petrology: 61: 251-265.

Hawthorne, F.C., and Ito, J. (1977) Synthesis and crystal structure refinement of transition-metal orthopyroxenes. I: orthoenstatite and (Mg,Mn,Co) orthopyroxene. Canadian Mineralogist: 15: 321-338.

Weidner, D.J., Wang, H., and Ito, J. (1978) Elasticity of orthoenstatite. Physics of the Earth and Planetary Interiors 17: 7-13.

Ralph, R.L. and Ghose, S. (1980) Enstatite, Mg2Si2O6: compressibility and crystal structure at 21 kbar (abs.). Eos: 61: 409.

Ohashi, Y. (1984) Polysynthetically-twinned structures of enstatite and wollastonite. Physics and Chemistry of Minerals: 10: 217-229.

Zeitschrift für Kristallographie (1986): 176: 159.

Duffy, T.S. and Vaughan, M.T. (1988) Elasticity of enstatite and its relationship to crystal structure. Journal of Geophysical Research: 93: 383-391.

Angel, R.J. and Hugh-Jones, D.A. (1994) Equation of state and thermodynamic properties of enstatite pyroxenes. Journal of Geophysical Research: 99: 19777-19783.

Hugh-Jones, D.A. and Angel, R.J. (1994) A compressional study of MgSiO3 orthoenstatite up to 8.5 GPa. American Mineralogist: 79: 405-410.

Yang, H. and Ghose, S. (1994) High-temperature single-crystal X-ray diffraction studies of the ortho-proto phase transition in enstatite, Mg2Si2O6 at 1360 K. Physics and Chemistry of Minerals: 22: 300-310.

Zhao, Y., Schiferl, D., and Shankland, T.J. (1995) A high P-T single-crystal X-ray diffraction study of thermoelasticity of MgSiO3 orthoenstatite. Pysics and Chemistry of Minerals: 22: 393-398.

Flesch, L.M., Li., B., and Liebermann, R.C. (1998) Sound velocities of polycrystalline MgSiO3-orthopyroxene to 10 GPa at room temperature. American Mineralogist: 83: 444-450.

Jackson, J.M., Sinogeikin, S.V., and Bass, J.D. (1999) Elasticity of MgSiO3 orthoenstatite. American Mineralogist: 84: 677-680.

Jackson, J.M., Palko, J., Sinogeikin, S.V., Bass, J.D., Andrault, D., and Zha, C. (2001) High-temperature single-crystal elasticity and thermal exansion of orthoenstatite. Eos (Fall Meeting Supplement), Abstract T31C-0853.

Angel, R.J. and Jackson, M.J. (2002) Elasticity and equation of state of orthoenstatite, MgSiO3. American Mineralogist: 87: 558-561.

Tarantino, S.C., Domeneghetti, M.C., Carpenter, M.A., Shaw, C.J.S., and Tazzoli, V. (2002a) Mixing properties of the enstatite-ferrosilite solid solution: I. A macroscopic perspective. European Journal of Mineralogy: 14: 525-536.

Tarantino, S.C., Boffa Ballaran, T., Carpenter, M.A., Domeneghetti, M.C., and Tazzoli, V. (2002b) Mixing properties of the enstatite-ferrosilite solid solution: II A microscopic perspective. Eurpean Journal of Mineralogy: 14: 537-547.

Lin, C.C. (2003) Pressure-induced metastable phase transition in orthoenstatite (MgSiO3) at room temperature: a Raman spectroscopic study. Journal of Solid State Chemistry: 174: 403-411.

Jackson, J.M., Sinogeikin, S.V., Carpenter, M.A., and Bass, J.D. (2004) Novel phase transition in orthoenstatite. American Mineralogist: 89: 239-245.

Kung, J., Li, B.S., Uchida, T., Wang, Y.B., Neuville, D., and Liebermann, R.C. (2004) In situ measurements of sound velocities and densities across the orthopyroxene - high-pressure clinopyroxene transition in MgSiO3 at high-pressure. Physics of the Earth and Planetary Interiors: 147: 27-44.

Nestola, F., Gatta, G.D., and Ballaran, T.B. (2006) The effect of Ca substitution on the elastic and structural behavior of orthoenstatite. American MIneralogist: 91: 809-815.

Internet Links for Enstatite

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    Localities for Enstatite

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