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Ferrisicklerite

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Big Photo

Palermo No. 1 Mine (Palermo #1 pegmatite), Groton, Grafton Co., New Hampshire, USA
© 2007 Peter Cristofono

Show Ferrisicklerite Photos (5)



Formula:
Li
 
1-x
(Fe
3+
x
Fe
2+
1-x
)PO
 
4
System:OrthorhombicColour:Yellow-brown to dark ...
Hardness:4
Member of:Triphylite Group
Name:From FERRI- for trivalent iron (ferric iron) and Sicklerite in allusion to its composition as the ferric iron end member of the series with sicklerite.


Ferrisicklerite-Sicklerite Series

Occurs only as an alteration product of Triphylite and Lithiophilite, commonly as rims around partly altered masses or crystals of the latter species.

Classification of Ferrisicklerite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/A.02-30
Nickel-Strunz 10th (pending) edition ID:8.AB.10

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
B : With medium-sized cations
Dana 7th edition ID:38.1.4.1
Dana 8th edition ID:38.1.4.1

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
1 : ABXO4
Hey's CIM Ref.:19.1.12

19 : Phosphates
1 : Phosphates of the alkali metals
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Type Occurrence of Ferrisicklerite

Type Locality:Sidi Bou Othmane, El Kelaâ des Sraghna Province, Marrakech-Tensift-El Haouz Region, Morocco
Year of Discovery:1937

Physical Properties of Ferrisicklerite

Diaphaneity (Transparency):Opaque
Colour:Yellow-brown to dark brown
Streak:Light yellow-brown, brown, reddish brown
Hardness (Mohs):4
Cleavage:Distinct/Good
On {100}, good.
Density (measured):3.2 - 3.4 g/cm3

Crystallography of Ferrisicklerite

Crystal System:Orthorhombic
Cell Parameters:a = 5.91Å, b = 10.02Å, c = 4.79Å
Ratio:a:b:c = 0.59 : 1 : 0.478
Unit Cell Volume:V 283.66 ų (Calculated from Unit Cell)
Morphology:Massive.

Optical Data of Ferrisicklerite

Type:Biaxial (-)
RI values: nα = 1.790 nβ = 1.805 nγ = 1.820
2V:Measured: 85° , Calculated: 88°
Maximum Birefringence:δ = 0.030

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:single; r > v, very strong.
Pleochroism:Visible
Comments:X = a = Dark reddish
Y = Lighter reddish
Z = Very light reddish

Chemical Properties of Ferrisicklerite

Formula:
Li
 
1-x
(Fe
3+
x
Fe
2+
1-x
)PO
 
4
Essential elements:Fe, Li, O, P
All elements listed in formula:Fe, Li, O, P

Relationship of Ferrisicklerite to other Species

Series:Forms a series with Sicklerite (see here)
Member of:Triphylite Group
Other Members of Group:

- +
Karenwebberite
Na(Fe
2+
 
,Mn
2+
 
)PO
 
4
Lithiophilite
LiMn
2+
 
PO
 
4
Natrophilite
NaMn
2+
 
PO
 
4
Sicklerite
Li
 
1-x
(Mn
2+
1-x
Mn
3+
x
)PO
 
4
Triphylite
LiFe
2+
 
PO
 
4
Related Minerals - Nickel-Strunz Grouping):

- +
8.AB.05Farringtonite
Mg
 
3
(PO
 
4
)
 
2
8.AB.10Heterosite
(Fe
3+
 
,Mn
3+
 
)PO
 
4
8.AB.10Lithiophilite
LiMn
2+
 
PO
 
4
8.AB.10Natrophilite
NaMn
2+
 
PO
 
4
8.AB.10Purpurite
(Mn
3+
 
,Fe
3+
 
)PO
 
4
8.AB.10Sicklerite
Li
 
1-x
(Mn
2+
1-x
Mn
3+
x
)PO
 
4
8.AB.10Simferite
Li(Mg,Fe
3+
 
,Mn
3+
 
)
 
2
(PO
 
4
)
 
2
8.AB.10Triphylite
LiFe
2+
 
PO
 
4
8.AB.10Karenwebberite
Na(Fe
2+
 
,Mn
2+
 
)PO
 
4
8.AB.15Sarcopside
(Fe
2+
 
,Mn
2+
 
,Mg)
 
3
(PO
 
4
)
 
2
8.AB.15Chopinite
(Mg,Fe
2+
 
)
 
3
(PO
 
4
)
 
2
8.AB.20Beusite
(Mn
2+
 
,Fe
2+
 
,Ca,Mg)
 
3
(PO
 
4
)
 
2
8.AB.20Graftonite
(Fe
2+
 
,Mn
2+
 
,Ca)
 
3
(PO
 
4
)
 
2
8.AB.25Xanthiosite
Ni
 
3
(AsO
 
4
)
 
2
8.AB.30Lammerite
Cu
 
3
(AsO
 
4
)
 
2
8.AB.30Lammerite-β
Cu
 
3
(AsO
 
4
)
 
2
8.AB.35Mcbirneyite
Cu
 
3
(VO
 
4
)
 
2
8.AB.35Stranskiite
Zn
 
2
Cu(AsO
 
4
)
 
2
8.AB.35Pseudolyonsite
Cu
 
3
(VO
 
4
)
 
2
8.AB.40Lyonsite
Cu
 
3
Fe
 
4
(VO
 
4
)
 
6
Related Minerals - Hey's Index Grouping:

- +
19.1.1Lithiophosphate
Li
 
3
PO
 
4
19.1.2Olympite
Na
 
5
Li(PO
 
4
)
 
2
19.1.3Nahpoite
Na
 
2
HPO
 
4
19.1.4Dorfmanite
Na
 
2
HPO
 
4
 · 2H
 
2
O
19.1.5Nalipoite
NaLi
 
2
PO
 
4
19.1.6Stercorite
Na(NH
 
4
)HPO
 
4
 · 4H
 
2
O
19.1.7Archerite
(K,NH
 
4
)(H
 
2
PO
 
4
)
19.1.8Biphosphammite
(NH
 
4
,K)(H
 
2
PO
 
4
)
19.1.9Phosphammite
(NH
 
4
)
 
2
(HPO
 
4
)
19.1.10Lithiophilite
LiMn
2+
 
PO
 
4
19.1.11Sicklerite
Li
 
1-x
(Mn
2+
1-x
Mn
3+
x
)PO
 
4
19.1.13Triphylite
LiFe
2+
 
PO
 
4
19.1.14Tavorite
LiFe
3+
 
(PO
 
4
)(OH)
19.1.15Marićite
NaFe
2+
 
(PO
 
4
)
Related Minerals - Dana Grouping):

- +
38.1.4.2Sicklerite
Li
 
1-x
(Mn
2+
1-x
Mn
3+
x
)PO
 
4
38.1.4.3Simferite
Li(Mg,Fe
3+
 
,Mn
3+
 
)
 
2
(PO
 
4
)
 
2

Other Names for Ferrisicklerite

Synonyms:
Fe-sicklerite
Other Languages:
German:Ferrisicklerit
Fe-sicklerit
Pseudoheterosit
Russian:Феррисиклерит
Simplified Chinese:铁磷锂锰矿
Spanish:Ferrisicklerita
Pseudoheterosita
Traditional Chinese:鐵磷鋰錳礦

Other Information

Other Information:Soluble in acids.

Alters to the Heterosite-Purpurite Series by oxidation of the Mn'' and leaching of the Li.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ferrisicklerite

Reference List:

- +
Quensel (1937) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 59: 77.

Björling and Westgren (1938) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 60: 67.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 672.

American Mineralogist (1937): 22: 875.

American Mineralogist (1941): 26: 681.

Acta Crystallographica: B32: 2761-2764.

Internet Links for Ferrisicklerite

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    • Localities for Ferrisicklerite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Angola
     
    • Namibe Province
      • Giraul pegmatite field
    		Antonio Olimpio Gonçalves, Joan Carles Melgarejo, Pura Alfonso Abella (2009) SEQUENCE OF CRYSTALLISATION OF PEGMATITES: THE ANGOLA CASE. Estudos Geológicos v. 19 (2), pp 35-39
    Argentina
     
    • San Luis
      • Coronel Pringles Department
        • Totoral pegmatitic field
          • La Florida
    		OYARZABAL, J. and GALLISKI, M.A.. Hureaulite, Mn+25(H2O)4[PO3(OH)]2[PO4]2, from different deposits of the Totoral pegmatitic field, San Luis. Rev. Asoc. Geol. Argent. [online]. 2007, vol.62, n.2, pp. 210-216.
    OYARZABAL, J. and GALLISKI, M.A.. Hureaulite, Mn+25(H2O)4[PO3(OH)]2[PO4]2, from different deposits of the Totoral pegmatitic field, San Luis. Rev. Asoc. Geol. Argent. [online]. 2007, vol.62, n.2, pp. 210-216.
    Australia
     
    • Western Australia
      • Upper Gascoyne Shire
        • Yinnietharra (Yinnietharra Station)
    		Pegmatites of Western Australia; M.I. Jacobson, M.A. Calderwood, B.A. Grguric; Hesperian Press, Perth, WA
    Austria
     
    • Carinthia
      • Koralpe
        • Moschkogel - Weinebene area
          • Brandrücken
    		G. Niedermayr, I. Praetzel: Mineralien Kärntens, 1995
    Brazil
     
    • Minas Gerais
      • Doce valley
        • Divino das Laranjeiras
          • Linópolis
    		Cassedanne, J.P. (1983): Famous mineral localities: The Córrego Frio mine and vicinity, Minas Gerais, Brazil. Mineralogical Record, 14 (4): 227-237 [ p.233-4]
        • Galiléia
          • Sapucaia do Norte
    		Cassedanne, J.P. & Baptista, A. (1999): Famous Mineral Localities: The Sapucaia Pegmatite Minas Gerais, Brazil. Mineralogical Record, 30: 347-360 + 365; Baijot, M., Hatert, F. & Philippo, S. (2012): Mineralogy and geochemistry of phosphates and silicates in the Sapucaia pegmatite, Minas Gerais, Brazil: Genetic implications. Canadian Mineralogist. 50, 1531-1554
    • Paraíba
      • Borborema mineral province
        • Frei Martinho
    		Mineralogical Record: 22: 183.
        • Pedra Lavrada
    		Am Min (1955) 40:55-63
    Canada
     
    • Manitoba
      • Lac-du-Bonnet area
        • Bernic Lake
    		Econ Geol (1995) 90:658-675
    China
     
    • Fujian Province
      • Nanping Prefecture
        • Yanping District
    		Huan Hu, Rucheng Wang, Fontan, F., Aicheng Zhang, and Jiadeng Chen (2007): Presented at the International Symposium: Granitic Pegmatites: The State of the Art, May 06–12, 2007, Porto, Portugal.
    • Xinjiang Autonomous Region
      • Yili Hasake Autonomous Prefecture (Ili Kazakh Autonomous Prefecture)
    		Zhiguo Liu, Dawei Dong, Milan Liu,Yu Sui, Wenhui Su, Zhengnan Qian, and Zhe Li (2005): Hyperfine Interactions 163(1-4), 13-27.
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Central Bohemia Region
        • Kutná Hora (Kuttenberg)
    		Povondra, P., Pivec, E. (eds.) et al.: Přibyslavice peraluminuous granite. Acta universitatis carolinae, Geologica, 1987, no. 3, s . 183 – 283.
    Finland
     
    • Southern Finland Region
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II:
    France
     
    • Languedoc-Roussillon
      • Pyrénées-Orientales
    		P. Keller, F. Fontan, F. Velasco Roldan, J.C. Melgarejo i Draper : "Stanekite a new Phosphate Mineral in Pegmatites at Karibib (Namibia) and French Pyrénées (France)", European Journal of Mineralogy, 1977, 9, 475-482
    • Midi-Pyrénées
      • Ariège
        • Auzat
    		Inventaire Minéralogique de la France Ariège T.2 éditions BRGM
        • Le Bosc
          • Cirque de Pénitence
    		Inventaire mineralogique de l'Ariege (Editions BRGM 1984)
    Germany
     
    • Bavaria
      • Lower Bavaria
        • Bavarian Forest
          • Zwiesel
            • Rabenstein
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 673; Weiss: "Mineralfundstellen, Deutschland West", Weise (Munich), 1990
      • Upper Palatinate
        • Oberpfälzer Wald
          • Vohenstrauß
            • Waidhaus
              • Hagendorf
    		Mücke, A., Schnorrer-Köhler, G., Haase, J., (1989): Über einige Neufunde (Matulait, Chalkantit, und Jarosit)....., Der Aufschluss, Vol. 40, 295-307
    Wittern: "Mineralfundorte in Deutschland", 2001
    Italy
     
    • Lombardy
      • Lecco Province
        • Colico
    		Vignola, P., Fransolet, A.M., Guastoni, A. & Appiani, R. (2011). Le pegmatiti di Piona. Recenti studi sui filoni Malpensata, Luna e Sommafiume. Rivista Mineralogica Italiana, 1/2011, 30-38
        • Vestreno
    		• Vignola, P., Fransolet, A.M., Guastoni, A. & Appiani, R. (2011). Le pegmatiti di Piona. Recenti studi sui filoni Malpensata, Luna e Sommafiume. Rivista Mineralogica Italiana, 1/2011, 30-38.
      • Sondrio Province
        • Bodengo Valley
    		Guastoni, A., et al. (2007): [Title]. Mineralogical Magazine 71,579-585
    Kazakhstan
     
    • Eastern Kazakhstan Province (Shyghys Qazaqstan Oblysy; Vostochno-Kazakhstanskaya Oblast')
      • Kalba Range
        • Belogorskii Town
    		Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Morocco
     
    • Marrakech-Tensift-El Haouz Region
      • El Kelaâ des Sraghna Province
    		Bulletin de Minéralogie 99 (1976), 274
    Favreau, G. (2012): Deux pegmatites à phosphates de Sidi Bou Othmane (Maroc). Le Cahier des Micromonteurs, 3-2012, 71-109
    • Souss-Massa-Draâ Region
      • Ouarzazate Province
        • Tazenakht
    		FRANSOLET, A.-M., ABRAHAM, K. et SPEETJENS, J.-M. (1985) Evolution génétique et signification des associations de phosphates de la pegmatite d'Angarf-Sud, Plaine de Tazenakht, Anti-Atlas, Maroc. Bull. Minéral., 108, 551-574
    Namibia
     
    • Erongo Region
      • Karibib District
        • Okatjimukuju Farm 55 (Friedrichsfelde Farm)
    		P. Keller and O. von Knorring, Eur. J. Mineral. , 1989, 1, pp. 567-593.
        • Tsaobismund Farm 85
    		Contrib Mineral Petrol (1986) 92:502-517
        • Usakos
    		Von Bezing, L., Bode, R., and Jahn, S., (2008) Namibia Minerals and Localities. Edition Schloss Freudenstein, Bode Verlag GmbH, Haltern. 409 (in English).
    • Karas Region
      • Bethanie District
    		Bezing, L. von, Bode, R. & Jahn, S. (2008): Namibia Minerals and Localities. Edition Schloss Freudenstein, Bode Verlag GmbH, Haltern: 393 (in English)
    Poland
     
    • Lower Silesia (Dolnośląskie)
      • Sowie Mts
    		Pieczka A., Łobos K., Sachanbiński M. 2004: The first occurence of elbaite in Poland. Mineralogia Polonica, vol. 35, 3-14
      • Sudetes Mts
        • Sowie Mts.
    		Łodziński M. & Sitarz M. 2008: Chemical and Spectroscopic Characterization of Some Phosphates Accessory Minerals from Pegmatites of the Sowie Mts (Owles Mts), SW Poland. EUCMOS, Spectroscopy Applied to Archaeology, Arts, Geology and Mineralogy, p. 278
      • Świdnica District
    		Pieczka A., Gołębiowska B., Skowroński, A. (2003): Ferrisicklerite and other phosphate minerals from the Lutomia pegmatite (SW Poland, Lower Silesia, Góry Sowie Mts) Book of Abstracts. Int. Symp. on Light Elements in Rock-forming Minerals, Nove Mesto na Morave, Czech Republic, June 20-25 2003, 63-64
    Portugal
     
    • Vila Real District
    		Martins, T., Lima, A., Simmons, W.B. Falster, A.U. & Noronha, F. (2011): Geochemical fractionation of Nb-Ta oxides in Li-bearing pegmatites from the Barroso-Alvão pegmatite field, Northern Portugal. Canadian Mineralogist. 49, 777-791
    Novák, M. et al. (2009): Ferronigerite with dominant substitution TiSn-1 in muscovite+chlorite aggregate from massive quartz nodule associated with a petalite-rich aplite-pegmatite of the Barroso-Alvão pegmatite field, Northern Portugal. N. Jb. Mineral. Abh. 186, 67-78.
    Rwanda
     
    • Southern Province
      • Gitarama
    		Royal Museum for Central Africa, Belgium Collection, # 9914
    • Western Province
      • Gatumba District
    		Bertossa, A., 1967. Inventaire des minéraux du Rwanda. Bulletin du Service Géologique de Rwanda 4, 25-45.; Daltry, V.D.C. and O. von Knorring (1998) Type-Mineralogy of Rwanda with Particular Reference to the Buranga Pegmatite. Geologica Belgica 1:1-9
    South Korea
     
    • Jeollabuk-do (Cholla-pukto; Jeonrabugdo)
      • Changsu-gun
        • Kyenae-myon
    		Kinosaki, Y. (1940) Jour. Min. Soc. Korea, 23, 11.
    Spain
     
    • Castile and Leon
      • Salamanca
        • Garcirrey
    		American Mineralogist 89:110-125 (2004); Encarnación Roda-Robles, Alfonso Pesquera (2007) Locality no. 4: The Phosphates-Rich Cañada Pegmatite (Aldehuela de La Bóveda, Salamanca, Spain) in ALEXANDRE LIMA & ENCARNACIÓN RODA ROBLES ed (2007) GRANITIC PEGMATITES: THE STATE OF THE ART - FIELD TRIP GUIDEBOOK. MEMÓRIAS N. º 9, UNIV. DO PORTO, FACULDADE DE CIÊNCIAS, DEPARTAMENTO DE GEOLOGIA pp 67-72.
    Encarnación Roda-Robles, Alfonso Pesquera (2007) Locality no. 3: Lepidolite-spodumene-rich and cassiterite-rich pegmatites from the Feli open-pit, (La Fregeneda, Salamanca, Spain) in ALEXANDRE LIMA & ENCARNACIÓN RODA ROBLES ed (2007) GRANITIC PEGMATITES: THE STATE OF THE ART - FIELD TRIP GUIDEBOOK. MEMÓRIAS N. º 9, UNIV. DO PORTO, FACULDADE DE CIÊNCIAS, DEPARTAMENTO DE GEOLOGIA pp 55-64
      • Zamora
        • Villar del Buey
          • Pinilla de Fermoselle
    • Catalonia
      • Girona (Gerona)
        • Alt Empordà
          • Cadaqués
    		Bareche, E. (2005) "Els minerals de Catalunya. Segle XX" Ed. Museu Mollfulleda de Mineralogia - Grup Mineralògic Català, 269 p.
    Sweden
     
    • Södermanland
      • Norrö
    		Gustafsson, Lars & Otter, Bertil (1991): Mineralförekomster i Stockholmstrakten.Del 2. STEIN 18(4),4-12
      • Utö
    		Langhof, J., Jonson, E, Gustafsson, L. & Otter, B. (1998): Utö- en klassisk svensk mineralfyndort. Bergverksmuseets Skrift 14, 29-31
    • Västerbotten
      • Skellefteå
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 673.
    Switzerland
     
    • Ticino (Tessin)
      • Lago Maggiore
        • Brissago
    		Stalder, H. A., Wagner, A., Graeser, S. and Stuker, P. (1998): "Mineralienlexikon der Schweiz", Wepf (Basel), p. 161.
    USA
     
    • Alabama
      • Coosa Co.
    		Rocks & Minerals: 70(5): 320-333.
    • California
    		San Diego Natural History Museum
    • Colorado
      • Larimer Co.
        • Crystal Mountain Pegmatite District (Storm Mountain District)
    		Minerals of Colorado (1997) Eckels, E. B.
    Minerals of Colorado (1997) Eckels, E. B.
    Minerals of Colorado (1997) Eckels, E. B.
          • Storm Mountain
    		Rocks & Minerals: 62: 234.
    • Connecticut
      • Middlesex Co.
        • East Hampton
    		Schooner (1958)
    • Maine
      • Oxford Co.
        • Newry
    		GUIDEBOOK 1 Mineral Collecting in the Maine Pegmatite Belt Prepared by members of Maine Federation Club 1972 pg 20-21
    • Massachusetts
      • Essex Co.
        • Andover
    		Gleba, 1978. Mass. Mineral & Fossil Loc.
        • North Andover
    		Harvard Mineralogical Museum, Ex. Ed Grew collection
    • New Hampshire
      • Cheshire Co.
        • Walpole
    		Tom Mortimer, http://mindatnh.org
      • Grafton Co.
        • Groton
    		Rocks & Min.: 16:208-211.; USGS Prof Paper 255; USGS Prof Paper 353; NIZAMOFF, James W., SIMMONS, William B., and FALSTER, Alexander U. (2004) PHOSPHATE MINERALOGY AND PARAGENESIS OF THE PALERMO #2 PEGMATITE, NORTH GROTON, NEW HAMPSHIRE Geological Society of America Abstracts with Programs, Vol. 36, No. 5, p. 115
    Rocks & Min., May 1999.; Geological Society of America Abstracts with Programs, Vol. 36, No. 5, p. 115
      • Strafford Co.
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 673.
        • Strafford
          • Parker Mountain
    		Dana 7:II:673; Switzer (1938) The Paragenesis of the Center Strafford, New Hampshire Pegmatite. American Mineralogist 23:811 ; Rocks & Minerals 80:4 pp234-241
    • North Carolina
      • Cleveland Co.
        • Kings Mountain District
    		Rocks and Minerals, (1985) 60:76-82
    • South Dakota
      • Custer Co.
        • Custer District
          • Fourmile
    		SDSMT Bull 18 Roberts and Rapp "Mineralogy of the Black Hills"
    Rocks & Minerals: 60: 117-118.
    Rocks & Minerals: 60: 117.
      • Pennington Co.
        • Keystone District
          • Glendale
    		Rocks & Minerals: 60: 116.
    R&M 75:3 pp 156-169
          • Keystone
    		Rocks & Minerals: 67(6): 380-388.
    Am Min 70:9-10 pp 1044-1049
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