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Hibschite

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Formula:
Ca
 
3
Al
 
2
(SiO
 
4
)
 
3-x
(OH)
 
4x
(x = 0.2-1.5)
System:IsometricColour:Usually colorless, pale ...
Hardness:
Member of:Garnet Structural Group
Name:
Named by Felix Cornu in 1905 for Josef Emanuel Hibsch [March 26, 1852 in Hummel, Bohemia (Böhmen) - November 4, 1940 Vienna (Wien), Austria], geologist with the Landwirtschaftliche Akademie (Academy of Agriculture) at Tetschen (Decin), Bohemia.


Grossular-Hibschite Series, and the Hibschite-Katoite Series.

In part synonymous with "Hydrogrossular", a variety of Grossular with part of the orthosilicate ions replaced by hydroxide ions. Often considered to be a discrete mineral species itself (current nomenclature is inconsistent, however: since hibschite is OH-dominant it could be considered an SiO4-bearing katoite).

The OH analogue of igumnovite.

Classification of Hibschite

IMA status:Approved 1983
Explanation of status:A redefined (IMA 83-B) mineral, replacing hydrogrossular and plazolite root names.
Strunz 8th edition ID:8/A.08-80
Nickel-Strunz 10th (pending) edition ID:9.AD.25

9 : SILICATES (Germanates)
A : Nesosilicates
D : Nesosilicates without additional anions; cations in [6] and/or greater coordination
Dana 8th edition ID:51.4.3d.1

51 : NESOSILICATES Insular SiO4 Groups Only
4 : Insular SiO4 Groups Only with cations in [6] and >[6] coordination
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Type Occurrence of Hibschite

Type Locality:Mariánská Skála (Mariánská hora; Marienberg), Ústí nad Labem (Aussig), Ústí Region, Bohemia (Böhmen; Boehmen), Czech Republic
General Appearance of Type Material:Colorless to pale yellow overgrowths on "titaniferous melanite" crystal.
Year of Discovery:1905

Physical Properties of Hibschite

Lustre:Vitreous, Sub-Vitreous
Diaphaneity (Transparency):Transparent
Colour:Usually colorless, pale yellow, may have tints of gray, green to bluish green, also may be smoky gray to black.
Comment:Dark color may be due to zonation with melanite.
Streak:White
Hardness (Mohs):
Comment:May be as hard as 7
Tenacity:Brittle
Cleavage:None Observed
Fracture:Irregular/Uneven, Sub-Conchoidal
Density (measured):3.06 - 3.25 g/cm3
Density (calculated):3.28 g/cm3

Crystallography of Hibschite

Crystal System:Isometric
Class (H-M):m3m (4/m 3 2/m) - Hexoctahedral
Space Group:Ia3d {I41/a 3 2/d}
Cell Parameters:a = 12Å
Unit Cell Volume:V 1,728.00 ų (Calculated from Unit Cell)
Z:8
Morphology:Crystals are rare, but may be dominantly octahedral. Occasionally dodecahedral.
Comment:a varies from 11.90 to 12.287
X-Ray Powder Diffraction:
d-spacingIntensity
3.00 (80)
2.68 (100)
2.46 (50)
2.19 (50)
1.95 (60)
1.73 (50)
1.66 (50)
1.61 (80)
Comments:31-250; 45-1447; 3-801; 42-570 (calculated)

Optical Data of Hibschite

Type:Isotropic

Chemical Properties of Hibschite

Formula:
Ca
 
3
Al
 
2
(SiO
 
4
)
 
3-x
(OH)
 
4x


(x = 0.2-1.5)
Essential elements:Al, Ca, H, O, Si
All elements listed in formula:Al, Ca, H, O, Si
Common Impurities:Fe,Mn,Mg,S

Relationship of Hibschite to other Species

Series:Forms a series with Grossular (see here)
Forms a series with Katoite (see here)
Member of:Garnet Structural Group
Other Members of Group:

- +
Almandine
Fe
2+
3
Al
 
2
(SiO
 
4
)
 
3
Andradite
Ca
 
3
Fe
3+
2
(SiO
 
4
)
 
3
Berzeliite
NaCa
 
2
(Mg,Mn
2+
 
)
 
2
(AsO
 
4
)
 
3
Bitikleite-(SnAl)
Ca
 
3
SbSn(AlO
 
4
)
 
3
Bitikleite-(SnFe)
Ca
 
3
SbSn(Fe
3+
 
O
 
4
)
 
3
Bitikleite-(ZrFe)
Ca
 
3
SbZr(Fe
3+
 
O
 
4
)
 
3
Calderite
(Mn
2+
 
,Ca)
 
3
(Fe
3+
 
,Al)
 
2
(SiO
 
4
)
 
3
Goldmanite
Ca
 
3
V
3+
2
(SiO
 
4
)
 
3
Grossular
Ca
 
3
Al
 
2
(SiO
 
4
)
 
3
Henritermierite
Ca
 
3
(Mn
3+
 
,Al)
 
2
(SiO
 
4
)
 
2
(OH)
 
4
Irinarassite
Ca
 
3
Sn
 
2
Al
 
2
SiO
 
12
Katoite
Ca
 
3
Al
 
2
(SiO
 
4
)
 
3-x
(OH)
 
4x
Kerimasite
Ca
 
3
Zr
 
2
(SiO
 
4
)(Fe
3+
 
O
 
4
)
 
2
Kimzeyite
Ca
 
3
(Zr,Ti)
 
2
((Si,Al,Fe
3+
 
)O
 
4
)
 
3
Knorringite
Mg
 
3
Cr
 
2
(SiO
 
4
)
 
3
Majorite
Mg
 
3
(Fe
2+
 
,Si,Al)
 
2
(SiO
 
4
)
 
3
Momoiite
(Mn
2+
 
,Ca)
 
3
V
3+
2
(SiO
 
4
)
 
3
Morimotoite
Ca
 
3
(Ti,Fe
2+
 
,Fe
3+
 
)
 
2
((Si,Fe
3+
 
)O
 
4
)
 
3
Palenzonaite
(Ca,Na)
 
3
CaMn
2+
2
(VO
 
4
)
 
3
Pyrope
Mg
 
3
Al
 
2
(SiO
 
4
)
 
3
Schäferite
Ca
 
2
NaMg
 
2
(VO
 
4
)
 
3
Schorlomite
Ca
 
3
(Ti,Fe
3+
 
)
 
2
((Si,Fe
3+
 
)O
 
4
)
 
3
Spessartine
Mn
2+
3
Al
 
2
(SiO
 
4
)
 
3
Titanoan Andradite
Toturite
Ca
 
3
Sn
 
2
(SiO
 
4
)(Fe
3+
 
O
 
4
)
 
2
Uvarovite
Ca
 
3
Cr
 
2
(SiO
 
4
)
 
3
Yafsoanite
Ca
 
3
Zn
 
3
(TeO
 
6
)
 
2
Related Minerals - Nickel-Strunz Grouping):

- +
9.AD.05Larnite
Ca
 
2
SiO
 
4
9.AD.10Calcio-Olivine
Ca
 
2
SiO
 
4
9.AD.15Merwinite
Ca
 
3
Mg(SiO
 
4
)
 
2
9.AD.20Bredigite
Ca
 
7
Mg(SiO
 
4
)
 
4
9.AD.25Andradite
Ca
 
3
Fe
3+
2
(SiO
 
4
)
 
3
9.AD.25Almandine
Fe
2+
3
Al
 
2
(SiO
 
4
)
 
3
9.AD.25Calderite
(Mn
2+
 
,Ca)
 
3
(Fe
3+
 
,Al)
 
2
(SiO
 
4
)
 
3
9.AD.25Goldmanite
Ca
 
3
V
3+
2
(SiO
 
4
)
 
3
9.AD.25Grossular
Ca
 
3
Al
 
2
(SiO
 
4
)
 
3
9.AD.25Henritermierite
Ca
 
3
(Mn
3+
 
,Al)
 
2
(SiO
 
4
)
 
2
(OH)
 
4
9.AD.25Hydroandradite
Ca
 
3
Fe
3+
2
(SiO
 
4
)
 
3-x
(OH)
 
4x
9.AD.25Katoite
Ca
 
3
Al
 
2
(SiO
 
4
)
 
3-x
(OH)
 
4x
9.AD.25Kimzeyite
Ca
 
3
(Zr,Ti)
 
2
((Si,Al,Fe
3+
 
)O
 
4
)
 
3
9.AD.25Knorringite
Mg
 
3
Cr
 
2
(SiO
 
4
)
 
3
9.AD.25Majorite
Mg
 
3
(Fe
2+
 
,Si,Al)
 
2
(SiO
 
4
)
 
3
9.AD.25Morimotoite
Ca
 
3
(Ti,Fe
2+
 
,Fe
3+
 
)
 
2
((Si,Fe
3+
 
)O
 
4
)
 
3
9.AD.25Pyrope
Mg
 
3
Al
 
2
(SiO
 
4
)
 
3
9.AD.25Schorlomite
Ca
 
3
(Ti,Fe
3+
 
)
 
2
((Si,Fe
3+
 
)O
 
4
)
 
3
9.AD.25Spessartine
Mn
2+
3
Al
 
2
(SiO
 
4
)
 
3
9.AD.25Uvarovite
Ca
 
3
Cr
 
2
(SiO
 
4
)
 
3
9.AD.25Wadalite
(Ca,Mg)
 
6
(Al,Fe
3+
 
)
 
4
((Si,Al)O
 
4
)
 
3
O
 
4
Cl
 
3
9.AD.25Holtstamite
Ca
 
3
(Al,Mn
3+
 
)
 
2
(SiO
 
4
)
 
2
(OH)
 
4
9.AD.25Kerimasite
Ca
 
3
Zr
 
2
(SiO
 
4
)(Fe
3+
 
O
 
4
)
 
2
9.AD.25Toturite
Ca
 
3
Sn
 
2
(SiO
 
4
)(Fe
3+
 
O
 
4
)
 
2
9.AD.25Momoiite
(Mn
2+
 
,Ca)
 
3
V
3+
2
(SiO
 
4
)
 
3
9.AD.30Coffinite
(U
4+
 
,Th)(SiO
 
4
)
 
1-x
(OH)
 
4x
9.AD.30Hafnon
HfSiO
 
4
9.AD.30Thorite
(Th,U)SiO
 
4
9.AD.30Thorogummite
(Th,U)(SiO
 
4
)
 
1-x
(OH)
 
4x
9.AD.30Zircon
ZrSiO
 
4
9.AD.30Stetindite
Ce
4+
 
SiO
 
4
9.AD.35Huttonite
ThSiO
 
4
9.AD.35Tombarthite-(Y)
Y
 
4
(Si,H
 
4
)
 
4
O
 
12-x
(OH)
 
4+2x
9.AD.40Eulytine
Bi
 
4
(SiO
 
4
)
 
3
9.AD.45Reidite
ZrSiO
 
4

Other Names for Hibschite

Synonyms:
PlasoliteTransvaal Jade
Other Languages:
German:Hibschit
Russian:Гибшит
Spanish:Hibschita

Other Information

Fluorescence in UV light:Generally non-fluorescent. One locality (Mosjoen, Nordland, Norway) has distinct orange fluorescence SW UV.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Hibschite

Reference List:

- +
Bulletin de Minéralogie: 107 (1984), 605.

European Journal of Mineralogy (1989): 1: 363.

Neues Jahrbuch für Mineralogie, Monatshefte (1983), 251-258.

American Mineralogist (1985): 70: 873.

American Mineralogist (1989): 74: 840.

Neues Jahrbuch für Mineralogie, Monatshefte (2001), 49.

Pertlik, F. (2003): Bibliography of hibschite, a hydrogarnet of grossular type. GeoLines 15, 113-119.

Internet Links for Hibschite

Search Engines:
  • Look for Hibschite on Google
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  • External Links:
  • Look for Hibschite on Webmineral
  • Look for Hibschite on Athena Mineralogy[Link Broken?]
  • Look for Hibschite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Hibschite details from Handbook of Mineralogy (PDF)
  • Mineral Dealers:
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  • Specimens:The following Hibschite specimens are currently listed for sale on minfind.com.
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  • Localities for Hibschite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • New South Wales
      • Yancowinna Co.
    Birch BH Book
    Austria
     
    • Lower Austria
      • Waldviertel
        • Drosendorf-Zissersdorf
          • Pingendorf
    Kolitsch, U. (2008)
    Canada
     
    • Ontario
      • Thunder Bay District
        • Nipigon
          • Seagull Lake area
    Chakhmouradian, A. R. & Medici, L. (2006): "Clinohydroxylapatite: a new apatite-group mineral from northwest Ontario (Canada), and new data on the extent of Na-S substitution in natural apatites", European Journal of Mineralogy 18, 105-112
    • Québec
      • Laurentides
        • Deux-Montagnes RCM
          • Saint-Joseph-du-Lac
            • Oka complex
    Sabina (1968)
      • Montérégie
        • Rouville RCM
          • Mont Saint-Hilaire
    Horváth & Pfenninger-Horváth (2000)
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Ústí Region
        • Ústí nad Labem (Aussig)
    Ulrych, J. et al. (2000): Tertiary phonolite laccolith of Mariánská hora hill, N. Bohemia: geological, petrological and mineralogical characteristics. Acta Montana IRSM AS CR, series A No. 15 (116), p. 5-44.
    • Moravia (Mähren; Maehren)
      • Vysočina Region
        • Havlíčkův Brod (Německý Brod; Deutschbrod)
    Pauliš, P.: Nejzajímavější mineralogická naleziště Čech II. Kutná Hora: Kuttna, 2003, s. 96 - 98.
    France
     
    • Auvergne
      • Haute-Loire
        • La Chaise-Dieu
          • Cistrières
            • Pervenchères
    • Provence-Alpes-Côte d'Azur
      • Hautes-Alpes
        • Briançon
          • Montgenèvre
    Bull. Minéral. , 1984, 107, pp. 345-356.
    Germany
     
    • Bavaria
      • Franconia
        • Maroldsweisach
    Wittern: "Mineralfundorte in Deutschland", 2001
    • Lower Saxony
      • Harz
        • Bad Harzburg
    No reference listed
    • Rhineland-Palatinate
      • Eifel
        • Mayen
          • Ettringen
            • Bellerberg volcano
    [Blass, G., Graf, H.W., Neue Mineralienfunde aus der Eifel und dem Siegerland, Mineralien-Welt 10/3, 23, 1999] [A. Wittern: Mineralfundorte in Deutschland, Schweizerbart (Stuttgart), 2001]
    Israel
     
    • Negev
    Gross, S. (1977): The Mineralogy of the Hatrurim Formation, Israel. Geological Survey of Israel, Bulletin no. 70, 80 pp.
    Italy
     
    • Campania
      • Naples Province
        • Somma-Vesuvius Complex
          • Monte Somma
            • Ercolano
              • San Vito
    Russo, M., Punzo, I. (2004): I minerali del Somma-Vesuvio, AMI
    • Liguria
      • Savona Province
        • Urbe
          • Vara
            • Bric Mundu (Bric Mondo; Bric Mondu)
    NHM collection (was hessonite)
    • Tuscany
      • Lucca Province
        • Garfagnana
          • Villa Collemandina
    • Veneto
      • Vicenza Province
        • Cornedo Vicentino
          • Spagnago
    Boscardin M.,Daleffe A.,Rocchetti I., Zordan A. (2011) " Minerali del Vicentino - Aggiornamenti, località e nuove determinazioni " Museo di Archeologia e Scienze Naturali “G. Zannato” – Montecchio Maggiore (Vicenza), pp.183
    - Boscardin M.,Daleffe A.,Rocchetti I., Zordan A. (2011) " Minerali del Vicentino - Aggiornamenti, località e nuove determinazioni " Museo di Archeologia e Scienze Naturali “G. Zannato” – Montecchio Maggiore (Vicenza), pp.183
    Japan
     
    • Honshu Island
      • Kanto Region
        • Chiba Prefecture
          • Awa-gun
            • Tawara-mura
    Dr. Kameki Kinoshita collection (curated at Geological Survey of Japan)
    Morocco
     
    • Souss-Massa-Draâ Region
      • Ouarzazate Province
        • Tazenakht
    S. Weiß: Lapis 31(7/8), 72-73 (2006)
    Norway
     
    • Telemark
      • Hjartdal
        • Sauland
          • Kleppan
      • Skien
    Jamtveit B., Dahlgren S. and Austrheim H. (1997): High-grade contact metamorphism of calcareous rocks from the Oslo Rift, Southern Norway. American Mineralogist. 82 : 1241 - 1254
    Poland
     
    • Lower Silesia (Dolnośląskie)
      • Gogołów-Jordanów Massif
    DUBIŃSKA E., 1995: Rodingites of the eastern part of Jordanów-Gogołów serpentynite massif, Lower Silesia, Poland. Can. Mineral., 33, 585-608.GALUSKIN E., SZEŁĘG E., 2003: The first finding of Ag-amalgamates in rodingites (Nasławice, Lower Silesia, Poland). Mineralogical Society of Poland - Special Papers, Vol. 22.
    Romania
     
    • Caras-Severin Co.
      • Banat Mts
        • Ocna de Fier-Dognecea District
    http://minerals-of-the-carpathians.eu
    • Hunedoara Co.
      • Hunedoara
    Marincea, Ş., Bilal, E., Verkaeren, J., Pascal, M.-L., and Fonteilles, M. (2001) Superposed paragenesis in spurrite-, tilleyite- and gehlenite-bearing skarns from Cornet Hill, Apuseni Mountains, Romania. Canadian Mineralogist: 39: 1435-1453.
    Russia
     
    • Eastern-Siberian Region
      • Saha Republic (Sakha Republic; Yakutia)
    Am Min 90: 1688-1692
    • Urals Region
      • Southern Urals
        • Chelyabinsk Oblast'
    Cesnokov, B., M. Kotrly, and T. Nisanbajev (1998): Brennende Abraumhalden und Aufschlüsse im Tscheljabinsker Kohlenbecken - eine reiche Mineralienküche. Mineralien-Welt, 9 (3), 54-63 (in German).
    Cesnokov, B., M. Kotrly, and T. Nisanbajev (1998): Brennende Abraumhalden und Aufschlüsse im Tscheljabinsker Kohlenbecken - eine reiche Mineralienküche. Mineralien-Welt, 9 (3), 54-63 (in German).
    Slovakia
     
    • Košice Region
      • Spišská Nová Ves Co.
        • Hnilec
    Koděra, M. et al., 1986 a 1990 : Topografická mineralógia Slovenska, diel 1- 3, Veda – Vydavateľstvo SAV, Bratislava, 1990, 1 – 1590k
    South Africa
     
    • Limpopo Province
    Minerals of South Africa
    • Mpumalanga Province
      • Eastern Bushveld Complex
        • Steelport
    Minerals of South Africa
    • Northern Cape Province
      • Kalahari manganese fields
        • Hotazel
    Minerals of South Africa
        • Kuruman
          • N'Chwaning Mines
    Minerals of South Africa
    • Northwest Province
      • Western Bushveld Complex
        • Brits District
    Minerals of South Africa
    Minerals of South Africa
    Minerals of South Africa
    Minerals of South Africa
    Minerals of South Africa
    Spain
     
    • Aragón
      • Teruel
        • Loscos
    Calvo, M. (2008) Minerales de Aragón. Prames (Zaragoza) 463 pages
    Sweden
     
    • Värmland
      • Filipstad
    Nysten, P., Holtstam, D. and Jonsson, E. (1999) The Långban minerals. In Långban - The mines,their minerals, geology and explorers (D. Holtstam and J. Langhof, eds.), Swedish Museum of Natural History and Raster Förlag, Stockholm & Chr. Weise Verlag, Munich, pp. 89-183.
        • Persberg district
          • Pajsberg
    Nysten, P. (2004): Harstigen ett mineralogisk eldorado i Bergslagen. Norsk Bergverksmuseum Skrift 28: 5-13
    USA
     
    • California
      • Riverside Co.
        • Crestmore
    [micromounts@yahoogroups.com]
    • Washington
      • Jefferson Co.
        • Mount Jupiter
          • Elkhorn Group
    Minerals of Washington, Bart Cannon, 1975
      • Mason Co.
        • Copper Creek (Boulder Creek)
    Cannon, B. (1975): Minerals of Washington, p.39
    Mineral and/or Locality
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