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Gahnite

Formula:
ZnAl
 
2
O
 
4
System:IsometricColour:Dark blue-green, yellow, ...
Lustre:VitreousHardness:7½ - 8
Name:For Swedish chemist and mineralogist, Johan Gottlieb Gahn (1745-1818).

Classification of Gahnite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:4/B.01-40
Nickel-Strunz 10th (pending) edition ID:4.BB.05

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
B : Metal: Oxygen = 3:4 and similar
B : With only medium-sized cations
Dana 8th edition ID:7.2.1.4

7 : MULTIPLE OXIDES
2 : AB2X4
Hey's CIM Ref.:7.5.5

7 : Oxides and Hydroxides
5 : Oxides of Zn, Cd and Hg
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Type Occurrence of Gahnite

Type Locality:Falu mine, Falun, Dalarna, Sweden
Year of Discovery:1807

Physical Properties of Gahnite

Lustre:Vitreous
Colour:Dark blue-green, yellow, brown, black
Streak:Grey
Hardness (Mohs):7½ - 8
Tenacity:Brittle
Fracture:Irregular/Uneven, Conchoidal
Density (calculated):4.62 g/cm3

Crystallography of Gahnite

Crystal System:Isometric
Class (H-M):m3m (4/m 3 2/m) - Hexoctahedral
Space Group:Fd3m (F41/d 3 2/m)
Cell Parameters:a = 8.062Å
Unit Cell Volume:V 524.00 ų (Calculated from Unit Cell)
Morphology:Crystals usually octahedral.
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data: Peaks:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Gahnite

Type:Isotropic

Chemical Properties of Gahnite

Formula:
ZnAl
 
2
O
 
4
Essential elements:Al, O, Zn
All elements listed in formula:Al, O, Zn
Common Impurities:Fe,Mg

Relationship of Gahnite to other Species

Series:Forms a series with Spinel (see here)
Forms a series with Hercynite (see here)
Related to:
  • Spinel Group
  • Related Minerals - Nickel-Strunz Grouping):

    - +
    4.BB.05Brunogeierite
    (Ge,Fe)Fe
     
    2
    O
     
    4
    4.BB.05Chromite
    FeCr
     
    2
    O
     
    4
    4.BB.05Cochromite
    (Co,Ni,Fe)(Cr,Al)
     
    2
    O
     
    4
    4.BB.05Coulsonite
    FeV
     
    2
    O
     
    4
    4.BB.05Cuprospinel
    Cu
    2+
     
    Fe
    3+
    2
    O
     
    4
    4.BB.05Filipstadite
    (Mn,Mg)
     
    2
    (Sb
     
    .5
    Fe
     
    .5
    )O
     
    4
    4.BB.05Franklinite
    Zn
    2+
     
    Fe
    3+
    2
    O
     
    4
    4.BB.05Galaxite
    (Mn,Fe,Mg)(Al,Fe)
     
    2
    O
     
    4
    4.BB.05Hercynite
    FeAl
     
    2
    O
     
    4
    4.BB.05Jacobsite
    Mn
    2+
     
    Fe
    3+
    2
    O
     
    4
    4.BB.05Manganochromite
    (Mn,Fe)(Cr,V)
     
    2
    O
     
    4
    4.BB.05Magnesiocoulsonite
    MgV
     
    2
    O
     
    4
    4.BB.05Magnesiochromite
    MgCr
     
    2
    O
     
    4
    4.BB.05Magnesioferrite
    MgFe
    3+
    2
    O
     
    4
    4.BB.05Magnetite
    Fe
    2+
     
    Fe
    3+
    2
    O
     
    4
    4.BB.05Nichromite
    (Ni,Co,Fe)(Cr,Fe,Al)
     
    2
    O
     
    4
    4.BB.05Qandilite
    (Mg,Fe)
     
    2
    (Ti,Fe,Al)O
     
    4
    4.BB.05Spinel
    MgAl
     
    2
    O
     
    4
    4.BB.05Trevorite
    Ni
    2+
     
    Fe
    3+
    2
    O
     
    4
    4.BB.05Ulvöspinel
    Fe
     
    2
    TiO
     
    4
    4.BB.05Vuorelainenite
    (Mn,Fe)(V,Cr)
     
    2
    O
     
    4
    4.BB.05Zincochromite
    ZnCr
     
    2
    O
     
    4
    4.BB.10Hausmannite
    MnMn
     
    2
    O
     
    4
    4.BB.10Hetaerolite
    ZnMn
     
    2
    O
     
    4
    4.BB.10Hydrohetaerolite
    ZnMn
     
    2
    O
     
    4
    ·H
     
    2
    O
    4.BB.10Iwakiite
    Mn(Fe,Mn)
     
    2
    O
     
    4
    4.BB.15Maghemite
    Fe
     
    2
    O
     
    3
    4.BB.15Titanomaghemite
    Fe
    3+
     
    (Fe
    3+
     
    ,Ti
    4+
     
    ,Fe
    2+
     
    ,[])
     
    2
    O
     
    4
    4.BB.20Tegengrenite
    (Mg,Mn
    2+
     
    )
     
    2
    Sb
    5+
    0.5
    (Mn
    3+
     
    ,Si,Ti)
     
    0.5
    O
     
    4
    4.BB.25Xieite
    Fe
    2+
     
    Cr
     
    2
    O
     
    4
    Related Minerals - Hey's Index Grouping:

    - +
    7.5.1Zincite
    (Zn,Mn
    2+
     
    ,Fe
    2+
     
    )O
    7.5.2Sweetite
    Zn(OH)
     
    2
    7.5.3Ashoverite
    Zn(OH)
     
    2
    7.5.4Wülfingite
    Zn(OH)
     
    2
    7.5.6Hetaerolite
    ZnMn
     
    2
    O
     
    4
    7.5.7Hydrohetaerolite
    ZnMn
     
    2
    O
     
    4
    ·H
     
    2
    O
    7.5.8Chalcophanite
    (Zn,Fe,Mn)Mn
     
    3
    O
     
    7
    ·3H
     
    2
    O
    7.5.9Woodruffite
    Zn(Mn
    4+
     
    ,Mn
    3+
     
    )
     
    5
    O
     
    10
    ·3½H
     
    2
    O
    7.5.10Franklinite
    Zn
    2+
     
    Fe
    3+
    2
    O
     
    4
    7.5.11Monteponite
    CdO
    7.5.12Montroydite
    HgO

    Other Names for Gahnite

    Synonyms:
    AutomaliteAutomoliteDysluiteFahlunite (of Karsten)Gahnite (of von Moll)
    Spinellus superiusZinc Spinel
    Other Languages:
    French:Spinelle Zincifère
    German:Gahnit
    Automalit
    Automolit
    Zinkspinell
    Italian:Gahnite
    Portuguese:Gahnita
    Russian:Ганит
    Spanish:Automalita
    Automolita
    Gahnita
    Varieties:
    KreittoniteLimaiteManganoan Gahnite

    Other Information

    Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

    References for Gahnite

    Reference List:Palache, Charles, Harry Berman & Clifford Frondel (1944), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Seventh edition, Volume I: 689-697.

    Mineralogical Magazine: 62: 41-54.

    Spry, P.G. (1987) Compositional zoning in zincian spinel. Canadian Mineralogist: 25: 97-104.

    Waerenborgh, J.C., Annersten, H., Ericsson, T., Figueiredo, M.O., and Cabral, J.M.P. (1990) A Mössbauer study of natural gahnite spinels showing strongly temperature dependent quadrupole splitting distributions. European Journal of Mineralogy: 2: 267-271.

    O'Neill, H.St.C. and Dollase, W.A. (1994) Crystal structures and cation distribution in simple spinels from powder XRD structural refinements: MgCr2O4, ZnCr2O4, Fe3O4, and the temperature dependence of the cation distribution in ZnAl2O4. Physics and Chemistry of Minerals: 20: 541-555.

    Internet Links for Gahnite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Gahnite in the Natural History Museum (London) online catalogue
  • Gahnite details from Handbook of Mineralogy (PDF)
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    Localities for Gahnite

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