Kentrolite
A valid IMA mineral species - grandfathered
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About Kentrolite
Formula:
Pb2Mn3+2(Si2O7)O2
Colour:
Black, sometimes with dark red internal reflections
Lustre:
Sub-Adamantine, Resinous, Greasy
Hardness:
5
Specific Gravity:
6.26
Crystal System:
Orthorhombic
Name:
Named in 1880 by Alexis Damour and Gerhard von Rath from the Greek ÎșΔΜÏÏÎŻ for "thorn" or "spike", in allusion to its habit. The type locality is given by Damour & von Rath (1881) as "im sĂŒdlichen Chile" (in southern Chile).
Unique Identifiers
Mindat ID:
2185
Long-form identifier:
mindat:1:1:2185:8
GUID
(UUID V4):
(UUID V4):
0a85c4d2-f295-4881-bd9d-c733b02fa6be
IMA Classification of Kentrolite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Pb2Mn3+2O2(Si2O7)
Classification of Kentrolite
9.BE.80
9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
56.2.10.2
56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination
56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination
14.13.7
14 : Silicates not Containing Aluminum
13 : Silicates of Pb
14 : Silicates not Containing Aluminum
13 : Silicates of Pb
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Ken | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Kentrolite
Sub-Adamantine, Resinous, Greasy
Transparency:
Translucent
Colour:
Black, sometimes with dark red internal reflections
Streak:
Brown to yellowish brown
Hardness:
5 on Mohs scale
Hardness Data:
Measured
Tenacity:
Brittle
Cleavage:
Distinct/Good
{110}
{110}
Fracture:
Irregular/Uneven
Density:
6.26 g/cm3 (Measured) 6.29 g/cm3 (Calculated)
Optical Data of Kentrolite
Type:
Biaxial (+)
RI values:
nα = 2.100 nβ = 2.200 nγ = 2.310
2V:
Measured: 88° , Calculated: 88°
Birefringence:
0.21
Max Birefringence:
δ = 0.210
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
strong r < v
Optical Extinction:
Parallel
Pleochroism:
Strong
Comments:
X= bright yellowish pink
Y= reddish brown
Z= deep brownish red
Y= reddish brown
Z= deep brownish red
Chemistry of Kentrolite
Mindat Formula:
Pb2Mn3+2(Si2O7)O2
Elements listed:
Common Impurities:
Ti,Al,Fe,Zn,Mg
Chemical Analysis
Oxide wt%:
1 | |
---|---|
SiO2 | 28.35 % |
TiO2 | 0.05 % |
Al2O3 | 2.37 % |
Fe2O3 | 30.82 % |
MnO | 28.99 % |
MgO | 0.81 % |
CaO | 2.10 % |
BaO | 2.29 % |
PbO | 0.86 % |
Na2O | 1.35 % |
K2O | 0.40 % |
P2O5 | 0.05 % |
H2O | 0.48 % |
S | 0.01 % |
Total: | 98.93 % |
Sample references:
ID | Locality | Reference | Notes |
---|---|---|---|
1 | Klint mine, FolkÀrna, Avesta, Dalarna County, Sweden | Wet chemical analysis by Dr. A. Bygdén of the Geological Survey of Sweden. |
Crystallography of Kentrolite
Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pbcm
Cell Parameters:
a = 6.961 Å, b = 11.018 Å, c = 9.964 Å
Ratio:
a:b:c = 0.632 : 1 : 0.904
Unit Cell V:
764.20 Ă
Âł (Calculated from Unit Cell)
Morphology:
Prismatic to equant. Isolated crystals or rosettes, sheaflike groups, massive.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0001395 | Kentrolite | Moore P B, Sen Gupta P K, Shen J, Schlemper E O (1991) The kentrolite-melanotekite series, 4Pb2(Mn,Fe)2O2[Si2O7]: Chemical crystallographic relations, lone-pair splitting, and cation relation to 8URe2 American Mineralogist 76 1389-1399 | 1991 | 0 | 293 | ||
0004536 | Kentrolite | Dorsam G, Liebscher A, Wunder B, Franz G (2008) Crystal structures of synthetic melanotekite (Pb2Fe2Si2O9), kentrolite (Pb2Mn2Si2O9), and the aluminum analogue (Pb2Al2Si2O9) American Mineralogist 93 573-583 | 2008 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
5.56 Ă | (60) |
3.71 Ă | (80) |
3.51 Ă | (80) |
3.24 Ă | (80) |
2.96 Ă | (50) |
2.90 Ă | (100) |
2.86 Ă | (100) |
2.74 Ă | (100) |
Comments:
20-586 (natural)
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-đ alteration and/or metamorphism | |
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits |
Geological Setting:
Oxide zinc deposits.
Type Occurrence of Kentrolite
Other Language Names for Kentrolite
Relationship of Kentrolite to other Species
Forms a series with:
Common Associates
Associated Minerals Based on Photo Data:
40 photos of Kentrolite associated with Rhodochrosite | MnCO3 |
7 photos of Kentrolite associated with Vanadinite | Pb5(VO4)3Cl |
6 photos of Kentrolite associated with Arsenic-bearing Vanadinite | Pb5[(V,As)O4]3Cl |
5 photos of Kentrolite associated with Calcite | CaCO3 |
5 photos of Kentrolite associated with Baryte | BaSO4 |
4 photos of Kentrolite associated with Axinite-(Mn) | Ca2Mn2+Al2BSi4O15(OH) |
2 photos of Kentrolite associated with Cerussite | PbCO3 |
2 photos of Kentrolite associated with Braunite | Mn2+Mn3+6(SiO4)O8 |
2 photos of Kentrolite associated with Aragonite | CaCO3 |
2 photos of Kentrolite associated with Quartz | SiO2 |
Related Minerals - Strunz-mindat Grouping
9.BE. | Paralomonosovite | Na6â»4Ti4(Si2O7)2[PO3OH][PO2(OH)2]O2(OF) |
9.BE. | CĂĄmaraite | Ba3Na(Fe2+,Mn)8Ti4(Si2O7)4O4(OH,F)7 |
9.BE. | ChristofschÀferite-(Ce) | Ce3CaMnTiFe(3+)Ti2(Si2O7)2O8 |
9.BE. | Bobshannonite | Na2KBa(Mn,Na)8(Nb,Ti)4(Si2O7)4O4(OH)4(O,F)2 |
9.BE. | Calciomurmanite | (Na,â»)2Ca(Ti,Mg,Nb)4[Si2O7]2O2(OH,O)2(H2O)4 |
9.BE. | Batievaite-(Y) | Y2Ca2Ti(Si2O7)2(OH)2(H2O)4 |
9.BE. | Delhuyarite-(Ce) | Ce4Mg(Fe3+,W)3â»(Si2O7)2O6(OH)2 |
9.BE.X | Asimowite | Fe2+4O(Si2O7) |
9.BE. | Moxuanxueite | NaCa6Zr(Si2O7)2OF3 |
9.BE. | Alexkuznetsovite-(Ce) | Ce2Mn(CO3)(Si2O7) |
9.BE. | Biraite-(La) | La2Fe2+(CO3)(Si2O7) |
9.BE. | Zinkgruvanite | Ba4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2 |
9.BE. | Madeiraite | Na2Ca2Fe2Zr2(Si2O7)2O2F2 |
9.BE. | Bortolanite | Ca2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(OF)F2 |
9.BE. | Nacareniobsite-(Y) | Na3Ca3YNb(Si2O7)2OF3 |
9.BE. | Pilanesbergite | Na2Ca2Fe2Ti2(Si2O7)2O2F2 |
9.BE. | Alfredcasparite | Sr2TiO(Si2O7) |
9.BE.02 | Wadsleyite | Mg4O(Si2O7) |
9.BE.05 | Hennomartinite | SrMn3+2(Si2O7)(OH)2 · H2O |
9.BE.05 | Lawsonite | CaAl2(Si2O7)(OH)2 · H2O |
9.BE.05 | Noelbensonite | BaMn3+2(Si2O7)(OH)2 · H2O |
9.BE.05 | Itoigawaite | SrAl2(Si2O7)(OH)2 · H2O |
9.BE.05 | Cortesognoite | CaV2(Si2O7)(OH)2 · H2O |
9.BE.07 | Ilvaite | CaFe3+Fe2+2(Si2O7)O(OH) |
9.BE.07 | Manganilvaite | CaFe2+Fe3+Mn2+(Si2O7)O(OH) |
9.BE.07 | Amamoorite | CaMn2+2Mn3+(Si2O7)O(OH) |
9.BE.10 | Suolunite | Ca2(H2Si2O7) · H2O |
9.BE.12 | Jaffeite | Ca6(Si2O7)(OH)6 |
9.BE.15 | Fresnoite | Ba2Ti(Si2O7)O |
9.BE.17 | Baghdadite | Ca6Zr2(Si2O7)2O4 |
9.BE.17 | Burpalite | Na2CaZr(Si2O7)F2 |
9.BE.17 | Cuspidine | Ca8(Si2O7)2F4 |
9.BE.17 | Hiortdahlite | Na2Ca4(Ca0.5Zr0.5)Zr(Si2O7)2OF3 |
9.BE.17 | Janhaugite | (Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2 |
9.BE.17 | LĂ„venite | Na2Ca2Mn2Zr2(Si2O7)2O2F2 |
9.BE.17 | Niocalite | (Ca,Nb)4(Si2O7)(O,OH,F)2 |
9.BE.17 | Normandite | NaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OF |
9.BE.17 | Wöhlerite | Na2Ca4ZrNb(Si2O7)2O3F |
9.BE.20 | Mosandrite-(Ce) | (Ca3REE)[(H2O)2Ca0.5â»0.5]Ti(Si2O7)2(OH)2(H2O)2 |
9.BE.20 | Nacareniobsite-(Ce) | Na3Ca3(Ce,REE)Nb(Si2O7)2OF3 |
9.BE.20 | Roumaite | (Ca,Na,REE,â»)7(Nb,Ti)[Si2O7]2OF3 |
9.BE.20 | Rinkite-(Y) | Na2Ca4YTi(Si2O7)2OF3 |
9.BE.22 | Götzenite | NaCa6Ti(Si2O7)2OF3 |
9.BE.22 | Hainite-(Y) | Na2Ca4(Y,REE)Ti(Si2O7)2OF3 |
9.BE.22 | Rosenbuschite | Na6Ca6Zr3Ti(Si2O7)4O2F6 |
9.BE.22 | Kochite | Na3Ca2MnZrTi(Si2O7)2OF3 |
9.BE.22 | Fogoite-(Y) | Na3Ca2Y2Ti(Si2O7)2OF3 |
9.BE.23 | Dovyrenite | Ca6Zr(Si2O7)2(OH)4 |
9.BE.25 | Barytolamprophyllite | (Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F) |
9.BE.25 | Ericssonite | BaMn2+2Fe3+(Si2O7)O(OH) |
9.BE.25 | Lamprophyllite | (Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2 |
9.BE.25 | Ericssonite-2O | BaMn2+2Fe3+(Si2O7)O(OH) |
9.BE.25 | Seidozerite | Na4MnZr2Ti(Si2O7)2O2F2 |
9.BE.25 | Nabalamprophyllite | (BaNa)Ti2Na3Ti(Si2O7)2O2(OH)2 |
9.BE.25 | Grenmarite | Na4MnZr3(Si2O7)2O2F2 |
9.BE.25 | SchĂŒllerite | Ba2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4 |
9.BE.25 | Kazanskyite | BaNa3Ti2Nb(Si2O7)2O2(OH)2(H2O)4 |
9.BE.25 | Lileyite | Ba2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2 |
9.BE.25 | Emmerichite | Ba2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2 |
9.BE.25 | Saamite | Baâ»Na3Ti2Nb(Si2O7)2O2(OH)F(H2O)2 |
9.BE.25 | Fluorlamprophyllite | Na3(SrNa)Ti3(Si2O7)2O2F2 |
9.BE.25 | Fluorbarytolamprophyllite | (Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2] |
9.BE.27 | Murmanite | Na2Ti2(Si2O7)O2 · 2H2O |
9.BE.27 | Vigrishinite | NaZnTi4(Si2O7)2O3(OH)(H2O)4 |
9.BE.27 | Kolskyite | CaNa2Ti4(Si2O7)2O4(H2O)7 |
9.BE.27 | Selivanovaite | NaFe3+Ti4(Si2O7)2O4(H2O)4 |
9.BE.30 | Epistolite | (Naâ»)Nb2Na3Ti(Si2O7)2O2(OH)2(H2O)4 |
9.BE.32 | Lomonosovite | Na5Ti2(Si2O7)(PO4)O2 |
9.BE.35 | Vuonnemite | Na11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH) |
9.BE.37 | Sobolevite | Na13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3 |
9.BE.40 | Innelite | Ba4Ti2Na(NaMn2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)] |
9.BE.40 | Phosphoinnelite | Na3Ba4Ti3(Si2O7)2(PO4,SO4)2O2F |
9.BE.42 | Yoshimuraite | Ba2Mn2Ti(Si2O7)(PO4)O(OH) |
9.BE.45 | Quadruphite | Na6Na2(CaNa)2Na2Ti2Na2Ti2(Si2O7)2(PO4)4O4F2 |
9.BE.47 | Polyphite | Na5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2 |
9.BE.50 | Bornemanite | Na6BaTi2Nb(Si2O7)2(PO4)O2(OH)F |
9.BE.50 | Shkatulkalite | Na2Nb2Na3Ti(Si2O7)2O2(FO)(H2O)4(H2O)3 |
9.BE.55 | Bafertisite | Ba2Fe2+4Ti2(Si2O7)2O2(OH)2F2 |
9.BE.55 | Hejtmanite | Ba2Mn2+4Ti2(Si2O7)2O2(OH)2F2 |
9.BE.55 | Bykovaite | (Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2O |
9.BE.55 | Nechelyustovite | (Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2O |
9.BE.60 | Delindeite | (Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2O |
9.BE.62 | Orthochevkinite | (Ce,La,Ca,Na,Th)4(Fe2+,Mg)2(Ti,Fe3+)3Si4O22 |
9.BE.62 va | Strontium Perrierite | (Ce,Sr,La,Ca)4Fe2+(Ti,Zr,Fe)2Ti2(Si2O7)2O8 |
9.BE.62 | Chevkinite-(Nd) | (Nd,REE)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8 ? |
9.BE.62 | Perrierite-(Nd) | Nd4MgFe3+2Ti2(Si2O7)2O8 ? |
9.BE.65 | Bussenite | Na2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3F |
9.BE.67 | Jinshajiangite | BaNaFe2+4Ti2(Si2O7)2O2(OH)2F |
9.BE.67 | Perraultite | BaNaMn2+4Ti2(Si2O7)2O2(OH)2F |
9.BE.70 | Karnasurtite-(Ce) | (Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2O |
9.BE.70 | Perrierite-(Ce) | Ce4MgFe3+2Ti2(Si2O7)2O8 |
9.BE.70 | Strontiochevkinite | (Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8 |
9.BE.70 | Chevkinite-(Ce) | Ce4(Ti,Fe2+,Fe3+)5O8(Si2O7)2 |
9.BE.70 | Polyakovite-(Ce) | (Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8 |
9.BE.70 | Rengeite | Sr4ZrTi4(Si2O7)2O8 |
9.BE.70 | Matsubaraite | Sr4Ti5(Si2O7)2O8 |
9.BE.70 | Dingdaohengite-(Ce) | (Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe2+)2Ti2(Si2O7)2O8 |
9.BE.70 | Maoniupingite-(Ce) | (Ce,Ca)4(Fe3+,Ti,Fe2+,â»)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8 |
9.BE.70 | Perrierite-(La) | (La,Ce,Ca)4(Fe2+,Mn)(Ti,Fe3+,Al)4[(Si2O7)O4]2 |
9.BE.70 | UM2008-53-SiO:SrTiZr | Sr4ZrTi4(Si2O7)2O8 |
9.BE.70 | Hezuolinite | (Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8 |
9.BE.72 | Fersmanite | Ca4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3 |
9.BE.75 | Belkovite | Ba3(Nb,Ti)6(Si2O7)2O12 |
9.BE.77 | Nasonite | Pb6Ca4(Si2O7)3Cl2 |
9.BE.80 | Melanotekite | Pb2Fe3+2(Si2O7)O2 |
9.BE.82 | Tilleyite | Ca5(Si2O7)(CO3)2 |
9.BE.82 | Alexkuznetsovite-(La) | La2Mn(CO3)(Si2O7) |
9.BE.85 | Killalaite | Ca6.4(H0.6Si2O7)2(OH)2 |
9.BE.87 | Stavelotite-(La) | (La,Nd,Ca)3Mn2+3Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O30 |
9.BE.90 | Biraite-(Ce) | Ce2Fe2+(Si2O7)(CO3) |
9.BE.90 | Magnesiorowlandite-(Y) | Y4(Mg,Fe)(Si2O7)2F2 |
9.BE.92 | Cervandonite-(Ce) | (Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH) |
9.BE.92 | Chirvinskyite | (Na,Ca)13(Fe,Mn,â»)2(Ti,Zr)5(Si2O7)4(OH,O)12 · 2H2O |
9.BE.95 | Batisivite | BaV3+8Ti6(Si2O7)O22 |
9.BE.95 | Rusinovite | Ca10(Si2O7)3Cl2 |
9.BE.97 | SchlĂŒterite-(Y) | (Y,REE)2AlSi2O7(OH)2F |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Kentrolite
mindat.org URL:
https://www.mindat.org/min-2185.html
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References for Kentrolite
Reference List:
Localities for Kentrolite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Chile (TL) | |
France | |
| Jordi Fabre specimens (more info available on fabreminerals.com forum) +1 other reference |
Italy | |
| Olmi F. et al. (SS) +2 other references |
| Marco Bonifazi find & collection. +1 other reference |
Kazakhstan | |
| Frank Dzubeck +1 other reference |
Frank Dzubeck | |
| Frank Dzubeck +1 other reference |
Mexico | |
| Espejel-Garcia et al. (2012, December) |
Namibia | |
| Dunn (1991) |
Norway | |
| Raade (1982) +2 other references |
South Africa | |
| Moore et al. (2011) +2 other references |
| Von Bezing (1991) |
Sweden | |
| Geijer (1939) |
| |
Gatedal (2003) | |
Gatedal (2003) | |
| Holtstam et al. (1999) |
Adolfsson (1979) | |
| Knut Eldjarn Collection |
Gatedal (n.d.) | |
| |
| Ounchanum et al. (1987) |
UK | |
| Turner (2006) +2 other references |
| Day (1999) |
| Burr (1996) |
USA | |
| Collected by |
| Palache (1935) +2 other references |
| NMBMMR New Mexico Mineral symposium (2001) |
Min Rec 20:1 p59 |
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LĂ„ngban Mine, LĂ„ngban Ore District, Filipstad, VĂ€rmland County, Sweden