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Harkerite

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Big Photo

Tazheranskii Massif, Lake Baikal area, Irkutskaya Oblast', Prebaikalia (Pribaikal'e), Eastern-Siberian Region, Russia
© Pavel M. Kartashov

Show Harkerite Photos (8)



Formula:
Ca
 
12
Mg
 
4
Al(BO
 
3
)
 
3
(SiO
 
4
)
 
4
(CO
 
3
)
 
5
 · H
 
2
O
System:TrigonalColour:White; also tannish brown
Name:
Named in 1948 by Cecil Edgar Tilley for systematic petrologists Alfred Harker (February 19, 1859 - July 28, 1939) of the Scottish Geological Survey.


White to tannish brown pseudo-octahedral crystals.

Classification of Harkerite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:8/B.31-60
Nickel-Strunz 10th (pending) edition ID:6.AB.70

6 : BORATES
A : Monoborates
B : BO3, with additional anions; 1(D) + OH, etc.
Dana 8th edition ID:17.1.9.1

17 : COMPOUND CARBONATES
1 : Miscellaneous
Hey's CIM Ref.:17.5.16

17 : Silicates Containing other Anions
5 : Borosilicates
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Type Occurrence of Harkerite

Type Locality:Camas Malag, Torrin, Broadford, Isle of Skye, North West Highlands (Inverness-shire), Scotland, UK
Year of Discovery:1948
Associated Minerals at type locality:
MagnetiteDiopsideCalciteBornite

Occurrences of Harkerite

Geological Setting:High temperature contact metamorphism assemblages.

Physical Properties of Harkerite

Lustre:Sub-Vitreous, Waxy, Dull
Diaphaneity (Transparency):Translucent
Colour:White; also tannish brown
Streak:White
Tenacity:Brittle
Cleavage:None Observed
Fracture:Irregular/Uneven
Density (measured):2.96 g/cm3
Density (calculated):3.00 g/cm3

Crystallography of Harkerite

Crystal System:Trigonal
Class (H-M):3m (3 2/m) - Hexagonal Scalenohedral
Space Group:R3m {R3 2/m}
Cell Parameters:a = 18.131Å
α = 33.46°
Unit Cell Volume:V 0.00 ų (Calculated from Unit Cell)
Morphology:Octahedrons
Comment:Pseudo-isometric Fd3m
X-Ray Powder Diffraction:
d-spacingIntensity
5.22 (70)
3.39 (60)
3.01 (60)
2.84 (60)
2.61 (100)
2.13 (80)
1.84 (90)
1.51 (70)
Comments:10-0465

Optical Data of Harkerite

Type:Uniaxial
RI values: nα = 1.649 - 1.653 nβ = 1.649 - 1.653
Maximum Birefringence:δ = 1.649

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Optical Extinction:May be anomalously biaxial
Pleochroism:Non-pleochroic

Chemical Properties of Harkerite

Formula:
Ca
 
12
Mg
 
4
Al(BO
 
3
)
 
3
(SiO
 
4
)
 
4
(CO
 
3
)
 
5
 · H
 
2
O
Essential elements:Al, B, C, Ca, H, Mg, O, Si
All elements listed in formula:Al, B, C, Ca, H, Mg, O, Si
Common Impurities:TR,Ce,Fe,Mn,Sr,F,Cl

Relationship of Harkerite to other Species

Common Associates:
PhlogopiteMonticelliteMagnetiteDiopsideChalcocite
Calcite
Related Minerals - Nickel-Strunz Grouping):

- +
6.AB.05Hambergite
Be
 
2
(BO
 
3
)(OH)
6.AB.10Berborite
Be
 
2
(BO
 
3
)(OH,F) · H
 
2
O
6.AB.15Jeremejevite
Al
 
6
(BO
 
3
)
 
5
(F,OH)
 
3
6.AB.20Warwickite
(Mg,Fe
2+
 
)
 
3
Ti(BO
 
3
)
 
2
O
 
2
6.AB.20Yuanfuliite
Mg(Fe
3+
 
,Fe
2+
 
,Al,Ti,Mg)(BO
 
3
)O
6.AB.25Karlite
Mg
 
7
(BO
 
3
)
 
3
(OH,Cl)
 
5
6.AB.30Azoproite
(Mg,Fe
2+
 
)
 
2
(Fe
3+
 
,Ti,Mg)(BO
 
3
)O
 
2
6.AB.30Bonaccordite
Ni
 
2
Fe
3+
 
(BO
 
3
)O
 
2
6.AB.30Fredrikssonite
Mg
 
2
(Mn
3+
 
,Fe
3+
 
)(BO
 
3
)O
 
2
6.AB.30Ludwigite
Mg
 
2
Fe
3+
 
(BO
 
3
)O
 
2
6.AB.30Vonsenite
Fe
2+
2
Fe
3+
 
(BO
 
3
)O
 
2
6.AB.35Pinakiolite
(Mg,Mn
2+
 
)
 
2
Mn
3+
 
(BO
 
3
)O
 
2
6.AB.40Blatterite
(Mn
2+
 
,Mg)
 
2
(Mn
3+
 
,Sb
3+
 
,Fe
3+
 
)(BO
 
3
)O
 
2
6.AB.40Chestermanite
Mg
 
2
(Fe
3+
 
,Mn
3+
 
,Al,Sb
3+
 
)(BO
 
3
)O
 
2
6.AB.40Orthopinakiolite
(Mg,Mn
2+
 
)
 
2
Mn
3+
 
(BO
 
3
)O
 
2
6.AB.40Takéuchiite
(Mg,Mn
2+
 
)
 
2
(Mn
3+
 
,Fe
3+
 
)(BO
 
3
)O
 
2
6.AB.45Hulsite
(Fe
2+
 
,Mg)
 
2
(Fe
3+
 
,Sn)(BO
 
3
)O
 
2
6.AB.45Magnesiohulsite
(Mg,Fe
2+
 
)
 
2
(Fe
3+
 
,Sn,Mg)(BO
 
3
)O
 
2
6.AB.45Aluminomagnesiohulsite
(Mg,Fe
2+
 
)
 
2
(Al,Mg,Sn)(BO
 
3
)O
 
2
6.AB.50Fluoborite
Mg
 
3
(BO
 
3
)(F,OH)
 
3
6.AB.50Hydroxylborite
Mg
 
3
(BO
 
3
)(OH)
 
3
6.AB.55Shabynite
Mg
 
5
(BO
 
3
)(OH)
 
5
(Cl,OH)
 
2
 · 4H
 
2
O
6.AB.55Wightmanite
Mg
 
5
(BO
 
3
)O(OH)
 
5
 · 2H
 
2
O
6.AB.60Gaudefroyite
Ca
 
4
Mn
3+
2-3
(BO
 
3
)
 
3
(CO
 
3
)(O,OH)
 
3
6.AB.65Sakhaite
Ca
 
12
Mg
 
4
(BO
 
3
)
 
7
(CO
 
3
)
 
4
(OH)
 
2
Cl
6.AB.75Pertsevite-(F)
Mg
 
2
(BO
 
3
)(F,OH)
6.AB.75Pertsevite-(OH)
Mg
 
2
(BO
 
3
)(OH)
6.AB.80Jacquesdietrichite
Cu
 
2
(H
 
2
BO
 
3
)(OH)
 
3
6.AB.85Painite
CaZrAl
 
9
(BO
 
3
)O
 
15
Related Minerals - Hey's Index Grouping:

- +
17.5.1Manandonite
LiAl
 
4
(BSi
 
3
O
 
10
)(OH)
 
6
17.5.2Reedmergnerite
Na[BSi
 
3
O
 
8
]
17.5.3Searlesite
Na(H
 
2
BSi
 
2
O
 
7
)
17.5.4Olenite
Na(Al
 
3
)Al
 
6
(Si
 
6
O
 
18
)(BO
 
3
)
 
3
O
 
3
(OH)
17.5.5Elbaite
Na(Li
 
1.5
Al
 
1.5
)Al
 
6
(Si
 
6
O
 
18
)(BO
 
3
)
 
3
(OH)
 
3
(OH)
17.5.6Kalborsite
K
 
6
Al
 
4
BSi
 
6
O
 
20
(OH)
 
4
Cl
17.5.7Boromuscovite
KAl
 
2
(BSi
 
3
O
 
10
)(OH)
 
2
17.5.8Poudretteite
KNa
 
2
B
 
3
Si
 
12
O
 
30
17.5.9Liddicoatite
Ca(Li
 
2
Al)Al
 
6
(Si
 
6
O
 
18
)(BO
 
3
)
 
3
(OH)
 
3
(OH)
17.5.10Datolite
Ca(HBSiO
 
5
)
17.5.11Danburite
CaB
 
2
Si
 
2
O
 
8
17.5.12Howlite
Ca
 
2
B
 
5
SiO
 
9
(OH)
 
5
17.5.13Bakerite
Ca
 
4
(H
 
5
B
 
5
Si
 
3
O
 
20
)
17.5.14Oyelite
Ca
 
10
Si
 
8
B
 
2
O
 
29
 · 12.5H
 
2
O
17.5.15Kornerupine
Mg
 
3
Al
 
6
(Si,Al,B)
 
5
O
 
21
(OH)
17.5.17Serendibite
(Ca,Na)
 
2
(Mg,Fe
2+
 
)
 
3
(Al,Fe
3+
 
)
 
3
[O
 
2
|(Si,Al,B)
 
6
O
 
18
]
17.5.18Stillwellite-(Ce)
(Ce,La,Ca)BSiO
 
5
17.5.19Tadzhikite-(Ce)
(Ca,Ce)
 
4
(Ce,Y)
 
2
(Ti
4+
 
,Fe
3+
 
,Al)[B
 
4
Si
 
4
O
 
22
](OH)
 
2
17.5.20Melanocerite-(Ce)
(Ce,Ca)
 
5
(Si,B)
 
3
O
 
12
(OH,F) · nH
 
2
O
17.5.21Okanoganite-(Y)
(Na,Ca)
 
3
(Y,Ce)
 
12
Si
 
6
B
 
2
O
 
27
F
 
14
17.5.22Tritomite-(Ce)
(Ce,La,Y,Th)
 
5
(Si,B)
 
3
(O,OH,F)
 
13
17.5.23Tritomite-(Y)
(Y,Ca,La,Fe)
 
5
(Si,B,Al)
 
3
(O,OH,F)
 
13
17.5.24Cappelenite-(Y)
Ba(Y,Ce)
 
6
Si
 
3
B
 
6
O
 
24
F
 
2
17.5.25Dumortierite
(Al,Fe
3+
 
)
 
7
(SiO
 
4
)
 
3
(BO
 
3
)O
 
3
17.5.26Holtite
Al
 
6
(Al,Ta)(SiO
 
4
,SbO
 
4
,AsO
 
4
)
 
3
(BO
 
3
)O
 
3
17.5.27Dravite
Na(Mg
 
3
)Al
 
6
(Si
 
6
O
 
18
)(BO
 
3
)
 
3
(OH)
 
3
(OH)
17.5.28 Ferridravite
17.5.29Axinite-(Mg)
Ca
 
2
MgAl
 
2
BSi
 
4
O
 
15
OH
17.5.30Uvite
Ca(Mg
 
3
)MgAl
 
5
(Si
 
6
O
 
18
)(BO
 
3
)
 
3
(OH)
 
3
(F/OH)
17.5.31Garrelsite
Ba
 
3
NaSi
 
2
B
 
7
O
 
16
(OH)
 
4
17.5.32Tienshanite
KNa
 
3
Na
 
6
Ca
 
2
Ba
 
6
Mn
 
6
(Ti
4+
 
,Nb)
 
6
B
 
12
Si
 
36
O
 
114
(O,OH,F)
 
11
17.5.33Leucosphenite
BaNa
 
4
Ti
 
2
B
 
2
Si
 
10
O
 
30
17.5.34Taramellite
Ba
 
4
(Fe
3+
 
,Ti,Fe
2+
 
,Mg)
 
4
(B
 
2
Si
 
8
O
 
27
)O
 
2
Cl
 
x
17.5.35Titantaramellite
Ba
 
4
(Ti,Fe
3+
 
,Fe
2+
 
,Mg)
 
4
(B
 
2
Si
 
8
O
 
27
)O
 
2
Cl
 
x
17.5.36Nagashimalite
Ba
 
4
(V,Ti)
 
4
B
 
2
Si
 
8
O
 
27
(O,OH)
 
2
Cl
17.5.37Chromium-dravite
Na(Mg
 
3
)Cr
3+
6
(Si
 
6
O
 
18
)(BO
 
3
)
 
3
(OH)
 
3
(OH)
17.5.38Wawayandaite
Ca
 
6
Mn
 
2
BBe
 
9
Si
 
6
O
 
23
(OH,Cl)
 
15
17.5.39Werdingite
(Mg,Fe)
 
2
Al
 
14
Si
 
4
B
 
4
O
 
37
17.5.40Axinite-(Mn)
Ca
 
2
Mn
2+
 
Al
 
2
BSi
 
4
O
 
15
(OH)
17.5.41Axinite
17.5.42Tinzenite
(CaMn
2+
 
)
 
2
Mn
2+
 
Al
 
2
BSi
 
4
O
 
15
(OH)
17.5.44Schorl
Na(Fe
2+
3
)Al
 
6
(Si
 
6
O
 
18
)(BO
 
3
)
 
3
(OH)
 
3
(OH)
17.5.45Fluor-buergerite
Na(Fe
3+
3
)Al
 
6
(Si
 
6
O
 
18
)(BO
 
3
)
 
3
O
 
3
F
17.5.46Feruvite
Ca(Fe
2+
 
)
 
3
MgAl
 
5
(Si
 
6
O
 
18
)(BO
 
3
)
 
3
(OH)
 
3
(OH)
17.5.47Axinite-(Fe)
Ca
 
2
Fe
2+
 
Al
 
2
BSi
 
4
O
 
15
OH
17.5.48Homilite
Ca
 
2
(Fe
2+
 
,Mg)B
 
2
Si
 
2
O
 
10
17.5.49Grandidierite
(Mg,Fe
2+
 
)(Al,Fe
3+
 
)
 
3
(SiO
 
4
)(BO
 
3
)O
 
2
17.5.50Hyalotekite
(Ba,Pb,Ca,K)
 
6
(B,Si,Al)
 
2
(Si,Be)
 
10
O
 
28
(F,Cl)
17.5.51Hellandite-(Y)
(Ca,Y)
 
6
(Al,Fe
3+
 
)Si
 
4
B
 
4
O
 
20
(OH)
 
4

Other Names for Harkerite

Other Languages:
German:Harkerit
Russian:Харкерит
Simplified Chinese:碳硼硅钙镁石
Spanish:Harkerita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Harkerite

Reference List:

- +
American Mineralogist (1952) 37: 359.

American Mineralogist (1977) 62: 263-272.

Grew, E.S., Yates, M.G., Adams, P., Kirkby, R., and Wiedenbeck, M. (1999) Harkerite from the Crestmore Quarry, Riverside County, California and Cascade Slide, Adirondack Mountains, New York: A contrast in metamorphic pressure. Canadian Mineralogist: 37: 277-296.

Grew, E.S., and Anovitz, L.M. (1996) BORON: Mineralogy, Petrology and Geochemistry, second edition, as revised (2002), Reviews in Mineralogy, v. 33, Mineralogical Society of America.

Internet Links for Harkerite

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    • Localities for Harkerite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    China
     
    • Guangdong Province
      • Heyuan Prefecture
        • Lianping Co.
    		Wang, S. (1983): Bull. lnst. Min. Deposits, Chinese Acad. Geol. Sci. 9, 72; Lianshun Feng (1986): Geology and Prospecting 22(3), 21-27
    Italy
     
    • Latium
      • Rome Province
    		Barbieri, M., Cozzupoli, D., Federico, M., Fornaseri, M., & Tolomeo, L. (1973). Harkerite negli inclusi del peperino dei Colli Albani. Periodico di Mineralogia, 42 (3), 687-688; Barbieri, M., Cozzupoli, D., Federico, M., Fornaseri, M., Merlino, S., Orlandi, P., & Tolomeo, L. (1977). Harkerite from the Alban Hills, Italy. Lithos, 10, 133-141.
    Christof Schäfer collection
    Kazakhstan
     
    • Karagandy Province (Qaragandy Oblysy; Karaganda Oblast')
      • Balkhash (Balqash; Karatas; Prebalkhashie) Region
        • Sayak
          • Sayak group skarn deposits
    		Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Namibia
     
    • Otjozondjupa Region
      • Grootfontein District
        • Kombat
    		Dunn, P.J. (1991), Rare minerals of the Kombat Mine, Mineralogical Record: 22(6): 421-425.
    Russia
     
    • Eastern-Siberian Region
      • Prebaikalia (Pribaikal'e)
        • Irkutskaya Oblast'
          • Lake Baikal area
    		Koneva A.A., Uschapovskaya Z.F. (1991) On harkerite and bultfonteinite from skarns of Tazheran alkaline massif, - Geologiya i Geofizika, 2, p.74-78.
      • Saha Republic (Sakha Republic; Yakutia)
        • Polar Yakutia
          • Dogdo River Basin
            • Tas-Khayakhtakh Range
    		Aleksandrov, S.M. (1998): Geochemistry of skarn and ore formation in dolomites. VSP (Utrecht, Tokyo), 300 pp.
    Sweden
     
    • Värmland
      • Filipstad
        • Nordmark (Nordmarksberg)
    		GFF 117 (1995), 151-152
    UK
     
    • Scotland
      • North West Highlands (Inverness-shire)
        • Isle of Skye
          • Broadford
            • Kilchrist
            • Torrin
    		C.E. Tilley: Mineral. Mag. 29:621-667 (1951)
    USA
     
    • California
      • Riverside Co.
        • Crestmore
    		Grew, et al (1999) Canadian Mineralogist: 37: 277-296; [http://www.mineralogicalassociation.ca/doc/abstracts/cm2_Vol37_Avr99.pdf; micromounts@yahoogroups.com]
    • New York
      • Essex Co.
        • Keene
          • Cascade Mountain
    		Canadian Mineralogist (1999): 37: 277-296; Grew e al (1999), Canadian Mineralogist: 37: 277-296.; Contrib. Mineral. Petrol. 74, 143-152 (1980)
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