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Julienite

Formula:
Na
 
2
[Co(SCN)
 
4
] · 8H
 
2
O
System:MonoclinicColour:Blue
Name:For the Belgian scientist Henri Julien (d. 1920), who discovered the mineral.


Sodium tetrathiocyanatocobaltate(II) octahydrate - a complex salt.

A very rare mineral occurring as crusts.

Classification of Julienite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:9/A.02-50
Nickel-Strunz 10th (pending) edition ID:10.AD.05

10 : ORGANIC COMPOUNDS
A : Salts of organic acids
D : Cyanates
Dana 8th edition ID:50.2.3.1

50 : ORGANIC COMPOUNDS
2 : Mellitates, Citrates, Cyanates, Acetates and Formates
Hey's CIM Ref.:30.1

30 : Thiocyanates
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Type Occurrence of Julienite

Type Locality:Shamitumba (Chamibumba), Shinkolobwe, Central area, Katanga Copper Crescent, Katanga (Shaba), Democratic Republic of Congo (Zaïre)
General Appearance of Type Material:Blue incrustations
Year of Discovery:1935
Geological Setting of type material:White talc schist
Associated Minerals at type locality:
Cobaltian Wad

Physical Properties of Julienite

Diaphaneity (Transparency):Translucent
Colour:Blue
Streak:Blue.
Comment:Hardness not determined.
Density (measured):1.648 g/cm3
Density (calculated):1.61 g/cm3

Crystallography of Julienite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Cell Parameters:a = 18.941Å, b = 19.209Å, c = 5.460Å
β = 91.64°
Ratio:a:b:c = 0.986 : 1 : 0.284
Unit Cell Volume:V 1,985.74 ų (Calculated from Unit Cell)
Z:4
Morphology:Crystals as minute needles,elongated [001], aggregated into crusts; acicular [001].
Twinning:On {110} as the twin plane,or around [001].
Comment:Pseudotetragonal. Space Group = P21/n, based on synthetic material.

Optical Data of Julienite

Type:Uniaxial (+)
RI values: nω = 1.556 nε = 1.645
Maximum Birefringence:δ = 0.089

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Julienite

Formula:
Na
 
2
[Co(SCN)
 
4
] · 8H
 
2
O
Essential elements:C, Co, H, N, Na, O, S
All elements listed in formula:C, Co, H, N, Na, O, S

Relationship of Julienite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
10.AD.10Kafehydrocyanite
K
 
4
[Fe(CN)
 
6
] · H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
30.2Kafehydrocyanite
K
 
4
[Fe(CN)
 
6
] · H
 
2
O

Other Names for Julienite

Other Languages:
German:Julienit
Russian:Джульенит
Spanish:Julienita

Other Information

Other Information:Readily soluble in water, soluble in alcohol, yielding a pink solution.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Julienite

Reference List:Schoep, A. (1928) Natuurw. Tijdschr., Antwerp: 10: 58.

Foshag, W.F. (1932) American Mineralogist, 17, #10, 496.

Schoep, A. and V. Billiet (1935) Contribution à l’étude du réseau de la julienite [Na2Co(CSN)4 •8H2O]. Zeits. Krist., 91, 229–234 (in French).

Palache, Charles, Harry Berman & Clifford Frondel (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Seventh edition, Volume II: 1106-1107.

Mereiter, K. and A. Preisinger (1982) The structure of sodium tetraisothiocyanatocobaltate(II) octahydrate Na2[Co(NCS)4].8H2O. Acta Crystallographica (1982): B38: 1084-1088.

Internet Links for Julienite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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  • Julienite details from Handbook of Mineralogy (PDF)
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    Localities for Julienite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Democratic Republic of Congo (Zaïre)
     
    • Katanga (Shaba)
      • Katanga Copper Crescent
        • Central area
          • Shinkolobwe
    Schoep, A. and V. Billiet (1935) Contribution à l’étude du réseau de la julienite [Na2Co(CSN)4 •8H2O]. Zeits. Krist., 91, 229–234 (in French); Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1106; Mereiter, K. and A. Preisinger (1982) Acta Crystallographica (1982): B38: 1084-1088.
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