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Krautite

Formula:
MnHAsO
 
4
·H
 
2
O
System:Monoclinic

Classification of Krautite

IMA status:Approved
Strunz 8th edition ID:7/C.05-20
Nickel-Strunz 10th (pending) edition ID:8.CB.15

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
B : With only medium-sized cations, RO4:H2O = 1:1
Dana 8th edition ID:39.1.3.1

39 : HYDRATED ACID PHOSPHATES,ARSENATES AND VANADATES
1 : A[HXO4]·xH2O
Hey's CIM Ref.:20.8.7

20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn
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Type Occurrence of Krautite

Type Locality:Sacarîmb (Sãcãrâmb; Szekerembe; Nagyág), Hunedoara Co., Romania
Year of Discovery:1975

Crystallography of Krautite

Crystal System:Monoclinic
Cell Parameters:a = 8.01Å, b = 15.95Å, c = 6.8Å
β = 96.6°
Ratio:a:b:c = 0.502 : 1 : 0.426
Unit Cell Volume:V 863.01 ų (Calculated from Unit Cell)

Optical Data of Krautite

Type:Biaxial (+)
RI values: nα = 1.620 nβ = 1.639 nγ = 1.686
2V:Measured: 65° , Calculated: 68°
Maximum Birefringence:δ = 0.066

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r < v strong

Chemical Properties of Krautite

Formula:
MnHAsO
 
4
·H
 
2
O
Essential elements:As, H, Mn, O
All elements listed in formula:As, H, Mn, O

Relationship of Krautite to other Species

Member of Group:
Krautite Group:
MHAsO
 
4
·nH
 
2
O (n = 1, 2)
Related Minerals - Nickel-Strunz Grouping):

- +
8.CB.05Serrabrancaite
MnPO
 
4
·H
 
2
O
8.CB.10Hureaulite
(Mn,Fe)
 
5
(PO
 
3
OH)
 
2
(PO
 
4
)
 
2
·4H
 
2
O
8.CB.10Sainfeldite
Ca
 
5
(AsO
 
3
OH)
 
2
(AsO
 
4
)
 
2
·4H
 
2
O
8.CB.10Villyaellenite
(Mn,Ca,Zn)
 
5
(AsO
 
3
OH)
 
2
(AsO
 
4
)
 
2
·4H
 
2
O
8.CB.10UM1997-09-AsO:CaHMgZn
(Mg,Ca,Zn)
 
5
(AsO
 
4
)
 
2
[AsO
 
3
(OH)]
 
2
·4H
 
2
O
8.CB.10IMA2008-047
Cd
 
3
Zn
 
2
(AsO
 
3
OH)
 
2
(AsO
 
4
)
 
2
·4H
 
2
O
8.CB.10Miguelromeroite
Mn
 
5
(AsO
 
3
OH)
 
2
(AsO
 
4
)
 
2
·4H
 
2
O
8.CB.15Fluckite
CaMnH
 
2
(AsO
 
4
)
 
2
·2H
 
2
O
8.CB.20Cobaltkoritnigite
(Co,Zn)[HAsO
 
4
] · H
 
2
O
8.CB.20Koritnigite
Zn[HAsO
 
4
] · H
 
2
O
8.CB.25Yvonite
Cu[HAsO
 
4
] · 2H
 
2
O
8.CB.30Geminite
Cu
 
2
[As
 
2
O
 
7
] · 3H
 
2
O
8.CB.35Schubnelite
Fe
 
2-x
V
 
2
O
 
4
(OH)
 
4
8.CB.40Radovanite
Cu
 
2
Fe
3+
 
[(As
3+
 
O
 
2
(OH)]
 
2
[As
5+
 
O
 
4
]·H
 
2
O
8.CB.45Kazakhstanite
Fe
 
5
V
 
3
V
 
12
O
 
39
(OH)
 
9
·9H
 
2
O
8.CB.50Kolovratite
(Zn,Ni,Cu)
 
2-5
Al
 
4-6
(Si,V
4+
 
,V
5+
 
)
 
4
(O,OH)
 
20
·7.5H
 
2
O
8.CB.55Irhtemite
Ca
 
4
Mg[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 4H
 
2
O
8.CB.60Burgessite
Co
 
2
(H
 
2
O)
 
4
[AsO
 
3
OH]
 
2
(H
 
2
O)}
Related Minerals - Hey's Index Grouping:

- +
20.8.1Sarkinite
Mn
2+
2
[OH|AsO
 
4
]
20.8.2Eveite
Mn
2+
2
[OH|AsO
 
4
]
20.8.3Arsenoclasite
Mn
2+
5
[(OH)
 
2
|AsO
 
4
]
 
2
20.8.4Flinkite
Mn
2+
2
Mn
3+
 
AsO
 
4
(OH)
 
4
20.8.5Jarosewichite
Mn
 
3
MnAsO
 
4
(OH)
 
6
20.8.6Allactite
Mn
2+
7
(AsO
 
4
)
 
2
(OH)
 
8
20.8.8Synadelphite
Mn
2+
9
[(OH)
 
9
|As
3+
 
O
 
3
|(As
5+
 
O
 
4
)
 
2
] · 2H
 
2
O
20.8.9Sterlinghillite
Mn
 
3
(AsO
 
4
)
 
2
·4H
 
2
O
20.8.10Geigerite
Mn
 
5
[HAsO
 
4
|AsO
 
4
]
 
2
· 10H
 
2
O
20.8.11Akrochordite
(Mn
2+
 
,Mg)
 
5
[(OH)
 
2
|AsO
 
4
]
 
2
· 4H
 
2
O
20.8.12Manganohörnesite
(Mn,Mg)
 
3
(AsO
 
4
)
 
2
·8H
 
2
O
20.8.13Fluckite
CaMnH
 
2
(AsO
 
4
)
 
2
·2H
 
2
O
20.8.14Brandtite
Ca
 
2
(Mn
2+
 
,Mg)[AsO
 
4
]
 
2
· 2H
 
2
O
20.8.15Parabrandtite
Ca
 
2
Mn
2+
 
[AsO
 
4
]
 
2
· 2H
 
2
O
20.8.16Wallkilldellite-(Mn)
Ca
 
2
Mn
2+
3
[(OH)
 
2
|AsO
 
4
]
 
2
· 9H
 
2
O
20.8.17Berzeliite
NaCa
 
2
(Mg,Mn
2+
 
)
 
2
[AsO
 
4
]
 
3
20.8.18Manganberzeliite
(Ca,Na)
 
3
(Mn
2+
 
,Mg)
 
2
[AsO
 
4
]
 
3
20.8.19Magnesiochlorophoenicite
(Mg,Mn)
 
3
Zn
 
2
(AsO
 
4
)(OH,O)
 
6
20.8.20Villyaellenite
(Mn,Ca,Zn)
 
5
(AsO
 
3
OH)
 
2
(AsO
 
4
)
 
2
·4H
 
2
O
20.8.21Hematolite
(Mn,Mg,Al)
 
15
(AsO
 
3
)(AsO
 
4
)
 
2
(OH)
 
23
20.8.22Grischunite
NaCa
 
2
Mn
2+
5
Fe
3+
 
[AsO
 
4
]
 
6
· 2H
 
2
O

Other Names for Krautite

Synonyms:
IMA1974-028
Other Languages:
German:Krautit
Russian:Краутит
Spanish:Krautita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Krautite

Reference List:American Mineralogist (1976): 61: 503.

American Mineralogist (1979): 1248-1254.

Beneke, K. & Lagaly, G. (1981): Krautite, MnHAsO4·H2O – an intracrystalline
reactive mineral. Am. Mineral., 66, 432–435.

American Mineralogist (1990): 75: 1140.

Internet Links for Krautite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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  • Krautite details from Handbook of Mineralogy (PDF)
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    Localities for Krautite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • New South Wales
      • Clive Co.
        • Clive
    Ashley, P.M. & Lottermoser, B. G. (1999): Arsenic contamination at the Mole River mine, northern New South Wales. Australian Journal of Earth Sciences, 46, 861-874.
    Chile
     
    • Atacama Region
      • Copiapó Province
        • Tierra Amarilla
          • Pampa Larga district
    analysed material from a german Museum collection
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Karlovy Vary Region
        • Krušné Hory Mts (Erzgebirge)
          • Ostrov
            • Jáchymov (St Joachimsthal)
    Lapis 2002(7/8), 52
    Romania
     
    • Hunedoara Co.
    Am. Min. 61, 503 (1976)
    Mineral and/or Locality
    Google
     
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