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Lishizhenite

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Formula:
ZnFe
 
2
(SO
 
4
)
 
4
 · 14H
 
2
O
System:TriclinicColour:Pale violet to yellowish ...
Hardness:3½
Name:
For Li Shizhen (1518-1593), famous Chinese pharmacologist.
This page provides mineralogical data about Lishizhenite.

Classification of Lishizhenite

IMA status:Approved
Strunz 8th edition ID:6/C.11-15
Nickel-Strunz 10th (pending) edition ID:7.CB.75

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
B : With only medium-sized cations
Dana 8th edition ID:29.7.2.2

29 : HYDRATED ACID AND NORMAL SULFATES
7 : AB2(XO4)4·H2O
Hey's CIM Ref.:25.11.28

25 : Sulphates
11 : Sulphates of Fe and other metals
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Type Occurrence of Lishizhenite

Type Locality:Xitieshan Pb-Zn deposit, Da Qaidam (Dachaidan) Co., Haixi Autonomous Prefecture, Qinghai (Chinghai) Province, China
Place of Conservation of Type Material:Geology museum, Beijing, China
Year of Discovery:1990
Geological Setting of type material:Veinlets in anhydrite in oxidation zone of Pb-Zn deposit.

Physical Properties of Lishizhenite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent
Colour:Pale violet to yellowish brown.
Streak:White
Hardness (Mohs):3½
Cleavage:Perfect
Nearly perfect on {010}
poor on {001}
Density (measured):2.206 g/cm3
Density (calculated):2.201 g/cm3

Crystallography of Lishizhenite

Crystal System:Triclinic
Class (H-M):1 - Pinacoidal
Space Group:P1
Cell Parameters:a = 6.477(1) Å, b = 15.298(3) Å, c = 6.309(1) Å
α = 90.2(1)°, β = 101.11(1)°, γ = 93.97°
Ratio:a:b:c = 0.423 : 1 : 0.412
Unit Cell Volume:V 611.85 ų (Calculated from Unit Cell)
Z:1
Morphology:Tabular to prismatic to 8mm, aggregates.

Optical Data of Lishizhenite

Type:Biaxial (-)
RI values: nα = 1.522(2) nβ = 1.568(1) nγ = 1.578(4)
2V:Measured: 47° , Calculated: 48°
Maximum Birefringence:δ = 0.056

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low
Dispersion:relatively strong r>v

Chemical Properties of Lishizhenite

Formula:
ZnFe
 
2
(SO
 
4
)
 
4
 · 14H
 
2
O
Essential elements:Fe, H, O, S, Zn
All elements listed in formula:Fe, H, O, S, Zn
Empirical Formula:
ZnFe
3+
2
(SO
 
4
)
 
4
 · 14H
 
2
O

Relationship of Lishizhenite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
7.CB.05Dwornikite
(Ni,Fe)SO
 
4
 · H
 
2
O
7.CB.05Gunningite
ZnSO
 
4
 · H
 
2
O
7.CB.05Kieserite
MgSO
 
4
 · H
 
2
O
7.CB.05Poitevinite
(Cu,Fe,Zn)SO
 
4
 · H
 
2
O
7.CB.05Szmikite
MnSO
 
4
 · H
 
2
O
7.CB.05Szomolnokite
FeSO
 
4
 · H
 
2
O
7.CB.05Cobaltkieserite
CoSO
 
4
 · H
 
2
O
7.CB.07Sanderite
MgSO
 
4
 · 2H
 
2
O
7.CB.10Bonattite
CuSO
 
4
 · 3H
 
2
O
7.CB.15Aplowite
(Co,Mn,Ni)SO
 
4
 · 4H
 
2
O
7.CB.15Boyleite
(Zn,Mg)SO
 
4
 · 4H
 
2
O
7.CB.15Ilesite
(Mn,Zn,Fe)SO
 
4
 · 4H
 
2
O
7.CB.15Rozenite
FeSO
 
4
 · 4H
 
2
O
7.CB.15Starkeyite
MgSO
 
4
 · 4H
 
2
O
7.CB.15Drobecite
CdSO
 
4
 · 4H
 
2
O
7.CB.15Cranswickite
MgSO
 
4
 · 4H
 
2
O
7.CB.20Chalcanthite
CuSO
 
4
 · 5H
 
2
O
7.CB.20Jôkokuite
MnSO
 
4
 · 5H
 
2
O
7.CB.20Pentahydrite
MgSO
 
4
 · 5H
 
2
O
7.CB.20Siderotil
FeSO
 
4
 · 5H
 
2
O
7.CB.25Bianchite
(Zn,Fe)SO
 
4
 · 6H
 
2
O
7.CB.25Chvaleticeite
(Mn,Mg)SO
 
4
 · 6H
 
2
O
7.CB.25Ferrohexahydrite
FeSO
 
4
 · 6H
 
2
O
7.CB.25Hexahydrite
MgSO
 
4
 · 6H
 
2
O
7.CB.25Moorhouseite
(Co,Ni,Mn)SO
 
4
 · 6H
 
2
O
7.CB.25Nickelhexahydrite
(Ni,Mg,Fe)SO
 
4
 · 6H
 
2
O
7.CB.30Retgersite
NiSO
 
4
 · 6H
 
2
O
7.CB.35Bieberite
CoSO
 
4
 · 7H
 
2
O
7.CB.35Boothite
CuSO
 
4
 · 7H
 
2
O
7.CB.35Mallardite
MnSO
 
4
 · 7H
 
2
O
7.CB.35Melanterite
FeSO
 
4
 · 7H
 
2
O
7.CB.35Zincmelanterite
(Zn,Cu,Fe)SO
 
4
 · 7H
 
2
O
7.CB.35Alpersite
(Mg,Cu)[SO
 
4
] · 7H
 
2
O
7.CB.40Epsomite
MgSO
 
4
 · 7H
 
2
O
7.CB.40Goslarite
ZnSO
 
4
 · 7H
 
2
O
7.CB.40Morenosite
NiSO
 
4
 · 7H
 
2
O
7.CB.45Alunogen
Al
 
2
(SO
 
4
)
 
3
 · 17H
 
2
O
7.CB.45Meta-alunogen
Al
 
2
(SO
 
4
)
 
3
 · 12H
 
2
O
7.CB.50Aluminocoquimbite
FeAl(SO
 
4
)
 
3
 · 9H
 
2
O
7.CB.55Coquimbite
Fe
 
2-x
Al
 
x
(SO
 
4
)
 
3
 · 9H
 
2
O, x ~0.5
7.CB.55Paracoquimbite
Fe
 
2
(SO
 
4
)
 
3
 · 9H
 
2
O
7.CB.55Rhomboclase
(H
 
5
O
 
2
)Fe
3+
 
(SO
 
4
)
 
2
 · 2H
 
2
O
7.CB.60Kornelite
Fe
 
2
(SO
 
4
)
 
3
 · 7H
 
2
O
7.CB.65Quenstedtite
Fe
 
2
(SO
 
4
)
 
3
 · 10H
 
2
O
7.CB.70Lausenite
Fe
 
2
(SO
 
4
)
 
3
·6H
 
2
O
7.CB.75Römerite
Fe
2+
 
Fe
3+
2
(SO
 
4
)
 
4
 · 14H
 
2
O
7.CB.80Ransomite
CuFe
 
2
(SO
 
4
)
 
4
 · 6H
 
2
O
7.CB.85Apjohnite
Mn
2+
 
Al
 
2
(SO
 
4
)
 
4
 · 22H
 
2
O
7.CB.85Bílinite
Fe
2+
 
Fe
3+
2
(SO
 
4
)
 
4
 · 22H
 
2
O
7.CB.85Dietrichite
(Zn,Fe
2+
 
,Mn
2+
 
)Al
 
2
(SO
 
4
)
 
4
 · 22H
 
2
O
7.CB.85Halotrichite
FeAl
 
2
(SO
 
4
)
 
4
 · 22H
 
2
O
7.CB.85Pickeringite
MgAl
 
2
(SO
 
4
)
 
4
 · 22H
 
2
O
7.CB.85Redingtonite
(Fe
2+
 
,Mg,Ni)(Cr,Al)
 
2
(SO
 
4
)
 
4
·22H
 
2
O
7.CB.85Wupatkiite
(Co,Mg,Ni)Al
 
2
(SO
 
4
)
 
4
·22H
 
2
O
7.CB.90Meridianiite
MgSO
 
4
 · 11H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
25.11.1Natrojarosite
NaFe
 
3
(SO
 
4
)
 
2
(OH)
 
6
25.11.2Sideronatrite
Na
 
2
Fe(SO
 
4
)
 
2
(OH) · 3H
 
2
O
25.11.3Metasideronatrite
Na
 
4
Fe
 
2
(SO
 
4
)
 
4
(OH)
 
2
 · 2H
 
2
O
25.11.4Ferrinatrite
Na
 
3
Fe(SO
 
4
)
 
3
 · 3H
 
2
O
25.11.5Amarillite
NaFe(SO
 
4
)
 
2
 · 6H
 
2
O
25.11.6Yavapaiite
KFe(SO
 
4
)
 
2
25.11.7Krausite
KFe(SO
 
4
)
 
2
 · H
 
2
O
25.11.8Goldichite
KFe(SO
 
4
)
 
2
 · 4H
 
2
O
25.11.9Jarosite
KFe
3+
 
 
3
(SO
 
4
)
 
2
(OH)
 
6
25.11.10Voltaite
K
 
2
Fe
2+
5
Fe
3+
3
Al(SO
 
4
)
 
12
 · 18H
 
2
O
25.11.11Ungemachite
K
 
3
Na
 
8
Fe(SO
 
4
)
 
6
(NO
 
3
)
 
2
 · 6H
 
2
O
25.11.12Metavoltine
Na
 
6
K
 
2
FeFe
 
6
(SO
 
4
)
 
12
O
 
2
 · 18H
 
2
O
25.11.13Sabieite
(NH
 
4
)Fe
3+
 
(SO
 
4
)
 
2
25.11.14Ammoniojarosite
(NH
 
4
)Fe
3+
3
(SO
 
4
)
 
2
(OH)
 
6
25.11.15Clairite
(NH
 
4
)
 
2
Fe
 
3
(SO
 
4
)
 
4
(OH)
 
3
 · 3H
 
2
O
25.11.16Mohrite
(NH
 
4
)
 
2
Fe(SO
 
4
)
 
2
 · 6H
 
2
O
25.11.17Lonecreekite
(NH
 
4
)Fe
3+
 
(SO
 
4
)
 
2
 · 12H
 
2
O
25.11.18Godovikovite
(NH
 
4
)Al(SO
 
4
)
 
2
25.11.19Botryogen
MgFe
3+
 
(SO
 
4
)
 
2
(OH) · 7H
 
2
O
25.11.21Slavíkite
(H
 
3
O
+
 
)
 
3
Mg
 
6
Fe
 
15
(SO
 
4
)
 
21
(OH)
 
18
 · 99H
 
2
O
25.11.23Sturmanite
Ca
 
6
(Fe
3+
 
,Al,Mn
3+
 
)
 
2
(SO
 
4
)
 
2
[B(OH)
 
4
](OH)
 
12
 · 25H
 
2
O
25.11.24Millosevichite
(Al,Fe)
 
2
(SO
 
4
)
 
3
25.11.25Aluminocopiapite
Al
 
2/3
Fe
3+
4
(SO
 
4
)
 
6
(OH)
 
2
 · 20H
 
2
O
25.11.26Halotrichite
FeAl
 
2
(SO
 
4
)
 
4
 · 22H
 
2
O
25.11.27Idrizite
(Mg,Fe)(Al,Fe)
 
2
(SO
 
4
)
 
3
(OH)
 
2
 · 15H
 
2
O or near
25.11.29Zincovoltaite
K
 
2
Zn
 
5
Fe
3+
3
Al(SO
 
4
)
 
12
 · 18H
 
2
O

Other Names for Lishizhenite

Synonyms:
IMA1989-002
Other Languages:
German:Lishizhenit
Spanish:Lishizhenita

Other Information

Other Information:Soluble in water, becomes dull and dark red or yellowish brown on exposure to air.
Special Storage/
Display Requirements:		Becomes dull and dark red or yellowish brown on exposure to air.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Lishizhenite

Reference List:

- +
Li Wanmao and Chen Guoying (1990): Lishizhenite - A new zinc sulphate mineral. Acta Mineralogica Sinica 10(4), 299-305 (in Chinese with English abstract). - New Minerals 1990-1994, 106 (abstract).

American Mineralogist (1991), 76, 2022.

Internet Links for Lishizhenite

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    • Localities for Lishizhenite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    China
     
    • Qinghai (Chinghai) Province
      • Haixi Autonomous Prefecture
        • Da Qaidam (Dachaidan) Co.
    		Li Wanmao and Chen Guoying (1990): Acta Mineralogica Sinica 10(4), 299-305.
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