Help mindat.org|Log In|Register|
Home PageMindat NewsThe Mindat ManualHistory of MindatCopyright StatusManagement TeamContact UsAdvertise on Mindat
Donate to MindatSponsor a PageSponsored PagesTop Available PagesMindat AdvertisersAdvertise on MindatThe Mindat Store
Minerals by PropertiesMinerals by ChemistryRandom MineralSearch by minIDLocalities Near MeSearch GlossaryMore Search Options
Search For:
Mineral Name:
Locality Name:
Keyword(s):
 
The Mindat ManualAdd a New PhotoRate PhotosLocality Edit ReportAdd Glossary Item
StatisticsMember ListBooks & MagazinesMineral Shows & EventsThe Mindat DirectoryHow to Link to MindatDevice Settings
Photo SearchPhoto GalleriesNew Photos TodayNew Photos YesterdayMembers' Photo GalleriesPast Photo of the Day Gallery

Kryzhanovskite

This page is currently not sponsored. Click here to sponsor this page.
Formula:
(Fe3+,Mn2+)3(PO4)2(OH,H2O)3
System:
Orthorhombic
Hardness:
3½ - 4
Garyansellite-Kryzhanovskite Series.

Can be derived from phosphoferrite by oxidation.

Classification of Kryzhanovskite

Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
8.CC.05

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
C : With only medium-sized cations, RO4:H2O = 1:1.5
40.3.2.2

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O
19.12.17

19 : Phosphates
12 : Phosphates of Mn
mindat.org URL:
http://www.mindat.org/min-2281.html
Please feel free to link to this page.

Type Occurrence of Kryzhanovskite

Year of Discovery:
1950

Physical Properties of Kryzhanovskite

Hardness (Mohs):
3½ - 4

Crystallography of Kryzhanovskite

Crystal System:
Orthorhombic
Cell Parameters:
a = 9.4Å, b = 9.97Å, c = 8.53Å
Ratio:
a:b:c = 0.943 : 1 : 0.856
Unit Cell Volume:
V 799.41 ų (Calculated from Unit Cell)

Optical Data of Kryzhanovskite

Type:
Biaxial
Dispersion:
strong

Chemical Properties of Kryzhanovskite

Formula:
(Fe3+,Mn2+)3(PO4)2(OH,H2O)3
Essential elements:
All elements listed in formula:

Relationship of Kryzhanovskite to other Species

Series:
Forms a series with Garyansellite (see here)
Other Members of Group:
CorreianevesiteFe2+Mn22+(PO4)2 · 3H2O
Garyansellite(Mg,Fe)3(PO4)2(OH,O) · 1.5H2O
LandesiteMn2+3-xFex3+(PO4)2(OH)x · (3-x)H2O
Phosphoferrite(Fe2+,Mn2+)3(PO4)2 · 3H2O
Reddingite(Mn2+,Fe2+)3(PO4)2 · 3H2O
8.CC.05Garyansellite(Mg,Fe)3(PO4)2(OH,O) · 1.5H2O
8.CC.05LandesiteMn2+3-xFex3+(PO4)2(OH)x · (3-x)H2O
8.CC.05Phosphoferrite(Fe2+,Mn2+)3(PO4)2 · 3H2O
8.CC.05Reddingite(Mn2+,Fe2+)3(PO4)2 · 3H2O
8.CC.10KaatialaiteFe(H2AsO4)3 · 5H2O
8.CC.15LeogangiteCu10(AsO4)4(SO4)(OH)6 · 8H2O
19.12.1MetaswitzeriteMn3(PO4)2 · 4H2O
19.12.2BermaniteMn2+Mn23+(PO4)2(OH)2 · 4H2O
19.12.3NatrophiliteNaMn2+PO4
19.12.4SidorenkiteNa3Mn2+(CO3)(PO4)
19.12.5Niahite(NH4)(Mn2+,Mg)(PO4) · H2O
19.12.6RobertsiteCa3Mn43+(PO4)3O2 · 3H2O
19.12.7PararobertsiteCa2Mn33+(PO4)3O2 · 3H2O
19.12.8SinkankasiteMn2+Al(PO3OH)2(OH) · 6H2O
19.12.9MangangordoniteMn2+Al2(PO4)2(OH)2 · 8H2O
19.12.10Heterosite(Fe3+,Mn3+)PO4
19.12.11Purpurite(Mn3+,Fe3+)PO4
19.12.12Wolfeite(Fe2+,Mn2+)2(PO4)(OH)
19.12.13Triploidite(Mn2+,Fe2+)2(PO4)(OH)
19.12.14LipscombiteFe2+Fe23+(PO4)2(OH)2
19.12.15FrondeliteMn2+Fe43+(PO4)3(OH)5
19.12.16RockbridgeiteFe2+Fe43+(PO4)3(OH)5
19.12.18LandesiteMn2+3-xFex3+(PO4)2(OH)x · (3-x)H2O
19.12.19Phosphoferrite(Fe2+,Mn2+)3(PO4)2 · 3H2O
19.12.20Reddingite(Mn2+,Fe2+)3(PO4)2 · 3H2O
19.12.21EarlshannoniteMn2+Fe23+(PO4)2(OH)2 · 4H2O
19.12.22Hureaulite(Mn,Fe)5(PO4)2(HPO4)2 · 4H2O
19.12.23Switzerite(Mn,Fe)3(PO4)2 · 7H2O
19.12.24LaueiteMn2+Fe23+(PO4)2(OH)2 · 8H2O
19.12.25PseudolaueiteMn2+Fe23+(PO4)2(OH)2 · 8H2O
19.12.26StrunziteMn2+Fe23+(PO4)2(OH)2 · 6H2O
19.12.27StewartiteMn2+Fe23+(PO4)2(OH)2 · 8H2O
19.12.28Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3
19.12.29Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3
19.12.30Fillowite{Mn2+}{Na8}{Ca4Na4}{(Mn2+,Fe2+)43}(PO4)36
19.12.31JohnsomervilleiteNa10Ca6Mg18Fe25(PO4)36
19.12.32WicksiteNaCa2(Fe2+,Mn2+)4MgFe3+(PO4)6 · 2H2O
19.12.33Dickinsonite-(KMnNa){KNa}{Mn2+◻}{Ca}{Na3}{Mn132+}{Al}(PO4)12(OH)2
19.12.34Sarcopside(Fe2+,Mn2+,Mg)3(PO4)2
19.12.35Ludlamite(Fe,Mn,Mg)3(PO4)2 · 4H2O
19.12.36Graftonite(Fe2+,Mn2+,Ca)3(PO4)2
19.12.37WilhelmvierlingiteCaMnFe3+(PO4)2(OH) · 2H2O
19.12.38FairfielditeCa2(Mn2+,Fe2+)(PO4)2 · 2H2O
19.12.39Beusite(Mn2+,Fe2+,Ca,Mg)3(PO4)2
19.12.40MesseliteCa2(Fe2+,Mn2+)(PO4)2 · 2H2O
19.12.41Jahnsite-(CaMnFe){Ca}{Mn2+}{Fe22+}{Fe23+}(PO4)4(OH)2 · 8H2O
19.12.42Jahnsite-(CaMnMn){Ca}{Mn2+}{Mn22+}{Fe23+}(PO4)4(OH)2 · 8H2O
19.12.43Jahnsite-(CaMnMg){Ca}{Mn2+}{(Mg,Fe2+)2}{Fe23+}(PO4)4(OH)2 · 8H2O
19.12.44KeckiteCaMn2+Fe23+Fe23+(PO4)4(OH)3(H2O)7
19.12.45StanfielditeCa7Ca2Mg9(PO4)12
19.12.46Laubmannite(Fe2+,Mn2+,Ca)3Fe63+(PO4)4(OH)12
19.12.47ZodaciteCa4Mn2+Fe43+(PO4)6(OH)4 · 12H2O
19.12.48HagendorfiteNaCaMn2+Fe22+(PO4)3
19.12.49Maghagendorfite(□,Na,)(Na,Ca,Fe2+)Mn(Mg,Fe2+,Fe3+)3(PO4)3
19.12.50VaruliteNaCaMn2+Mn22+(PO4)3
19.12.51GriphiteNa4Li2Ca6(Mn2+,Fe2+,Mg)19Al8(PO4)24(F,OH)8
19.12.52Attakolite(Ca,Sr)Mn(Al,Fe)4(HPO4,PO4)3(SiO4,PO4)(OH)4
19.12.53Arrojadite-(KFe){KNa}{Fe2+◻}{Ca}{Na2◻}{Fe132+}{Al}(PO4)11(HPO4)(OH)2
19.12.54Lun'okite(Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2O
19.12.55Eosphorite(Mn2+,Fe2+)Al(PO4)(OH)2 · H2O
19.12.56Ernstite(Mn2+,Fe3+)Al(PO4)(OH,O)2 · H2O
19.12.57Childrenite(Fe2+,Mn2+)Al(PO4)(OH)2 · H2O
19.12.58BobfergusoniteNa2Mn5FeAl(PO4)6
19.12.59QingheiiteNaMn3+Mg(Al,Fe3+)(PO4)3
19.12.60Whiteite-(CaFeMg){Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O
19.12.61Whiteite-(CaMnMg){Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O
19.12.62Whiteite-(MnFeMg){(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O
19.12.63Rittmannite{(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2O
19.12.64ZanazziiteCa2Mg5Be4(PO4)6(OH)4 · 6H2O
19.12.65Samuelsonite(Ca,Ba)Ca8Fe22+Mn22+Al2(PO4)10(OH)2

Other Names for Kryzhanovskite

Other Information

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Kryzhanovskite

Reference List:
Ginzburg, A. I. (1950): Kruzhanovskite, a new phosphate mineral. Doklady Akademii Nauk SSSR 72, 763-766. [Abs. in American Mineralogist (1951): 36: 382].

Moore, P.B. (1971): The Fe2+3(H2O)n(PO4)2 homologous series: crystal-chemical relations and oxidized equivalents. American Mineralogist 56, 1-17.

Moore, P.B. (1974): Complete mixed valence solid solution series in Fe32+(H20)3(PO4)2 (phosphoferrite) Fe33+(OH)3(PO4)2 (kryzhanovskite). Nature 251, 305-306.

Moore, P.B.; Araki, T. (1976): Mixed-valence solid-solution series. Crystal structures of phosphoferrite, Fe32+(H2O)3[PO4]2, and kryzhanovskite, Fe33+(OH)3[PO4]2. Inorganic Chemistry 15, 316-321.

Moore, P. B.; Araki, T.; Kampf, A. R. (1980): Nomenclature of the phosphoferrite structure type: refinements of landesite and kryzhanovskite. Mineralogical Magazine 43, 789-795.

Internet Links for Kryzhanovskite

Specimens:
The following Kryzhanovskite specimens are currently listed for sale on minfind.com.

Localities for Kryzhanovskite

map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
(TL) indicates type locality for a valid mineral species. (FRL) indicates first recorded locality for everything else. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
Canada
 
  • Yukon Territory
    • Dawson Mining District
MinRec 23:4-47
[Mineralogical Record Vol 23 No.4 pp23-25]
        • Kulan Camp (Area A; Area 1)
Robinson, G.W., Van Velthuizen, J., Ansell, H.G. & Sturman, B.D. (1992): Mineralogy of the Rapid Creek and Big Fish River area, Yukon Territory. Mineralogical Record 23, 1-47
Robinson, G.W., Van Velthuizen, J., Ansell, H.G. & Sturman, B.D. (1992): Mineralogy of the Rapid Creek and Big Fish River area, Yukon Territory. Mineralogical Record 23, 1-47
Germany
 
  • Bavaria
    • Upper Palatinate
      • Waidhaus
        • Hagendorf
http://www.berthold-weber.de/h_miner.htm
Italy
 
  • Lombardy
    • Lecco Province
      • Dorio
Vignola P., Diella V., Ferrari E.S., Fransolet A.-M. (2011): Complex mechanisms of alteration in a graftonite + sacropside+ triphylite association from the Luna pegmatite, Piona, Lecco Province, Italy. Can. Mineral., 49, 765-776.
Kazakhstan (TL)
 
  • Eastern Kazakhstan Province (Shyghys Qazaqstan Oblysy; Vostochno-Kazakhstanskaya Oblast')
    • Kalba Range
      • Belogorskii Town
Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
Morocco
 
  • Marrakech-Tensift-El Haouz Region
    • El Kelaâ des Sraghna Province
      • Sidi Bou Othmane
Favreau, G. (2012): Deux pegmatites à phosphates de Sidi Bou Othmane (Maroc). Le Cahier des Micromonteurs, 3-2012, 71-109
Namibia
 
  • Erongo Region
    • Karibib District
      • Okatjimukuju Farm 55 (Friedrichsfelde Farm)
P. Keller and O. von Knorring, Eur. J. Mineral. , 1989, 1, pp. 567-593.
      • Usakos
        • Sandamap North Farm 115 (Sandamab)
Collection Elmar Lackner
Poland
 
  • Lower Silesia (Dolnośląskie)
    • Sowie Mts
Pieczka A., Łobos K., Sachanbiński M. 2004: The first occurence of elbaite in Poland. Mineralogia Polonica, vol. 35, 3-14
    • Sudetes Mts
      • Sowie Mts
Łodziński M. & Sitarz M. 2008: Chemical and Spectroscopic Characterization of Some Phosphates Accessory Minerals from Pegmatites of the Sowie Mts (Owles Mts), SW Poland. EUCMOS, Spectroscopy Applied to Archaeology, Arts, Geology and Mineralogy, p. 278
Portugal
 
  • Guarda District
    • Sabugal
      • Bendada
Schnorrer-Köhler (1991), Mineral Occurrences.
  • Viana do Castelo District
    • Caminha
      • Arga de Baixo
Pedro Alves collection
    • Ponte de Lima
      • Cabração
Pedro Alves collection
  • Viseu District
    • Mangualde
Spain
 
  • Castile and Leon
    • Zamora
      • Villar del Buey
        • Pinilla de Fermoselle
Switzerland
 
  • Ticino (Tessin)
    • Lago Maggiore
Vignola, P., Diella, V., Oppizzi, P., Tiepolo, M. & Weiss, S. (2008): Phosphate assemblages from the Brissago granitic pegmatite, Western Southern Alps, Switzerland. Can. Mineral. 46, 635-650.
USA
 
  • Nevada
    • Lyon Co.
      • Singatse Range
        • Yerington District
NBMG Spec. Pub. 31 Minerals of Nevada
  • New Hampshire
    • Grafton Co.
      • Groton
NIZAMOFF, James W., SIMMONS, William B., and FALSTER, Alexander U. (2004) PHOSPHATE MINERALOGY AND PARAGENESIS OF THE PALERMO #2 PEGMATITE, NORTH GROTON, NEW HAMPSHIRE Geological Society of America Abstracts with Programs, Vol. 36, No. 5, p. 115
Whitmore & Lawrence, 2004. The Pegmatite Mines Known As Palermo, p. 96.; Geological Society of America Abstracts with Programs, Vol. 36, No. 5, p. 115
  • South Dakota
    • Custer Co.
      • Custer District
        • Custer
Rocks & Min.:60:117.
        • Fourmile
Mineralogical Record: 17: 237-254; Rocks & Minerals: 60: 117.
    • Pennington Co.
      • Keystone District
        • Glendale
Rocks & Minerals: 60: 116.
Mineral and/or Locality  
Mindat.org is an outreach project of the Hudson Institute of Mineralogy, a 501(c)(3) not-for-profit organization.
Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2015, except where stated. Mindat.org relies on the contributions of thousands of members and supporters.
Privacy Policy - Terms & Conditions - Contact Us Current server date and time: May 29, 2015 13:24:01 Page generated: May 28, 2015 16:36:47