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Lotharmeyerite

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Ojuela Mine, Mapimí, Mun. de Mapimí, Durango, Mexico
© JBS 2006

Show Lotharmeyerite Photos (7)



Formula:
Ca(Zn,Mn
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
System:MonoclinicColour:Dark red. dark orange ...
Lustre:Sub-VitreousHardness:3
Member of:Tsumcorite Group
Name:
For German chemist Julius Lothar Meyer (1830-1895) who developed early concepts for the periodic table of elements.
Isostructural with:Tsumcorite


Visually indistinguishable from manganlotharmeyerite.

Classification of Lotharmeyerite

IMA status:Approved 1985
Strunz 8th edition ID:7/C.31-20
Nickel-Strunz 10th (pending) edition ID:8.CG.15

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
G : With large and medium-sized cations, RO4:H2O = 1:1
Dana 7th edition ID:40.2.11.1
Dana 8th edition ID:37.1.6.1

37 : ANHYDROUS ACID PHOSPHATES, ARSENATES AND VANADATES
1 : Miscellaneous
Hey's CIM Ref.:20.3.18

20 : Arsenates (also arsenates with phosphate, but without other anions)
3 : Arsenates of Zn, Cd or Hg
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Type Occurrence of Lotharmeyerite

Type Locality:Ojuela Mine, Mapimí, Mun. de Mapimí, Durango, Mexico
Year of Discovery:1983
Geological Setting of type material:Oxidized zones of arsenic-bearing deposits.
Associated Minerals at type locality:
CryptomelaneAdamite

Occurrences of Lotharmeyerite

Geological Setting:Oxidation zone of arsenic containing polymetallic ore deposits.

Physical Properties of Lotharmeyerite

Lustre:Sub-Vitreous
Diaphaneity (Transparency):Translucent
Colour:Dark red. dark orange brown
Streak:Pale orange to yellow-orange
Hardness (Mohs):3
Tenacity:Brittle
Cleavage:Distinct/Good
Good on {001}
Fracture:Irregular/Uneven
Density (measured):4.23(5) g/cm3
Density (calculated):4.29(4) g/cm3

Crystallography of Lotharmeyerite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m {B1 1 2/m} {C2/m} {C1 2/m 1}
Space Group Setting:C2/m
Cell Parameters:a = 9.066(4) Å, b = 6.276(2) Å, c = 7.408(2) Å
β = 116.16°
Ratio:a:b:c = 1.445 : 1 : 1.18
Unit Cell Volume:V 378.33 ų (Calculated from Unit Cell)
Z:2
Morphology:Equant to tapering bladelike crystals to 6mm.
Twinning:Probable about [h0l]
Comment:MR (1984) 15:223
X-Ray Powder Diffraction:
d-spacingIntensity
4.94 (80)
3.41 (90)
3.18 (90)
2.91 (90)
2.82 (80)
2.71 (80)
2.56 (100)
1.687 (80)
Comments:ICDD 35-620

Optical Data of Lotharmeyerite

Type:Biaxial (+)
RI values: nα = 1.797 nβ = 1.804 nγ = 1.815
2V:Measured: 80° , Calculated: 78°
Birefringence:0.018
Maximum Birefringence:δ = 0.018

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:r >> v strong, inclined
Optical Extinction:Inclined
Pleochroism:Strong
Comments:X=Y= yellow-orange
Z= red-brown
Comments:Also given as "dark red orange to light pink-orange"

Chemical Properties of Lotharmeyerite

Formula:
Ca(Zn,Mn
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
Essential elements:As, Ca, H, O, Zn
All elements listed in formula:As, Ca, H, Mn, O, Zn

Relationship of Lotharmeyerite to other Species

Member of:Tsumcorite Group
Other Members of Group:

- +
Cabalzarite
Ca(Mg,Al,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
Cobaltlotharmeyerite
Ca(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
Cobalttsumcorite
Pb(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
Ferrilotharmeyerite
Ca(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
Gartrellite
Pb(Cu,Fe
3+
 
,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
 · 2(H
 
2
O,OH)
Helmutwinklerite
Pb(Zn,Cu)
 
2
(AsO
 
4
)
 
2
 · 2H
 
2
O
Krettnichite
(Pb,Sr)(Mn
3+
 
,Co)
 
2
(VO
 
4
)
 
2
 · 2(OH,H
 
2
O)
Lukrahnite
Ca(Cu,Zn)(Fe
3+
 
,Zn)(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
Manganlotharmeyerite
Ca(Mn
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
Mawbyite
Pb(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
Mounanaite
PbFe
3+
2
(VO
 
4
)
 
2
 · 2(OH,F)
Natrochalcite
NaCu
 
2
(SO
 
4
)
 
2
(OH) · 2H
 
2
O
Nickelschneebergite
(Bi
3+
 
,Ca)(Ni,Co,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
Phosphogartrellite
Pb(Cu,Fe
3+
 
)
 
2
(PO
 
4
,AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
Rappoldite
Pb(Co,Ni,Zn)
 
2
(AsO
 
4
)
 
2
 · 2H
 
2
O
Schneebergite
(Bi
3+
 
,Ca)(Co,Ni,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
Thometzekite
Pb(Cu,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
 · 2(H
 
2
O,OH)
Tsumcorite
Pb(Zn,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
Unnamed (Ni-analogue of Cobalttsumcorite)
Pb(Ni,Co)
 
2
(AsO
 
4
)
 
2
 · 2H
 
2
O
Yancowinnaite
PbCuAl(AsO
 
4
)
 
2
OH · H
 
2
O
Zincgartrellite
Pb(Zn,Fe
3+
 
,Cu)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
Related Minerals - Nickel-Strunz Grouping):

- +
8.CG.05Cassidyite
Ca
 
2
(Ni
2+
 
,Mg)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Collinsite
Ca
 
2
(Mg,Fe
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Fairfieldite
Ca
 
2
(Mn
2+
 
,Fe
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Gaitite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Messelite
Ca
 
2
(Fe
2+
 
,Mn
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Parabrandtite
Ca
 
2
Mn
2+
 
(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Talmessite
Ca
 
2
Mg(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Hillite
Ca
 
2
(Zn,Mg)(PO
 
4
)
 
2
 · 2 H
 
2
O
8.CG.10Brandtite
Ca
 
2
(Mn
2+
 
,Mg)(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Roselite
Ca
 
2
(Co
2+
 
,Mg)(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Wendwilsonite
Ca
 
2
(Mg,Co
2+
 
)(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Zincroselite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Rruffite
Ca
 
2
Cu(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.15Ferrilotharmeyerite
Ca(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Mawbyite
Pb(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Mounanaite
PbFe
3+
2
(VO
 
4
)
 
2
 · 2(OH,F)
8.CG.15Thometzekite
Pb(Cu,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Tsumcorite
Pb(Zn,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Cobaltlotharmeyerite
Ca(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Cabalzarite
Ca(Mg,Al,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Krettnichite
(Pb,Sr)(Mn
3+
 
,Co)
 
2
(VO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Cobalttsumcorite
Pb(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Nickellotharmeyerite
Ca(Ni,Fe
3+
 
,Co)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Manganlotharmeyerite
Ca(Mn
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Schneebergite
(Bi
3+
 
,Ca)(Co,Ni,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Nickelschneebergite
(Bi
3+
 
,Ca)(Ni,Co,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.20Gartrellite
Pb(Cu,Fe
3+
 
,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.20Helmutwinklerite
Pb(Zn,Cu)
 
2
(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.20Zincgartrellite
Pb(Zn,Fe
3+
 
,Cu)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.20Rappoldite
Pb(Co,Ni,Zn)
 
2
(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.20Phosphogartrellite
Pb(Cu,Fe
3+
 
)
 
2
(PO
 
4
,AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.20Lukrahnite
Ca(Cu,Zn)(Fe
3+
 
,Zn)(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.25Pottsite
HPbBi(VO
 
4
)
 
2
 · 2H
 
2
O
8.CG.35Nickeltalmessite
Ca
 
2
Ni(AsO
 
4
)
 
2
 · 2H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
20.3.1Adamite
Zn
 
2
(AsO
 
4
)(OH)
20.3.2Paradamite
Zn
 
2
(AsO
 
4
)(OH)
20.3.3Koritnigite
Zn(HAsO
 
4
) · H
 
2
O
20.3.4Legrandite
Zn
 
2
(AsO
 
4
)(OH) · H
 
2
O
20.3.5Warikahnite
Zn
 
3
(AsO
 
4
)
 
2
 · 2H
 
2
O
20.3.6Köttigite
Zn
 
3
(AsO
 
4
)
 
2
 · 8H
 
2
O
20.3.7Stranskiite
Zn
 
2
Cu(AsO
 
4
)
 
2
20.3.8Philipsburgite
(Cu,Zn)
 
6
(AsO
 
4
,PO
 
4
)
 
2
(OH)
 
6
 · H
 
2
O
20.3.9Austinite
CaZn(AsO
 
4
)(OH)
20.3.10Prosperite
CaZn
 
2
(AsO
 
4
)(HAsO
 
4
)(OH)
20.3.11Gaitite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
20.3.12Zincroselite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
20.3.13O'Danielite
Na(Zn,Mg)
 
3
H
 
2
(AsO
 
4
)
 
3
20.3.14Johillerite
Na(Mg,Zn)
 
3
Cu(AsO
 
4
)
 
3
20.3.15Holdenite
(Mn
2+
 
,Mg)
 
6
Zn
 
3
(AsO
 
4
)
 
2
(SiO
 
4
)(OH)
 
8
20.3.16Chudobaite
(Mg,Zn)
 
5
(AsO
 
4
)
 
2
(HAsO
 
4
)
 
2
 · 10H
 
2
O
20.3.17Chlorophoenicite
(Mn,Mg)
 
3
Zn
 
2
(AsO
 
4
)(OH,O)
 
6
20.3.19Metaköttigite
(Zn,Fe,Fe)
 
3
(AsO
 
4
)
 
2
 · 8(H
 
2
O,OH)
20.3.20Ojuelaite
ZnFe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
20.3.21Fahleite
Zn
 
5
CaFe
 
2
(AsO
 
4
)
 
6
 · 14H
 
2
O
20.3.22Keyite
Cu
2+
3
Zn
 
4
Cd
 
2
(AsO
 
4
)
 
6
 · 2H
 
2
O
Related Minerals - Dana Grouping):

- +
40.2.11.2Ferrilotharmeyerite
Ca(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)

Other Names for Lotharmeyerite

Other Languages:
German:Lotharmeyerit
Spanish:Lotharmeyerita

Other Information

Fluorescence in UV light:Not fluorescent
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Lotharmeyerite

Reference List:

- +
American Mineralogist (1983): 68: 849.

Mineralogical Record (1983) 14:35; (1984): 15: 223-226.

American Mineralogist (1985): 70: 1334.

Brugger, J., Krivovichev, S.V., Kolitsch, U., Meisser, N., Andrut, M., Ansermet, S., Burns, P.C. (2002) Description and crystal structure of manganlotharmeyerite, Ca[Mn 3+, ◻,Mg]2{AsO4,[AsO2(OH)2]}2(OH,H2O)2 from the Starlera Mn deposit,Swiss Alps, and a redefinition of lotharmeyerite. Canadian Mineralogist: 40: 1597-1608.

Yang, Y.W., Evans, S.H., Downs, R.T., Yang, H. (2012): Lotharmeyerite, Ca(Zn,Mn)2(AsO4)2(H2O,OH)2. Acta Crystallographica, E68, i9-i10.

Internet Links for Lotharmeyerite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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    • Localities for Lotharmeyerite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Wolfach
          • Oberwolfach
            • Rankach valley
    		KOLITSCH, U., GRÖBNER, J. BLASS, G., GRAF, H.-W. & PRING, A. (2005): Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis 30 (9), 35-39; 58.
    Mexico
     
    • Durango
      • Mun. de Mapimí
        • Mapimí
    		Min.Rec.(1983) 14, 35-36
    Thomas P. Moore (2008) Lapis, 33, #7-8, 33-40.
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