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Fillowite

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Kiluli, Rwanda
© 2007, JGW

Formula:
{Mn
2+
 
}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mn
2+
 
,Fe
2+
 
)
 
43
}[PO
 
4
]
 
36
System:TrigonalColour:Wax-yellow, yellowish ...
Hardness:
Name:After A.N. Fillow of Branchville, Connecticut, USA, original owner and operator of the Branchville pegmatite and mine, and who first collected the rare manganese phosphates that made the locality famous.

Classification of Fillowite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/A.08-20
Nickel-Strunz 10th (pending) edition ID:8.AC.50

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th edition ID:38.2.9.1
Dana 8th edition ID:38.2.5.1

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
Hey's CIM Ref.:19.12.30

19 : Phosphates
12 : Phosphates of Mn
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Type Occurrence of Fillowite

Type Locality:Abija N. Fillow Quarry (Branchville Quarry), Branchville, Redding, Fairfield Co., Connecticut, USA
Year of Discovery:1879
Geological Setting of type material:Pegmatite
Associated Minerals at type locality:
TriploiditeReddingiteFairfieldite

Physical Properties of Fillowite

Lustre:Resinous, Greasy
Diaphaneity (Transparency):Transparent, Translucent
Comment:Sub-resinous to greasy.
Colour:Wax-yellow, yellowish brown, reddish brown; colourless; colourless to yellow in transmitted light.
Streak:White
Hardness (Mohs):
Tenacity:Brittle
Cleavage:Very Good
On {001}, nearly perfect.
Fracture:Irregular/Uneven
Density (measured):3.43 g/cm3

Crystallography of Fillowite

Crystal System:Trigonal
Class (H-M):3 - Rhombohedral
Space Group:R3
Cell Parameters:a = 15.25Å, c = 4.33Å
Ratio:a:c = 1 : 0.284
Unit Cell Volume:V 872.08 ų (Calculated from Unit Cell)
Z:3
Morphology:Granular crystalline masses.

Optical Data of Fillowite

Type:Uniaxial (+)
RI values: nω = 1.671 nε = 1.676
Maximum Birefringence:δ = 0.005

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High

Chemical Properties of Fillowite

Formula:
{Mn
2+
 
}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mn
2+
 
,Fe
2+
 
)
 
43
}[PO
 
4
]
 
36
Essential elements:Ca, Mn, Na, O, P
All elements listed in formula:Ca, Fe, Mn, Na, O, P

Relationship of Fillowite to other Species

Member of Group:
Fillowite Group:
Related Minerals - Nickel-Strunz Grouping):

- +
8.AC.05Howardevansite
NaCuFe
 
2
(VO
 
4
)
 
3
8.AC.10Alluaudite
(Na,Ca)Mn
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
,Mg)
 
2
(PO
 
4
)
 
3
8.AC.10Arseniopleite
NaCaMn
2+
 
(Mn
2+
 
,Mg)
 
2
(AsO
 
4
)
 
3
8.AC.10Caryinite
(Na,Pb)(Ca,Na)(Ca,Mn
2+
 
)(Mn
2+
 
,Mg,Fe
3+
 
)
 
2
[AsO
 
4
]
 
3
8.AC.10Ferroalluaudite
(Na,Ca)Fe
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)
 
3
8.AC.10Hagendorfite
NaCaMn
2+
 
Fe
2+
2
(PO
 
4
)
 
3
8.AC.10Johillerite
Na(Mg,Zn)
 
3
Cu[AsO
 
4
]
 
3
8.AC.10Maghagendorfite
NaMn(Mg,Fe,Fe)
 
3
(PO
 
4
)
 
3
8.AC.10Nickenichite
Na
 
0.8
Ca
 
0.4
Cu
 
0.4
(Mg,Fe)
 
3
(AsO
 
4
)
 
3
8.AC.10Varulite
NaCaMn
2+
 
Mn
2+
2
(PO
 
4
)
 
3
8.AC.10Ferrohagendorfite
NaCaFe
2+
 
Fe
2+
2
(PO
 
4
)
 
3
8.AC.10Bradaczekite
NaCu
 
4
(AsO
 
4
)
 
3
8.AC.10Yazganite
NaFe
3+
2
(Mg,Mn
2+
 
)[AsO
 
4
]
 
3
· H
 
2
O
8.AC.10IMA2008-054
NaCaMn
 
2
(PO
 
4
)[PO
 
3
(OH)]
 
2
8.AC.10IMA2008-064
Na
 
16
Mn
2+
 
 
25
Al
 
8
(PO
 
4
)
 
30
8.AC.15Bobfergusonite
Na
 
2
Mn
 
5
FeAl(PO
 
4
)
 
6
8.AC.15Ferrowyllieite
(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO
 
4
)
 
3
8.AC.15Qingheiite
NaMn
3+
 
Mg(Al,Fe
3+
 
)[PO
 
4
]
 
3
8.AC.15Rosemaryite
(Na,Ca,Mn)(Mn,Fe
2+
 
)(Fe
3+
 
,Mg)Al(PO
 
4
)
 
3
8.AC.15Wyllieite
(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO
 
4
)
 
3
8.AC.15Ferrorosemaryite
[]NaFe
2+
 
Fe
3+
 
Al(PO
 
4
)
 
3
8.AC.20Marićite
NaFe
2+
 
[PO
 
4
]
8.AC.25Berzeliite
NaCa
 
2
(Mg,Mn
2+
 
)
 
2
[AsO
 
4
]
 
3
8.AC.25Manganberzeliite
(Ca,Na)
 
3
(Mn
2+
 
,Mg)
 
2
[AsO
 
4
]
 
3
8.AC.25Palenzonaite
(Ca,Na)
 
3
CaMn
2+
2
[VO
 
4
]
 
3
8.AC.25Schäferite
Ca
 
2
NaMg
 
2
[VO
 
4
]
 
3
8.AC.30Brianite
Na
 
2
CaMg[PO
 
4
]
 
2
8.AC.35Vitusite-(Ce)
Na
 
3
(Ce,La,Nd)(PO
 
4
)
 
2
8.AC.40Olgite
Ba(NaSr)
 
2
Na[PO
 
4
]
 
2
8.AC.40Bario-olgite
Ba(Na,Sr,REE)
 
2
Na[PO
 
4
]
 
2
8.AC.45Strontiowhitlockite
Sr
 
9
Mg[PO
 
4
]
 
6
[HPO
 
4
]
8.AC.45Whitlockite
Ca
 
9
Mg[PO
 
3
OH][PO
 
4
]
 
6
8.AC.45Merrillite
Ca
 
18
Na
 
2
Mg
2+
2
[PO
 
4
]
 
14
8.AC.45Tuite
Ca
 
3
[PO
 
4
]
 
2
8.AC.45Ferromerrillite
Ca
 
9
Fe
2+
 
Na[PO
 
4
]
 
7
8.AC.45Bobdownsite
Ca
 
9
Mg(PO
 
3
F)(PO
 
4
)
 
6
8.AC.50Chladniite
{Ca}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mg,Fe
2+
 
)
 
43
}[PO
 
4
]
 
36
8.AC.50Johnsomervilleite
{Ca}{Na
 
6
[ ]
 
2
}{Ca
 
6
Na
 
2
}{(Fe
2+
 
,Mg,Mn
2+
 
)
 
43
}[PO
 
4
]
 
36
8.AC.50Galileiite
{Fe
2+
 
}{Na
 
8
}{Fe
2+
4
Na
 
4
}{Fe
2+
43
}[PO
 
4
]
 
36
8.AC.50Stornesite-(Y)
{(Y, Ca)}{Na
 
6
[ ]
 
2
}{(Ca,Na)
 
8
}{(Mg,Fe
2+
 
)
 
43
}[PO
 
4
]
 
36
8.AC.50Xenophyllite
Na
 
4
Fe
2+
7
[PO
 
4
]
 
6
8.AC.55Harrisonite
Ca(Fe
2+
 
,Mg)
 
6
[PO
 
4
|SiO
 
4
]
 
2
8.AC.60Kosnarite
KZr
 
2
(PO
 
4
)
 
3
8.AC.65Panethite
(Na,Ca)
 
2
(Mg,Fe
2+
 
)
 
2
[PO
 
4
]
 
2
8.AC.70Stanfieldite
Ca
 
7
Ca
 
2
Mg
 
9
[PO
 
4
]
 
12
8.AC.75Ronneburgite
K
 
2
MnV
 
4
O
 
12
8.AC.80Tillmannsite
(Ag
 
3
Hg)[(VO
 
4
, AsO
 
4
)]
8.AC.85Filatovite
K[(Al,Zn)
 
2
(As,Si)
 
2
O
 
8
]
Related Minerals - Hey's Index Grouping:

- +
19.12.1Metaswitzerite
Mn
 
3
(PO
 
4
)
 
2
·4H
 
2
O
19.12.2Bermanite
Mn
2+
 
(H
 
2
O)
 
4
[Mn
3+
2
(OH)
 
2
(PO
 
4
)
 
2
]
19.12.3Natrophilite
NaMn
2+
 
[PO
 
4
]
19.12.4Sidorenkite
Na
 
3
Mn
2+
 
[PO
 
4
|CO
 
3
]
19.12.5Niahite
(NH
 
4
)(Mn
2+
 
,Mg)[PO
 
4
] · H
 
2
O
19.12.6Robertsite
Ca
 
3
Mn
3+
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
· 3H
 
2
O
19.12.7Pararobertsite
Ca
 
2
Mn
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
19.12.8Sinkankasite
H
 
2
Mn
2+
 
Al[OH|(PO
 
4
)
 
2
] · 6H
 
2
O
19.12.9Mangangordonite
Mn
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
· 8H
 
2
O
19.12.10Heterosite
(Fe
3+
 
,Mn
3+
 
)[PO
 
4
]
19.12.11Purpurite
(Mn
3+
 
,Fe
3+
 
)[PO
 
4
]
19.12.12Wolfeite
(Fe
2+
 
,Mn
2+
 
)
 
2
[OH|PO
 
4
]
19.12.13Triploidite
(Mn
2+
 
,Fe
2+
 
)
 
2
[OH|PO
 
4
]
19.12.14Lipscombite
(Fe
2+
 
,Mn
2+
 
)Fe
3+
2
[OH|PO
 
4
]
 
2
19.12.15Frondelite
Mn
2+
 
Fe
3+
4
[(OH)
 
5
|(PO
 
4
)
 
3
]
19.12.16Rockbridgeite
Fe
2+
 
Fe
3+
4
[(OH)
 
5
|(PO
 
4
)
 
3
]
19.12.17Kryzhanovskite
MnFe
 
2
(PO
 
4
)
 
2
(OH)
 
2
·H
 
2
O
19.12.18Landesite
Mn
2+
3-x
Fe
3+
x
[(OH)
 
x
|(PO
 
4
)
 
2
] · (3-x)H
 
2
O
19.12.19Phosphoferrite
(Fe,Mn)
 
3
(PO
 
4
)
 
2
·3H
 
2
O
19.12.20Reddingite
(Mn,Fe)
 
3
(PO
 
4
)
 
2
·3H
 
2
O
19.12.21Earlshannonite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
·4H
 
2
O
19.12.22Hureaulite
(Mn,Fe)
 
5
(PO
 
3
OH)
 
2
(PO
 
4
)
 
2
·4H
 
2
O
19.12.23Switzerite
(Mn,Fe)
 
3
(PO
 
4
)
 
2
·7H
 
2
O
19.12.24Laueite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
· 8H
 
2
O
19.12.25Pseudolaueite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
· 8H
 
2
O
19.12.26Strunzite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
· 6H
 
2
O
19.12.27Stewartite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
· 8H
 
2
O
19.12.28Alluaudite
(Na,Ca)Mn
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
,Mg)
 
2
(PO
 
4
)
 
3
19.12.29Ferroalluaudite
(Na,Ca)Fe
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)
 
3
19.12.31Johnsomervilleite
{Ca}{Na
 
6
[ ]
 
2
}{Ca
 
6
Na
 
2
}{(Fe
2+
 
,Mg,Mn
2+
 
)
 
43
}[PO
 
4
]
 
36
19.12.32Wicksite
NaCa
 
2
(Fe
2+
 
,Mn
2+
 
)
 
4
MgFe
3+
 
[PO
 
4
]
 
6
· 2H
 
2
O
19.12.33Dickinsonite-(KMnNa)
{KNa}{Mn
2+
 
[ ]}{Ca}{Na
 
3
}{Mn
2+
13
}{Al}[(OH)
 
2
|(PO
 
4
)
 
12
]
19.12.34Sarcopside
(Fe
2+
 
,Mn
2+
 
,Mg)
 
3
[PO
 
4
]
 
2
19.12.35Ludlamite
(Fe,Mn,Mg)
 
3
(PO
 
4
)
 
2
·4H
 
2
O
19.12.36Graftonite
(Fe
2+
 
,Mn
2+
 
,Ca)
 
3
[PO
 
4
]
 
2
19.12.37Wilhelmvierlingite
CaMnFe
3+
 
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
19.12.38Fairfieldite
Ca
 
2
(Mn
2+
 
,Fe
2+
 
)[PO
 
4
]
 
2
· 2H
 
2
O
19.12.39Beusite
(Mn
2+
 
,Fe
2+
 
,Ca,Mg)
 
3
[PO
 
4
]
 
2
19.12.40Messelite
Ca
 
2
(Fe
2+
 
,Mn
2+
 
)[PO
 
4
]
 
2
· 2H
 
2
O
19.12.41Jahnsite-(CaMnFe)
CaMn
2+
 
Fe
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.42Jahnsite-(CaMnMn)
CaMn
2+
 
Mn
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.43Jahnsite-(CaMnMg)
CaMn
2+
 
(Mg,Fe
2+
 
)
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.44Keckite
CaMnMn
2+
2
Fe
3+
3
(PO
 
4
)
 
4
(OH)
 
3
(H
 
2
O)
 
7
19.12.45Stanfieldite
Ca
 
7
Ca
 
2
Mg
 
9
[PO
 
4
]
 
12
19.12.46Laubmannite
(Fe
2+
 
,Mn
2+
 
,Ca)
 
3
Fe
3+
6
[(OH)
 
3
|PO
 
4
]
 
4
19.12.47Zodacite
Ca
 
4
Mn
2+
 
Fe
3+
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
· 12H
 
2
O
19.12.48Hagendorfite
NaCaMn
2+
 
Fe
2+
2
(PO
 
4
)
 
3
19.12.49Maghagendorfite
NaMn(Mg,Fe,Fe)
 
3
(PO
 
4
)
 
3
19.12.50Varulite
NaCaMn
2+
 
Mn
2+
2
(PO
 
4
)
 
3
19.12.51Griphite
Na
 
4
Li
 
2
Ca
 
6
(Mn
2+
 
,Fe
2+
 
,Mg)
 
19
Al
 
8
[(F,OH)|(PO
 
4
)
 
3
]
 
8
19.12.52Attakolite
(Ca,Sr)Mn(Al,Fe)
 
4
[(OH)
 
4
|(SiO
 
4
,PO
 
4
)|(HPO
 
4
,PO
 
4
)
 
3
]
19.12.53Arrojadite-(KFe)
{KNa}{Fe
2+
 
[ ]}{Ca}{Na
 
2
[ ]}{Fe
2+
13
}{Al}[(OH)
 
2
|HPO
 
4
|(PO
 
4
)
 
11
]
19.12.54Lun'okite
(Mn,Ca)(Mg,Fe,Mn)Al(PO
 
4
)
 
2
OH·4H
 
2
O
19.12.55Eosphorite
(Mn
2+
 
,Fe
2+
 
)Al[(OH)
 
2
|PO
 
4
] · H
 
2
O
19.12.56Ernstite
(Mn
2+
 
,Fe
3+
 
)Al[(OH,O)
 
2
|PO
 
4
] · H
 
2
O
19.12.57Childrenite
(Fe
2+
 
,Mn
2+
 
)Al[(OH)
 
2
|PO
 
4
] · H
 
2
O
19.12.58Bobfergusonite
Na
 
2
Mn
 
5
FeAl(PO
 
4
)
 
6
19.12.59Qingheiite
NaMn
3+
 
Mg(Al,Fe
3+
 
)[PO
 
4
]
 
3
19.12.60Whiteite-(CaFeMg)
Ca(Fe
2+
 
,Mn
2+
 
)Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.61Whiteite-(CaMnMg)
CaMn
2+
 
Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.62Whiteite-(MnFeMg)
(Mn
2+
 
,Ca)(Fe
2+
 
,Mn
2+
 
)Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.63Rittmannite
(Mn
2+
 
,Ca)Mn
2+
 
(Fe
2+
 
,Mn
2+
 
,Mg)
 
2
(Al,Fe
3+
 
)
 
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.64Zanazziite
Ca
 
2
(Mg,Fe)(Mg,Fe,Al)
 
4
Be
 
4
[(OH)
 
4
|(PO
 
4
)
 
6
] · 6H
 
2
O
19.12.65Samuelsonite
(Ca,Ba)Ca
 
8
Fe
2+
2
Mn
2+
2
Al
 
2
[(OH)
 
2
|(PO
 
4
)
 
10
]
Related Minerals - Dana Grouping):

- +
38.2.9.2Johnsomervilleite
{Ca}{Na
 
6
[ ]
 
2
}{Ca
 
6
Na
 
2
}{(Fe
2+
 
,Mg,Mn
2+
 
)
 
43
}[PO
 
4
]
 
36
38.2.9.3Chladniite
{Ca}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mg,Fe
2+
 
)
 
43
}[PO
 
4
]
 
36
38.2.9.4Galileiite
{Fe
2+
 
}{Na
 
8
}{Fe
2+
4
Na
 
4
}{Fe
2+
43
}[PO
 
4
]
 
36
38.2.9.5Stornesite-(Y)
{(Y, Ca)}{Na
 
6
[ ]
 
2
}{(Ca,Na)
 
8
}{(Mg,Fe
2+
 
)
 
43
}[PO
 
4
]
 
36
38.2.9.6Xenophyllite
Na
 
4
Fe
2+
7
[PO
 
4
]
 
6

Other Names for Fillowite

Other Languages:
German:Fillowit
Russian:Филловит
Spanish:Fillowita
Varieties:
Mg-Fillowite

Other Information

Other Information:Soluble in acids.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Fillowite

Reference List:Brush and Dana (1879) American Journal of Science: 17: 363.

Brush and Dana (1879) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 3: 578.

Brush and Dana (1890) American Journal of Science: 39: 215 (Wells' analysis).

Larsen, E.S. (1921) The Microscopic Determination of the Nonopaque Minerals, First edition, USGS Bulletin 679: 75.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 719-720.

American Mineralogist (1981): 66: 827-842.

Internet Links for Fillowite

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    Localities for Fillowite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • Manitoba
      • Cross Lake
    Handbook of Mineralogy - Anthony, Bideaux, Bladh, Nichols; The Canadian Mineralogist Vol. 36,pp. 367-376 (1998)
    China
     
    • Xinjiang (Xinjiang-Uygur) Autonomous Region
      • Yili Hasake (Ili Kazakh) Autonomous Prefecture
        • Aletai (Altay) Prefecture
          • Qinghe (Qinggil; Chinggil) Co.
    [var: Mg-Fillowite] Ma Zhesheng, Shi Nicheng, and Ye Danian (2005): Science in China, Series D (Earth Sciences), 48(5), 635-646.
    Rwanda
     
    • Western Province
      • Gatumba District
    Spain
     
    • Catalonia
      • Girona (Gerona)
        • Alt Empordà
          • Cadaqués
    Bareche, E. (2005) "Els minerals de Catalunya. Segle XX" Ed. Museu Mollfulleda de Mineralogia - Grup Mineralògic Català, 269 p.
    Uganda
     
    • Masaka District
    USA
     
    • Arizona
      • Yavapai Co.
    American Mineralogist (1982): 67: 97-113.
    • Connecticut
      • Fairfield Co.
        • Redding
          • Branchville
    American Mineralogist (1946): 31: 329-345; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 720.
    • New Hampshire
      • Cheshire Co.
        • Sullivan
    unverified Rob Lavinsky specimen
    • Wisconsin
      • Florence Co.
        • Fern
    The Mineralogy and Geochemistry of the Animikie Red Ace Pegmatite, Florence County, Wisconsin. Alexander U. Falster, Wm. B. Simmons, and Karen L. Webber, Recent Research Developments in Mineralogy, 1(1996); Rocks and Minerals 63:455
    Mineral and/or Locality
    Google
     
    www.mindat.org Web
    Copyright © Jolyon Ralph and Ida Chau 1993-2009. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 18th Nov 2009 01:58:18