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Epidote-(Pb)

Formula:
{CaPb}{Al
 
3
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
System:MonoclinicColour:Dark brick-red (TL), ...
Hardness:6 - 7


Epidote Group

Called Hancockite for decades; renamed by the Epidote Subcommittee of the CNMMN in 2006.

Classification of Epidote-(Pb)

IMA status:Approved 2006
Strunz 8th edition ID:8/C.23-90
Nickel-Strunz 10th (pending) edition ID:9.BG.05

9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
Dana 8th edition ID:58.2.1a.8

58 : SOROSILICATES Insular, Mixed, Single, and Larger Tetrahedral Groups
2 : Insular, Mixed, Single, and Larger Tetrahedral Groups with cations in [6] and higher coordination; single and double groups (n = 1, 2)
Hey's CIM Ref.:16.14.16

16 : Silicates Containing Aluminum and other Metals
14 : Aluminosilicates of Ti, Zr, Sn and Pb
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Type Occurrence of Epidote-(Pb)

Type Locality:Franklin Mine, Franklin, Franklin Mining District, Sussex Co., New Jersey, USA
Year of Discovery:1899
Associated Minerals at type locality:
WillemiteHendricksiteAndradite

Physical Properties of Epidote-(Pb)

Lustre:Vitreous, Dull
Diaphaneity (Transparency):Transparent, Translucent, Opaque
Colour:Dark brick-red (TL), greenish-brown, yellow-brown
Hardness (Mohs):6 - 7

Crystallography of Epidote-(Pb)

Crystal System:Monoclinic
Cell Parameters:a = 9.03Å, b = 5.62Å, c = 10.29Å
β = 115.93°
Ratio:a:b:c = 1.607 : 1 : 1.831
Unit Cell Volume:V 469.63 ų (Calculated from Unit Cell)
Structure
  Reference
Dollase W A (1971) Refinement of the crystal structures of epidote, allanite and hancockite. American Mineralogist 56:447-464.

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More Crystal Structures
Click here to view more crystal structures at the American Mineralogist Crystal Structure Database

Optical Data of Epidote-(Pb)

Type:Biaxial (-)
RI values: nα = 1.790 nβ = 1.810 nγ = 1.830
2V:Measured: 50° , Calculated: 88°
Maximum Birefringence:δ = 0.040

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:r > v perceptible

Chemical Properties of Epidote-(Pb)

Formula:
{CaPb}{Al
 
3
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
Essential elements:Al, H, O, Pb, Si
All elements listed in formula:Al, Ca, H, O, Pb, Si
Common Impurities:Ca,Sr,Fe,Ti,Mn,Mg,Ba

Relationship of Epidote-(Pb) to other Species

Related to:
  • Epidote Group
  • Related Minerals - Nickel-Strunz Grouping):
    9.BG.05Allanite-(Ce)
    {CaCe}{Al
     
    2
    Fe
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Allanite-(La)
    {CaLa}{Al
     
    2
    Fe
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Allanite-(Y)
    {CaY}{Al
     
    2
    Fe
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Clinozoisite
    {Ca
     
    2
    }{Al
     
    3
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Dissakisite-(Ce)
    {CaCe}{Al
     
    2
    Mg}[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Dollaseite-(Ce)
    {CaCe}{MgAlMg}[F|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Epidote
    {Ca
     
    2
    }{Al
     
    2
    Fe
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Khristovite-(Ce)
    {CaCe}{MgAlMn
    2+
     
    }[F|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Mukhinite
    {Ca
     
    2
    }{Al
     
    2
    V
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Piemontite
    {Ca
     
    2
    }{Al
     
    2
    Mn
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Piemontite-(Sr)
    {CaSr}{Al
     
    2
    Mn
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Manganiandrosite-(La)
    {LaMn
    2+
     
    }{Mn
    3+
     
    AlMn
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Tawmawite
    Ca
     
    2
    (Al,Fe
    3+
     
    ,Cr)
     
    3
    [O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Manganipiemontite-(Sr)
    {CaSr}{Mn
    3+
     
    AlMn
    3+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Ferriallanite-(Ce)
    {CaCe}{Fe
    3+
     
    AlFe
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Clinozoisite-(Sr)
    CaSrAl
     
    3
    (Si
     
    2
    O
     
    7
    )(SiO
     
    4
    )O(OH)
    9.BG.05Ferriepidote
    9.BG.05Manganiandrosite-(Ce)
    (Mn
    2+
     
    ,Ca)(Ce,REE)AlMn
    3+
     
    Mn
    2+
     
    (Si
     
    2
    O
     
    7
    )(SiO
     
    4
    )O(OH)
    9.BG.05Dissakisite-(La)
    {CaLa}{Al
     
    2
    Mg}[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Vanadoandrosite-(Ce)
    {Mn
    2+
     
    Ce}{V
    3+
     
    AlMn
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05Androsite-(La)
    9.BG.05Uedaite-(Ce)
    {Mn
    2+
     
    Ce}{Al
     
    2
    Fe
    2+
     
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.05IMA2006-055
    CaSrAl
     
    2
    Fe
    3+
     
    (Si
     
    2
    O
     
    7
    )(SiO
     
    4
    )O(OH)
    9.BG.10Zoisite
    {Ca
     
    2
    }{Al
     
    3
    }[O|OH|SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.15Macfallite
    Ca
     
    2
    (Mn
    3+
     
    ,Al)
     
    3
    [(OH)
     
    3
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.15Sursassite
    Mn
     
    2
    Al
     
    3
    [(OH)
     
    3
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ]
    9.BG.20Julgoldite-(Fe2+)
    Ca
     
    2
    (Fe
    2+
     
    ,Mg)(Fe
    3+
     
    ,Al)
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Okhotskite
    Ca
     
    8
    (Mn,Mg)
     
    4
    (Mn,Al,Fe)
     
    8
    Si
     
    12
    O
     
    56-n
    (OH)
     
    n
    9.BG.20Pumpellyite-(Fe2+)
    Ca
     
    2
    Fe
    2+
     
    Al
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Pumpellyite-(Fe3+)
    Ca
     
    2
    (Fe
    3+
     
    ,Mg,Fe
    2+
     
    )(Al,Fe
    3+
     
    )
     
    2
    [(OH,O)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Pumpellyite-(Mg)
    Ca
     
    2
    MgAl
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Pumpellyite-(Mn2+)
    Ca
     
    2
    (Mn
    2+
     
    ,Mg)(Al,Mn
    3+
     
    ,Fe
    3+
     
    )
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Shuiskite
    Ca
     
    2
    (Mg,Al)(Cr,Al)
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · 2H
     
    2
    O
    9.BG.20Julgoldite-(Fe3+)
    Ca
     
    2
    (Fe
    3+
     
    ,Mg)(Fe
    3+
     
    ,Al)
     
    2
    [(OH,O)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Pumpellyite-(Al)
    Ca
     
    2
    (Al,Fe
    2+
     
    ,Mg)Al
     
    2
    [(OH,O)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Poppiite
    Ca
     
    2
    (V
    3+
     
    ,Fe
    3+
     
    ,Mg)(V
    3+
     
    ,Al)
     
    2
    [(OH,O)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.20Julgoldite-(Mg)
    Ca
     
    2
    (Mg,Fe
    2+
     
    )(Fe
    3+
     
    ,Al)
     
    2
    [(OH)
     
    2
    |SiO
     
    4
    |Si
     
    2
    O
     
    7
    ] · H
     
    2
    O
    9.BG.25Ganomalite
    Pb
     
    9
    Ca
     
    5
    Mn[O|SiO
     
    4
    |(Si
     
    2
    O
     
    7
    )
     
    4
    ]
    9.BG.30Rustumite
    Ca
     
    10
    (Si
     
    2
    O
     
    7
    )
     
    2
    (SiO
     
    4
    )Cl
     
    2
    (OH)
     
    2
    9.BG.35Vesuvianite
    Ca
     
    10
    (Mg,Fe)
     
    2
    Al
     
    4
    Si
     
    9
    O
     
    34
    (OH)
     
    4
    9.BG.35Wiluite
    Ca
     
    19
    (Al,Mg,Fe,Ti)
     
    13
    (B,Al,[ ])
     
    5
    Si
     
    18
    O
     
    68
    (O,OH)
     
    10
    9.BG.35Manganvesuvianite
    Ca
     
    19
    Mn(Al,Mn,Fe)
     
    19
    (Mg,Mn)
     
    2
    Si
     
    18
    O
     
    69
    (OH)
     
    9
    9.BG.35Fluorvesuvianite
    Ca
     
    19
    (Al,Mg,Fe
    2+
     
    )
     
    13
    [(F,OH,O)
     
    10
    |(SiO
     
    4
    )
     
    10
    |(Si
     
    2
    O
     
    7
    )
     
    4
    ]
    9.BG.40Vyuntspakhkite-(Y)
    Y
     
    4
    Al
     
    3
    Si
     
    5
    O
     
    18
    (OH)
     
    5
    9.BG.45Dellaite
    Ca
     
    6
    Si
     
    3
    O
     
    11
    (OH)
     
    2
    9.BG.50Gatelite-(Ce)
    CaCe
     
    3
    Al
     
    2
    (Al,Mg)(Mg,Fe
    2+
     
    ,Al)[(O,F)|(OH,O)
     
    2
    |(SiO
     
    4
    )
     
    3
    |Si
     
    2
    O
     
    7
    ]
    9.BG.55Västmanlandite-(Ce)
    Ca(Ce,La)
     
    3
    Al
     
    2
    Mg
     
    2
    [F|(OH)
     
    2
    |(SiO
     
    4
    )
     
    3
    |Si
     
    2
    O
     
    7
    ]
    Related Minerals - Hey's Index Grouping:
    16.14.1Zorite
    Na
     
    2
    Ti(Si,Al)
     
    3
    O
     
    9
    ·nH
     
    2
    O
    16.14.2Vinogradovite
    (Na,Ca,K)
     
    4
    Ti
     
    4
    AlSi
     
    6
    O
     
    23
    (OH)·2H
     
    2
    O
    16.14.3Rhönite
    Ca
     
    2
    (Mg,Fe
    2+
     
    ,Fe
    3+
     
    ,Ti)
     
    6
    [O
     
    2
    |(Si,Al)
     
    6
    O
     
    18
    ]
    16.14.4Kaersutite
    [Na][Ca
     
    2
    ][Mg
     
    4
    Ti][O|OH|Al
     
    2
    Si
     
    6
    O
     
    22
    ]
    16.14.5Ferrokaersutite
    [Na][Ca
     
    2
    ][Fe
    2+
    4
    Ti][O|OH|Al
     
    2
    Si
     
    6
    O
     
    22
    ]
    16.14.6Jonesite
    Ba
     
    4
    (K,Na)
     
    2
    Ti
     
    4
    Al
     
    2
    [O|(SiO
     
    4
    )
     
    2
    |Si
     
    3
    O
     
    9
    ]
     
    2
    · 6H
     
    2
    O
    16.14.7Lourenswalsite
    (K,Ba)
     
    2
    (Ti,Mg,Ca,Fe)
     
    4
    (Si,Al,Fe)
     
    6
    O
     
    14
    (OH)
     
    12
    16.14.8Labuntsovite-Mn
    Na
     
    4
    K
     
    4
    (Ba,K)
     
    2
    Mn
    2+
     
    (Ti,Nb)
     
    8
    [(O,OH)
     
    2
    |Si
     
    4
    O
     
    12
    ]
     
    4
    · 10-12H
     
    2
    O
    16.14.9Kimzeyite
    Ca
     
    3
    (Zr,Ti)
     
    2
    [(Si,Al,Fe
    3+
     
    )O
     
    4
    ]
     
    3
    16.14.10Ellenbergerite
    Mg
     
    6
    Al
     
    6
    Ti[(OH)
     
    6
    |(HSiO
     
    4
    )
     
    4
    |(SiO
     
    4
    )
     
    4
    ]
    16.14.11Carlosturanite
    (Mg,Fe,Ti)
     
    21
    (Si,Al)
     
    12
    O
     
    28
    (OH)
     
    34
    16.14.12Eakerite
    Ca
     
    2
    SnAl
     
    2
    Si
     
    6
    O
     
    18
    (OH)
     
    2
    ·2H
     
    2
    O
    16.14.13Plumalsite
    Pb
     
    4
    Al
     
    2
    (SiO
     
    3
    )
     
    7
    16.14.14Wickenburgite
    CaPb
     
    3
    Al
     
    2
    Si
     
    10
    O
     
    24
    (OH)
     
    6
    16.14.15Maricopaite
    Pb
     
    7
    Ca
     
    2
    (Si,Al)
     
    48
    O
     
    100
    ·32H
     
    2
    O
    16.14.17Burckhardtite
    Pb
     
    2
    (Fe,Mn)AlTeO
     
    2
    Si
     
    3
    O
     
    10
    (OH)
     
    2
    ·H
     
    2
    O
    16.14.18Mathewrogersite
    Pb
     
    7
    (Fe
    2+
     
    ,Cu)Al
     
    3
    Ge[(OH,H
     
    2
    O)
     
    6
    |(Si
     
    3
    O
     
    9
    )
     
    4
    ]

    Other Names for Epidote-(Pb)

    Synonyms:
    Hancockite
    German names:
    Epidot-(Pb)Hancockit
    Russian names:
    Эпидот-(Pb)
    Spanish names:
    Hancockita

    Other Information

    Health Warning:Contains Pb.

    References for Epidote-(Pb)

    Reference List:Palache, C. (1935), The Minerals of Franklin and Sterling Hill, Sussex County, New Jersey. USGS Profesional Paper 180: 98.

    Dollase, W.A. (1971), Refinement of the crystal structures of epidote, allanite and hancockite: American Mineralogist: 56: 447-464.

    Frondel, C. (1972): The minerals of Franklin and Sterling Hill - a checklist.

    Mineralogical Magazine (1985): 49: 721.

    Dunn, Pete J. (1995): Franklin and Sterling Hill New Jersey: the world’s most magnificent mineral deposits, Part3: 406.

    Armbruster, T., Bonazzi, P., Akasaka, M., Bermanec, V., Chopin, C., Gieré R., Heuss-Assbichler, S., Liebscher, A., Menchetti, S., Pan, Y., Pasero, M. (2006): Recommended nomenclature of epidote-group minerals. European Journal of Mineralogy, 18, 551-567.

    Internet Links for Epidote-(Pb)

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  • Look for Epidote-(Pb) on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Epidote-(Pb) in the Natural History Museum (London) online catalogue
  • Hancockite details from Handbook of Mineralogy (PDF)
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    Localities for Epidote-(Pb)

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Republic of Macedonia
     
    • Pelagonian massif
    http://www.geologia-croatica.hr/abstract/gc-51-1-04.html
    Sweden
     
    • Värmland
      • Filipstad
    Christy, A.G. & Gatedal, K. (2005): Extremely Pb-rich rock-forming silicates including a beryllian scapolite and associated minerals in a skarn from Långban, Värmland, Sweden. Mineralogical Magazine, 69, 995-1018.
        • Nordmark
    Kjell Gatedal; Mineralogical Magazine (1994) 58 (1), 172-174
    USA
     
    • New Jersey
      • Sussex Co.
        • Franklin Mining District
          • Franklin
    Frondel, C.: The minerals of Franklin and Sterling Hill - a checklist (1972); Palache(1935):98; Dunn(1995):Pt3:406.
    Mineral and/or Locality
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