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Hainite

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Formula:
Na4Ca8(Ti,Zr,Mn)3(Si2O7)4F4
System:
Triclinic
Hardness:
5
Name:
For the type locality.
Rosenbuschite Group.

Long regarded as a doubtful species, said to be related to Rosenbuschite, but an independent species after all (Christiansen et al., 2003). The crystal structure of the type material has been determined by Giester et al. (2005).

Classification of Hainite

Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
9.BE.22

9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
56.2.4.9

56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination
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First Recorded Occurrence of Hainite

Year of Discovery:
1893
Associated Minerals at First Recorded Locality:

Physical Properties of Hainite

Hardness (Mohs):
5

Crystallography of Hainite

Crystal System:
Triclinic
Cell Parameters:
a = 9.594Å, b = 5.702Å, c = 7.288Å
α = 89.89°, β = 101.09°, γ = 101.17°
Ratio:
a:b:c = 1.683 : 1 : 1.278
Unit Cell Volume:
V 383.55 ų

Optical Data of Hainite

Type:
Biaxial (+)
Dispersion:
relatively strong

Chemical Properties of Hainite

Formula:
Na4Ca8(Ti,Zr,Mn)3(Si2O7)4F4
Essential elements:
All elements listed in formula:
Common Impurities:
Al,La,Ce,Fe,Nb,Ta

Relationship of Hainite to other Species

Other Members of Group:
Calcian SeidozeriteNa8CaMn2+Zr3Ti3(Si2O7)4O4F4
GötzeniteNa2Ca5Ti(Si2O7)2F4
Grenmarite(Na,Ca)4(Mn,Na)(Zr,Mn)2(Zr,Ti)(Si2O7)2(O,F)4
Kochite(Na,Ca)3Ca2(Mn,Ca)ZrTi(Si2O7)2(F,O)4
Rosenbuschite(Ca,Na)3(Zr,Ti)(Si2O7)OF
SeidozeriteNa8Mn22+Zr3Ti3(Si2O7)4O4F4
9.BE.02Wadsleyite(Mg,Fe2+)2(SiO4)
9.BE.05HennomartiniteSrMn23+(Si2O7)(OH)2 · H2O
9.BE.05LawsoniteCaAl2(Si2O7)(OH)2 · H2O
9.BE.05NoelbensoniteBaMn23+(Si2O7)(OH)2 · H2O
9.BE.05ItoigawaiteSrAl2(Si2O7)(OH)2 · H2O
9.BE.07IlvaiteCaFe22+Fe3+(Si2O7)O(OH)
9.BE.07ManganilvaiteCa(Mn2+,Fe2+)2Fe3+(Si2O7)O(OH)
9.BE.10SuoluniteCa2(H2Si2O7) · H2O
9.BE.12JaffeiteCa6(Si2O7)(OH)6
9.BE.15FresnoiteBa2Ti(Si2O7)O
9.BE.17BaghdaditeCa3(Zr,Ti)(Si2O7)O2
9.BE.17BurpaliteNa2CaZr(Si2O7)F2
9.BE.17CuspidineCa4(Si2O7)(F,OH)2
9.BE.17Hiortdahlite(Ca,Na)3(Zr,Ti)(Si2O7)(O,OH,F)2
9.BE.17Janhaugite(Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2
9.BE.17Låvenite(Na,Ca)2(Mn2+,Fe2+)(Zr,Ti)(Si2O7)(O,OH,F)2
9.BE.17Niocalite(Ca,Nb)4(Si2O7)(O,OH,F)2
9.BE.17NormanditeNaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OF
9.BE.17WöhleriteNaCa2(Zr,Nb)(Si2O7)(O,OH,F)2
9.BE.17Hiortdahlite INa4Ca8Zr2(Nb,Mn,Ti,Fe,Mg,Al)2(Si2O7)4O3F5
9.BE.17MarianoiteNa2Ca4(Nb,Zr)2(Si2O7)2(O,F)4
9.BE.20Mosandrite(◻,Ca,Na)3(Ca,REE)4Ti(Si2O7)2[H2O,OH,F]4 · H2O
9.BE.20Nacareniobsite-(Ce)Na3Ca3(Ce,La,Nd)Nb(Si2O7)2OF3
9.BE.22GötzeniteNa2Ca5Ti(Si2O7)2F4
9.BE.22Rosenbuschite(Ca,Na)3(Zr,Ti)(Si2O7)OF
9.BE.22Kochite(Na,Ca)3Ca2(Mn,Ca)ZrTi(Si2O7)2(F,O)4
9.BE.23DovyreniteCa6Zr(Si2O7)2(OH)4
9.BE.25Barytolamprophyllite(Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F)
9.BE.25EricssoniteBaMn22+Fe3+(Si2O7)O(OH)
9.BE.25Lamprophyllite(Sr,K,Ba)2(Na,Ti,Mn2+,Fe3+)4Ti2(Si2O7)2O(O,OH,F)
9.BE.25Ericssonite-2OBaMn22+Fe3+(Si2O7)O(OH)
9.BE.25SeidozeriteNa8Mn22+Zr3Ti3(Si2O7)4O4F4
9.BE.25NabalamprophylliteNa3(Ba,Na)2Ti3(Si2O7)2O2(OH,F)2
9.BE.25Grenmarite(Na,Ca)4(Mn,Na)(Zr,Mn)2(Zr,Ti)(Si2O7)2(O,F)4
9.BE.25SchülleriteBa2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4
9.BE.25LileyiteBa2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2
9.BE.27MurmaniteNa2Ti2(Si2O7)O2 · 2H2O
9.BE.30EpistoliteNa2(Nb,Ti)2(Si2O7)O2 · nH2O
9.BE.32LomonosoviteNa5Ti2(Si2O7)(PO4)O2
9.BE.35VuonnemiteNa11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH)
9.BE.37SoboleviteNa13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3
9.BE.40InneliteNa2CaBa4Ti3(Si2O7)2(SO4)2O4
9.BE.40PhosphoinneliteNa3Ba4Ti3(Si2O7)2(PO4,SO4)2O2F
9.BE.42YoshimuraiteBa2Mn2Ti(Si2O7)(PO4)O(OH)
9.BE.45QuadruphiteNa14Ca2Ti4(Si2O7)2(PO4)2O2F
9.BE.47PolyphiteNa5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2
9.BE.50BornemaniteNa6BaTi2Nb(Si2O7)2(PO4)O2(OH)F
9.BE.50ShkatulkaliteNa10Mn2+Ti3Nb3(Si2O7)6(OH)2F · 12H2O
9.BE.55BafertisiteBa(Fe2+,Mn2+)2Ti(Si2O7)O(F,OH)2
9.BE.55HejtmaniteBa(Mn2+,Fe2+)2Ti(Si2O7)O(OH,F)
9.BE.55Bykovaite(Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2O
9.BE.55Nechelyustovite(Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2O
9.BE.60Delindeite(Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2O
9.BE.65BusseniteNa2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3F
9.BE.67JinshajiangiteBaNaFe42+Ti2(Si2O7)2O2(OH)2F
9.BE.67PerraultiteBaNaMn42+Ti2 (Si2O7)2O2(OH)2F
9.BE.67SurkhobiteNaCaBa2Mn8Ti4(Si2O7)4O5F5
9.BE.70Karnasurtite-(Ce)(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2O
9.BE.70Perrierite-(Ce)(Ce,Ca,Th)4(Fe2+,Mg)Fe23+(Ti,Fe3+)2(Si2O7)2O8
9.BE.70Strontiochevkinite(Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8
9.BE.70Chevkinite-(Ce)(Ce,La,Ca,Th)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8
9.BE.70Polyakovite-(Ce)(Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8
9.BE.70RengeiteSr4ZrTi4(Si2O7)2O8
9.BE.70MatsubaraiteSr4Ti5(Si2O7)2O8
9.BE.70Dingdaohengite-(Ce)(Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe2+)2Ti2(Si2O7)2O8
9.BE.70Maoniupingite-(Ce)(Ce,Ca)4(Fe3+,Ti,Fe2+,◻)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8
9.BE.70Perrierite-(La)(La,Ce,Ca)4(Fe,Mn2+,Mg)Fe23+(Ti,Fe3+)2(Si2O7)2O8
9.BE.70UKI-2008-(SiO:SrTiZr)Sr4ZrTi4(Si2O7)2O8
9.BE.70Hezuolinite(Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8
9.BE.72FersmaniteCa4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3
9.BE.75BelkoviteBa3(Nb,Ti)6(Si2O7)2O12
9.BE.77NasonitePb6Ca4(Si2O7)3Cl2
9.BE.80KentrolitePb2Mn23+(Si2O7)O2
9.BE.80MelanotekitePb2Fe23+(Si2O7)O2
9.BE.82TilleyiteCa5(Si2O7)(CO3)2
9.BE.85KillalaiteCa6.4(H0.6Si2O7)2(OH)2
9.BE.87Stavelotite-(La)(La,Nd,Ca)3Mn32+Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O5
9.BE.90Biraite-(Ce)Ce2Fe2+(Si2O7)(CO3)
9.BE.92Cervandonite-(Ce)(Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH)
9.BE.95BatisiviteBaV83+Ti6(Si2O7)O22

Other Names for Hainite

Name in Other Languages:

Other Information

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Hainite

Reference List:
Blumrich, J. (1893): Die Phonolithe des Friedländer Bezirkes in Nordböhmen, Zeitschrift für Kristallographie, Mineralogie und Petrographie, Vol. 13, No 6, 465-495

Crystallography Reports: 40: 574-578.

Johan, Z. & Cech, F. (1989): New data on hainite, Na2Ca4((Ti,Zr,Mn,Fe,Nb,Ta)1.500.50)(Si2O7)2F4 and its crystallochemical relationship with götzenite, Na2Ca5Ti(Si2O7)2F4. Comptes Rendus de l'Academie des Sciences, Série II, 308, 1237-1242 (in French).

Atencio, D., Coutinho, J. M. V., Ulbrich, M. N. C., Vlach, S. R. F., Rastsvetaeva, R. K. & Pushcharovsky, D. Y. (1999). Hainite from Poços de Caldas, Minas Gerais, Brazil. Canadian Mineralogist, 37, 91-98.

Christiansen, C.C., Johnsen, O., and Makovicky, E. (2003): Crystal chemistry of the rosenbuschite group. Canadian Mineralogist 41, 1203-1224.

Giester, G., Pertlik, F. & Ulrych, J. (2005): Die Kristallstruktur des Minerals Hainit. Mitt. Österr. Mineral. Ges. 151, 45. (in German) [Poster abstract]


Internet Links for Hainite

Localities for Hainite

map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
(TL) indicates type locality for a valid mineral species. (FRL) indicates first recorded locality for everything else. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
Brazil
 
  • Minas Gerais
Atencio, D., Coutinho, J. M. V., Ulbrich, M. N. C., Vlach, S. R. F., Rastsvetaeva, R. K., & Pushcharovsky, D. Y. (1999). Hainite from Poços de Caldas, Minas Gerais, Brazil. The Canadian Mineralogist, 37, 91-98.
      • Poços de Caldas
ATENCIO, D., COUTINHO, J.M.C., ULBRICH, M.N.C., VLACH, S.R.F., RASTVETAEVA, R.K. & PUSHCHAROVSKY, D.Yu. (1999) Hainite from Poços de Caldas, Minas Gerais, Brazil. Canadian Mineralogist, 37, 91-98.
Atencio et al (1999) Can. Min. 37, 91-98
Czech Republic
 
  • Bohemia (Böhmen; Boehmen)
    • Liberec Region
      • Jizerské Mtn (Iser Mtn)
Johan, Z. & Cech, F. (1989): New data on hainite, Na2Ca4((Ti,Zr,Mn,Fe,Nb,Ta)1.500.50)(Si2O7)2F4 and its crystallochemical relationship with götzenite, Na2Ca5Ti(Si2O7)2F4. Comptes Rendus de l'Academie des Sciences, Série II, 308, 1237-1242 (in French).; Blumrich, J. (1893): Die Phonolithe des Friedländer Bezirkes in Nordböhmen, Zeitschrift für Kristallographie, Mineralogie und Petrographie, Vol. 13, No 6, 465-495
    • Ústí Region
      • Most
        • Želenice
Pazdernik, P.: Compositional variations in the sodalite-bearing nephelinite phonolite from Želenický vrch Hill, North Bohemia. Acta Universitatis Carolinae – Geologica, 1997, vol. 42, no. 2, pp. 65-79.
Norway
 
  • Vestfold
    • Larvik
      • Langesundsfjorden
Christiansen, C.C. & Johnsen, O. (2003): Crystal chemistry of the Rosenbuschite group. Canadian Mineralogist. 41: 1203-1224
Christiansen, C.C. & Johnsen, O. (2003): Crystal chemistry of the Rosenbuschite group. Canadian Mineralogist. 41: 1203-1224; Larsen, A. O. (ed.) (2010): The Langesundsfjord. History, geology, pegmatites, minerals. Bode Verlag Gmbh, Salzhemmendorf, Germany, 240p
Andersen, T., Erambert, M., Larsen, A.O. & Selbekk, R.S. (2012): Petrology of nepheline syenite pegmatites in the Oslo Rift, Norway: Zr and Ti mineral assemblages in miaskitic and agpaitic pegmatites in the Larvik Plutonic Complex. Mineralogia Polonica. 43 (2), 3- 34
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