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Götzenite

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Big Photo

Laach lake volcanic complex, Eifel Mts, Rhineland-Palatinate, Germany
© Stephan Wolfsried

Show Götzenite Photos (16)



Formula:
Na
 
2
Ca
 
5
Ti(Si
 
2
O
 
7
)
 
2
F
 
4
System:TriclinicColour:Very pale yellow, tan, ...
Lustre:Vitreous, GreasyHardness:5½ - 6
Member of:Rosenbuschite Group
Name:
Named for Gustav Adolf von Götzen (1866-1910), German traveler who was the first person to climb Mt. Shaheru, North Kivu, Zaire, the Type Locality for the species.


Rosenbuschite Group.

Classification of Götzenite

IMA status:Approved
Strunz 8th edition ID:8/C.12-10
Nickel-Strunz 10th (pending) edition ID:9.BE.22

9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
Dana 7th edition ID:56.2.5.4
Dana 8th edition ID:56.2.5.4

56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination
Hey's CIM Ref.:17.2.7

17 : Silicates Containing other Anions
2 : Silicates with fluoride
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Type Occurrence of Götzenite

Type Locality:Mt Shaheru, Mt Nyiragongo, Goma, Kivu, Democratic Republic of Congo (Zaïre)
Place of Conservation of Type Material:Smithsonian 142981
Geological Setting of type material:Nephelinite
Associated Minerals at type locality:
Combeite

Occurrences of Götzenite

Geological Setting:hornfels and marble xenoliths

Physical Properties of Götzenite

Lustre:Vitreous, Greasy
Diaphaneity (Transparency):Transparent
Colour:Very pale yellow, tan, off-white, colorless, white.
Streak:White
Hardness (Mohs):5½ - 6
Cleavage:Perfect
Perfect on {100}, good on {001}
Density (measured):3.03 - 3.14 g/cm3
Density (calculated):2.84 g/cm3

Crystallography of Götzenite

Crystal System:Triclinic
Class (H-M):1 - Pinacoidal
Space Group:P1
Cell Parameters:a = 9.667Å, b = 5.731Å, c = 7.334Å
α = 90°, β = 101.05°, γ = 101.31°
Ratio:a:b:c = 1.687 : 1 : 1.28
Unit Cell Volume:V 390.74 ų (Calculated from Unit Cell)
Z:1
Morphology:Prismatic, acicular, skeletal.
Twinning:Lamellar twinning on {001}
ubiquitos

Optical Data of Götzenite

Type:Biaxial (+)
RI values: nα = 1.651 - 1.662 nβ = 1.653 - 1.665 nγ = 1.659 - 1.672
2V:Measured: 38° to 74°, Calculated: 62° to 68°
Maximum Birefringence:δ = 0.008 - 0.010

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r > v strong

Chemical Properties of Götzenite

Formula:
Na
 
2
Ca
 
5
Ti(Si
 
2
O
 
7
)
 
2
F
 
4
Essential elements:Ca, F, Na, O, Si, Ti
All elements listed in formula:Ca, F, Na, O, Si, Ti

Relationship of Götzenite to other Species

Member of:Rosenbuschite Group
Other Members of Group:

- +
Calcian Seidozerite
Na
 
8
CaMn
2+
 
Zr
 
3
Ti
 
3
(Si
 
2
O
 
7
)
 
4
O
 
4
F
 
4
Grenmarite
(Zr,Mn)
 
2
(Zr,Ti)(Mn,Na)(Na,Ca)
 
4
(Si
 
2
O
 
7
)
 
2
(O,F)
 
4
Hainite
Na
 
4
Ca
 
8
(Ti,Zr,Mn)
 
3
(Si
 
2
O
 
7
)
 
4
F
 
4
Kochite
(Na,Ca)
 
3
Ca
 
2
(Mn,Ca)ZrTi(Si
 
2
O
 
7
)
 
2
(F,O)
 
4
Rosenbuschite
(Ca,Na)
 
3
(Zr,Ti)(Si
 
2
O
 
7
)OF
Seidozerite
Na
 
8
Mn
2+
2
Zr
 
3
Ti
 
3
(Si
 
2
O
 
7
)
 
4
O
 
4
F
 
4
Related Minerals - Nickel-Strunz Grouping):

- +
9.BE.02Wadsleyite
(Mg,Fe
2+
 
)
 
2
(SiO
 
4
)
9.BE.05Hennomartinite
SrMn
3+
2
(Si
 
2
O
 
7
)(OH)
 
2
 · H
 
2
O
9.BE.05Lawsonite
CaAl
 
2
(Si
 
2
O
 
7
)(OH)
 
2
 · H
 
2
O
9.BE.05Noelbensonite
BaMn
3+
2
(Si
 
2
O
 
7
)(OH)
 
2
 · H
 
2
O
9.BE.05Itoigawaite
SrAl
 
2
(Si
 
2
O
 
7
)(OH)
 
2
 · H
 
2
O
9.BE.07Ilvaite
CaFe
2+
2
Fe
3+
 
(Si
 
2
O
 
7
)O(OH)
9.BE.07Manganilvaite
Ca(Mn
2+
 
,Fe
2+
 
)
 
2
Fe
3+
 
(Si
 
2
O
 
7
)O(OH)
9.BE.10Suolunite
Ca
 
2
(H
 
2
Si
 
2
O
 
7
) · H
 
2
O
9.BE.12Jaffeite
Ca
 
6
(Si
 
2
O
 
7
)(OH)
 
6
9.BE.15Fresnoite
Ba
 
2
Ti(Si
 
2
O
 
7
)O
9.BE.17Baghdadite
Ca
 
3
(Zr,Ti)(Si
 
2
O
 
7
)O
 
2
9.BE.17Burpalite
Na
 
2
CaZr(Si
 
2
O
 
7
)F
 
2
9.BE.17Cuspidine
Ca
 
4
(Si
 
2
O
 
7
)(F,OH)
 
2
9.BE.17Hiortdahlite
(Ca,Na)
 
3
(Zr,Ti)(Si
 
2
O
 
7
)(O,OH,F)
 
2
9.BE.17Janhaugite
(Na,Ca)
 
3
(Mn
2+
 
,Fe
2+
 
)
 
3
(Ti,Zr,Nb)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH,F)
 
2
9.BE.17Låvenite
(Na,Ca)
 
2
(Mn
2+
 
,Fe
2+
 
)(Zr,Ti)(Si
 
2
O
 
7
)(O,OH,F)
 
2
9.BE.17Niocalite
(Ca,Nb)
 
4
(Si
 
2
O
 
7
)(O,OH,F)
 
2
9.BE.17Normandite
NaCa(Mn,Fe)(Ti,Nb,Zr)(Si
 
2
O
 
7
)OF
9.BE.17Wöhlerite
NaCa
 
2
(Zr,Nb)(Si
 
2
O
 
7
)(O,OH,F)
 
2
9.BE.17Hiortdahlite I
Na
 
4
Ca
 
8
Zr
 
2
(Nb,Mn,Ti,Fe,Mg,Al)
 
2
(Si
 
2
O
 
7
)
 
4
O
 
3
F
 
5
9.BE.17Marianoite
Na
 
2
Ca
 
4
(Nb,Zr)
 
2
(Si
 
2
O
 
7
)
 
2
(O,F)
 
2
9.BE.20Mosandrite
Na
 
2
Ca
 
4
(REE)(Si
 
2
O
 
7
)
 
2
OF
 
3
9.BE.20Nacareniobsite-(Ce)
Na
 
3
Ca
 
3
(Ce,La,Nd)Nb(Si
 
2
O
 
7
)
 
2
OF
 
3
9.BE.22Hainite
Na
 
4
Ca
 
8
(Ti,Zr,Mn)
 
3
(Si
 
2
O
 
7
)
 
4
F
 
4
9.BE.22Rosenbuschite
(Ca,Na)
 
3
(Zr,Ti)(Si
 
2
O
 
7
)OF
9.BE.22Kochite
(Na,Ca)
 
3
Ca
 
2
(Mn,Ca)ZrTi(Si
 
2
O
 
7
)
 
2
(F,O)
 
4
9.BE.23Dovyrenite
Ca
 
6
Zr(Si
 
2
O
 
7
)
 
2
(OH)
 
4
9.BE.25Barytolamprophyllite
(Ba,Na)
 
2
(Na,Ti,Fe
3+
 
)
 
4
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O(OH,F)
9.BE.25Ericssonite
BaMn
2+
2
Fe
3+
 
(Si
 
2
O
 
7
)O(OH)
9.BE.25Lamprophyllite
(Sr,K,Ba)
 
2
(Na,Ti,Mn
2+
 
,Fe
3+
 
)
 
4
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O(O,OH,F)
9.BE.25Ericssonite-2O
BaMn
2+
2
Fe
3+
 
(Si
 
2
O
 
7
)O(OH)
9.BE.25Seidozerite
Na
 
8
Mn
2+
2
Zr
 
3
Ti
 
3
(Si
 
2
O
 
7
)
 
4
O
 
4
F
 
4
9.BE.25Nabalamprophyllite
Na
 
3
(Ba,Na)
 
2
Ti
 
3
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH,F)
 
2
9.BE.25Grenmarite
(Zr,Mn)
 
2
(Zr,Ti)(Mn,Na)(Na,Ca)
 
4
(Si
 
2
O
 
7
)
 
2
(O,F)
 
4
9.BE.27Murmanite
Na
 
2
Ti
 
2
(Si
 
2
O
 
7
)O
 
2
 · 2H
 
2
O
9.BE.30Epistolite
Na
 
2
(Nb,Ti)
 
2
(Si
 
2
O
 
7
)O
 
2
 · nH
 
2
O
9.BE.32Lomonosovite
Na
 
5
Ti
 
2
(Si
 
2
O
 
7
)(PO
 
4
)O
 
2
9.BE.35Vuonnemite
Na
 
11
Ti
4+
 
Nb
 
2
(Si
 
2
O
 
7
)
 
2
(PO
 
4
)
 
2
O
 
3
(F,OH)
9.BE.37Sobolevite
Na
 
13
Ca
 
2
Mn
 
2
Ti
 
3
(Si
 
2
O
 
7
)
 
2
(PO
 
4
)
 
4
O
 
3
F
 
3
9.BE.40Innelite
Na
 
2
CaBa
 
4
Ti
 
3
(Si
 
2
O
 
7
)
 
2
(SO
 
4
)
 
2
O
 
4
9.BE.40Phosphoinnelite
Na
 
3
Ba
 
4
Ti
 
3
(Si
 
2
O
 
7
)
 
2
(PO
 
4
,SO
 
4
)
 
2
O
 
2
F
9.BE.42Yoshimuraite
Ba
 
2
Mn
 
2
Ti(Si
 
2
O
 
7
)(PO
 
4
)O(OH)
9.BE.45Quadruphite
Na
 
14
Ca
 
2
Ti
 
4
(Si
 
2
O
 
7
)
 
2
(PO
 
4
)
 
2
O
 
2
F
9.BE.47Polyphite
Na
 
5
(Na
 
4
Ca
 
2
)Ti
 
2
(Si
 
2
O
 
7
)(PO
 
4
)
 
3
O
 
2
F
 
2
9.BE.50Bornemanite
Na
 
6
BaTi
 
2
Nb(Si
 
2
O
 
7
)
 
2
(PO
 
4
)O
 
2
(OH)F
9.BE.50Shkatulkaite
Na
 
10
Mn
2+
 
Ti
 
3
Nb
 
3
(Si
 
2
O
 
7
)
 
6
(OH)
 
2
F · 12H
 
2
O
9.BE.55Bafertisite
Ba(Fe
3+
 
,Mn
2+
 
)
 
2
Ti(Si
 
2
O
 
7
)O(O,OH)
 
2
9.BE.55Hejtmanite
Ba(Mn
2+
 
,Fe
2+
 
)
 
2
Ti(Si
 
2
O
 
7
)O(OH,F)
9.BE.55Bykovaite
(Ba,Na,K)
 
2
(Na,Ti,Mn)
 
4
(Ti,Nb)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
(H
 
2
O,F,OH)
 
2
 · 3.5H
 
2
O
9.BE.55Nechelyustovite
(Ba,Sr,K)
 
2
(Na,Ti,Mn)
 
4
(Ti,Nb)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
(O,H
 
2
O,F)
 
2
 · 4.5H
 
2
O
9.BE.60Delindeite
(Na,K)
 
2
(Ba,Ca)
 
2
(Ti,Fe,Al)
 
3
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH)
 
2
 · 2H
 
2
O
9.BE.65Bussenite
Na
 
2
Ba
 
2
Fe
2+
 
Ti(Si
 
2
O
 
7
)(CO
 
3
)(OH)
 
3
F
9.BE.67Jinshajiangite
BaNaFe
2+
4
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH)
 
2
F
9.BE.67Perraultite
BaNaMn
2+
4
Ti
 
2
 (Si
 
2
O
 
7
)
 
2
O
 
2
(OH)
 
2
F
9.BE.67Surkhobite
NaCaBa
 
2
Mn
 
8
Ti
 
4
(Si
 
2
O
 
7
)
 
4
O
 
5
F
 
5
9.BE.70Karnasurtite-(Ce)
(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si
 
2
O
 
7
)(OH)
 
4
 · 3H
 
2
O
9.BE.70Perrierite-(Ce)
(Ce,Ca,Th)
 
4
(Fe
2+
 
,Mg)Fe
3+
2
(Ti,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Strontiochevkinite
(Sr,La,Ce,Ca)
 
4
Fe
2+
 
(Ti,Zr)
 
2
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Chevkinite-(Ce)
(Ce,La,Ca,Th)
 
4
(Fe
2+
 
,Mg)(Fe
2+
 
,Ti,Fe
3+
 
)
 
2
(Ti,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Polyakovite-(Ce)
(Ce,Ca)
 
4
(Mg,Fe
2+
 
)(Cr
3+
 
,Fe
3+
 
)
 
2
(Ti,Nb)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Rengeite
Sr
 
4
ZrTi
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Matsubaraite
Sr
 
4
Ti
 
5
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Dingdaohengite-(Ce)
(Ce,La)
 
4
Fe
2+
 
(Ti,Fe
2+
 
,Mg,Fe
2+
 
)
 
2
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Maoniupingite-(Ce)
(Ce,Ca)
 
4
(Fe
3+
 
,Ti,Fe
2+
 
,◻)(Ti,Fe
3+
 
,Fe
2+
 
,Nb)
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Perrierite-(La)
(La,Ce,Ca)
 
4
(Fe,Mn
2+
 
,Mg)Fe
3+
2
(Ti,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70UKI-2008-(SiO:SrTiZr)
Sr
 
4
ZrTi
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Hezuolinite
(Sr,REE)
 
4
Zr(Ti,Fe
3+
 
)
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.72Fersmanite
Ca
 
4
(Na,Ca)
 
4
(Ti,Nb)
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
F
 
3
9.BE.75Belkovite
Ba
 
3
(Nb,Ti)
 
6
(Si
 
2
O
 
7
)
 
2
O
 
12
9.BE.77Nasonite
Pb
 
6
Ca
 
4
(Si
 
2
O
 
7
)
 
3
Cl
 
2
9.BE.80Kentrolite
Pb
 
2
Mn
3+
2
(Si
 
2
O
 
7
)O
 
2
9.BE.80Melanotekite
Pb
 
2
Fe
3+
2
(Si
 
2
O
 
7
)O
 
2
9.BE.82Tilleyite
Ca
 
5
(Si
 
2
O
 
7
)(CO
 
3
)
 
2
9.BE.85Killalaite
Ca
 
3
(Si
 
2
O
 
7
) · 0.5H
 
2
O
9.BE.87Stavelotite-(La)
(La,Nd,Ca)
 
3
Mn
2+
3
Cu(Mn
3+
 
,Fe
3+
 
,Mn
4+
 
)
 
26
(Si
 
2
O
 
7
)
 
6
O
 
5
9.BE.90Biraite-(Ce)
Ce
 
2
Fe
2+
 
(Si
 
2
O
 
7
)(CO
 
3
)
9.BE.92Cervandonite-(Ce)
(Ce,Nd,La)(Fe
3+
 
,Fe
2+
 
,Ti,Al)
 
3
O
 
2
(Si
 
2
O
 
7
)(As
3+
 
O
 
3
)(OH)
9.BE.95Batisivite
BaV
3+
8
Ti
 
6
(Si
 
2
O
 
7
)O
 
22
Related Minerals - Hey's Index Grouping:

- +
17.2.1Topaz
Al
 
2
(SiO
 
4
)(F,OH)
 
2
17.2.2Polylithionite
KLi
 
2
Al(Si
 
4
O
 
10
)(F,OH)
 
2
17.2.3Leifite
(Na,H
 
2
O)Na
 
6
[F
 
2
|Be
 
2
Al
 
2
(Al,Si)Si
 
15
O
 
39
]
17.2.5Meliphanite
(Ca,Na)
 
2
(Be,Al)[Si
 
2
O
 
6
(OH,F)]
17.2.6Sarcolite
Na
 
2
Ca
 
12
(Ca,K,Fe,Sr,Mg)
 
2
Al
 
8
Si
 
12
(P,Si)O
 
52
F
 
2
17.2.8Kuliokite-(Y)
Y
 
4
Al(SiO
 
4
)
 
2
(OH)
 
2
F
 
5
17.2.9Zinnwaldite
KLiFe
2+
 
Al(AlSi
 
3
O
 
10
)(F,OH)
 
2
17.2.10Magbasite
KBa(Al,Sc)(Mg,Fe)
 
6
Si
 
6
O
 
20
F
 
2
17.2.11Eckermannite
[Na][Na
 
2
][(Mg,Fe
2+
 
)
 
4
Al]Si
 
8
O
 
22
(OH)
 
2

Other Names for Götzenite

Synonyms:
Calcium-RinkiteGoetzenite
Other Languages:
German:Götzenit
Russian:Гётценит
Spanish:Götzenita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Götzenite

Reference List:

- +
Soviet Physics – Crystallography: 16: 1167-1172.

Internet Links for Götzenite

Search Engines:
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    • External Links:
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  • Look for Götzenite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Götzenite details from Handbook of Mineralogy (PDF)
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    • Localities for Götzenite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • Québec
      • Montérégie
        • Rouville RCM
          • Mont Saint-Hilaire
    		Horváth, L and Gault, R.A. (1990), The mineralogy of Mont Saint-Hilaire Quebec. Mineralogical Record: 21: 284-359.
    Democratic Republic of Congo (Zaïre)
     
    • Kivu
    		Berger, V.I., Singer, D.A., and Orris, G.J. (2009): USGS Open-File Report 09-1139
      • Goma
        • Mt Nyiragongo
    		NJMM (2000), 496; Mineralogical Magazine 1957 31 : 698-699.
    Germany
     
    • Baden-Württemberg
      • Kaiserstuhl
        • Bötzingen
    		No reference listed
    • Rhineland-Palatinate
      • Eifel Mts
        • Daun
          • Schalkenmehren
    		[MinRec 32:499]
          • Üdersdorf
    		Hentschel, G., Die Minerale der Üdersdorfer Lava, Lapis, Weise Verlag, München, 11/1989
        • Laach lake volcanic complex
          • Kruft
    		Blass, G., Götzenit als Neufund in einem sanidinitischen Auswürfling des Laacher-See-Vulkans, Mineralien-Welt 2/6, 76-78, 1991
          • Mendig
            • Niedermendig
    		Blass, G., Götzenit als Neufund in einem sanidinitischen Auswürfling des Laacher-See-Vulkans, Mineralien-Welt 2/6, 76-78, 1991
    Blass, G., Götzenit als Neufund in einem sanidinitischen Auswürfling des Laacher-See-Vulkans, Mineralien-Welt 2/6, 76-78, 1991
              • Wingertsberg Mt.
    		Blass, G., Götzenit als Neufund in einem sanidinitischen Auswürfling des Laacher-See-Vulkans, Mineralien-Welt 2/6, 76-78, 1991
    Greenland
     
    • Tunu (East Greenland) Province
    		Christiansen, C.C. & Johnsen, O. (2003): Crystal chemistry of the Rosenbuschite group. Canadian Mineralogist. 41: 1203-1224
    Italy
     
    • Umbria
      • Terni Province
        • Marsciano
          • San Venanzo
    		Stoppa, F., Sharygin, V.V., and Cundari, A. (1997): Mineralogy and Petrology 61, 27-45.; F. Stoppa and Y. Liu, Eur. J. Mineral. , 1995, 7, pp. 391-402.
    Kenya
     
    • Nyanza Province
    		Berger, V.I., Singer, D.A., and Orris, G.J. (2009): USGS Open-File Report 09-1139
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Khibiny Massif
            • Eveslogchorr Mt
    		Pavel M. Kartashov analytical data
    www.koeln.netsurf.de/~w.steffens/lovo.htm
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