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Keyite

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Big Photo

Tsumeb Mine (Tsumcorp Mine), Tsumeb, Otjikoto (Oshikoto) Region, Namibia
© Christian Rewitzer

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Formula:
Cu
2+
3
Zn
 
4
Cd
 
2
(AsO
 
4
)
 
6
 · 2H
 
2
O
System:MonoclinicColour:blue
Name:For prominent US mineral dealer, Charles Locke Key (b.1935).
This page provides mineralogical data about Keyite.

Classification of Keyite

IMA status:Approved 1975
Strunz 8th edition ID:7/C.30-20
Nickel-Strunz 10th (pending) edition ID:8.CA.50

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
A : With small and large/medium cations
Dana 8th edition ID:40.2.18.

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
2 : AB2(XO4)2·xH2O
Hey's CIM Ref.:20.3.22

20 : Arsenates (also arsenates with phosphate, but without other anions)
3 : Arsenates of Zn, Cd or Hg
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Type Occurrence of Keyite

Type Locality:Tsumeb Mine (Tsumcorp Mine), Tsumeb, Otjikoto (Oshikoto) Region, Namibia

Physical Properties of Keyite

Colour:blue
Density (measured):5.106 g/cm3

Crystallography of Keyite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Cell Parameters:a = 11.654(3) Å, b = 12.780(5) Å, c = 6.840(3) Å
β = 99.11°
Ratio:a:b:c = 0.912 : 1 : 0.535
Unit Cell Volume:V 1005.8 ų
Z:2
Comment:space group I2/a
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Keyite

Type:Biaxial
RI values: nα = 1.800 nγ = 1.870
Maximum Birefringence:δ = 0.070

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r > v

Chemical Properties of Keyite

Formula:
Cu
2+
3
Zn
 
4
Cd
 
2
(AsO
 
4
)
 
6
 · 2H
 
2
O
Essential elements:As, Cd, Cu, H, O, Zn
All elements listed in formula:As, Cd, Cu, H, O, Zn

Relationship of Keyite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
8.CA.05Fransoletite
Ca
 
3
Be
 
2
(PO
 
4
)
 
2
(HPO
 
4
)
 
2
 · 4H
 
2
O
8.CA.05Parafransoletite
Ca
 
3
Be
 
2
(PO
 
4
)
 
2
(HPO
 
4
)
 
2
 · 4H
 
2
O
8.CA.10Ehrleite
Ca
 
4
Be
 
3
Zn
 
2
(PO
 
4
)
 
6
 · 9H
 
2
O
8.CA.15Faheyite
(Mn,Mg,Na)Be
 
2
Fe
 
2
(PO
 
4
)
 
4
 · 6H
 
2
O
8.CA.20Gainesite
Na(Na,K)(Be,Li)Zr
 
2
(PO
 
4
)
 
4
 · 1.5-2H
 
2
O
8.CA.20Mccrillisite
NaCs(Be,Li)Zr
 
2
(PO
 
4
)
 
4
 · 1-2H
 
2
O
8.CA.20Selwynite
NaK(Be,Al)Zr
 
2
(PO
 
4
)
 
4
 · 2H
 
2
O
8.CA.25Pahasapaite
Li
 
8
(Ca,Li,K)
 
10.5
Be
 
24
(PO
 
4
)
 
24
 · 38H
 
2
O
8.CA.30Hopeite
Zn
 
3
(PO
 
4
)
 
2
 · 4H
 
2
O
8.CA.35Warikahnite
Zn
 
3
(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CA.40Phosphophyllite
Zn
 
2
Fe(PO
 
4
)
 
2
 · 4H
 
2
O
8.CA.45Parascholzite
CaZn
 
2
(PO
 
4
)
 
2
 · 2H
 
2
O
8.CA.45Scholzite
CaZn
 
2
(PO
 
4
)
 
2
 · 2H
 
2
O
8.CA.55Pushcharovskite
K
 
0.6
Cu
 
18
(AsO
 
4
)(HAsO
 
4
)
 
10
(H
 
2
AsO
 
4
)
 
4
(OH)
 
9.6
·18.6H
 
2
O
8.CA.60Prosperite
CaZn
 
2
(AsO
 
4
)(HAsO
 
4
)(OH)
8.CA.65Gengenbachite
KFe
3+
3
(HPO
 
4
)
 
4
(H
 
2
PO
 
4
)
 
2
 · 6H
 
2
O
8.CA.70Parahopeite
Zn
 
3
(PO
 
4
)
 
2
 · 4H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
20.3.1Adamite
Zn
 
2
(AsO
 
4
)(OH)
20.3.2Paradamite
Zn
 
2
(AsO
 
4
)(OH)
20.3.3Koritnigite
Zn(HAsO
 
4
) · H
 
2
O
20.3.4Legrandite
Zn
 
2
(AsO
 
4
)(OH) · H
 
2
O
20.3.5Warikahnite
Zn
 
3
(AsO
 
4
)
 
2
 · 2H
 
2
O
20.3.6Köttigite
Zn
 
3
(AsO
 
4
)
 
2
 · 8H
 
2
O
20.3.7Stranskiite
Zn
 
2
Cu(AsO
 
4
)
 
2
20.3.8Philipsburgite
(Cu,Zn)
 
6
(AsO
 
4
,PO
 
4
)
 
2
(OH)
 
6
 · H
 
2
O
20.3.9Austinite
CaZn(AsO
 
4
)(OH)
20.3.10Prosperite
CaZn
 
2
(AsO
 
4
)(HAsO
 
4
)(OH)
20.3.11Gaitite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
20.3.12Zincroselite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
20.3.13O'Danielite
Na(Zn,Mg)
 
3
H
 
2
(AsO
 
4
)
 
3
20.3.14Johillerite
Na(Mg,Zn)
 
3
Cu(AsO
 
4
)
 
3
20.3.15Holdenite
(Mn
2+
 
,Mg)
 
6
Zn
 
3
(AsO
 
4
)
 
2
(SiO
 
4
)(OH)
 
8
20.3.16Chudobaite
(Mg,Zn)
 
5
(AsO
 
4
)
 
2
(HAsO
 
4
)
 
2
 · 10H
 
2
O
20.3.17Chlorophoenicite
(Mn,Mg)
 
3
Zn
 
2
(AsO
 
4
)(OH,O)
 
6
20.3.18Lotharmeyerite
Ca(Zn,Mn
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
20.3.19Metaköttigite
(Zn,Fe,Fe)
 
3
(AsO
 
4
)
 
2
 · 8(H
 
2
O,OH)
20.3.20Ojuelaite
ZnFe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
20.3.21Fahleite
Zn
 
5
CaFe
 
2
(AsO
 
4
)
 
6
 · 14H
 
2
O

Other Names for Keyite

Synonyms:
IMA1975-002
Other Languages:
German:Keyit
Russian:Кейит
Spanish:Keyita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Keyite

Reference List:

- +
American Mineralogist (1977) 62: 1259.

Canadian Mineralogist (1996) 34: 623-630.

Internet Links for Keyite

Search Engines:
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    • External Links:
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  • Look for Keyite on Wikipedia
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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Keyite details from Handbook of Mineralogy (PDF)
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    • Specimens:The following Keyite specimens are currently listed for sale on minfind.com.
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    • Localities for Keyite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Greece
     
    • Attikí (Attica; Attika) Prefecture
      • Lavrion (Laurion; Laurium) District
        • Lavrion District Mines
          • Lavrion (Laurion; Laurium)
    		No reference listed
    Rieck, B: Seltene Arsenate aus der Kamariza und weitere Neufunde. LAPIS 24 (1999) 7/8, 68-76 (in German)
    Namibia
     
    • Otjikoto (Oshikoto) Region
      • Tsumeb
    		Min.Rec.(1977) 62, 59 and 87-90; Rocks & Min.: 62:440.
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    Copyright © Jolyon Ralph and Ida Chau 1993-2012. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them. Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. Mindat does not offer minerals for sale. If you would like to add information to improve the quality of our database, then click here to register.
    Current server date and time: 30th Jan 2012 12:31:23
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