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Ianthinite

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Formula:
U
4+
 
(UO
 
2
)
 
5
O
 
7
· 10H
 
2
O
System:OrthorhombicColour:Violet-black; dark ...
Lustre:Sub-MetallicHardness:2 - 3
Name:From the Greek ιάνθινος ("ianthinos"), violet colored, in allusion to its color.


Not very stable under ambient conditions; will dehydrate to schoepite (while becoming yellow and opaque) and further members of the schoepite group.

Classification of Ianthinite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:4/H.01-10
Nickel-Strunz 10th (pending) edition ID:4.GA.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
G : Uranyl Hydroxides
A : Without additional cations
Dana 7th edition ID:5.6.1.1
Dana 8th edition ID:5.6.1.1

5 : OXIDES CONTAINING URANIUM OR THORIUM
6 : AX6O17·xH2O
Hey's CIM Ref.:7.16.7

7 : Oxides and Hydroxides
16 : Oxides of U
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Type Occurrence of Ianthinite

Type Locality:Shinkolobwe Mine (Kasolo Mine), Shinkolobwe, Katanga Copper Crescent, Katanga (Shaba), Democratic Republic of Congo (Zaïre)
Year of Discovery:1926

Physical Properties of Ianthinite

Lustre:Sub-Metallic
Diaphaneity (Transparency):Transparent
Colour:Violet-black; dark violet in transmitted light
Streak:Brown, violet
Hardness (Mohs):2 - 3
Cleavage:Perfect
Perfect on {001}

Crystallography of Ianthinite

Crystal System:Orthorhombic
Class (H-M):mm2 - Pyramidal
Space Group:Amm2
Cell Parameters:a = 11.52Å, b = 7.15Å, c = 30.3Å
Ratio:a:b:c = 1.611 : 1 : 4.238
Unit Cell Volume:V 2,495.75 ų (Calculated from Unit Cell)
Morphology:Tiny rectangular plates {001} elongated [010]. Also prismatic [010], or thick tabular {001}.

Optical Data of Ianthinite

Type:Biaxial (-)
RI values: nα = 1.674 nβ = 1.900 nγ = 1.920
2V:Measured: 58° , Calculated: 30°
Maximum Birefringence:δ = 0.246

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:r > v perceptible
Pleochroism:Visible
Comments:X = c = colourless
Y = b = violet
Z = a = dark violet

Chemical Properties of Ianthinite

Formula:
U
4+
 
(UO
 
2
)
 
5
O
 
7
· 10H
 
2
O
Essential elements:H, O, U
All elements listed in formula:H, O, U

Relationship of Ianthinite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
4.GA.05Metaschoepite
UO
 
3
· 1-2H
 
2
O
4.GA.05Paraschoepite
UO
 
3
· 2H
 
2
O
4.GA.05Schoepite
(UO
 
2
)
 
8
O
 
2
(OH)
 
12
· 12H
 
2
O
4.GA.05Paulscherrerite
UO
 
2
(OH)
 
2
4.GA.15Metastudtite
UO
 
4
· 2H
 
2
O
4.GA.15Studtite
[(UO
 
2
)(O
 
2
)(H
 
2
O)
 
2
] · H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
7.16.1Uraninite
UO
 
2
7.16.2Schoepite
(UO
 
2
)
 
8
O
 
2
(OH)
 
12
· 12H
 
2
O
7.16.3Paraschoepite
UO
 
3
· 2H
 
2
O
7.16.4Metaschoepite
UO
 
3
· 1-2H
 
2
O
7.16.5Metastudtite
UO
 
4
· 2H
 
2
O
7.16.6Studtite
[(UO
 
2
)(O
 
2
)(H
 
2
O)
 
2
] · H
 
2
O
7.16.8Compreignacite
K
 
2
(UO
 
2
)
 
6
O
 
4
(OH)
 
6
· 7H
 
2
O
7.16.9Vandenbrandeite
Cu(UO
 
2
)(OH)
 
4
7.16.10Roubaultite
Cu
 
2
(UO
 
2
)
 
3
(OH)
 
10
· 5H
 
2
O
7.16.11Becquerelite
Ca(UO
 
2
)
 
6
O
 
4
(OH)
 
6
· 8H
 
2
O
7.16.12Rameauite
K
 
2
Ca(UO
 
2
)
 
6
(OH)
 
16
· H
 
2
O
7.16.13Agrinierite
K
 
2
(Ca,Sr)(UO
 
2
)
 
3
O
 
3
(OH)
 
2
· 5H
 
2
O
7.16.14Protasite
Ba(UO
 
2
)
 
3
O
 
3
(OH)
 
2
· 3H
 
2
O
7.16.15Billietite
Ba(UO
 
2
)
 
6
O
 
4
(OH)
 
6
· 4-8H
 
2
O
7.16.16Bauranoite
Ba(UO
 
2
)
 
2
(OH)
 
6
· 1-2H
 
2
O
7.16.17Metacalciouranoite
(Ca,Ba,Pb,K
 
2
)U
 
2
O
 
7
· 2H
 
2
O
7.16.18Calciouranoite
(Ca,Ba,Pb)U
 
2
O
 
7
· 5H
 
2
O
7.16.19Orthobrannerite
U
4+
 
U
6+
 
Ti
 
4
O
 
12
(OH)
 
2
7.16.20Thorutite
(Th,U,Ca)Ti
 
2
(O,OH)
 
6
7.16.21Davidite-(La)
(La,Ce)(Y,U,Fe)(Ti,Fe)
 
20
(O,OH)
 
38
7.16.22Davidite-(Ce)
(Ce,La)(Y,U,Fe)(Ti,Fe)
 
20
(O,OH)
 
38
7.16.23Brannerite
(U
4+
 
,REE,Th,Ca)(Ti,Fe
3+
 
,Nb)
 
2
(O,OH)
 
6
7.16.24Fourmarierite
Pb(UO
 
2
)
 
4
O
 
3
(OH)
 
4
· 4H
 
2
O
7.16.25Richetite
Pb(UO
 
2
)
 
4
O
 
5
· 4H
 
2
O
7.16.26Curite
Pb
 
3
(UO
 
2
)
 
8
O
 
8
(OH)
 
6
· 3H
 
2
O
7.16.27Masuyite
Pb(UO
 
2
)
 
3
O
 
3
(OH)
 
2
· 3H
 
2
O
7.16.28Vandendriesscheite
PbU
 
7
O
 
22
· 12H
 
2
O
7.16.29Metavandendriesscheite
PbU
 
7
O
 
22
· nH
 
2
O n < 12
7.16.30Sayrite
Pb
 
2
(UO
 
2
)
 
5
O
 
6
(OH)
 
2
· 4H
 
2
O
7.16.31Wölsendorfite
(Pb,Ca)U
 
2
O
 
7
· 2H
 
2
O
7.16.32Clarkeite
(Na,Ca,Pb)(UO
 
2
)O(OH) · 0-1H
 
2
O
7.16.33Uranosphaerite
Bi(UO
 
2
)O
 
2
(OH)

Other Names for Ianthinite

Synonyms:
JanthinietLanthiniteLanthinite (of Schoep)Lanthite
Other Languages:
German:Ianthinit
Janthinit
Lanthinit
Lanthit
Lianthinit
Simplified Chinese:水斑铀矿
Spanish:Ianthinita
Lanthinita
Lanthita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ianthinite

Reference List:

- +
Schoep (1926), Naturrw. Tijdschr.: 7: 97.

Schoep (1927), Soc. géol. Belgique, Ann.: 49: B310.

Palache, C. (1934), American Mineralogist: 19: 309.

Palache, Charles, Harry Berman & Clifford Frondel (1944), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Volume I: Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, Inc., New York. 7th edition, revised and enlarged: 633-634.

American Mineralogist (1959): 44: 1103.

Burns, P.C., Finch, R.J., Hawthorne, F.C., Miller, M.L., and Ewing, R.C. (1997c) The crystal structure of ianthinite, [U 4+ 2(UO2)4O6(OH)4(H2O)4](H2O)5: a possible phase for Pu 4+ incorporation during the oxidation of spent nuclear fuel. Journal of Nuclear Mater.: 249: 199-206.

American Mineralogist: 83 (1998): 911.

Burns, P.C. (2005) U 6+ minerals and inorganic compounds: insights into an expanded structural hierarchy of crystal structures. Canadian Mineralogist: 43: 1839-1894.

Internet Links for Ianthinite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Ianthinite details from Handbook of Mineralogy (PDF)
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  • Localities for Ianthinite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • Tasmania
      • Rossarden district
    Bottrill (unpub)
    Democratic Republic of Congo (Zaïre)
     
    • Katanga (Shaba)
      • Katanga Copper Crescent
        • Kolwezi District
          • Kolwezi
        • Shinkolobwe
    [Bull. de Min.82 (1959), 80; Clark, 1993 - "Hey's Mineral Index"]
        • Swambo
    MinRec 20:287-288
    France
     
    • Auvergne
      • Puy-de-Dôme
        • Puy-Guillaume
          • Lachaux
    Le Règne Minéral, Hors Série IV (1998)
    J. Geffroy, J.A. Sarcia, J. Chervet : "Les Minéraux Uranifères Français", 1960, Institut National des Sciences et Techniques Nucléaires / Saclay - PUF.
    • Burgundy
      • Saône-et-Loire
        • Gueugnon
          • Neuvy-Grandchamp
    Le Règne Minéral, Hors Série IV, 1998
    • Languedoc-Roussillon
      • Hérault
        • Lodève
    Le Règne Minéral, Hors Série IV (1998)
    [Le Cahier des Micromonteurs, 1998, 2, p.13-26]
    [Le Règne Minéral 1997, 13, p.5-18]
    • Limousin
      • Haute-Vienne
        • Compreignac
    Le Règne Minéral, Hors Série IV, 1998
    Le Règne Minéral, Hors Série IV (1998)
        • Saint-Sylvestre
    Le Règne Minéral, Hors Série IV, 1998
    • Poitou-Charentes
      • Deux-Sèvres
        • La Chapelle Largeau
    Le Cahier des micromonteurs, 2002, N°75, pp 8-25
        • Saint-Amand-sur-Sèvre
    Le Cahier des micromonteurs, 2002, N°75, pp 8-25
    • Rhône-Alpes
      • Loire
        • Saint-Just-en-Chevalet
          • Saint-Priest-la-Prugne
    Le Règne Minéral, Hors Série IV, 1998
    J. Chervet et G. Branche : "Contribution à l'Etude des Minéraux Secondaires d'Uranium Français", Annales de l'Ecole Nationale Supérieure de Géologie Appliquée et de Prospection Minière de l'Université de Nancy, 1955 ; J.-J. Périchaud: "Où trouver les minéraux d'Auvergne", Vol. 1, Editions l'Instant Durable (Clermont-Ferrand), 1985, p. 92
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Menzenschwand
    No reference listed
        • Wolfach
          • Oberwolfach
            • Rankach valley
    KOLITSCH, U. (1997): Ianthinit und weitere Neufunde aus der Grube Clara im mittleren Schwarzwald. - Erzgräber 11 (2), 76-88; WALENTA, K. (1999): Neue Mineralfunde von der Grube Clara. 8. Folge, 1. Teil. Lapis 24 (11), 34-37; Gröbner, J., Kolitsch, U. und Bayerl, R. (2005): Interessante Uranmineralien im Stinkspat der Grube Clara. Lapis 30 (10), 34-39; 90; Gröbner, J., Bayerl, R. und Kolitsch, U. (2006): Weitere Beobachtungen zu den Uran- und Vanadium-Paragenesen der Grube Clara aus den Jahren 2002, 2004 und 2005. Erzgräber 20, 1-10
    • Bavaria
      • Upper Palatinate
        • Oberpfälzer Wald
          • Mähring
            • Uranium deposit
    Weiss: "Mineralfundstellen, Deutschland West", 1990
        • Schwandorf
          • Wölsendorf Fluorite mining District
            • Wölsendorf East District (Wölsendorf - Nabburg District)
    No reference listed
    Italy
     
    • Sardinia
      • Cagliari Province
        • Capoterra
    Olmi F., Sabelli C., Senesi F., Stara P., 2002. La mineralizzazione uranifera di Arcu su Linnarbu. Riv. Miner. Ital., 3: 148-169.
    • Trentino-Alto Adige
      • Trento Province
        • Condino
    Campostrini, I., Demartin, F., & Gramaccioli, C. M. (2006). Rio Giulis. Minerali secondari del giacimento uranifero presso Condino, Trento. Rivista Mineralogica Italiana, 30(3), 152-165.
    Mexico
     
    • Chihuahua
      • Mun. de Aldama
        • Peña Blanca District
          • Sierra Peña Blanca
    http://www.swri.org/4org/d20/ghs/PBlanca/mineral.html
    Slovakia
     
    • Banská Bystrica Region
      • Rimavská Sobota Co.
    Koděra et all.,1990: Topografická mineralógia Slovenska, I-III, 1590p
    • Košice Region
      • Spišská Nová Ves Co.
        • Hnilčík
    Koděra, M. et al., 1986 a 1990 : Topografická mineralógia Slovenska, diel 1- 3, Veda – Vydavateľstvo SAV, Bratislava, 1990, 1 – 1590k
        • Spišská Nová Ves Mining District
          • Novoveská Huta
    Koděra et all.,1990: Topografická mineralógia Slovenska, I-III, 1590p
    USA
     
    • Colorado
      • Gunnison Co.
        • Marshall Pass District
    Minerals of Colorado (1997) E.B. Eckels
      • Saguache Co.
        • Marshall Pass District
    Minerals of Colorado (1997) Eckel, E. B.; Am Min 50:909-923
    Minerals of Colorado (1997) Eckels, E. B.
    Mineral and/or Locality
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