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Kryzhanovskite

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Formula:
(Fe
3+
 
,Mn
2+
 
)
 
3
(PO
 
4
)
 
2
(OH,H
 
2
O)
 
3
System:OrthorhombicHardness:3½ - 4
Member of:Phosphoferrite Group


Garyansellite-Kryzhanovskite Series.

Can be derived from phosphoferrite by oxidation.

Classification of Kryzhanovskite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/C.08-40
Nickel-Strunz 10th (pending) edition ID:8.CC.05

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
C : With only medium-sized cations, RO4:H2O = 1:1.5
Dana 8th edition ID:40.3.2.2

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O
Hey's CIM Ref.:19.12.17

19 : Phosphates
12 : Phosphates of Mn
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Type Occurrence of Kryzhanovskite

Type Locality:Ak-Kezen' pegmatite, Belogorskii Town, Kalba Range, Eastern Kazakhstan Province (Shyghys Qazaqstan Oblysy; Vostochno-Kazakhstanskaya Oblast'), Kazakhstan
Year of Discovery:1950

Physical Properties of Kryzhanovskite

Hardness (Mohs):3½ - 4

Crystallography of Kryzhanovskite

Crystal System:Orthorhombic
Cell Parameters:a = 9.4Å, b = 9.97Å, c = 8.53Å
Ratio:a:b:c = 0.943 : 1 : 0.856
Unit Cell Volume:V 799.41 ų (Calculated from Unit Cell)

Optical Data of Kryzhanovskite

Type:Biaxial
Dispersion:strong

Chemical Properties of Kryzhanovskite

Formula:
(Fe
3+
 
,Mn
2+
 
)
 
3
(PO
 
4
)
 
2
(OH,H
 
2
O)
 
3
Simplified for copy/paste:(Fe3+,Mn2+)3(PO4)2(OH,H2O)3
Essential elements:Fe, H, O, P
All elements listed in formula:Fe, H, Mn, O, P

Relationship of Kryzhanovskite to other Species

Series:Forms a series with Garyansellite (see here)
Member of:Phosphoferrite Group
Other Members of Group:

- +
Correianevesite
Fe
2+
 
Mn
2+
2
(PO
 
4
)
 
2
· 3H
 
2
O
Garyansellite
(Mg,Fe)
 
3
(PO
 
4
)
 
2
(OH,O) · 1.5H
 
2
O
Landesite
Mn
2+
3-x
Fe
3+
x
(PO
 
4
)
 
2
(OH)
 
x
· (3-x)H
 
2
O
Phosphoferrite
(Fe
2+
 
,Mn
2+
 
)
 
3
(PO
 
4
)
 
2
· 3H
 
2
O
Reddingite
(Mn
2+
 
,Fe
2+
 
)
 
3
(PO
 
4
)
 
2
· 3H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
8.CC.05Garyansellite
(Mg,Fe)
 
3
(PO
 
4
)
 
2
(OH,O) · 1.5H
 
2
O
8.CC.05Landesite
Mn
2+
3-x
Fe
3+
x
(PO
 
4
)
 
2
(OH)
 
x
· (3-x)H
 
2
O
8.CC.05Phosphoferrite
(Fe
2+
 
,Mn
2+
 
)
 
3
(PO
 
4
)
 
2
· 3H
 
2
O
8.CC.05Reddingite
(Mn
2+
 
,Fe
2+
 
)
 
3
(PO
 
4
)
 
2
· 3H
 
2
O
8.CC.10Kaatialaite
Fe(H
 
2
AsO
 
4
)
 
3
· 5H
 
2
O
8.CC.15Leogangite
Cu
 
10
(AsO
 
4
)
 
4
(SO
 
4
)(OH)
 
6
· 8H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
19.12.1Metaswitzerite
Mn
 
3
(PO
 
4
)
 
2
· 4H
 
2
O
19.12.2Bermanite
Mn
2+
 
Mn
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
19.12.3Natrophilite
NaMn
2+
 
PO
 
4
19.12.4Sidorenkite
Na
 
3
Mn
2+
 
(CO
 
3
)(PO
 
4
)
19.12.5Niahite
(NH
 
4
)(Mn
2+
 
,Mg)(PO
 
4
) · H
 
2
O
19.12.6Robertsite
Ca
 
3
Mn
3+
4
(PO
 
4
)
 
3
O
 
2
· 3H
 
2
O
19.12.7Pararobertsite
Ca
 
2
Mn
3+
3
(PO
 
4
)
 
3
O
 
2
· 3H
 
2
O
19.12.8Sinkankasite
H
 
2
Mn
2+
 
Al(PO
 
4
)
 
2
(OH) · 6H
 
2
O
19.12.9Mangangordonite
Mn
2+
 
Al
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.10Heterosite
(Fe
3+
 
,Mn
3+
 
)PO
 
4
19.12.11Purpurite
(Mn
3+
 
,Fe
3+
 
)PO
 
4
19.12.12Wolfeite
(Fe
2+
 
,Mn
2+
 
)
 
2
(PO
 
4
)(OH)
19.12.13Triploidite
(Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)(OH)
19.12.14Lipscombite
(Fe
2+
 
,Mn
2+
 
)Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
19.12.15Frondelite
Mn
2+
 
Fe
3+
4
(PO
 
4
)
 
3
(OH)
 
5
19.12.16Rockbridgeite
Fe
2+
 
Fe
3+
4
(PO
 
4
)
 
3
(OH)
 
5
19.12.18Landesite
Mn
2+
3-x
Fe
3+
x
(PO
 
4
)
 
2
(OH)
 
x
· (3-x)H
 
2
O
19.12.19Phosphoferrite
(Fe
2+
 
,Mn
2+
 
)
 
3
(PO
 
4
)
 
2
· 3H
 
2
O
19.12.20Reddingite
(Mn
2+
 
,Fe
2+
 
)
 
3
(PO
 
4
)
 
2
· 3H
 
2
O
19.12.21Earlshannonite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
19.12.22Hureaulite
(Mn,Fe)
 
5
(PO
 
4
)
 
2
(HPO
 
4
)
 
2
· 4H
 
2
O
19.12.23Switzerite
(Mn,Fe)
 
3
(PO
 
4
)
 
2
· 7H
 
2
O
19.12.24Laueite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.25Pseudolaueite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.26Strunzite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 6H
 
2
O
19.12.27Stewartite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.28Alluaudite
(Na,Ca)Mn
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
,Mg)
 
2
(PO
 
4
)
 
3
19.12.29Ferroalluaudite
(Na,Ca)Fe
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)
 
3
19.12.30Fillowite
{Mn
2+
 
}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mn
2+
 
,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
19.12.31Johnsomervilleite
Na
 
10
Ca
 
6
Mg
 
18
Fe
 
25
(PO
 
4
)
 
36
19.12.32Wicksite
NaCa
 
2
(Fe
2+
 
,Mn
2+
 
)
 
4
MgFe
3+
 
(PO
 
4
)
 
6
· 2H
 
2
O
19.12.33Dickinsonite-(KMnNa)
{KNa}{Mn
2+
 
◻}{Ca}{Na
 
3
}{Mn
2+
13
}{Al}(PO
 
4
)
 
12
(OH)
 
2
19.12.34Sarcopside
(Fe
2+
 
,Mn
2+
 
,Mg)
 
3
(PO
 
4
)
 
2
19.12.35Ludlamite
(Fe,Mn,Mg)
 
3
(PO
 
4
)
 
2
· 4H
 
2
O
19.12.36Graftonite
(Fe
2+
 
,Mn
2+
 
,Ca)
 
3
(PO
 
4
)
 
2
19.12.37Wilhelmvierlingite
CaMnFe
3+
 
(PO
 
4
)
 
2
(OH) · 2H
 
2
O
19.12.38Fairfieldite
Ca
 
2
(Mn
2+
 
,Fe
2+
 
)(PO
 
4
)
 
2
· 2H
 
2
O
19.12.39Beusite
(Mn
2+
 
,Fe
2+
 
,Ca,Mg)
 
3
(PO
 
4
)
 
2
19.12.40Messelite
Ca
 
2
(Fe
2+
 
,Mn
2+
 
)(PO
 
4
)
 
2
· 2H
 
2
O
19.12.41Jahnsite-(CaMnFe)
{Ca}{Mn
2+
 
}{Fe
2+
2
}{Fe
3+
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.42Jahnsite-(CaMnMn)
{Ca}{Mn
2+
 
}{Mn
2+
2
}{Fe
3+
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.43Jahnsite-(CaMnMg)
{Ca}{Mn
2+
 
}{(Mg,Fe
2+
 
)
 
2
}{Fe
3+
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.44Keckite
CaMn
2+
 
Fe
3+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
3
(H
 
2
O)
 
7
19.12.45Stanfieldite
Ca
 
7
Ca
 
2
Mg
 
9
(PO
 
4
)
 
12
19.12.46Laubmannite
(Fe
2+
 
,Mn
2+
 
,Ca)
 
3
Fe
3+
6
(PO
 
4
)
 
4
(OH)
 
12
19.12.47Zodacite
Ca
 
4
Mn
2+
 
Fe
3+
4
(PO
 
4
)
 
6
(OH)
 
4
· 12H
 
2
O
19.12.48Hagendorfite
NaCaMn
2+
 
Fe
2+
2
(PO
 
4
)
 
3
19.12.49Maghagendorfite
(□,Na,)(Na,Ca,Fe
2+
 
)Mn(Mg,Fe
2+
 
,Fe
3+
 
)
 
3
(PO
 
4
)
 
3
19.12.50Varulite
NaCaMn
2+
 
Mn
2+
2
(PO
 
4
)
 
3
19.12.51Griphite
Na
 
4
Li
 
2
Ca
 
6
(Mn
2+
 
,Fe
2+
 
,Mg)
 
19
Al
 
8
(PO
 
4
)
 
24
(F,OH)
 
8
19.12.52Attakolite
(Ca,Sr)Mn(Al,Fe)
 
4
(HPO
 
4
,PO
 
4
)
 
3
(SiO
 
4
,PO
 
4
)(OH)
 
4
19.12.53Arrojadite-(KFe)
{KNa}{Fe
2+
 
◻}{Ca}{Na
 
2
◻}{Fe
2+
13
}{Al}(PO
 
4
)
 
11
(HPO
 
4
)(OH)
 
2
19.12.54Lun'okite
(Mn,Ca)(Mg,Fe,Mn)Al(PO
 
4
)
 
2
OH · 4H
 
2
O
19.12.55Eosphorite
(Mn
2+
 
,Fe
2+
 
)Al(PO
 
4
)(OH)
 
2
· H
 
2
O
19.12.56Ernstite
(Mn
2+
 
,Fe
3+
 
)Al(PO
 
4
)(OH,O)
 
2
· H
 
2
O
19.12.57Childrenite
(Fe
2+
 
,Mn
2+
 
)Al(PO
 
4
)(OH)
 
2
· H
 
2
O
19.12.58Bobfergusonite
Na
 
2
Mn
 
5
FeAl(PO
 
4
)
 
6
19.12.59Qingheiite
NaMn
3+
 
Mg(Al,Fe
3+
 
)(PO
 
4
)
 
3
19.12.60Whiteite-(CaFeMg)
{Ca}{(Fe
2+
 
,Mn
2+
 
)}{Mg
 
2
}{Al
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.61Whiteite-(CaMnMg)
{Ca}{Mn
2+
 
}{Mg
 
2
}{Al
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.62Whiteite-(MnFeMg)
{(Mn
2+
 
,Ca)}{(Fe
2+
 
,Mn
2+
 
)}{Mg
 
2
}{Al
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.63Rittmannite
{(Mn
2+
 
,Ca)}{Mn
2+
 
}{(Fe
2+
 
,Mn
2+
 
,Mg)
 
2
}{(Al,Fe
3+
 
)
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.64Zanazziite
Ca
 
2
Mg
 
5
Be
 
4
(PO
 
4
)
 
6
(OH)
 
4
· 6H
 
2
O
19.12.65Samuelsonite
(Ca,Ba)Ca
 
8
Fe
2+
2
Mn
2+
2
Al
 
2
(PO
 
4
)
 
10
(OH)
 
2

Other Names for Kryzhanovskite

Synonyms:
KruzhanovskiteKryjanovskite
Other Languages:
German:Kryzhanovskit
Kruzhanovskit
Kruzhanowskit
Kryjanovskit
Kryschanowskit
Kryshanovskit
Kryshanowskit
Russian:Крыжановскит
Spanish:Kruzhanovskita
Kryjanovskita
Kryzhanovskita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Kryzhanovskite

Reference List:

- +
Ginzburg, A. I. (1950): Kruzhanovskite, a new phosphate mineral. Doklady Akademii Nauk SSSR 72, 763-766. [Abs. in American Mineralogist (1951): 36: 382].

Moore, P.B. (1971): The Fe2+3(H2O)n(PO4)2 homologous series: crystal-chemical relations and oxidized equivalents. American Mineralogist 56, 1-17.

Moore, P.B. (1974): Complete mixed valence solid solution series in Fe32+(H20)3(PO4)2 (phosphoferrite) Fe33+(OH)3(PO4)2 (kryzhanovskite). Nature 251, 305-306.

Moore, P.B.; Araki, T. (1976): Mixed-valence solid-solution series. Crystal structures of phosphoferrite, Fe32+(H2O)3[PO4]2, and kryzhanovskite, Fe33+(OH)3[PO4]2. Inorganic Chemistry 15, 316-321.

Moore, P. B.; Araki, T.; Kampf, A. R. (1980): Nomenclature of the phosphoferrite structure type: refinements of landesite and kryzhanovskite. Mineralogical Magazine 43, 789-795.

Internet Links for Kryzhanovskite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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    Localities for Kryzhanovskite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • Yukon Territory
      • Dawson Mining District
    MinRec 23:4-47
    [Mineralogical Record Vol 23 No.4 pp23-25]
          • Kulan Camp (Area A; Area 1)
    Robinson, G.W., Van Velthuizen, J., Ansell, H.G. & Sturman, B.D. (1992): Mineralogy of the Rapid Creek and Big Fish River area, Yukon Territory. Mineralogical Record 23, 1-47
    Robinson, G.W., Van Velthuizen, J., Ansell, H.G. & Sturman, B.D. (1992): Mineralogy of the Rapid Creek and Big Fish River area, Yukon Territory. Mineralogical Record 23, 1-47
    Germany
     
    • Bavaria
      • Upper Palatinate
        • Oberpfälzer Wald
          • Vohenstrauß
            • Waidhaus
              • Hagendorf
    http://www.berthold-weber.de/h_miner.htm
    Italy
     
    • Lombardy
      • Lecco Province
        • Vestreno
    Vignola et al. (2011): Complex mechanisms of alteration in a graftonite + sacropside+ triphylite association from the Luna pegmatite, Piona, Lecco Province, Italy. Canadian Mineralogist. 49, 765-776.
    Kazakhstan
     
    • Eastern Kazakhstan Province (Shyghys Qazaqstan Oblysy; Vostochno-Kazakhstanskaya Oblast')
      • Kalba Range
        • Belogorskii Town
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Morocco
     
    • Marrakech-Tensift-El Haouz Region
      • El Kelaâ des Sraghna Province
        • Sidi Bou Othmane
    Favreau, G. (2012): Deux pegmatites à phosphates de Sidi Bou Othmane (Maroc). Le Cahier des Micromonteurs, 3-2012, 71-109
    Namibia
     
    • Erongo Region
      • Karibib District
        • Okatjimukuju Farm 55 (Friedrichsfelde Farm)
    P. Keller and O. von Knorring, Eur. J. Mineral. , 1989, 1, pp. 567-593.
        • Usakos
          • Sandamap North Farm 115 (Sandamab)
    Collection Elmar Lackner
    Poland
     
    • Lower Silesia (Dolnośląskie)
      • Sowie Mts
    Pieczka A., Łobos K., Sachanbiński M. 2004: The first occurence of elbaite in Poland. Mineralogia Polonica, vol. 35, 3-14
      • Sudetes Mts
        • Sowie Mts
    Łodziński M. & Sitarz M. 2008: Chemical and Spectroscopic Characterization of Some Phosphates Accessory Minerals from Pegmatites of the Sowie Mts (Owles Mts), SW Poland. EUCMOS, Spectroscopy Applied to Archaeology, Arts, Geology and Mineralogy, p. 278
    Portugal
     
    • Guarda District
      • Sabugal
        • Bendada
    Schnorrer-Köhler (1991), Mineral Occurrences.
    • Viana do Castelo District
      • Caminha
        • Arga de Baixo
    Pedro Alves collection
      • Ponte de Lima
        • Cabração
    Pedro Alves collection
    • Viseu District
      • Mangualde
    Spain
     
    • Castile and Leon
      • Zamora
        • Villar del Buey
          • Pinilla de Fermoselle
    Switzerland
     
    • Ticino (Tessin)
      • Lago Maggiore
    Vignola, P., Diella, V., Oppizzi, P., Tiepolo, M. & Weiss, S. (2008): Phosphate assemblages from the Brissago granitic pegmatite, Western Southern Alps, Switzerland. Can. Mineral. 46, 635-650.
    USA
     
    • Nevada
      • Lyon Co.
        • Yerington District
    NBMG Spec. Pub. 31 Minerals of Nevada
    • New Hampshire
      • Grafton Co.
        • Groton
    NIZAMOFF, James W., SIMMONS, William B., and FALSTER, Alexander U. (2004) PHOSPHATE MINERALOGY AND PARAGENESIS OF THE PALERMO #2 PEGMATITE, NORTH GROTON, NEW HAMPSHIRE Geological Society of America Abstracts with Programs, Vol. 36, No. 5, p. 115
    Whitmore & Lawrence, 2004. The Pegmatite Mines Known As Palermo, p. 96.; Geological Society of America Abstracts with Programs, Vol. 36, No. 5, p. 115
    • South Dakota
      • Custer Co.
        • Custer District
          • Custer
    Rocks & Min.:60:117.
          • Fourmile
    Mineralogical Record: 17: 237-254; Rocks & Minerals: 60: 117.
      • Pennington Co.
        • Keystone District
          • Glendale
    Rocks & Minerals: 60: 116.
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