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Ferrisicklerite

Big Photo

Palermo No. 1 Mine (Palermo #1 pegmatite), Groton, Grafton Co., New Hampshire, USA
© 2007 Peter Cristofono

Show Ferrisicklerite Photos (3)
Formula:
(Fe
3+
 
,LiMn
2+
 
)[PO
 
4
]
System:OrthorhombicColour:Yellow-brown to dark ...
Hardness:4
Name:From FERRI- for trivalent iron (ferric iron) and Sicklerite in allusion to its composition as the ferric iron end member of the series with sicklerite.


Ferrisicklerite-Sicklerite Series

Occurs only as an alteration product of Triphylite and Lithiophilite, commonly as rims around partly altered masses or crystals of the latter species.

Classification of Ferrisicklerite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/A.02-30
Nickel-Strunz 10th (pending) edition ID:8.AB.10

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
B : With medium-sized cations
Dana 7th edition ID:38.1.4.1
Dana 8th edition ID:38.1.4.1

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
1 : ABXO4
Hey's CIM Ref.:19.1.12

19 : Phosphates
1 : Phosphates of the alkali metals
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Type Occurrence of Ferrisicklerite

Type Locality:Sidi Bou Othmane, El Kelaâ des Sraghna Province, Marrakech-Tensift-El Haouz Region, Morocco
Year of Discovery:1937

Physical Properties of Ferrisicklerite

Diaphaneity (Transparency):Opaque
Colour:Yellow-brown to dark brown
Streak:Light yellow-brown, brown, reddish brown
Hardness (Mohs):4
Cleavage:Distinct/Good
On {100}, good.
Density (measured):3.2 - 3.4 g/cm3

Crystallography of Ferrisicklerite

Crystal System:Orthorhombic
Cell Parameters:a = 5.91Å, b = 10.02Å, c = 4.79Å
Ratio:a:b:c = 0.59 : 1 : 0.478
Unit Cell Volume:V 283.66 ų (Calculated from Unit Cell)
Morphology:Massive.

Optical Data of Ferrisicklerite

Type:Biaxial (-)
RI values: nα = 1.790 nβ = 1.805 nγ = 1.820
2V:Measured: 85° , Calculated: 88°
Maximum Birefringence:δ = 0.030

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:single; r > v, very strong.
Pleochroism:Visible
Comments:X = a = Dark reddish
Y = Lighter reddish
Z = Very light reddish

Chemical Properties of Ferrisicklerite

Formula:
(Fe
3+
 
,LiMn
2+
 
)[PO
 
4
]
Essential elements:Fe, O, P
All elements listed in formula:Fe, Li, Mn, O, P

Relationship of Ferrisicklerite to other Species

Series:Forms a series with Sicklerite (see here)
Related Minerals - Nickel-Strunz Grouping):

- +
8.AB.05Farringtonite
Mg
 
3
[PO
 
4
]
 
2
8.AB.10Heterosite
(Fe
3+
 
,Mn
3+
 
)[PO
 
4
]
8.AB.10Lithiophilite
LiMn
2+
 
[PO
 
4
]
8.AB.10Natrophilite
NaMn
2+
 
[PO
 
4
]
8.AB.10Purpurite
(Mn
3+
 
,Fe
3+
 
)[PO
 
4
]
8.AB.10Sicklerite
(LiMn
2+
 
,Fe
3+
 
)[PO
 
4
]
8.AB.10Simferite
Li(Mg,Fe
3+
 
,Mn
3+
 
)
 
2
[PO
 
4
]
 
2
8.AB.10Triphylite
LiFe
2+
 
[PO
 
4
]
8.AB.15Sarcopside
(Fe
2+
 
,Mn
2+
 
,Mg)
 
3
[PO
 
4
]
 
2
8.AB.15Chopinite
(Mg,Fe
2+
 
)
 
3
[PO
 
4
]
 
2
8.AB.20Beusite
(Mn
2+
 
,Fe
2+
 
,Ca,Mg)
 
3
[PO
 
4
]
 
2
8.AB.20Graftonite
(Fe
2+
 
,Mn
2+
 
,Ca)
 
3
[PO
 
4
]
 
2
8.AB.25Xanthiosite
Ni
 
3
[AsO
 
4
]
 
2
8.AB.30Lammerite
Cu
 
3
[AsO
 
4
]
 
2
8.AB.30IMA2009-002
Cu
 
3
(AsO
 
4
)
 
2
8.AB.35Mcbirneyite
Cu
 
3
(VO
 
4
)
 
2
8.AB.35Stranskiite
(Zn,Cu)
 
3
[AsO
 
4
]
 
2
8.AB.40Lyonsite
Cu
 
3
Fe
 
4
(VO
 
4
)
 
6
Related Minerals - Hey's Index Grouping:

- +
19.1.1Lithiophosphate
Li
 
3
[PO
 
4
]
19.1.2Olympite
Na
 
5
Li[PO
 
4
]
 
2
19.1.3Nahpoite
Na
 
2
HPO
 
4
19.1.4Dorfmanite
Na
 
2
(PO
 
3
OH)·2H
 
2
O
19.1.5Nalipoite
NaLi
 
2
[PO
 
4
]
19.1.6Stercorite
NaNH
 
4
HPO
 
4
·4H
 
2
O
19.1.7Archerite
(K,NH
 
4
)[H
 
2
PO
 
4
]
19.1.8Biphosphammite
(NH
 
4
,K)H
 
2
PO
 
4
19.1.9Phosphammite
(NH
 
4
)
 
2
HPO
 
4
19.1.10Lithiophilite
LiMn
2+
 
[PO
 
4
]
19.1.11Sicklerite
(LiMn
2+
 
,Fe
3+
 
)[PO
 
4
]
19.1.13Triphylite
LiFe
2+
 
[PO
 
4
]
19.1.14Tavorite
LiFe
3+
 
[OH|PO
 
4
]
19.1.15Marićite
NaFe
2+
 
[PO
 
4
]
Related Minerals - Dana Grouping):

- +
38.1.4.2Sicklerite
(LiMn
2+
 
,Fe
3+
 
)[PO
 
4
]
38.1.4.3Simferite
Li(Mg,Fe
3+
 
,Mn
3+
 
)
 
2
[PO
 
4
]
 
2

Other Names for Ferrisicklerite

Synonyms:
Fe-sicklerite
Other Languages:
German:Ferrisicklerit
Fe-sicklerit
Pseudoheterosit
Russian:Феррисиклерит
Spanish:Ferrisicklerita
Pseudoheterosita

Other Information

Other Information:Soluble in acids.

Alters to the Heterosite-Purpurite Series by oxidation of the Mn'' and leaching of the Li.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ferrisicklerite

Reference List:Quensel (1937) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 59: 77.

Björling and Westgren (1938) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 60: 67.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 672.

American Mineralogist (1937): 22: 875.

American Mineralogist (1941): 26: 681.

Acta Crystallographica: B32: 2761-2764.

Internet Links for Ferrisicklerite

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  • Raman and XRD data at RRUFF project
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    Localities for Ferrisicklerite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Argentina
     
    • San Luis
      • Coronel Pringles Department
        • La Florida
    		No reference listed
    Austria
     
    • Carinthia
      • Koralpe Mts
        • Moschkogel Mt. - Weinebene area
          • Brandrücken
    		G. Niedermayr, I. Praetzel: Mineralien Kärntens, 1995
    Brazil
     
    • Northeast Region
      • Paraíba
        • Borborema mineral province
          • Frei Martinho
    		Mineralogical Record: 22: 183.
    • Southeast Region
      • Minas Gerais
        • Doce valley
          • Divino das Laranjeiras
            • Linópolis
    		Cassedanne, J.P. (1983): Famous mineral localities: The Córrego Frio mine and vicinity, Minas Gerais, Brazil. Mineralogical Record, 14 (4): 227-237 [ p.233-4]
          • Galiléia
            • Sapucaia do Norte
    		Cassedanne, J.P. & Baptista, A. (1999): Famous Mineral Localities: The Sapucaia Pegmatite Minas Gerais, Brazil. Mineralogical Record, 30: 347-360 + 365
    Canada
     
    • Manitoba
      • Lac-du-Bonnet area
        • Bernic Lake
    		Econ Geol (1995) 90:658-675
    China
     
    • Fujian Province
      • Nanping Prefecture
        • Zhenghe Co.
    		Huan Hu, Rucheng Wang, Fontan, F., Aicheng Zhang, and Jiadeng Chen (2007): Presented at the International Symposium: Granitic Pegmatites: The State of the Art, May 06–12, 2007, Porto, Portugal.
    • Xinjiang (Xinjiang-Uygur) Autonomous Region
      • Yili Hasake (Ili Kazakh) Autonomous Prefecture
    		Zhiguo Liu, Dawei Dong, Milan Liu,Yu Sui, Wenhui Su, Zhengnan Qian, and Zhe Li (2005): Hyperfine Interactions 163(1-4), 13-27.
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Central Bohemia Region
        • Kutná Hora (Kuttenberg)
    		Povondra, P., Pivec, E. (eds.) et al.: Přibyslavice peraluminuous granite. Acta universitatis carolinae, Geologica, 1987, no. 3, s . 183 – 283.
    Finland
     
    • Etelä-Suomen Lääni
      • Orivesi
        • Eräjärvi area
    		No reference listed
    Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II:
    France
     
    • Languedoc-Roussillon
      • Pyrénées-Orientales
    		P. Keller, F. Fontan, F. Velasco Roldan, J.C. Melgarejo i Draper : "Stanekite a new Phosphate Mineral in Pegmatites at Karibib (Namibia) and French Pyrénées (France)", European Journal of Mineralogy, 1977, 9, 475-482
    • Midi-Pyrénées
      • Ariège
        • Auzat
    		Inventaire Minéralogique de la France Ariège T.2 éditions BRGM
        • Le Bosc
          • Cirque de Pénitence
    		Inventaire mineralogique de l\'Ariege (Editions BRGM 1984)
    Germany
     
    • Bavaria
      • Lower Bavaria
        • Bavarian Forest
          • Zwiesel
            • Rabenstein
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 673; Weiss: "Mineralfundstellen, Deutschland West", Weise (Munich), 1990
      • Upper Palatinate
        • Oberpfälzer Wald
          • Vohenstrauß
            • Waidhaus
              • Hagendorf
    		Mücke, A., Schnorrer-Köhler, G., Haase, J., (1989): Über einige Neufunde (Matulait, Chalkantit, und Jarosit)....., Der Aufschluss, Vol. 40, 295-307
    Wittern: "Mineralfundorte in Deutschland", 2001
    Italy
     
    • Lombardy
      • Sondrio Province
    		Guastoni, A., et al., Mineralogical Magazine 71,579-585(2007)
    Kazakhstan
     
    • Shyghys Qazaqstan Oblysy (Vostochno-Kazakhstanskaya [Eastern-Kazakhstan] Oblast')
      • Kalba Range
        • Belogorskii Town
    		Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Morocco
     
    • Marrakech-Tensift-El Haouz Region
      • El Kelaâ des Sraghna Province
    		Bulletin de Minéralogie 99 (1976), 274
    Namibia
     
    • Erongo Region
      • Karibib District
        • Okatjimukuju farm (Friedrichsfelde farm)
    		P. Keller and O. von Knorring, Eur. J. Mineral. , 1989, 1, pp. 567-593.
    Poland
     
    • Lower Silesia (Dolnośląskie)
      • Sowie Mts
    		Pieczka A., Łobos K., Sachanbiński M. 2004: The first occurence of elbaite in Poland. Mineralogia Polonica, vol. 35, 3-14
      • Świdnica District
    		Pieczka A., Gołębiowska B., Skowroński, A. (2003): Ferrisicklerite and other phosphate minerals from the Lutomia pegmatite (SW Poland, Lower Silesia, Góry Sowie Mts) Book of Abstracts. Int. Symp. on Light Elements in Rock-forming Minerals, Nove Mesto na Morave, Czech Republic, June 20-25 2003, 63-64
    Portugal
     
    • Vila Real District
      • Barroso-Alvão pegmatite field
    		Novák, M. et al. (2009): Ferronigerite with dominant substitution TiSn-1 in muscovite+chlorite aggregate from massive quartz nodule associated with a petalite-rich aplite-pegmatite of the Barroso-Alvão pegmatite field, Northern Portugal. N. Jb. Mineral. Abh. 186, 67-78.
    South Korea
     
    • Jeollabuk-do (Cholla-pukto; Jeonrabugdo)
      • Changsu-gun
        • Kyenae-myon
    		Kinosaki, Y. (1940) Jour. Min. Soc. Korea, 23, 11.
    Spain
     
    • Castile and Leon
      • Salamanca
    		American Mineralogist 89:110-125 (2004)
      • Zamora
    • Catalonia
      • Girona (Gerona)
        • Alt Empordà
          • Cadaqués
    		Bareche, E. (2005) "Els minerals de Catalunya. Segle XX" Ed. Museu Mollfulleda de Mineralogia - Grup Mineralògic Català, 269 p.
    Sweden
     
    • Södermanland
      • Stockholm
        • Haninge
    		Gustafsson, Lars & Otter, Bertil (1991): Mineralförekomster i Stockholmstrakten.Del 2. STEIN 18(4),4-12
    Langhof, J., Jonson, E, Gustafsson, L. & Otter, B. (1998): Utö- en klassisk svensk mineralfyndort. Bergverksmuseets Skrift 14, 29-31
    • Västerbotten
      • Skellefteå
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 673.
    Switzerland
     
    • Ticino (Tessin)
      • Lago Maggiore
        • Brissago
    		Stalder, H. A., Wagner, A., Graeser, S. and Stuker, P. (1998): "Mineralienlexikon der Schweiz", Wepf (Basel), p. 161.
    USA
     
    • Alabama
      • Coosa Co.
    		Rocks & Minerals: 70(5): 320-333.
    • California
    		San Diego Natural History Museum
    • Colorado
      • Larimer Co.
        • Crystal Mountain Pegmatite District (Storm Mountain District)
    		Minerals of Colorado (1997) Eckels, E. B.
    Minerals of Colorado (1997) Eckels, E. B.
    Minerals of Colorado (1997) Eckels, E. B.
          • Storm Mountain
    		Rocks & Minerals: 62: 234.
    • Connecticut
      • Middlesex Co.
        • East Hampton
    		Januzzi, R.E. and Seaman, David M. (1976) Mineral Localities Of Connecticut and Southern New York State and Pegmatite Minerals of the World.
    • Massachusetts
      • Essex Co.
        • Andover
    		Gleba, 1978. Mass. Mineral & Fossil Loc.
        • North Andover
    		Harvard Mineralogical Museum, Ex. Ed Grew collection
    • New Hampshire
      • Grafton Co.
        • Groton
    		Rocks & Min.: 16:208-211.
    Rocks & Min., May 1999.
      • Strafford Co.
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 673.
        • Strafford
          • Parker Mt
    		Dana 7:II:673; Switzer (1938) The Paragenesis of the Center Strafford, New Hampshire Pegmatite. American Mineralogist 23:811
    • North Carolina
      • Cleveland Co.
        • Kings Mountain District
    • South Dakota
      • Custer Co.
        • Custer District
          • Fourmile
    		SDSMT Bull 18 Roberts and Rapp "Mineralogy of the Black Hills"
    Rocks & Minerals: 60: 117-118.
    Rocks & Minerals: 60: 117.
      • Pennington Co.
        • Keystone District
          • Glendale
    		Rocks & Minerals: 60: 116.
    R&M 75:3 pp 156-169
          • Keystone
    		Rocks & Minerals: 67(6): 380-388.
    Am Min 70:9-10 pp 1044-1049
    Mineral and/or Locality
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