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Ferrobustamite

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Formula:
Ca(Fe
2+
 
,Ca,Mn
2+
 
)(Si
 
2
O
 
6
)
System:TriclinicHardness:6
Member of:Wollastonite Group


Wollastonite Group.

The Fe analogue of bustamite.

Classification of Ferrobustamite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:8/F.18-30
Nickel-Strunz 10th (pending) edition ID:9.DG.05

9 : SILICATES (Germanates)
D : Inosilicates
G : Inosilicates with 3-periodic single and multiple chains
Dana 8th edition ID:65.2.1.3

65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
2 : Single-Width Unbranched Chains, W=1 with chains P=3
Hey's CIM Ref.:14.18.17

14 : Silicates not Containing Aluminum
18 : Silicates of Mn and Na, K, Mg, Ca or Fe
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Type Occurrence of Ferrobustamite

Type Locality:Camas Malag, Torrin, Broadford, Isle of Skye, North West Highlands (Inverness-shire), Scotland, UK
Year of Discovery:1973

Physical Properties of Ferrobustamite

Hardness (Mohs):6

Crystallography of Ferrobustamite

Crystal System:Triclinic
Cell Parameters:a = 7.86Å, b = 7.25Å, c = 13.96Å
α = 89.73°, β = 95.47°, γ = 103.48°
Ratio:a:b:c = 1.084 : 1 : 1.926
Unit Cell Volume:V 769.95 ų (Calculated from Unit Cell)

Optical Data of Ferrobustamite

Type:Biaxial (-)
RI values: nα = 1.640 nγ = 1.653
2V:Measured: 60°
Maximum Birefringence:δ = 0.013

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:relatively weak

Chemical Properties of Ferrobustamite

Formula:
Ca(Fe
2+
 
,Ca,Mn
2+
 
)(Si
 
2
O
 
6
)
Essential elements:Ca, Fe, O, Si
All elements listed in formula:Ca, Fe, Mn, O, Si
Common Impurities:Ti,Mg

Relationship of Ferrobustamite to other Species

Member of:Wollastonite Group
Other Members of Group:

- +
Bustamite
CaMn
2+
 
(Si
 
2
O
 
6
)
Pectolite
NaCa
 
2
(HSi
 
3
O
 
9
)
Sérandite
Na(Mn
2+
 
,Ca)
 
2
(HSi
 
3
O
 
9
)
Tanohataite
LiMn
 
2
(HSi
 
3
O
 
9
)
Wollastonite
CaSiO
 
3
Related Minerals - Nickel-Strunz Grouping):

- +
9.DG.05Bustamite
CaMn
2+
 
(Si
 
2
O
 
6
)
9.DG.05Pectolite
NaCa
 
2
(HSi
 
3
O
 
9
)
9.DG.05Sérandite
Na(Mn
2+
 
,Ca)
 
2
(HSi
 
3
O
 
9
)
9.DG.05Wollastonite
CaSiO
 
3
9.DG.05Wollastonite-1A
CaSiO
 
3
9.DG.07Cascandite
Ca(Sc,Fe
3+
 
)(HSi
 
3
O
 
9
)
9.DG.08Plombièrite
Ca
 
5
(HSi
 
3
O
 
9
)
 
2
· 7H
 
2
O
9.DG.10Clinotobermorite
Ca
 
5
(Si
 
6
O
 
17
) · 5H
 
2
O
9.DG.10Riversideite
Ca
 
5
(HSi
 
3
O
 
9
)
 
2
· 2H
 
2
O
9.DG.10Tobermorite
Ca
 
4+x
(H
 
2-2x
Si
 
6
O
 
17
) · 5H
 
2
O
9.DG.15Foshagite
Ca
 
4
(Si
 
3
O
 
9
)(OH)
 
2
9.DG.20Jennite
Ca
 
9
(Si
 
3
O
 
9
)
 
2
(OH)
 
8
· 8H
 
2
O
9.DG.25Paraumbite
K
 
3
Zr
 
2
H(Si
 
3
O
 
9
)
 
2
· nH
 
2
O
9.DG.25Umbite
K
 
2
(Zr,Ti)Si
 
3
O
 
9
· H
 
2
O
9.DG.30Sørensenite
Na
 
4
SnBe
 
2
Si
 
6
O
 
16
(OH)
 
4
9.DG.35Xonotlite
Ca
 
6
(Si
 
6
O
 
17
)(OH)
 
2
9.DG.40Hillebrandite
Ca
 
2
(SiO
 
3
)(OH)
 
2
9.DG.45Zorite
Na
 
8
(Ti,Nb)
 
5
(Si
 
6
O
 
17
)
 
2
(OH,O)
 
5
· 14H
 
2
O
9.DG.45Chivruaiite
Ca
 
4
(Ti,Nb)
 
5
(Si
 
6
O
 
17
)
 
2
(OH,O)
 
5
· 13-14H
 
2
O
9.DG.50Haineaultite
(Na,Ca)
 
5
Ca(Ti,Nb)
 
5
(Si
 
6
O
 
17
)
 
2
(OH,F)
 
8
· 5H
 
2
O
9.DG.55Epididymite
Na
 
2
Be
 
2
Si
 
6
O
 
15
· H
 
2
O
9.DG.60Eudidymite
Na
 
2
Be
 
2
Si
 
6
O
 
15
· H
 
2
O
9.DG.65Elpidite
Na
 
2
ZrSi
 
6
O
 
15
· 3H
 
2
O
9.DG.70Fenaksite
(K,Na)
 
4
(Fe,Mn)
 
2
(Si
 
4
O
 
10
)
 
2
(OH,F)
9.DG.70Litidionite
CuNaKSi
 
4
O
 
10
9.DG.70Manaksite
KNaMnSi
 
4
O
 
10
9.DG.75Tinaksite
K
 
2
Na(Ca,Mn
2+
 
)
 
2
Ti[O|Si
 
7
O
 
18
(OH)]
9.DG.75Tokkoite
K
 
2
Ca
 
4
Si
 
7
O
 
17
(O,OH,F)
 
4
9.DG.75Senkevichite
CsKNaCa
 
2
Ti[O|Si
 
7
O
 
18
(OH)]
9.DG.80Canasite
K
 
2
Na
 
4
Ca
 
5
(Si
 
12
O
 
30
(OH,F)
 
4
9.DG.80Fluorcanasite
K
 
3
Na
 
3
Ca
 
5
Si
 
12
O
 
30
F
 
4
· H
 
2
O
9.DG.85Miserite
K(Ca,Ce)
 
4
Si
 
5
O
 
13
(OH)
 
3
9.DG.90Frankamenite
K
 
3
Na
 
3
Ca
 
5
(Si
 
12
O
 
30
)(F,OH)
 
4
· H
 
2
O
9.DG.92Charoite
(K,Sr)
 
15-16
(Ca,Na)
 
32
[Si
 
6
O
 
11
(O,OH)
 
6
]
 
2
[Si
 
12
O
 
18
(O,OH)
 
12
]
 
2
[Si
 
17
O
 
25
(O,OH)
 
18
]
 
2
(OH,F)
 
4
· ~3H
 
2
O
9.DG.95Yuksporite
(K,Ba)NaCa
 
2
(Si,Ti)
 
4
O
 
11
(F,OH) · H
 
2
O
9.DG.97Eveslogite
(Na,K,Ca,Sr,Ba)
 
48
[(Ti,Nb,Mn,Fe
2+
 
)
 
12
Si
 
48
O
 
144
(OH)
 
12
](F,OH,Cl)
 
14
Related Minerals - Hey's Index Grouping:

- +
14.18.1Nambulite
(Li,Na)Mn
 
4
Si
 
5
O
 
14
(OH)
14.18.2Natronambulite
(Na,Li)(Mn,Ca)
 
4
Si
 
5
O
 
14
OH
14.18.3Zakharovite
Na
 
4
Mn
 
5
Si
 
10
O
 
24
(OH)
 
6
· 6H
 
2
O
14.18.4Norrishite
KLiMn
3+
2
(Si
 
4
O
 
10
)O
 
2
14.18.5Shafranovskite
(Na,K)
 
6
(Mn,Fe)
 
3
Si
 
9
O
 
24
· 6H
 
2
O
14.18.6Abswurmbachite
CuMn
3+
6
(SiO
 
4
)O
 
8
14.18.7Donpeacorite
(Mn
2+
 
,Mg)Mg[SiO
 
3
]
 
2
14.18.8Kanoite
Mn
2+
 
(Mg,Mn
2+
 
)Si
 
2
O
 
6
14.18.9Caryopilite
(Mn,Mg)
 
3
(Si
 
2
O
 
5
)(OH)
 
4
14.18.10Gonyerite
(Mn
2+
 
,Mg)
 
5
Fe
3+
 
(Fe
3+
 
Si
 
3
O
 
10
)(OH)
 
8
14.18.11Tirodite
14.18.12Manganhumite
(Mn
2+
 
,Mg)
 
7
(SiO
 
4
)
 
3
(OH)
 
2
14.18.13Bustamite
CaMn
2+
 
(Si
 
2
O
 
6
)
14.18.14Glaucochroite
CaMn
2+
 
SiO
 
4
14.18.15Truscottite
(Ca,Mn)
 
14
Si
 
24
O
 
58
(OH)
 
8
· 2H
 
2
O
14.18.16Santaclaraite
CaMn
 
4
[Si
 
5
O
 
14
OH](OH) · H
 
2
O
14.18.18Johannsenite
CaMn
2+
 
Si
 
2
O
 
6
14.18.19Neltnerite
CaMn
3+
6
(SiO
 
4
)O
 
8
14.18.20Orlymanite
Ca
 
4
Mn
 
3
Si
 
8
O
 
20
(OH)
 
6
· 2H
 
2
O
14.18.21Inesite
Ca
 
2
(Mn,Fe)
 
7
Si
 
10
O
 
28
(OH)
 
2
· 5H
 
2
O
14.18.22Orientite
Ca
 
2
Mn
2+
 
Mn
3+
2
(Si
 
3
O
 
10
)(OH)
 
4
14.18.23Ruizite
Ca
 
2
Mn
3+
2
[(OH)
 
2
|H
 
2
Si
 
4
O
 
13
] · 2H
 
2
O
14.18.24Bostwickite
CaMn
 
6
Si
 
3
O
 
16
· 7H
 
2
O
14.18.25Kittatinnyite
Ca
 
2
Mn
 
2
Mn(SiO
 
4
)
 
2
(OH)
 
4
· 9H
 
2
O
14.18.26Lithiomarsturite
LiCa
 
2
Mn
 
2
Si
 
5
O
 
14
(OH)
14.18.27Sérandite
Na(Mn
2+
 
,Ca)
 
2
(HSi
 
3
O
 
9
)
14.18.28Kvanefjeldite
Na
 
4
(Ca,Mn)(Si
 
3
O
 
7
)
 
2
(OH)
 
2
14.18.29Marsturite
NaCaMn
 
3
Si
 
5
O
 
14
(OH)
14.18.30Raite
Na
 
4
Mn
2+
3
Ti
 
0.25
Si
 
8
O
 
20
(OH)
 
2
· 10H
 
2
O
14.18.31Richterite
{Na}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
14.18.32Byelorussite-(Ce)
NaBa
 
2
Ce
 
2
MnTi
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(F,OH) · H
 
2
O
14.18.33Deerite
(Fe,Mn)
 
6
(Fe,Al)
 
3
[Si
 
6
O
 
17
]O
 
3
(OH)
 
5
14.18.34Calderite
(Mn
2+
 
,Ca)
 
3
(Fe
3+
 
,Al)
 
2
(SiO
 
4
)
 
3
14.18.35Pyroxmangite
MnSiO
 
3
14.18.36Dannemorite
14.18.37Neotocite
(Mn,Fe,Mg)SiO
 
3
· H
 
2
O
14.18.38Babingtonite
Ca
 
2
(Fe,Mn)FeSi
 
5
O
 
14
(OH)
14.18.39Manganbabingtonite
Ca
 
2
(Mn,Fe)FeSi
 
5
O
 
14
(OH)
14.18.40Örebroite
Mn
2+
3
(Fe
3+
 
,Sb
5+
 
)(SiO
 
4
)(O,OH)
 
3

Other Names for Ferrobustamite

Synonyms:
Vogtite
Other Languages:
German:Ferrobustamit
Vogtit
Japanese:鉄バスタム石
Russian:Ферробустамит
Spanish:Ferrobustamita
Vogtita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ferrobustamite

Reference List:

- +
American Mineralogist: 59: 632.

Zeitschrift für Kristallographie: 138: 419-438.

Internet Links for Ferrobustamite

Search Engines:
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  • Look for Ferrobustamite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Ferrobustamite details from Handbook of Mineralogy (PDF)
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  • Localities for Ferrobustamite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • British Columbia
      • Golden Mining Division
    No reference listed
    • Northwest Territories
      • Mackenzie District
        • Blachford Lake alkaline complex
    SHEARD, E.R., WILLIAMS-JONES, A.E., HEILIGMANN, M., PEDERSON, C. AND TRUEMAN, D.L. (2012) Controls on the concentration of zirconium, niobium, and the rare earth elements in the Thor Lake rare metal deposit, Northwest Territories, Canada. Economic Geology, 107(1), 81-104.
    Sheard, E.R. (2010); SHEARD, E.R., WILLIAMS-JONES, A.E., HEILIGMANN, M., PEDERSON, C. AND TRUEMAN, D.L. (2012) Controls on the concentration of zirconium, niobium, and the rare earth elements in the Thor Lake rare metal deposit, Northwest Territories, Canada. Economic Geology, 107(1), 81-104.
    Germany
     
    • Rhineland-Palatinate
      • Westerwald
        • Linz am Rhein
          • Rheinbreitbach
            • Virneberg Mine (St Josephsberg Mine)
    Habel, B. (2006): Die Mineralien der Kupferschlacken der Grube „Virneberg“ bei Rheinbreitbach, Rhein. Mineralien-Welt 17 (1), 38-49.
    • Saxony-Anhalt
      • Mansfeld Basin
        • Hettstedt
          • Copper-Silver smelter (Gottesbelohnung smelter; slag locality)
    Besteman, Andre, et al, Hettstedt-smelter slag-dumps, Mansfeld Basin, Sachsen-Anhalt, Germany, The Strahlen Foundation.
    Greenland
     
    • Kitaa (West Greenland) Province
      • Narsaq
        • Ilimaussaq complex
          • Tasseq area
            • Tasseq Slopes (Taseq Slopes)
    Petersen, O.V., Johnsen, O., Niedermayr, G., Grice, J.D. (2004): Taseqite, a new member of the Eudialyte group from the Ilimaussaq alkaline complex, South Greenland, Neues Jahrbuch für Mineralogie, Monatshefte, 2004, No2, 83-96
    • Tunu (East Greenland) Province
      • Kangerlussuaq Firth
        • Kangerlussuaq complex
    Tegner, C. (1997): Contributions to Mineralogy and Petrology 128, 45-51.
    Italy
     
    • Umbria
      • Perugia Province
        • Spoleto
    Stoppa F., Sharygin V.V., 2009. Melilitolite intrusion and pelite digestion by high temperature kamafugitic magma at Colle Fabbri, Spoleto, Italy. Lithos, 112, 306-320.
    Japan
     
    • Honshu Island
      • Chubu Region
        • Fukui Prefecture
          • Ono City
    Excalibur Mineral Co. specimen
        • Gifu Prefecture
          • Seki City
    Excalibur Mineral Co. (Tony Nikischer) specimen
      • Chugoku Region
        • Okayama Prefecture
          • Takahashi City
    Matsueda, H. (1983) Journal of the Mining College, Akita University, Ser. A, Mining Geology, 6, #3, 259-292.
        • Shimane Prefecture
        • Yamaguchi Prefecture
          • Iwakuni City
    Econ Geol (1980) 75:1066-1082
    Econ Geol (1980) 75:173-183
      • Kanto Region
        • Ibaraki Prefecture
          • Kasama City
    Shimazaki H., 1977. Grossular-spessartine-almandine garnets from some japanese scheelite skarns. Canad. Miner., 15: 74-80
      • Tohoku Region
        • Iwate Prefecture
          • Kuji City
    D Ishiyama, et al (2000) J. Min. Coll. Akita Univ., Ser. A, 3, no. 3, 105-127.
    South Africa
     
    • Northern Cape Province
      • Kalahari manganese fields
        • Hotazel
    [Von Bezing, K. L. et al. (1991) - The Kalahari manganese field : an update, Mineralogical Record, 22 (3), 279-302]
    UK
     
    • Northern Ireland
      • Co. Antrim
        • Larne
    American Mineralogist, Volume 60, pages 209-212, 1975
    • Scotland
      • North West Highlands (Inverness-shire)
        • Isle of Skye
          • Broadford
            • Kilchrist
            • Torrin
    Am Min (1948), 33:736-738; American Mineralogist, Volume 59, pages 632-633, 1974
    Mineral and/or Locality
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