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Fillowite

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Formula:
{Mn
2+
 
}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mn
2+
 
,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
System:TrigonalColour:Greenish yellow to ...
Hardness:
Member of:Fillowite Group
Name:
Named by George J. Brush and Edward S. Dana in 1879 in honor of Abijah N. Fillow of Branchville [b. October 24, 1822 - November 10, 1895], Connecticut, USA, original owner and operator of the Branchville pegmatite and mine, as well as railroad station manager of Branchville Station, and who first collected the rare manganese phosphates that made the locality famous.

Classification of Fillowite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/A.08-20
Nickel-Strunz 10th (pending) edition ID:8.AC.50

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th edition ID:38.2.9.1
Dana 8th edition ID:38.2.5.1

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
Hey's CIM Ref.:19.12.30

19 : Phosphates
12 : Phosphates of Mn
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Type Occurrence of Fillowite

Type Locality:Fillow Quarry (Branchville Quarry; Branchville Mica Mine; Smith Mine), Branchville, Town of Ridgefield, Fairfield Co., Connecticut, USA
Year of Discovery:1879
Geological Setting of type material:Granite Pegmatite containing lithiophilite
Associated Minerals at type locality:
TriploiditeReddingiteFairfieldite

Physical Properties of Fillowite

Lustre:Sub-Vitreous, Resinous, Greasy
Diaphaneity (Transparency):Transparent, Translucent
Comment:Sub-resinous to greasy.
Colour:Greenish yellow to yellow green, yellowish brown, reddish brown; colourless; colourless to yellow in transmitted light.
Streak:White
Hardness (Mohs):
Tenacity:Brittle
Cleavage:Perfect
On {001}, nearly perfect.
Fracture:Irregular/Uneven
Density (measured):3.43 g/cm3
Density (calculated):3.42-3.54 g/cm3
Comment:Am Min 74:918 structure

Crystallography of Fillowite

Crystal System:Trigonal
Class (H-M):3 - Rhombohedral
Space Group:R3
Space Group Setting:R3
Cell Parameters:a = 15.25Å, c = 43.32Å
Ratio:a:c = 1 : 2.841
Unit Cell Volume:V 8,724.87 ų (Calculated from Unit Cell)
Z:18
Morphology:Granular crystalline masses, rarely as tiny <<1 mm pseudo-cubic rhombohedra in intergrown columns (<< 1 mm).
Comment:ICDD 18-516; Am Min 74:918 structure
X-Ray Powder Diffraction:
d-spacingIntensity
11.4 (40)
8.49 (20)
3.79 (40)
3.02 (70)
2.81 (100)
2.55 (60)
2.16 (20)
1.888 (40)
Comments:ICDD 18-516

Optical Data of Fillowite

Type:Uniaxial (+)
RI values: nω = 1.671 - 1.672 nε = 1.676
Birefringence:0.005
Maximum Birefringence:δ = 0.005

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:r < v strong
Comments:May be anomalously biaxial (+). 1.672, 1.672, 1.676. 2V = 30°

Chemical Properties of Fillowite

Formula:
{Mn
2+
 
}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mn
2+
 
,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
Essential elements:Ca, Mn, Na, O, P
All elements listed in formula:Ca, Fe, Mn, Na, O, P

Relationship of Fillowite to other Species

Member of:Fillowite Group
Other Members of Group:

- +
Chladniite
{Ca}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mg,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
Galileiite
{Fe
2+
 
}{Na
 
8
}{Fe
2+
4
Na
 
4
}{Fe
2+
43
}(PO
 
4
)
 
36
Johnsomervilleite
{Ca}{Na
 
6
[ ]
 
2
}{Ca
 
6
Na
 
2
}{(Fe
2+
 
,Mg,Mn
2+
 
)
 
43
}(PO
 
4
)
 
36
Stornesite-(Y)
{(Y, Ca)}{Na
 
6
 
2
}{(Ca,Na)
 
8
}{(Mg,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
Xenophyllite
Na
 
4
Fe
2+
7
(PO
 
4
)
 
6
Related Minerals - Nickel-Strunz Grouping):

- +
8.AC.05Howardevansite
NaCuFe
 
2
(VO
 
4
)
 
3
8.AC.10Alluaudite
(Na,Ca)Mn
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
,Mg)
 
2
(PO
 
4
)
 
3
8.AC.10Arseniopleite
NaCaMn
2+
 
(Mn
2+
 
,Mg)
 
2
(AsO
 
4
)
 
3
8.AC.10Caryinite
(Na,Pb)(Ca,Na)(Ca,Mn
2+
 
)(Mn
2+
 
,Mg,Fe
3+
 
)
 
2
(AsO
 
4
)
 
3
8.AC.10Ferroalluaudite
(Na,Ca)Fe
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)
 
3
8.AC.10Hagendorfite
NaCaMn
2+
 
Fe
2+
2
(PO
 
4
)
 
3
8.AC.10Johillerite
Na(Mg,Zn)
 
3
Cu(AsO
 
4
)
 
3
8.AC.10Maghagendorfite
(□,Na,)(Na,Ca,Fe
2+
 
)Mn(Mg,Fe
2+
 
,Fe
3+
 
)
 
3
(PO
 
4
)
 
3
8.AC.10Nickenichite
Na
 
0.8
Ca
 
0.4
Cu
 
0.4
(Mg,Fe)
 
3
(AsO
 
4
)
 
3
8.AC.10Varulite
NaCaMn
2+
 
Mn
2+
2
(PO
 
4
)
 
3
8.AC.10Ferrohagendorfite
NaCaFe
2+
 
Fe
2+
2
(PO
 
4
)
 
3
8.AC.10Bradaczekite
NaCu
 
4
(AsO
 
4
)
 
3
8.AC.10Yazganite
NaFe
3+
2
(Mg,Mn
2+
 
)(AsO
 
4
)
 
3
· H
 
2
O
8.AC.10Groatite
NaCaMn
 
2
(PO
 
4
)(HPO
 
4
)
 
2
8.AC.15Bobfergusonite
Na
 
2
Mn
 
5
FeAl(PO
 
4
)
 
6
8.AC.15Ferrowyllieite
(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO
 
4
)
 
3
8.AC.15Qingheiite
NaMn
3+
 
Mg(Al,Fe
3+
 
)(PO
 
4
)
 
3
8.AC.15Rosemaryite
(Na,Ca,Mn)(Mn,Fe
2+
 
)(Fe
3+
 
,Mg)Al(PO
 
4
)
 
3
8.AC.15Wyllieite
(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO
 
4
)
 
3
8.AC.15Ferrorosemaryite
◻NaFe
2+
 
Fe
3+
 
Al(PO
 
4
)
 
3
8.AC.15Qingheiite-(Fe2+)
Na
 
2
Fe
2+
 
MgAl(PO
 
4
)
 
3
8.AC.18Manitobaite
Na
 
16
Mn
2+
 
 
25
Al
 
8
(PO
 
4
)
 
30
8.AC.20Marićite
NaFe
2+
 
(PO
 
4
)
8.AC.25Berzeliite
NaCa
 
2
(Mg,Mn
2+
 
)
 
2
(AsO
 
4
)
 
3
8.AC.25Manganberzeliite
(Ca,Na)
 
3
(Mn
2+
 
,Mg)
 
2
(AsO
 
4
)
 
3
8.AC.25Palenzonaite
(Ca,Na)
 
3
CaMn
2+
2
(VO
 
4
)
 
3
8.AC.25Schäferite
Ca
 
2
NaMg
 
2
(VO
 
4
)
 
3
8.AC.30Brianite
Na
 
2
CaMg(PO
 
4
)
 
2
8.AC.35Vitusite-(Ce)
Na
 
3
(Ce,La,Nd)(PO
 
4
)
 
2
8.AC.40Olgite
(Sr,Ba)(Na,Sr,REE)
 
2
Na(PO
 
4
)
 
2
8.AC.40Bario-olgite
(Ba,Sr)(Na,Sr,REE)
 
2
Na(PO
 
4
)
 
2
·
8.AC.45Strontiowhitlockite
Sr
 
9
Mg(PO
 
4
)
 
6
(HPO
 
4
)
8.AC.45Whitlockite
Ca
 
9
Mg(PO
 
4
)
 
6
(HPO
 
4
)
8.AC.45Merrillite
Ca
 
9
NaMg(PO
 
4
)
 
7
8.AC.45Tuite
Ca
 
3
(PO
 
4
)
 
2
8.AC.45Ferromerrillite
Ca
 
9
NaFe
2+
 
(PO
 
4
)
 
7
8.AC.45Bobdownsite
Ca
 
9
Mg(PO
 
4
)
 
6
(PO
 
3
F)
8.AC.50Chladniite
{Ca}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mg,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
8.AC.50Johnsomervilleite
{Ca}{Na
 
6
[ ]
 
2
}{Ca
 
6
Na
 
2
}{(Fe
2+
 
,Mg,Mn
2+
 
)
 
43
}(PO
 
4
)
 
36
8.AC.50Galileiite
{Fe
2+
 
}{Na
 
8
}{Fe
2+
4
Na
 
4
}{Fe
2+
43
}(PO
 
4
)
 
36
8.AC.50Stornesite-(Y)
{(Y, Ca)}{Na
 
6
 
2
}{(Ca,Na)
 
8
}{(Mg,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
8.AC.50Xenophyllite
Na
 
4
Fe
2+
7
(PO
 
4
)
 
6
8.AC.55Harrisonite
Ca(Fe
2+
 
,Mg)
 
6
(PO
 
4
)
 
2
(SiO
 
4
)
 
2
8.AC.60Kosnarite
KZr
 
2
(PO
 
4
)
 
3
8.AC.65Panethite
(Na,Ca)
 
2
(Mg,Fe
2+
 
)
 
2
(PO
 
4
)
 
2
8.AC.70Stanfieldite
Ca
 
7
Ca
 
2
Mg
 
9
(PO
 
4
)
 
12
8.AC.75Ronneburgite
K
 
2
MnV
 
4
O
 
12
8.AC.80Tillmannsite
(Ag
 
3
Hg)(VO
 
4
,AsO
 
4
)
8.AC.85Filatovite
K(Al,Zn)
 
2
(As,Si)
 
2
O
 
8
Related Minerals - Hey's Index Grouping:

- +
19.12.1Metaswitzerite
Mn
 
3
(PO
 
4
)
 
2
· 4H
 
2
O
19.12.2Bermanite
Mn
2+
 
Mn
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
19.12.3Natrophilite
NaMn
2+
 
PO
 
4
19.12.4Sidorenkite
Na
 
3
Mn
2+
 
(CO
 
3
)(PO
 
4
)
19.12.5Niahite
(NH
 
4
)(Mn
2+
 
,Mg)(PO
 
4
) · H
 
2
O
19.12.6Robertsite
Ca
 
3
Mn
3+
4
(PO
 
4
)
 
3
O
 
2
· 3H
 
2
O
19.12.7Pararobertsite
Ca
 
2
Mn
3+
3
(PO
 
4
)
 
3
O
 
2
· 3H
 
2
O
19.12.8Sinkankasite
H
 
2
Mn
2+
 
Al(PO
 
4
)
 
2
(OH) · 6H
 
2
O
19.12.9Mangangordonite
Mn
2+
 
Al
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.10Heterosite
(Fe
3+
 
,Mn
3+
 
)PO
 
4
19.12.11Purpurite
(Mn
3+
 
,Fe
3+
 
)PO
 
4
19.12.12Wolfeite
(Fe
2+
 
,Mn
2+
 
)
 
2
(PO
 
4
)(OH)
19.12.13Triploidite
(Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)(OH)
19.12.14Lipscombite
(Fe
2+
 
,Mn
2+
 
)Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
19.12.15Frondelite
Mn
2+
 
Fe
3+
4
(PO
 
4
)
 
3
(OH)
 
5
19.12.16Rockbridgeite
Fe
2+
 
Fe
3+
4
(PO
 
4
)
 
3
(OH)
 
5
19.12.17Kryzhanovskite
(Fe
3+
 
,Mn
2+
 
)
 
2
(PO
 
4
)
 
2
(OH,H
 
2
O)
 
3
19.12.18Landesite
Mn
2+
3-x
Fe
3+
x
(PO
 
4
)
 
2
(OH)
 
x
· (3-x)H
 
2
O
19.12.19Phosphoferrite
(Fe
2+
 
,Mn
2+
 
)
 
3
(PO
 
4
)
 
2
· 3H
 
2
O
19.12.20Reddingite
(Mn
2+
 
,Fe
2+
 
)
 
3
(PO
 
4
)
 
2
· 3H
 
2
O
19.12.21Earlshannonite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
19.12.22Hureaulite
(Mn,Fe)
 
5
(PO
 
4
)
 
2
(HPO
 
4
)
 
2
· 4H
 
2
O
19.12.23Switzerite
(Mn,Fe)
 
3
(PO
 
4
)
 
2
· 7H
 
2
O
19.12.24Laueite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.25Pseudolaueite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.26Strunzite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 6H
 
2
O
19.12.27Stewartite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.28Alluaudite
(Na,Ca)Mn
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
,Mg)
 
2
(PO
 
4
)
 
3
19.12.29Ferroalluaudite
(Na,Ca)Fe
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)
 
3
19.12.31Johnsomervilleite
{Ca}{Na
 
6
[ ]
 
2
}{Ca
 
6
Na
 
2
}{(Fe
2+
 
,Mg,Mn
2+
 
)
 
43
}(PO
 
4
)
 
36
19.12.32Wicksite
NaCa
 
2
(Fe
2+
 
,Mn
2+
 
)
 
4
MgFe
3+
 
(PO
 
4
)
 
6
· 2H
 
2
O
19.12.33Dickinsonite-(KMnNa)
{KNa}{Mn
2+
 
◻}{Ca}{Na
 
3
}{Mn
2+
13
}{Al}(PO
 
4
)
 
12
(OH)
 
2
19.12.34Sarcopside
(Fe
2+
 
,Mn
2+
 
,Mg)
 
3
(PO
 
4
)
 
2
19.12.35Ludlamite
(Fe,Mn,Mg)
 
3
(PO
 
4
)
 
2
· 4H
 
2
O
19.12.36Graftonite
(Fe
2+
 
,Mn
2+
 
,Ca)
 
3
(PO
 
4
)
 
2
19.12.37Wilhelmvierlingite
CaMnFe
3+
 
(PO
 
4
)
 
2
(OH) · 2H
 
2
O
19.12.38Fairfieldite
Ca
 
2
(Mn
2+
 
,Fe
2+
 
)(PO
 
4
)
 
2
· 2H
 
2
O
19.12.39Beusite
(Mn
2+
 
,Fe
2+
 
,Ca,Mg)
 
3
(PO
 
4
)
 
2
19.12.40Messelite
Ca
 
2
(Fe
2+
 
,Mn
2+
 
)(PO
 
4
)
 
2
· 2H
 
2
O
19.12.41Jahnsite-(CaMnFe)
{Ca}{Mn
2+
 
}{Fe
2+
2
}{Fe
3+
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.42Jahnsite-(CaMnMn)
{Ca}{Mn
2+
 
}{Mn
2+
2
}{Fe
3+
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.43Jahnsite-(CaMnMg)
{Ca}{Mn
2+
 
}{(Mg,Fe
2+
 
)
 
2
}{Fe
3+
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.44Keckite
CaMn
2+
 
Fe
3+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
3
(H
 
2
O)
 
7
19.12.45Stanfieldite
Ca
 
7
Ca
 
2
Mg
 
9
(PO
 
4
)
 
12
19.12.46Laubmannite
(Fe
2+
 
,Mn
2+
 
,Ca)
 
3
Fe
3+
6
(PO
 
4
)
 
4
(OH)
 
12
19.12.47Zodacite
Ca
 
4
Mn
2+
 
Fe
3+
4
(PO
 
4
)
 
6
(OH)
 
4
· 12H
 
2
O
19.12.48Hagendorfite
NaCaMn
2+
 
Fe
2+
2
(PO
 
4
)
 
3
19.12.49Maghagendorfite
(□,Na,)(Na,Ca,Fe
2+
 
)Mn(Mg,Fe
2+
 
,Fe
3+
 
)
 
3
(PO
 
4
)
 
3
19.12.50Varulite
NaCaMn
2+
 
Mn
2+
2
(PO
 
4
)
 
3
19.12.51Griphite
Na
 
4
Li
 
2
Ca
 
6
(Mn
2+
 
,Fe
2+
 
,Mg)
 
19
Al
 
8
(PO
 
4
)
 
24
(F,OH)
 
8
19.12.52Attakolite
(Ca,Sr)Mn(Al,Fe)
 
4
(HPO
 
4
,PO
 
4
)
 
3
(SiO
 
4
,PO
 
4
)(OH)
 
4
19.12.53Arrojadite-(KFe)
{KNa}{Fe
2+
 
◻}{Ca}{Na
 
2
◻}{Fe
2+
13
}{Al}(PO
 
4
)
 
11
(HPO
 
4
)(OH)
 
2
19.12.54Lun'okite
(Mn,Ca)(Mg,Fe,Mn)Al(PO
 
4
)
 
2
OH · 4H
 
2
O
19.12.55Eosphorite
(Mn
2+
 
,Fe
2+
 
)Al(PO
 
4
)(OH)
 
2
· H
 
2
O
19.12.56Ernstite
(Mn
2+
 
,Fe
3+
 
)Al(PO
 
4
)(OH,O)
 
2
· H
 
2
O
19.12.57Childrenite
(Fe
2+
 
,Mn
2+
 
)Al(PO
 
4
)(OH)
 
2
· H
 
2
O
19.12.58Bobfergusonite
Na
 
2
Mn
 
5
FeAl(PO
 
4
)
 
6
19.12.59Qingheiite
NaMn
3+
 
Mg(Al,Fe
3+
 
)(PO
 
4
)
 
3
19.12.60Whiteite-(CaFeMg)
{Ca}{(Fe
2+
 
,Mn
2+
 
)}{Mg
 
2
}{Al
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.61Whiteite-(CaMnMg)
{Ca}{Mn
2+
 
}{Mg
 
2
}{Al
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.62Whiteite-(MnFeMg)
{(Mn
2+
 
,Ca)}{(Fe
2+
 
,Mn
2+
 
)}{Mg
 
2
}{Al
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.63Rittmannite
{(Mn
2+
 
,Ca)}{Mn
2+
 
}{(Fe
2+
 
,Mn
2+
 
,Mg)
 
2
}{(Al,Fe
3+
 
)
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.64Zanazziite
Ca
 
2
Mg
 
5
Be
 
4
(PO
 
4
)
 
6
(OH)
 
4
· 6H
 
2
O
19.12.65Samuelsonite
(Ca,Ba)Ca
 
8
Fe
2+
2
Mn
2+
2
Al
 
2
(PO
 
4
)
 
10
(OH)
 
2
Related Minerals - Dana Grouping):

- +
38.2.9.2Johnsomervilleite
{Ca}{Na
 
6
[ ]
 
2
}{Ca
 
6
Na
 
2
}{(Fe
2+
 
,Mg,Mn
2+
 
)
 
43
}(PO
 
4
)
 
36
38.2.9.3Chladniite
{Ca}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mg,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
38.2.9.4Galileiite
{Fe
2+
 
}{Na
 
8
}{Fe
2+
4
Na
 
4
}{Fe
2+
43
}(PO
 
4
)
 
36
38.2.9.5Stornesite-(Y)
{(Y, Ca)}{Na
 
6
 
2
}{(Ca,Na)
 
8
}{(Mg,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
38.2.9.6Xenophyllite
Na
 
4
Fe
2+
7
(PO
 
4
)
 
6

Other Names for Fillowite

Other Languages:
German:Fillowit
Russian:Филловит
Simplified Chinese:锰磷矿
Spanish:Fillowita
Varieties:
Mg-Fillowite

Other Information

Fluorescence in UV light:Not fluorescent.
Other Information:Soluble in acids.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Fillowite

Reference List:

- +
Brush and Dana (1879) American Journal of Science: 17: 363.

Brush and Dana (1879) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 3: 578.

Brush and Dana (1890) American Journal of Science: 39: 215 (Wells' analysis).

Larsen, E.S. (1921) The Microscopic Determination of the Nonopaque Minerals, First edition, USGS Bulletin 679: 75.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 719-720.

American Mineralogist (1965) 50:1647.

American Mineralogist (1981): 66: 827-842.

Internet Links for Fillowite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Fillowite details from Handbook of Mineralogy (PDF)
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  • Localities for Fillowite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • Manitoba
      • Cross Lake
    Handbook of Mineralogy - Anthony, Bideaux, Bladh, Nichols; The Canadian Mineralogist Vol. 36,pp. 367-376 (1998)
    • Nova Scotia
      • Yarmouth Co.
    Hughes, Steven G., "Internal Zonation and Mineralogy of the Brazil Lake Pegmatite", Unpublished B.Sc. Thesis, Saint Mary's University, Augist 1995.
    China
     
    • Xinjiang Autonomous Region
      • Yili Hasake Autonomous Prefecture (Ili Kazakh Autonomous Prefecture)
        • Aletai Prefecture (Altay Prefecture)
          • Qinghe Co. (Qinggil Co.; Chinggil Co.)
    [var: Mg-Fillowite] Ma Zhesheng, Shi Nicheng, and Ye Danian (2005): Science in China, Series D (Earth Sciences), 48(5), 635-646.
    Rwanda
     
    • Western Province
      • Gatumba District
    Daltry, V.D.C. and O. von Knorring (1998) Type-Mineralogy of Rwanda with Particular Reference to the Buranga Pegmatite. Geologica Belgica 1:1-9
    Can Mineral April 1998 v. 36 no. 2 p. 355-366
    Jaroslav Hyrsl and Excalibur Mineral Co. specimens
    Spain
     
    • Catalonia
      • Girona (Gerona)
        • Alt Empordà
          • Cadaqués
    Bareche, E. (2005) "Els minerals de Catalunya. Segle XX" Ed. Museu Mollfulleda de Mineralogia - Grup Mineralògic Català, 269 p.
    Uganda
     
    • Masaka District
    USA
     
    • Arizona
      • Yavapai Co.
    American Mineralogist (1982): 67: 97-113.
    • Connecticut
      • Fairfield Co.
        • Town of Ridgefield
          • Branchville
    Brush and Dana (1878); American Mineralogist (1946): 31: 329-345; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 720.; Rocks & Minerals (1995) 70:396-409
    • New Hampshire
      • Cheshire Co.
        • Sullivan
    unverified Rob Lavinsky specimen
    • Wisconsin
      • Florence Co.
        • Fern
    The Mineralogy and Geochemistry of the Animikie Red Ace Pegmatite, Florence County, Wisconsin. Alexander U. Falster, Wm. B. Simmons, and Karen L. Webber, Recent Research Developments in Mineralogy, 1(1996); Rocks and Minerals 63:455
    Mineral and/or Locality
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