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Johillerite

Big Photo

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure (Main Fracture) eruption, Tolbachik volcano, Kamchatka Oblast', Far-Eastern Region, Russia
© Brent Thorne 2007

Formula:
Na(Mg,Zn)
 
3
Cu[AsO
 
4
]
 
3
System:MonoclinicHardness:3
Name:After Professor Johannes-Erich Hiller (1911–1972), mineralogist, University of
Stuttgart, Stuttgart, Germany.
This page provides mineralogical data about Johillerite.

Classification of Johillerite

IMA status:Approved 1980
Strunz 8th edition ID:7/A.07-10
Nickel-Strunz 10th (pending) edition ID:8.AC.10

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th edition ID:38.2.7.2
Dana 8th edition ID:38.2.3.8

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
Hey's CIM Ref.:20.3.14

20 : Arsenates (also arsenates with phosphate, but without other anions)
3 : Arsenates of Zn, Cd or Hg
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Type Occurrence of Johillerite

Type Locality:Tsumeb Mine (Tsumcorp Mine), Tsumeb, Otjikoto (Oshikoto) Region, Namibia
Year of Discovery:1982

Physical Properties of Johillerite

Hardness (Mohs):3

Crystallography of Johillerite

Crystal System:Monoclinic
Cell Parameters:a = 11.87Å, b = 12.75Å, c = 6.77Å
β = 113.42°
Ratio:a:b:c = 0.931 : 1 : 0.531
Unit Cell Volume:V 940.18 ų (Calculated from Unit Cell)

Optical Data of Johillerite

Type:Biaxial (+)
RI values: nα = 1.715 nβ = 1.743 nγ = 1.783
2V:Measured: 80° , Calculated: 82°
Maximum Birefringence:δ = 0.068

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:weak

Chemical Properties of Johillerite

Formula:
Na(Mg,Zn)
 
3
Cu[AsO
 
4
]
 
3
Essential elements:As, Cu, Mg, Na, O
All elements listed in formula:As, Cu, Mg, Na, O, Zn

Relationship of Johillerite to other Species

Related Minerals - Nickel-Strunz Grouping):
8.AC.05Howardevansite
NaCuFe
 
2
(VO
 
4
)
 
3
8.AC.10Alluaudite
(Na,Ca)Mn
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
,Mg)
 
2
(PO
 
4
)
 
3
8.AC.10Arseniopleite
NaCaMn
2+
 
(Mn
2+
 
,Mg)
 
2
(AsO
 
4
)
 
3
8.AC.10Caryinite
(Na,Pb)(Ca,Na)((Ca,Mn
2+
 
)(Mn
2+
 
,Mg,Fe
3+
 
)[AsO
 
4
]
 
3
8.AC.10Ferroalluaudite
(Na,Ca)Fe
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)
 
3
8.AC.10Hagendorfite
NaCaMn
2+
 
Fe
2+
2
(PO
 
4
)
 
3
8.AC.10Maghagendorfite
NaMn(Mg,Fe,Fe)
 
3
(PO
 
4
)
 
3
8.AC.10Nickenichite
Na
 
0.8
Ca
 
0.4
Cu
 
0.4
(Mg,Fe)
 
3
(AsO
 
4
)
 
3
8.AC.10Varulite
NaCaMn
2+
 
Mn
2+
2
(PO
 
4
)
 
3
8.AC.10Ferrohagendorfite
(Na,Ca)
 
2
Fe
2+
 
(Fe
2+
 
,Fe
3+
 
)
 
2
(PO
 
4
)
 
3
8.AC.10Bradaczekite
NaCu
 
4
(AsO
 
4
)
 
3
8.AC.10Yazganite
NaFe
3+
2
(Mg,Mn
2+
 
)[AsO
 
4
]
 
3
 · H
 
2
O
8.AC.10Ferro-alluaudite
8.AC.15Bobfergusonite
Na
 
2
Mn
 
5
FeAl(PO
 
4
)
 
6
8.AC.15Ferrowyllieite
(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO
 
4
)
 
3
8.AC.15Qingheiite
NaMn
3+
 
Mg(Al,Fe
3+
 
)[PO
 
4
]
 
3
8.AC.15Rosemaryite
(Na,Ca,Mn)(Mn,Fe
2+
 
)(Fe
3+
 
,Mg)Al(PO
 
4
)
 
3
8.AC.15Wyllieite
(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO
 
4
)
 
3
8.AC.15Ferrorosemaryite
[]NaFe
2+
 
Fe
3+
 
Al(PO
 
4
)
 
3
8.AC.20Marićite
NaFe
2+
 
[PO
 
4
]
8.AC.25Berzeliite
NaCa
 
2
(Mg,Mn
2+
 
)
 
2
[AsO
 
4
]
 
3
8.AC.25Manganberzeliite
(Ca,Na)
 
3
(Mn
2+
 
,Mg)
 
2
[AsO
 
4
]
 
3
8.AC.25Palenzonaite
(Ca,Na)
 
3
CaMn
2+
2
[VO
 
4
]
 
3
8.AC.25Schäferite
Ca
 
2
NaMg
 
2
[VO
 
4
]
 
3
8.AC.30Brianite
Na
 
2
CaMg[PO
 
4
]
 
2
8.AC.35Vitusite-(Ce)
Na
 
3
(Ce,La,Nd)(PO
 
4
)
 
2
8.AC.40Olgite
Ba(NaSr)
 
2
Na[PO
 
4
]
 
2
8.AC.40Bario-olgite
Ba(Na,Sr,REE)
 
2
Na[PO
 
4
]
 
2
8.AC.45Strontiowhitlockite
Sr
 
9
MgH[PO
 
4
]
 
7
8.AC.45Whitlockite
Ca
 
9
Mg[PO
 
3
OH][PO
 
4
]
 
6
8.AC.45Merrillite
Ca
 
18
Na
 
2
Mg
2+
2
[PO
 
4
]
 
14
8.AC.45Tuite
Ca
 
3
[PO
 
4
]
 
2
8.AC.45Ferromerrillite
Ca
 
9
Fe
2+
 
Na[PO
 
4
]
 
7
8.AC.50Chladniite
{Ca}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mg,Fe
2+
 
)
 
43
}[PO
 
4
]
 
36
8.AC.50Fillowite
{Mn
2+
 
}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mn
2+
 
,Fe
2+
 
)
 
43
}[PO
 
4
]
 
36
8.AC.50Johnsomervilleite
{Ca}{Na
 
6
[ ]
 
2
}{Ca
 
6
Na
 
2
}{(Fe
2+
 
,Mg,Mn
2+
 
)
 
43
}[PO
 
4
]
 
36
8.AC.50Galileiite
{Fe
2+
 
}{Na
 
8
}{Fe
2+
4
Na
 
4
}{Fe
2+
43
}[PO
 
4
]
 
36
8.AC.50Stornesite-(Y)
{(Y, Ca)}{Na
 
6
[ ]
 
2
}{(Ca,Na)
 
8
}{(Mg,Fe
2+
 
)
 
43
}[PO
 
4
]
 
36
8.AC.50IMA2006-006
Na
 
4
Fe
2+
7
[PO
 
4
]
 
6
8.AC.55Harrisonite
Ca(Fe
2+
 
,Mg)
 
6
[PO
 
4
|SiO
 
4
]
 
2
8.AC.60Kosnarite
KZr
 
2
(PO
 
4
)
 
3
8.AC.65Panethite
(Na,Ca)
 
2
(Mg,Fe
2+
 
)
 
2
[PO
 
4
]
 
2
8.AC.70Stanfieldite
Ca
 
7
Ca
 
2
Mg
 
9
[PO
 
4
]
 
12
8.AC.75Ronneburgite
K
 
2
MnV
 
4
O
 
12
8.AC.80Tillmannsite
(Ag
 
3
Hg)[(VO
 
4
, AsO
 
4
)]
8.AC.85Filatovite
K[(Al,Zn)
 
2
(As,Si)
 
2
O
 
8
]
Related Minerals - Hey's Index Grouping:
20.3.1Adamite
Zn
 
2
(AsO
 
4
)(OH)
20.3.2Paradamite
Zn
 
2
[OH|AsO
 
4
]
20.3.3Koritnigite
Zn[HAsO
 
4
] · H
 
2
O
20.3.4Legrandite
Zn
 
2
[OH|AsO
 
4
] · H
 
2
O
20.3.5Warikahnite
Zn
 
3
(AsO
 
4
)
 
2
·2H
 
2
O
20.3.6Köttigite
Zn
 
3
(AsO
 
4
)
 
2
·8H
 
2
O
20.3.7Stranskiite
(Zn,Cu)
 
3
[AsO
 
4
]
 
2
20.3.8Philipsburgite
(Cu,Zn)
 
6
[(OH)
 
3
|(AsO
 
4
,PO
 
4
)]
 
2
 · H
 
2
O
20.3.9Austinite
CaZn[OH|AsO
 
4
]
20.3.10Prosperite
CaZn
 
2
[OH|HAsO
 
4
|AsO
 
4
]
20.3.11Gaitite
Ca
 
2
Zn[AsO
 
4
]
 
2
 · 2H
 
2
O
20.3.12Zincroselite
Ca
 
2
Zn[AsO
 
4
]
 
2
 · 2H
 
2
O
20.3.13O'Danielite
Na(Zn,Mg)
 
3
H
 
2
(AsO
 
4
)
 
3
20.3.15Holdenite
(Mn
2+
 
,Mg)
 
6
Zn
 
3
[(OH)
 
8
|(AsO
 
4
)
 
2
|SiO
 
4
]
20.3.16Chudobaite
(Na,K)(Mg,Zn)
 
2
H(AsO
 
4
)(OH,O)
 
6
20.3.17Chlorophoenicite
(Mn,Mg)
 
3
Zn
 
2
(AsO
 
4
)(OH,O)
 
6
20.3.18Lotharmeyerite
Ca(Zn,Mn
3+
 
)
 
2
[AsO
 
4
]
 
2
 · 2(H
 
2
O,OH)
20.3.19Metaköttigite
(Zn,Fe,Fe)
 
3
(AsO
 
4
)
 
2
·8(H
 
2
O,OH)
20.3.20Ojuelaite
ZnFe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
20.3.21Fahleite
Zn
 
5
CaFe
 
2
(AsO
 
4
)
 
6
·14H
 
2
O
20.3.22Keyite
(Cu,Zn,Cd)
 
3
(AsO
 
4
)
 
2
Related Minerals - Dana Grouping):
38.2.7.1O'Danielite
Na(Zn,Mg)
 
3
H
 
2
(AsO
 
4
)
 
3
38.2.7.3Nickenichite
Na
 
0.8
Ca
 
0.4
Cu
 
0.4
(Mg,Fe)
 
3
(AsO
 
4
)
 
3
38.2.7.5Yazganite
NaFe
3+
2
(Mg,Mn
2+
 
)[AsO
 
4
]
 
3
 · H
 
2
O

Other Names for Johillerite

Synonyms:
IMA1980-014
German names:
Johillerit
Russian names:
Йохиллерит
Spanish names:
Johillerita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Johillerite

Reference List:Keller, P., H. Hess, and P.J. Dunn (1982) Johillerit, Na(Mg, Zn)3Cu(AsO4)3,
ein neues Mineral aus Tsumeb, Namibia. Tschermaks Mineral. Petrog. Mitt., 29, 169–175 (in German with English abstract).

American Mineralogist (1982): 67: 1075 (abstract).

Keller, P. and Hess, H. (1988): Die Kristallstrukturen von O'Danielit, Na(Zn,Mg)3H2(AsO4)3 und Johillerit, Na(Mg,Zn)3Cu(AsO4)3. Neues Jahrbuch fuer Mineralogie Monatshefte 1988, 395-404. (in German).

Internet Links for Johillerite

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  • Raman and XRD data at RRUFF project
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    Localities for Johillerite

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    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Germany
     
    • North Rhine-Westphalia
      • Sauerland
        • Iserlohn
          • Letmathe
    		Wittern: "Mineralfundorte in Deutschland", 2001
    Namibia
     
    • Otjikoto (Oshikoto) Region
      • Tsumeb
    		Tschermak's Min.Petr.Mitt.(1982) 29, 169-175
    Russia
     
    • Far-Eastern Region
      • Kamchatka Oblast'
        • Tolbachik volcano
          • Great Fissure (Main Fracture) eruption
            • Northern Breakthrough (North Breach)
    		L.P. Vergasova et al.: Eur. J. Mineral. 16:533-543 (2004)
    Mineral and/or Locality
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