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Ferrohornblende

Formula:
☐[Ca
 
2
][Fe
2+
4
Al][(OH)
 
2
|AlSi
 
7
O
 
22
]
System:MonoclinicColour:Dark green to black, ...
Lustre:VitreousHardness:5 - 6
Name:From an old German term meaning "horn" and "blind" or "to deceive," in allusion to it occurring in ore deposits but not yielding any metal.


Amphibole Group. Calcic Clino-Amphibole Subgroup. Ferrohornblende-Magnesiohornblende Series.

Classification of Ferrohornblende

IMA status:Approved
Strunz 8th edition ID:8/F.10-50
Nickel-Strunz 10th (pending) edition ID:9.DE.10

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles
Hey's CIM Ref.:16.23.5

16 : Silicates Containing Aluminum and other Metals
23 : Aluminosilicates of Fe, Ca, and Mg
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Physical Properties of Ferrohornblende

Lustre:Vitreous
Colour:Dark green to black, greenish-brown, more rarely lighter green.
Streak:Pale grey-green, grey-white
Hardness (Mohs):5 - 6
Cleavage:Perfect
on {110}

Crystallography of Ferrohornblende

Crystal System:Monoclinic
Cell Parameters:a = 9.96Å, b = 18.19Å, c = 5.32Å
β = 104.87°
Ratio:a:b:c = 0.548 : 1 : 0.292
Unit Cell Volume:V 931.56 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data: Peaks:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Ferrohornblende

Type:Biaxial (-)
RI values: nα = 1.687 - 1.694 nβ = 1.700 - 1.707 nγ = 1.701 - 1.712
2V:Measured: 12° to 76°, Calculated: 30° to 62°
Maximum Birefringence:δ = 0.014 - 0.018

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:r > v or r < v

Chemical Properties of Ferrohornblende

Formula:
☐[Ca
 
2
][Fe
2+
4
Al][(OH)
 
2
|AlSi
 
7
O
 
22
]
Essential elements:Al, Ca, Fe, H, O, Si
All elements listed in formula:Al, Ca, Fe, H, O, Si
Common Impurities:Ti,Mn,Na,K

Relationship of Ferrohornblende to other Species

Series:Forms a series with Magnesiohornblende (see here)
Related Minerals - Nickel-Strunz Grouping):
9.DE.XIMA2007-053
KCa
 
2
(Fe
2+
4
Al)Si
 
6
Al
 
2
O
 
22
(OH)
 
2
9.DE.05Cummingtonite
[ ][Mg
 
2
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Grunerite
[ ][Fe
2+
2
][Fe
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Manganocummingtonite
[ ][Mn
2+
2
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Manganogrunerite
[ ][Mn
2+
2
][Fe
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Permanganogrunerite
[ ][Mn
2+
2
][Mn
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Actinolite
☐Ca
 
2
(Mg,Fe
2+
 
)
 
5
(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Alumino-ferro-hornblende
Ca
 
2
Fe
 
4
Al
 
2
Si
 
7
O
 
22
(OH)
 
2
9.DE.10Alumino-magnesio-hornblende
Ca
 
2
Mg
 
4
Al
 
2
Si
 
7
O
 
22
(OH)
 
2
9.DE.10Aluminotschermakite
☐[Ca
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Ferritschermakite
☐[Ca
 
2
][Mg
 
3
Fe
3+
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Ferro-Actinolite
☐[Ca
 
2
][(Fe
2+
 
,Mg)
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Ferrotschermakite
☐[Ca
 
2
][Fe
2+
3
Fe
3+
 
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Joesmithite
[(Ca,Pb)][(Ca,Pb)
 
2
][(Mg,Fe
2+
 
)
 
5
][(OH)
 
2
|BeSi
 
7
O
 
22
]
9.DE.10Magnesiohornblende
☐[Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.10Tremolite
☐[Ca
 
2
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Tschermakite
☐[Ca
 
2
][Mg
 
3
Fe
3+
 
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Ferri-Ferrotschermakite
9.DE.10Alumino-Ferrotschermakite
9.DE.10Cannilloite
[Ca][Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.10Fluor-cannilloite
[Ca][Ca
 
2
][Mg
 
4
Al][(F,OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.10Parvo-manganotremolite
☐[CaMn
2+
 
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Fluorotremolite
☐[Ca
 
2
][Mg
 
5
][F
 
2
|Si
 
8
O
 
22
]
9.DE.15Edenite
Na[Ca
 
2
][Mg
 
5
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Ferro-edenite
[Na][Ca
 
2
][Fe
2+
5
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Ferrokaersutite
[Na][Ca
 
2
][Fe
2+
4
Ti][O|OH|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Ferropargasite
[Na][Ca
 
2
][Fe
2+
4
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Hastingsite
[Na][Ca
 
2
][Fe
2+
4
Fe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Kaersutite
[Na][Ca
 
2
][Mg
 
4
Ti][O|OH|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Magnesiohastingsite
Na[Ca
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Magnesiosadanagaite
[Na][Ca
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Pargasite
[Na][Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Sadanagaite
[Na][Ca
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Fluoro-edenite
Na[Ca
 
2
][Mg
 
5
][(F,OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Potassic-Ferrisadanagaite
[K][Ca
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Potassic-Magnesiosadanagaite
[K][Ca
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Potassicpargasite
[K][Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Potassicsadanagaite
[K][Ca
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Fluoro-magnesiohastingsite
[Na][Ca
 
2
][Mg
 
4
Fe
3+
 
][F
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Fluoro-potassichastingsite
[K][Ca
 
2
][Fe
2+
4
Fe
3+
 
][(F,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Chloro-potassichastingsite
[K][Ca
 
2
][Fe
2+
4
Fe
3+
 
][(Cl,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Fluoropargasite
[Na][Ca
 
2
][Mg
 
4
Al][(F,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Parvo-mangano-edenite
Na[CaMn
2+
 
][Mg
 
5
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Chloro-potassicpargasite
[K][Ca
 
2
][Mg
 
4
Al][(Cl,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Chloro-potassic-ferro-edenite
[K][Ca
 
2
][Fe
2+
5
][(Cl,OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Potassic-magnesiohastingsite
[K][Ca
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Aluminobarroisite
☐[CaNa][Mg
 
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Aluminokatophorite
9.DE.20Aluminotaramite
Na[CaNa][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Barroisite
☐[CaNa][Mg
 
3
AlFe
3+
 
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferri-ferrobarroisite
☐[CaNa][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Alumino-ferrowinchite
9.DE.20Ferri-ferrowinchite
☐[CaNa][Fe
2+
4
(Fe
3+
 
,Al)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Ferribarroisite
☐[CaNa][Mg
 
3
Fe
3+
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferritaramite
Na[CaNa][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Ferrikatophorite
Na[CaNa][Fe
2+
4
(Fe
3+
 
,Al)][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Alumino-ferrobarroisite
☐[CaNa][Fe
2+
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferrobarroisite
☐[CaNa][Fe
2+
3
AlFe
3+
 
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferrorichterite
Na[CaNa][Fe
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Ferrowinchite
☐[CaNa][Fe
2+
4
(Al,Fe
3+
 
)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Katophorite
Na[CaNa][Fe
2+
4
(Al,Fe
3+
 
)][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferri-magnesiotaramite
Na[CaNa][Mg
 
3
Fe
3+
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Magnesiotaramite
Na[CaNa][Mg
 
3
AlFe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Richterite
Na[CaNa][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Taramite
Na[CaNa][Fe
2+
3
AlFe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Winchite
☐[CaNa][Mg
 
4
(Al,Fe
3+
 
)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Alumino-Magnesiotaramite
Na[CaNa][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Fluororichterite
Na[CaNa][Mg
 
5
][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Magnesiokatophorite
Na[CaNa][Mg
 
4
(Al,Fe
3+
 
)][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Fluoro-potassicrichterite
K[CaNa][Mg
 
5
][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Potassicrichterite
K[CaNa][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Parvowinchite
☐[Mn
2+
 
Na][Mg
 
4
(Al,Fe
3+
 
)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Ferriwinchite
☐[CaNa][Mg
 
4
(Fe
3+
 
,Al)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Fluoro-alumino-magnesiotaramite
Na[CaNa][Mg
 
3
Al
 
2
][F
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20IMA2007-015
K[CaNa][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.25Arfvedsonite
[Na][Na
 
2
][Fe
2+
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Eckermannite
[Na][Na
 
2
][(Mg,Fe
2+
 
)
 
4
Al][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferro-eckermannite
[Na][Na
 
2
][(Fe
2+
 
,Mg)
 
4
Al][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Clinoferroholmquistite
[ ][Li
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferroglaucophane
[ ][Na
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Glaucophane
[ ][Na
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Kornite
[(Na,K)][Na
 
2
][Mg
 
2
Mn
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Kôzulite
[Na][Na
 
2
][Mn
2+
4
(Fe
3+
 
,Al)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Leakeite
[Na][Na
 
2
][Mg
 
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Magnesioriebeckite
[ ][Na
 
2
][Mg
 
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Magnesio-arfvedsonite
[Na][Na
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Nybøite
[Na][Na
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.25Riebeckite
[ ][Na
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ungarettiite
[Na][Na
 
2
][Mn
2+
2
Mn
3+
3
][O
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferric-ferronyboite
9.DE.25Ferri-clinoferroholmquistite
[ ][Li
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferric-nyboite
9.DE.25Ferroleakeite
[Na][Na
 
2
][Fe
2+
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferronyböite
[Na][Na
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.25Fluoro-ferroleakeite
[Na][Na
 
2
][Fe
2+
2
Fe
3+
2
Li][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Sodic-ferri-clinoferroholmquistite
[(☐,Na)][(Li,☐)
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Fluoro-magnesio-arfvedsonite
[Na][Na
 
2
][Mg
 
4
Fe
3+
 
][(F,OH)
 
2
|[Si
 
8
O
 
22
]
9.DE.25Sodic-ferripedrizite
[Na][Li
 
2
][Mg
 
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Potassicleakeite
[K][Na
 
2
][Mg
 
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Fluoronybøite
[Na][Na
 
2
][Mg
 
3
Al
 
2
][(F,OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.25Ferriwhittakerite
Na(Na
 
1.0-1.5
Li
 
0.5-1.0
)
 
2
(Fe
3+
2
Mg
 
2
Li)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferri-ottoliniite
[](Na
 
1
Li
 
1
)(Fe
3+
2
Mg
 
3
)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Dellaventuraite
NaNa
 
2
(MgMn
3+
2
LiTi
4+
 
)Si
 
8
O
 
22
O
 
2
9.DE.25Fluoro-sodicpedrizite
[Na][Li
 
2
][Mg
 
2
Al
 
2
Li][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Potassicarfvedsonite
[(K,Na)][Na
 
2
][Fe
2+
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Obertiite
[Na][Na
 
2
][Mg
 
3
(Ti,Fe
3+
 
,Mn
3+
 
)
 
2
][O
 
2
|Si
 
8
O
 
22
]
9.DE.25Fluoro-potassic-magnesio-arfvedsonite
[(K,Na)][Na
 
2
][Mg
 
4
Fe
3+
 
][(F,OH)
 
2
|[Si
 
8
O
 
22
]
9.DE.25Sodic-ferri-ferropedrizite
[Na][Li
 
2
][Fe
2+
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Potassic-magnesio-arfvedsonite
[K][Na
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
Related Minerals - Hey's Index Grouping:
16.23.1Augite
(Ca,Na)(Mg,Fe
2+
 
,Al,Fe
3+
 
,Ti)[(Si,Al)
 
2
O
 
6
]
16.23.2Dorrite
Ca
 
2
(Mg,Fe
2+
 
)
 
2
Fe
3+
4
[O
 
2
|Al
 
4
Si
 
2
O
 
18
]
16.23.3Vesuvianite
Ca
 
10
(Mg,Fe)
 
2
Al
 
4
Si
 
9
O
 
34
(OH)
 
4
16.23.6Magnesiohornblende
☐[Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|AlSi
 
7
O
 
22
]
16.23.7Aerinite
Ca
 
5
(Fe
3+
 
,Al,Fe
2+
 
,Mg)(Al,Mg)
 
6
[HSi
 
12
O
 
36
(OH)
 
12
][(CO
 
3
)
 
1.2
(H
 
2
O)
 
12

Other Names for Ferrohornblende

Synonyms:
BarkeviciteFerro-actinolitic-hornblendeIstisuite
German names:
BarkevicitBarkevikit
Spanish names:
BarkevicitaBarkevikita
Varieties:
Philipstadite

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ferrohornblende

Reference List:Barnes, V.E. (1930) hanges in hornblende at about 800°. American Mineralogist: 15: 393-417.

Mineralogical Record: 29: 169-174.

Robinson, K., Gibbs, G.V., Ribbe, P.H., and Hall, M.R. (1973) Cation distribution in three hornblendes. American Journal of Science: 273A: 522-535.

Spear, F.S. (1981) An experimental study of hornblende stability and compositional variability in amphibolite. American Journal of Science: 281: 697-734.

Hawthorne, Frank C., and Roberta Oberti (2006), On the classification of amphiboles: Canadian Mineralogist:
44(1): 1-21.

Internet Links for Ferrohornblende

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  • Raman and XRD data at RRUFF project
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  • Search for Ferrohornblende in the Natural History Museum (London) online catalogue
  • Ferrohornblende details from Handbook of Mineralogy (PDF)
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    Localities for Ferrohornblende

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