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Hilgardite

A valid IMA mineral species - grandfathered
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About HilgarditeHide

07534030017057552327713.jpg
Eugene W. Hilgard
Formula:
Ca2B5O9Cl · H2O
Colour:
Colorless, light pink; colourless in transmitted light
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
2.67 - 2.71
Crystal System:
Triclinic
Name:
Named for Eugene Woldemar Hilgard (5 January 1833, Zweibrücken, Rhineland-Palatinate, Germany – 8 January 1916, Berkeley, California, United States), German-American geologist, one of the first to describe the Louisiana salt dome deposits. He is also considered the father of modern soil science in the United States.
Hilgardite Group.

Several polytypes are known, as well as Sr-bearing varieties.


Unique IdentifiersHide

Mindat ID:
1902
Long-form identifier:
mindat:1:1:1902:2
GUID
(UUID V4):
d6a20d1c-ab9f-47a2-b234-923d1ff109b6

IMA Classification of HilgarditeHide

Approved, 'Grandfathered' (first described prior to 1959)
First published:
1937

Classification of HilgarditeHide

6.ED.05

6 : BORATES
E : Pentaborates
D : Tekto-pentaborates
Dana 7th ed.:
26.5.14.1
26.5.14.1

26 : HYDRATED BORATES CONTAINING HYDROXYL OR HALOGEN
5 : Pentaborates
10.1.8/9/10

10 : Borates with other anions
1 : Borates with halide

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
HgrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HilgarditeHide

Vitreous
Transparency:
Transparent
Colour:
Colorless, light pink; colourless in transmitted light
Streak:
White
Hardness:
Cleavage:
Perfect
Perfect on the {010}, also on {100} but more difficult to realize.
Fracture:
Conchoidal
Density:
2.67 - 2.71 g/cm3 (Measured)    2.69 g/cm3 (Calculated)

Optical Data of HilgarditeHide

Type:
Biaxial (+)
RI values:
nα = 1.630 nβ = 1.636 nγ = 1.664
2V:
Measured: 35° , Calculated: 52°
Max Birefringence:
δ = 0.034
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r > v

Chemistry of HilgarditeHide

Mindat Formula:
Ca2B5O9Cl · H2O

Crystallography of HilgarditeHide

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Hilgardite-1TcHilgardite-3TcHilgardite-4M
   
 Triclinic Monoclinic 
 1 - Pedialm - Domatic
 P1 
   

a = 11.24 Å, b = 22.28 Å, c = 6.2 Å
α = 90°, β = 90°, γ = 91.2°
a = 11.470(3) Å, b = 11.321(4) Å, c = 6.321(5) Å
β = 90.02(7)°
 a:b:c = 0.504 : 1 : 0.278a:b:c = 1.013 : 1 : 0.558
 V 1,552.31 ų
(Calculated from Unit Cell)
V 820.79 ų
(Calculated from Unit Cell)
 2 

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000696HilgarditeGhose S, Wan C (1979) Hilgardite, Ca2[B5O9]Cl*H2O: a piezoelectric zeolite-type pentaborate American Mineralogist 64 187-1951979Choctow Salt Dome, Iberville Parish, Louisiana, USA0293
0000901HilgarditeWan C, Ghose S (1983) Parahilgardite, Ca6[B5O9]3Cl3*3H2O: a triclinic piezoelectric zeolite-type pentaborate American Mineralogist 68 604-6131983Iberville Parish, Louisiana, USA0293
0010290HilgarditeBurns P C, Hawthorne F C (1994) Refinement of the structure of hilgardite-1A Acta Crystallographica C50 653-6551994Penobsquis potash deposit, Sussex, New Brunswick0293
0015604HilgarditeRumanova I M, Iorysh Z I, Belov N V (1977) Crystal structure of triclinic chilgardite Ca2[B5O9]Cl*H2O = Ca2[B3+-B2deltaO9]Cl*H2O Soviet Physics Doklady 22 460-4621977not given0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
- Å()
Comments:
X-ray powder diffraction data can be found on the polytype pages.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
25 : Evaporites (prebiotic)
Geological Setting:
Marine evaporite deposits

Type Occurrence of HilgarditeHide

Place of Conservation of Type Material:
Harvard University, Cambridge, Massachusetts, USA, 100899, 100947, 106583.
National Museum of Natural History (Smithsonian), Washington, D.C., USA, R7822.
Geological Setting of Type Material:
Salt dome.
Associated Minerals at Type Locality:
Reference:
Hurlbut, C.S., Taylor, R.E. (1937) Hilgardite, a new mineral species from Choctaw Salt Dome, Louisiana. American Mineralogist: 22: 1052-1057.

Synonyms of HilgarditeHide

Other Language Names for HilgarditeHide

German:Hilgardit
Simplified Chinese:氯羟硼钙石
Spanish:Hilgardita
Traditional Chinese:氯羥硼鈣石

Varieties of HilgarditeHide

Strontiohilgardite
Strontiohilgardite-1TcA strontium-bearing (strontian) hilgardite-1Tc.

Relationship of Hilgardite to other SpeciesHide

Other Members of this group:
KurgantaiteCaSr[B5O9]Cl · H2OTric. 1 : P1
LeucostauritePb2[B5O9]Cl · 0.5H2OOrth. mm2 : Pnn2
TyretskiteCa2B5O9OH · H2OTric. 1 : P1

Common AssociatesHide

Associated Minerals Based on Photo Data:
63 photos of Hilgardite associated with BoraciteMg3(B7O13)Cl
16 photos of Hilgardite associated with VolkovskiteKCa4[B5O8OH]4[B(OH)3]2Cl · 4H2O
4 photos of Hilgardite associated with Hilgardite-3Tc
2 photos of Hilgardite associated with SylviteKCl
1 photo of Hilgardite associated with MagnesiteMgCO3

Related Minerals - Strunz-mindat GroupingHide

6.ED.05TyretskiteCa2B5O9OH · H2OTric. 1 : P1
6.ED.05KurgantaiteCaSr[B5O9]Cl · H2OTric. 1 : P1

Other InformationHide

Electrical:
Piezoelectric
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HilgarditeHide

References for HilgarditeHide

Reference List:

Localities for HilgarditeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • New Brunswick
    • Kings Co.
      • Cardwell Parish
        • Penobsquis
Grice et al. (1996) +1 other reference
      • Hammond Parish
        • Salt Springs evaporite deposit
Roulston et al. (1981) +1 other reference
      • Studholm Parish
Grice et al. (2005)
China
 
  • Yunnan
    • Pu'er
      • Jiangcheng County
[Hilgardite-3Tc] Li et al. (2015)
Germany
 
  • Lower Saxony
    • Göttingen District
      • Bovenden
        • Reyershausen
Clark (1993)
Israel
 
  • Southern District (HaDarom District)
Anthony (2003)
Kazakhstan
 
  • Aktobe Region
    • Shalkar District
      • Aksai Valley
Pekov (1998) +2 other references
  • Atyrau Region
    • Inder District
Pekov et al. (1993) +2 other references
Russia
 
  • Irkutsk Oblast
    • Lena-Angara salt Basin
Dimitri Belakovski
    • Nizhneilimsky District
      • Zheleznogorsk-Ilimsky
Mazurov et al. (2007)
Turkey
 
  • Eskişehir Province
    • Seyitgazi District
      • Kirka
[Hilgardite-4M] Koçak et al. (2016) +1 other reference
UK
 
  • England
    • North Yorkshire
      • Redcar and Cleveland
        • Loftus
BMS Collection hilgardite-1TC +2 other references
      • Scarborough
        • LCPs of Fylingdales and Hawsker-cum-Stainsacre
Smith et al. (2014)
Smith et al. (2014)
Kemp et al. (2016)
USA
 
  • Alabama
    • Clarke County
Rocks & Min.: 64:472. +1 other reference
  • Louisiana
    • Iberville Parish
      • Plaquemine
American Mineralogist 23:898 +1 other reference
 
Mineral and/or Locality  
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