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Labuntsovite-Mn

Formula:
Na
 
4
K
 
4
(Ba,K)
 
2
Mn
2+
 
(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
· 10-12H
 
2
O
System:MonoclinicHardness:6
Name:Named after the Russian mineralogists Aleksander Nikolaevich Labuntsov and Ekaterina Eutiikkieva Labuntsov-Kostyleva.


Labuntsovite Group.

This is the original labuntsovite. It is now designated labuntsovite-Mn for the dominance of manganese among the divalent cations.

Classification of Labuntsovite-Mn

IMA status:Approved
Strunz 8th edition ID:8/E.07-40
Nickel-Strunz 10th (pending) edition ID:9.CE.30e

9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
Hey's CIM Ref.:16.14.8

16 : Silicates Containing Aluminum and other Metals
14 : Aluminosilicates of Ti, Zr, Sn and Pb
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Type Occurrence of Labuntsovite-Mn

Co-type Localities:Yum'egor Pass, Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Pegmatite No. 19, Kuftn'yun Mt, Lovozero Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Year of Discovery:1955

Physical Properties of Labuntsovite-Mn

Hardness (Mohs):6

Crystallography of Labuntsovite-Mn

Crystal System:Monoclinic

Optical Data of Labuntsovite-Mn

Type:Biaxial (+)
RI values: nα = 1.684 - 1.695 nβ = 1.693 - 1.702 nγ = 1.792 - 1.814
2V:Measured: 20° to 44°, Calculated: 30° to 36°
Maximum Birefringence:δ = 0.108 - 0.119

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:strong

Chemical Properties of Labuntsovite-Mn

Formula:
Na
 
4
K
 
4
(Ba,K)
 
2
Mn
2+
 
(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
· 10-12H
 
2
O
Essential elements:H, K, O, Si, Ti
All elements listed in formula:Ba, H, K, Mn, Na, Nb, O, Si, Ti
Common Impurities:Fe,Mn,Mg,Ca

Relationship of Labuntsovite-Mn to other Species

Related Minerals - Nickel-Strunz Grouping):
9.CE.05Papagoite
CaCu[H
 
3
AlSi
 
2
O
 
9
]
9.CE.10Verplanckite
Ba
 
2
(Mn,Fe,Ti)Si
 
2
O
 
6
(O,OH,Cl,F)
 
2
·3H
 
2
O or near
9.CE.15Baotite
Ba
 
4
(Ti,Nb)
 
8
Si
 
4
O
 
28
Cl
9.CE.20Nagashimalite
Ba
 
4
(V,Ti)
 
4
B
 
2
Si
 
8
O
 
27
(O,OH)
 
2
Cl
9.CE.20Taramellite
Ba
 
4
(Fe
3+
 
,Ti,Fe
2+
 
,Mg)
 
4
(B
 
2
Si
 
8
O
 
27
)O
 
2
Cl
 
x
9.CE.20Titantaramellite
Ba
 
4
(Ti,Fe
3+
 
,Fe
2+
 
,Mg)
 
4
(B
 
2
Si
 
8
O
 
27
)O
 
2
Cl
 
x
9.CE.25Bario-orthojoaquinite
(Ba,Sr)
 
4
Fe
 
2
Ti
 
2
Si
 
8
O
 
26
·H
 
2
O
9.CE.25Byelorussite-(Ce)
Ba
 
2
NaCe
 
2
MnTi
 
2
Si
 
8
O
 
26
(F,OH) · H
 
2
O
9.CE.25Joaquinite-(Ce)
Ba
 
2
NaCe
 
2
FeTi
 
2
Si
 
8
O
 
26
(OH,F) · H
 
2
O
9.CE.25Orthojoaquinite-(Ce)
Ba
 
2
NaCe
 
2
FeTi
 
2
Si
 
8
O
 
26
(O,OH) · H
 
2
O
9.CE.25Strontiojoaquinite
Sr
 
2
Ba
 
2
(Na,Fe)
 
2
Ti
 
2
Si
 
8
O
 
24
(O,OH)
 
2
·H
 
2
O
9.CE.25Strontio-orthojoaquinite
Sr
 
2
Ba
 
2
(Na,Fe)
 
2
Ti
 
2
Si
 
8
O
 
24
(O,OH)
 
2
·H
 
2
O
9.CE.25Orthojoaquinite-(La)
Ba
 
2
NaLa
 
2
Fe
2+
 
Ti
 
2
Si
 
8
O
 
26
(O,OH)·H
 
2
O
9.CE.30aNenadkevichite
(Na,Ca)(Nb,Ti)Si
 
2
O
 
7
·2H
 
2
O
9.CE.30dLemmleinite-K
K
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 4H
 
2
O
9.CE.30aKorobitsynite
Na
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3-4H
 
2
O
9.CE.30cKuzmenkoite-Mn
K
 
2
Mn
2+
 
(Ti,Nb)
 
4
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
2
· 5H
 
2
O
9.CE.30bVuoriyarvite-K
K
 
2
(Nb,Ti)
 
2
[(O,OH)
 
2
|Si
 
4
O
 
12
] · 4H
 
2
O
9.CE.30bTsepinite-Na
Na
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30cKarupmøllerite-Ca
(Na,Ca,K)
 
2
Ca(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 7H
 
2
O
9.CE.30eLabuntsovite-Mg
Na
 
4
K
 
4
(Ba,K)
 
2
Mg(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
· 10H
 
2
O
9.CE.30eLabuntsovite-Fe
Na
 
4
K
 
4
(Ba,K)
 
2
Fe
2+
 
(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
· 10H
 
2
O
9.CE.30dLemmleinite-Ba
Na
 
2
K
 
2
Ba(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 5H
 
2
O
9.CE.30cGjerdingenite-Fe
K
 
2
Fe
2+
 
(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 6H
 
2
O
9.CE.30hNeskevaaraite-Fe
K
 
3
Na
 
2
Fe
2+
 
(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 5-6 H
 
2
O
9.CE.30bTsepinite-K
K
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30bParatsepinite-Ba
Ba
 
4
(Ti,Nb)
 
8
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
4
· 8H
 
2
O
9.CE.30bTsepinite-Ca
Ca(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30hAlsakharovite-Zn
NaSrKZn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 7 H
 
2
O
9.CE.30cGjerdingenite-Mn
K
 
2
Mn
2+
 
(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 6H
 
2
O
9.CE.30cLepkhenelmite-Zn
(Ba,K)
 
2
Zn(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 7H
 
2
O
9.CE.30bTsepinite-Sr
Sr(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30bParatsepinite-Na
(Na,Sr,K,Ca)
 
7
(Ti,Nb)
 
8
[Si
 
4
O
 
12
]
 
4
(O,OH)
 
8
·nH
 
2
O n ~ 8
9.CE.30fParalabuntsovite-Mg
Na
 
8
K
 
8
Mg
 
8
Ti
 
16
(Si
 
4
O
 
12
)
 
8
(O,OH)
 
16
· n(H
 
2
O)
9.CE.30cGjerdingenite-Ca
K
 
2
Ca(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 6H
 
2
O
9.CE.30cGjerdingenite-Na
K
 
2
Na
 
2
(Nb,Ti)
 
4
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
2
· 5H
 
2
O
9.CE.30hGutkovaite-Mn
K
 
2
CaMn(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 5H
 
2
O
9.CE.30cKuzmenkoite-Zn
K
 
2
Zn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
·6-8H
 
2
O
9.CE.30gOrganovaite-Mn
K
 
2
Mn(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 6H
 
2
O
9.CE.30gOrganovaite-Zn
K
 
2
Zn(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 6H
 
2
O
9.CE.30gParakuzmenkoite-Fe
(K,Ba)
 
4
Fe(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
· 14H
 
2
O
9.CE.30cIMA2008-001
(K,Na,Sr,Ba)
 
4
Ca
 
2
(Ti,Nb)
 
8
[Si
 
4
O
 
12
]
 
4
(OH,O)
 
8
·12H
 
2
O
9.CE.45Komarovite
(Ca,Mn)Nb
 
2
[O
 
3
|Si
 
2
O
 
7
] · 3.5H
 
2
O
9.CE.45Natrokomarovite
(Na,Ca,H)
 
2
Nb
 
2
Si
 
2
O
 
10
(OH,F)
 
2
·H
 
2
O
Related Minerals - Hey's Index Grouping:
16.14.1Zorite
Na
 
2
Ti(Si,Al)
 
3
O
 
9
·nH
 
2
O
16.14.2Vinogradovite
(Na,Ca,K)
 
4
Ti
 
4
AlSi
 
6
O
 
23
(OH)·2H
 
2
O
16.14.3Rhönite
Ca
 
2
(Mg,Fe
2+
 
,Fe
3+
 
,Ti)
 
6
[O
 
2
|(Si,Al)
 
6
O
 
18
]
16.14.4Kaersutite
[Na][Ca
 
2
][Mg
 
4
Ti][O|OH|Al
 
2
Si
 
6
O
 
22
]
16.14.5Ferrokaersutite
[Na][Ca
 
2
][Fe
2+
4
Ti][O|OH|Al
 
2
Si
 
6
O
 
22
]
16.14.6Jonesite
Ba
 
4
(K,Na)
 
2
Ti
 
4
Al
 
2
[O|(SiO
 
4
)
 
2
|Si
 
3
O
 
9
]
 
2
· 6H
 
2
O
16.14.7Lourenswalsite
(K,Ba)
 
2
(Ti,Mg,Ca,Fe)
 
4
(Si,Al,Fe)
 
6
O
 
14
(OH)
 
12
16.14.9Kimzeyite
Ca
 
3
(Zr,Ti)
 
2
[(Si,Al,Fe
3+
 
)O
 
4
]
 
3
16.14.10Ellenbergerite
Mg
 
6
Al
 
6
Ti[(OH)
 
6
|(HSiO
 
4
)
 
4
|(SiO
 
4
)
 
4
]
16.14.11Carlosturanite
(Mg,Fe,Ti)
 
21
(Si,Al)
 
12
O
 
28
(OH)
 
34
16.14.12Eakerite
Ca
 
2
SnAl
 
2
Si
 
6
O
 
18
(OH)
 
2
·2H
 
2
O
16.14.13Plumalsite
Pb
 
4
Al
 
2
(SiO
 
3
)
 
7
16.14.14Wickenburgite
CaPb
 
3
Al
 
2
Si
 
10
O
 
24
(OH)
 
6
16.14.15Maricopaite
Pb
 
7
Ca
 
2
(Si,Al)
 
48
O
 
100
·32H
 
2
O
16.14.16Epidote-(Pb)
{CaPb}{Al
 
3
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
16.14.17Burckhardtite
Pb
 
2
(Fe,Mn)AlTeO
 
2
Si
 
3
O
 
10
(OH)
 
2
·H
 
2
O
16.14.18Mathewrogersite
Pb
 
7
(Fe
2+
 
,Cu)Al
 
3
Ge[(OH,H
 
2
O)
 
6
|(Si
 
3
O
 
9
)
 
4
]

Other Names for Labuntsovite-Mn

Synonyms:
Labuntsovite (of Semenov and Burova)Unnamed (MSH UK-5)
Russian names:
Лабунцовит-Mn

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Labuntsovite-Mn

Reference List:Semenov, E.I., & Burova, T.A. (1955): On the new mineral, labuntsovite, and the so-called titanoelpidite. Doklady Akademii Nauk SSSR., 101, 1113-1116 (in Russian). English abstract: American Mineralogist, 41, (1956) 163.

Chukanov, N.V., Pekov, I.V. & Khomyakov, A.P. (2002): Recommended nomenclature for labuntsovite-group minerals. European Journal of Mineralogy, 14, 165-173.

Canadian Mineralogist (1999), 37: 901.

Internet Links for Labuntsovite-Mn

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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    Localities for Labuntsovite-Mn

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • Québec
      • Rouville Co.
        • Mont Saint-Hilaire
    Henderson, W. (1979), Oriented overgrowth of labuntsovite on elpidite from Mont St.-Hilaire, Quebec, Canada. Mineralogical Record: 10: 970., Horváth, L and Gault, R.A. (1990), The mineralogy of Mont Saint-Hilaire Quebec. Mineralogical Record: 21: 284-359.
      • Verchères Co.
        • Varennes & St-Amable
          • Saint-Amable sill
    Mineralogical Record: 29: 83.
    Namibia
     
    • Khomas Region
      • Windhoek District
        • Windhoek
          • Aris
    Petersen, O. V., Niedermayr, G., Pekov, I. V., Balić Žunić, T. and Brandstätter, F. (2004): Tsepinit-Na und Labuntsovit-Mn, seltene Mineralien aus dem Phonolith von Aris, Namibia. Mineralien-Welt, 15 (2), 44-48. (in German)
    Russia
     
    • Eastern-Siberian Region
      • Saha Republic (Sakha Republic; Yakutia)
        • Aldan Shield
          • Torgo River Basin
            • Davan
              • Chara River (Charo River)
    [Lapis 1993:4 p.13-20]
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Khibiny Massif
    [World of Stones 95:5-6, p64]
            • Kukisvumchorr Mt
    [World of Stones 95:5-6, p64]
          • Kovdor Massif
    [World of Stones 95:5-6, p64]
          • Lovozero Massif
    [AmMin 85:1562]
    [AmMin 85:1322]
            • Kuftn'yun Mt
          • Turii Cape
    www.koeln.netsurf.de/~w.steffens/vuori.htm
    USA
     
    • Arkansas
      • Hot Spring Co.
        • Magnet Cove
    Rocks & Min.:64:300-307.
    Mineral and/or Locality
    Google
     
    www.mindat.org Web
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