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Annite

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Formula:
KFe32+(AlSi3O10)(OH)2
System:
Monoclinic
Colour:
Black, brown
Lustre:
Vitreous
Hardness:
2½ - 3
Member of:
Name:
Originally named in 1868 by James Dwight Dana for a ferrian mica, but redefined as a ferroan mica by Alexander N. Winchell in 1925. Both authors named a mineral after the same locality at Rockport, Cape Ann, Essex Co., Massachusetts, USA.
Mica Group. Biotite-Phlogopite Series. The Fe analogue of phlogopite, shirozulite, and hendricksite. The Al analogue of tetraferriannite. The hydroxyl analogue of fluorannite.

Classification of Annite

Approved, 'Grandfathered' (first described prior to 1959)
8/H.11-110
9.EC.20

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.2.2b.3

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
16.18.4

16 : Silicates Containing Aluminum and other Metals
18 : Aluminosilicates of Fe and alkalis
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http://www.mindat.org/min-241.html
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Type Occurrence of Annite

Occurrences of Annite

Geological Setting:
Mg-low igneous and metamorphic rocks; associated minerals at Rockport, MA, USA

Physical Properties of Annite

Vitreous
Diaphaneity (Transparency):
Transparent, Translucent
Colour:
Black, brown
Hardness (Mohs):
2½ - 3
Tenacity:
Flexible
Cleavage:
Perfect
{001}
Density:
3.3 g/cm3 (Measured)    3.36 g/cm3 (Calculated)

Crystallography of Annite

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Space Group Setting:
C2/m
Cell Parameters:
a = 5.3860(9) Å, b = 9.3241(7) Å, c = 10.2683(9) Å
β = 100.63(1)°
Ratio:
a:b:c = 0.578 : 1 : 1.101
Unit Cell Volume:
V 506.82 ų (Calculated from Unit Cell)
Z:
2
Morphology:
tabular crystals or cleavage fragments, both having pseudohexagonal outlines, up to 15 cm in size; foliated masses
Twinning:
contact twins, composition surface {001}, twin axis [310]
X-Ray Powder Diffraction Data:
d-spacingIntensity
10.264 (100)
3.380 (80)
2.654 (70)
2.465 (40)
1.556 (40)
2.199 (20)
1.692 (20)
(
Comments:
synthetic material, 1M polytype

Optical Data of Annite

Type:
Biaxial (-)
RI values:
nα = 1.625 - 1.631 nβ = 1.690 nγ = 1.691 - 1.697
2V:
Calculated: 12° to 36°
Max Birefringence:
δ = 0.066
Image shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
weak to distinct (r < v)
Comments:
brown (X), dark brown (Y=Z)
Comments:
Orientation: Y=b; measured 2V according to the Handbook of Mineralogy is from 0 to 5 deg.

Chemical Properties of Annite

Formula:
KFe32+(AlSi3O10)(OH)2
All elements listed in formula:
Analytical Data:
Moina skarn, Tasmania / Kawai mine, Japan [wt.%]
SiO2 34.90 / 32.56 
TiO2 0.00 / 1.48
Al2O3 10.90 / 17.24 
FeO 36.19 / 34.25 
MnO 1.77 / 0.03
MgO 3.40 / 0.86
CaO 0.15 / 0.00
Na2O 0.00 / 0.28
K2O 8.10 / 8.20
F 2.22
Cl 0.24

total 97.87 / 94.90
Common Impurities:
Ti,Mn,Mg,Ca,Na,K,Cl

Relationship of Annite to other Species

Series:
Forms a series with Phlogopite (see here)
Member of:
Other Members of Group:
AluminoceladoniteK(Mg,Fe2+)Al(Si4O10)(OH)2
Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2
AspidoliteNaMg3(AlSi3O10)(OH)2
BalestraiteKLi2V5+Si4O12
Biotite
BityiteLiCaAl2(AlBeSi2O10)(OH)2
BoromuscoviteKAl2(BSi3O10)(OH)2
Brammallite(Na,H3O)(Al,Mg,Fe)2((Si,Al)4O10)(OH)2
CeladoniteK(Mg,Fe2+)Fe3+(Si4O10)(OH)2
Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2
ChromceladoniteK(Mg,Fe2+)(Cr,Al)(Si4O10)(OH)2
ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2
ClintoniteCa(Mg,Al)3(Al3SiO10)(OH)2
EastoniteKMg2Al(Al2Si2O10)(OH)2
EphesiteLiNaAl2(Al2Si2O10)(OH)2
FerroaluminoceladoniteK(Fe2+,Mg)(Al,Fe3+)(Si4O10)(OH)2
FerroceladoniteK(Fe2+,Mg)(Fe3+,Al)(Si4O10)(OH)2
Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2
FluoranniteKFe32+(AlSi3O10)(F,OH)2
FluorophlogopiteKMg3(AlSi3O10)(F,OH)2
Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2
Glauconite(K,Na)(Mg,Fe2+,Fe3+)(Fe3+,Al)(Si,Al)4O10(OH)2
HendricksiteK(Zn,Mg,Mn2+)3(AlSi3O10)(OH)2
IlliteK0.65Al2.0[Al0.65Si3.35O10](OH)2
Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2
Lepidolite
LuanshiweiiteKLiAl1.50.5(Si3.5Al0.5)O10(OH,F)2
MargariteCaAl2(Al2Si2O10)(OH)2
Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2
Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4
MuscoviteKAl2(AlSi3O10)(OH)2
NanpingiteCsAl2(AlSi3O10)(OH,F)2
Natro-glauconite(Na,K)(Fe3+,Al,Mg)2((Si,Al)4O10)(OH)2
NorrishiteKLiMn23+(Si4O10)O2
Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2
OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2
ParagoniteNaAl2(AlSi3O10)(OH)2
Phengite
PhlogopiteKMg3(AlSi3O10)(OH)2
PolylithioniteKLi2Al(Si4O10)(F,OH)2
PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2
RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2
ShirokshiniteKNaMg2(Si4O10)F2
ShirozuliteK(Mn2+,Mg)3(AlSi3O10)(OH)2
SiderophylliteKFe22+Al(Al2Si2O10)(OH)2
SokolovaiteCsLi2Al(Si4O10)F2
Suhailite(NH4)Fe32+(AlSi3O10)(OH)2
TainioliteKLiMg2(Si4O10)F2
TetraferrianniteKFe32+((Fe3+,Al)Si3O10)(OH)2
TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2
Tobelite(NH4,K)Al2(AlSi3O10)(OH)2
TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2
VoloshiniteRb(LiAl1.51.5)(Al0.5Si3.5)O10F2
Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4
YangzhumingiteKMg2.5(Si4O10)F2
ZinnwalditeKLiFe2+Al(AlSi3O10)(F,OH)2
Common Associates:
9.EC.05MinnesotaiteFe32+Si4O10(OH)2
9.EC.05TalcMg3Si4O10(OH)2
9.EC.05WillemseiteNi3Si4O10(OH)2
9.EC.10FerripyrophylliteFe3+Si2O5(OH)
9.EC.10PyrophylliteAl2Si4O10(OH)2
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2
9.EC.15CeladoniteK(Mg,Fe2+)Fe3+(Si4O10)(OH)2
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2
9.EC.15Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2
9.EC.15RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2
9.EC.15Tobelite(NH4,K)Al2(AlSi3O10)(OH)2
9.EC.15AluminoceladoniteK(Mg,Fe2+)Al(Si4O10)(OH)2
9.EC.15ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2
9.EC.15FerroaluminoceladoniteK(Fe2+,Mg)(Al,Fe3+)(Si4O10)(OH)2
9.EC.15FerroceladoniteK(Fe2+,Mg)(Fe3+,Al)(Si4O10)(OH)2
9.EC.15ChromceladoniteK(Mg,Fe2+)(Cr,Al)(Si4O10)(OH)2
9.EC.15TainioliteKLiMg2(Si4O10)F2
9.EC.15Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2
9.EC.20EphesiteLiNaAl2(Al2Si2O10)(OH)2
9.EC.20HendricksiteK(Zn,Mg,Mn2+)3(AlSi3O10)(OH)2
9.EC.20Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2
9.EC.20NorrishiteKLiMn23+(Si4O10)O2
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2
9.EC.20SiderophylliteKFe22+Al(Al2Si2O10)(OH)2
9.EC.20TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2
9.EC.20Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2
9.EC.20TetraferrianniteKFe32+((Fe3+,Al)Si3O10)(OH)2
9.EC.20TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2
9.EC.20FluoranniteKFe32+(AlSi3O10)(F,OH)2
9.EC.20ShirokshiniteKNaMg2(Si4O10)F2
9.EC.20ShirozuliteK(Mn2+,Mg)3(AlSi3O10)(OH)2
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2
9.EC.20FluorophlogopiteKMg3(AlSi3O10)(F,OH)2
9.EC.20UM2004-49-SiO:AlCsFHKLi(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20Suhailite(NH4)Fe32+(AlSi3O10)(OH)2
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2
9.EC.20OrloviteKLi2Ti(Si4O10)OF
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2
9.EC.25Brammallite(Na,H3O)(Al,Mg,Fe)2((Si,Al)4O10)(OH)2
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2
9.EC.35BityiteLiCaAl2(AlBeSi2O10)(OH)2
9.EC.35ClintoniteCa(Mg,Al)3(Al3SiO10)(OH)2
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V25+Si5O35 · 27H2O (?)
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2O
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2
9.EC.45SwineforditeLi(Al,Li,Mg)4((Si,Al)4O10)2(OH,F)4 · nH2O
9.EC.45ZincsiliteZn3(Si4O10)(OH)2 · 4H2O
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2O
9.EC.55Baileychlore(Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8
9.EC.55Chamosite(Fe2+,Mg,Al,Fe3+)6(Si,Al)4O10(OH,O)8
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8
9.EC.55Cookeite(Al2Li)Al2(AlSi3O10)(OH)8
9.EC.55FranklinfurnaceiteCa2Fe3+Mn32+Mn3+(Zn2Si2O10)(OH)8
9.EC.55Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8
9.EC.55Nimite(Ni,Mg,Al)6((Si,Al)4O10)(OH)8
9.EC.55Orthochamosite(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55PennantiteMn52+Al(AlSi3O10)(OH)8
9.EC.55SudoiteMg2Al3(Si3Al)O10)(OH)8
9.EC.55DonbassiteAl4.33(AlSi3O10)(OH)8
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8
9.EC.55BorocookeiteLi1+3xAl4-x(BSi3O10)(OH)8
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2O
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2O
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6
9.EC.75Ferrisurite(Pb,Ca)2.4Fe23+(Si4O10)(CO3)1.7(OH)3 · nH2O
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2O
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8
16.18.1NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2O
16.18.2Ferro-glaucophane◻[Na2][Fe32+Al2]Si8O22(OH)2
16.18.3TuhualiteNaFe2+Fe3+Si6O15
16.18.5SiderophylliteKFe22+Al(Al2Si2O10)(OH)2

Other Names for Annite

Name in Other Languages:
German:Annit
Japanese:鉄雲母
Russian:Аннит
Simplified Chinese:铁云母
Spanish:Annita
Traditional Chinese:鐵雲母

Other Information

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Annite

Reference List:
Dana, J.D., Brush, G.J. (1868) 291. Annite. in: A System of Mineralogy, Fifth Edition, John Wiley and Sons, New York, 308-308.

Hazen, R.M., Burnham, C.W. (1973) The crystal structure of one-layer phlogopite and annite. American Mineralogist: 58: 889-900.

Kwak, T.A.P. (1981) Sector–zoned annite85phlogopite15 micas from the Mt. Lindsay Sn—W—F(—Be) deposit, Tasmania, Australia. The Canadian Mineralogist: 19: 643-650.

Tlili, A., Smith, D.C., Beny, J.M., Boyer, H. (1989) A Raman microprobe study of natural micas. Mineralogical Magazine: 53: 165-179.

Rieder, M., Cavazzani, G., D'Yakonov, Y.S., Frank-Kamenetskii, V.A., Gottardi, G., Guggenheim, S., Koval, P.V., Müller, G., Neiva, A.M.R., Radaslovich, E.W., Robert, J.-L., Sassi, F.P., Takeda, H., Weiss, Z., Wones, D.R. (1998) Nomenclature of the micas. The Canadian Mineralogist: 36: 905-912.

Anthony, J.W., Bideaux, R.A., Bladh, K.W. and Nichols, M.C., Eds. Handbook of Mineralogy, Mineralogical Society of America, Chantilly, VA 20151-1110, USA. http://www.handbookofmineralogy.org/ (2016)

Internet Links for Annite

Specimens:
The following Annite specimens are currently listed for sale on minfind.com.

Localities for Annite

map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Mineral and/or Locality  
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