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Manganberzeliite

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Varenche Mine, Saint-Barthélemy, Nus, Aosta Valley, Italy
© Paolo Grosso

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Formula:
(Ca,Na)
 
3
(Mn
2+
 
,Mg)
 
2
[AsO
 
4
]
 
3
System:IsometricColour:Yellow-orange, yellowish ...
Hardness:4½ - 5
Name:For Jöns Jakob Berzelius, Swedish chemist (1779-1848) and the prefix MANGAN-, in allusion to it being the manganese dominant member of the series with berzeliite.


Berzeliite-Manganberzeliite Series. The manganese analogue of Berzeliite. Structurally related to Palenzonaite and to the Garnet Group of silicates.

Classification of Manganberzeliite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/A.08-40
Nickel-Strunz 10th (pending) edition ID:8.AC.25

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th edition ID:38.2.1.2
Dana 8th edition ID:38.2.1.2

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
Hey's CIM Ref.:20.8.18

20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn
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Type Occurrence of Manganberzeliite

Type Locality:Långban, Filipstad, Värmland, Sweden
Year of Discovery:1894

Physical Properties of Manganberzeliite

Lustre:Resinous
Colour:Yellow-orange, yellowish red; clourless to orange in transmitted light.
Comment:Depth of red tint increases with increase in the Mn content.
Hardness (Mohs):4½ - 5
Tenacity:Brittle
Cleavage:None Observed
Fracture:Irregular/Uneven, Sub-Conchoidal
Density (measured):4.28 - 4.46 g/cm3
Comment:Measured values are for the middle of the series with berzeliite to the Mn end member.

Crystallography of Manganberzeliite

Crystal System:Isometric
Class (H-M):m3m (4/m 3 2/m) - Hexoctahedral
Space Group:Ia3d (I41/a 3 2/d)
Cell Parameters:a = 12.52Å
Unit Cell Volume:V 1,962.52 ų (Calculated from Unit Cell)
Morphology:Crystals rare, as trapezohedrons with small modifying faces. Commonly massive or as rounded grains.

Optical Data of Manganberzeliite

Type:Isotropic

Chemical Properties of Manganberzeliite

Formula:
(Ca,Na)
 
3
(Mn
2+
 
,Mg)
 
2
[AsO
 
4
]
 
3
Essential elements:As, Ca, Mn, O
All elements listed in formula:As, Ca, Mg, Mn, Na, O

Relationship of Manganberzeliite to other Species

Series:Forms a series with Berzeliite (see here)
Related to:
  • Garnet Group
    • Related Minerals - Nickel-Strunz Grouping):
    8.AC.05Howardevansite
    NaCuFe
     
    2
    		(VO
     
    4
    		)
     
    3
    8.AC.10Alluaudite
    (Na,Ca)Mn
    2+
     
    		(Fe
    3+
     
    		,Mn
    2+
     
    		,Fe
    2+
     
    		,Mg)
     
    2
    		(PO
     
    4
    		)
     
    3
    8.AC.10Arseniopleite
    NaCaMn
    2+
     
    		(Mn
    2+
     
    		,Mg)
     
    2
    		(AsO
     
    4
    		)
     
    3
    8.AC.10Caryinite
    (Na,Pb)(Ca,Na)((Ca,Mn
    2+
     
    		)(Mn
    2+
     
    		,Mg,Fe
    3+
     
    		)[AsO
     
    4
    		]
     
    3
    8.AC.10Ferroalluaudite
    (Na,Ca)Fe
    2+
     
    		(Fe
    3+
     
    		,Mn
    2+
     
    		,Fe
    2+
     
    		)
     
    2
    		(PO
     
    4
    		)
     
    3
    8.AC.10Hagendorfite
    NaCaMn
    2+
     
    		Fe
    2+
    2
    		(PO
     
    4
    		)
     
    3
    8.AC.10Johillerite
    Na(Mg,Zn)
     
    3
    		Cu[AsO
     
    4
    		]
     
    3
    8.AC.10Maghagendorfite
    NaMn(Mg,Fe,Fe)
     
    3
    		(PO
     
    4
    		)
     
    3
    8.AC.10Nickenichite
    Na
     
    0.8
    		Ca
     
    0.4
    		Cu
     
    0.4
    		(Mg,Fe)
     
    3
    		(AsO
     
    4
    		)
     
    3
    8.AC.10Varulite
    NaCaMn
    2+
     
    		Mn
    2+
    2
    		(PO
     
    4
    		)
     
    3
    8.AC.10Ferrohagendorfite
    (Na,Ca)
     
    2
    		Fe
    2+
     
    		(Fe
    2+
     
    		,Fe
    3+
     
    		)
     
    2
    		(PO
     
    4
    		)
     
    3
    8.AC.10Bradaczekite
    NaCu
     
    4
    		(AsO
     
    4
    		)
     
    3
    8.AC.10Yazganite
    NaFe
    3+
    2
    		(Mg,Mn
    2+
     
    		)[AsO
     
    4
    		]
     
    3
    		 · H
     
    2
    		O
    8.AC.10Ferro-alluaudite
    8.AC.15Bobfergusonite
    Na
     
    2
    		Mn
     
    5
    		FeAl(PO
     
    4
    		)
     
    6
    8.AC.15Ferrowyllieite
    (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO
     
    4
    		)
     
    3
    8.AC.15Qingheiite
    NaMn
    3+
     
    		Mg(Al,Fe
    3+
     
    		)[PO
     
    4
    		]
     
    3
    8.AC.15Rosemaryite
    (Na,Ca,Mn)(Mn,Fe
    2+
     
    		)(Fe
    3+
     
    		,Mg)Al(PO
     
    4
    		)
     
    3
    8.AC.15Wyllieite
    (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO
     
    4
    		)
     
    3
    8.AC.15Ferrorosemaryite
    []NaFe
    2+
     
    		Fe
    3+
     
    		Al(PO
     
    4
    		)
     
    3
    8.AC.20Marićite
    NaFe
    2+
     
    		[PO
     
    4
    		]
    8.AC.25Berzeliite
    NaCa
     
    2
    		(Mg,Mn
    2+
     
    		)
     
    2
    		[AsO
     
    4
    		]
     
    3
    8.AC.25Palenzonaite
    (Ca,Na)
     
    3
    		CaMn
    2+
    2
    		[VO
     
    4
    		]
     
    3
    8.AC.25Schäferite
    Ca
     
    2
    		NaMg
     
    2
    		[VO
     
    4
    		]
     
    3
    8.AC.30Brianite
    Na
     
    2
    		CaMg[PO
     
    4
    		]
     
    2
    8.AC.35Vitusite-(Ce)
    Na
     
    3
    		(Ce,La,Nd)(PO
     
    4
    		)
     
    2
    8.AC.40Olgite
    Ba(NaSr)
     
    2
    		Na[PO
     
    4
    		]
     
    2
    8.AC.40Bario-olgite
    Ba(Na,Sr,REE)
     
    2
    		Na[PO
     
    4
    		]
     
    2
    8.AC.45Strontiowhitlockite
    Sr
     
    9
    		MgH[PO
     
    4
    		]
     
    7
    8.AC.45Whitlockite
    Ca
     
    9
    		Mg[PO
     
    3
    		OH][PO
     
    4
    		]
     
    6
    8.AC.45Merrillite
    Ca
     
    18
    		Na
     
    2
    		Mg
    2+
    2
    		[PO
     
    4
    		]
     
    14
    8.AC.45Tuite
    Ca
     
    3
    		[PO
     
    4
    		]
     
    2
    8.AC.45Ferromerrillite
    Ca
     
    9
    		Fe
    2+
     
    		Na[PO
     
    4
    		]
     
    7
    8.AC.50Chladniite
    {Ca}{Na
     
    8
    		}{Ca
     
    4
    		Na
     
    4
    		}{(Mg,Fe
    2+
     
    		)
     
    43
    		}[PO
     
    4
    		]
     
    36
    8.AC.50Fillowite
    {Mn
    2+
     
    		}{Na
     
    8
    		}{Ca
     
    4
    		Na
     
    4
    		}{(Mn
    2+
     
    		,Fe
    2+
     
    		)
     
    43
    		}[PO
     
    4
    		]
     
    36
    8.AC.50Johnsomervilleite
    {Ca}{Na
     
    6
    		[ ]
     
    2
    		}{Ca
     
    6
    		Na
     
    2
    		}{(Fe
    2+
     
    		,Mg,Mn
    2+
     
    		)
     
    43
    		}[PO
     
    4
    		]
     
    36
    8.AC.50Galileiite
    {Fe
    2+
     
    		}{Na
     
    8
    		}{Fe
    2+
    4
    		Na
     
    4
    		}{Fe
    2+
    43
    		}[PO
     
    4
    		]
     
    36
    8.AC.50Stornesite-(Y)
    {(Y, Ca)}{Na
     
    6
    		[ ]
     
    2
    		}{(Ca,Na)
     
    8
    		}{(Mg,Fe
    2+
     
    		)
     
    43
    		}[PO
     
    4
    		]
     
    36
    8.AC.50IMA2006-006
    Na
     
    4
    		Fe
    2+
    7
    		[PO
     
    4
    		]
     
    6
    8.AC.55Harrisonite
    Ca(Fe
    2+
     
    		,Mg)
     
    6
    		[PO
     
    4
    		|SiO
     
    4
    		]
     
    2
    8.AC.60Kosnarite
    KZr
     
    2
    		(PO
     
    4
    		)
     
    3
    8.AC.65Panethite
    (Na,Ca)
     
    2
    		(Mg,Fe
    2+
     
    		)
     
    2
    		[PO
     
    4
    		]
     
    2
    8.AC.70Stanfieldite
    Ca
     
    7
    		Ca
     
    2
    		Mg
     
    9
    		[PO
     
    4
    		]
     
    12
    8.AC.75Ronneburgite
    K
     
    2
    		MnV
     
    4
    		O
     
    12
    8.AC.80Tillmannsite
    (Ag
     
    3
    		Hg)[(VO
     
    4
    		, AsO
     
    4
    		)]
    8.AC.85Filatovite
    K[(Al,Zn)
     
    2
    		(As,Si)
     
    2
    		O
     
    8
    		]
    Related Minerals - Hey's Index Grouping:
    20.8.1Sarkinite
    Mn
    2+
    2
    		[OH|AsO
     
    4
    		]
    20.8.2Eveite
    Mn
    2+
    2
    		[OH|AsO
     
    4
    		]
    20.8.3Arsenoclasite
    Mn
    2+
    5
    		[(OH)
     
    2
    		|AsO
     
    4
    		]
     
    2
    20.8.4Flinkite
    Mn
    2+
    2
    		Mn
    3+
     
    		AsO
     
    4
    		(OH)
     
    4
    20.8.5Jarosewichite
    Mn
     
    3
    		MnAsO
     
    4
    		(OH)
     
    6
    20.8.6Allactite
    Mn
    2+
    7
    		(AsO
     
    4
    		)
     
    2
    		(OH)
     
    8
    20.8.7Krautite
    MnHAsO
     
    4
    		·H
     
    2
    		O
    20.8.8Synadelphite
    Mn
    2+
    9
    		[(OH)
     
    9
    		|As
    3+
     
    		O
     
    3
    		|(As
    5+
     
    		O
     
    4
    		)
     
    2
    		] · 2H
     
    2
    		O
    20.8.9Sterlinghillite
    Mn
     
    3
    		(AsO
     
    4
    		)
     
    2
    		·4H
     
    2
    		O
    20.8.10Geigerite
    Mn
     
    5
    		[HAsO
     
    4
    		|AsO
     
    4
    		]
     
    2
    		 · 10H
     
    2
    		O
    20.8.11Akrochordite
    (Mn
    2+
     
    		,Mg)
     
    5
    		[(OH)
     
    2
    		|AsO
     
    4
    		]
     
    2
    		 · 4H
     
    2
    		O
    20.8.12Manganohörnesite
    (Mn,Mg)
     
    3
    		(AsO
     
    4
    		)
     
    2
    		·8H
     
    2
    		O
    20.8.13Fluckite
    CaMnH
     
    2
    		(AsO
     
    4
    		)
     
    2
    		·2H
     
    2
    		O
    20.8.14Brandtite
    Ca
     
    2
    		(Mn
    2+
     
    		,Mg)[AsO
     
    4
    		]
     
    2
    		 · 2H
     
    2
    		O
    20.8.15Parabrandtite
    Ca
     
    2
    		Mn
    2+
     
    		[AsO
     
    4
    		]
     
    2
    		 · 2H
     
    2
    		O
    20.8.16Wallkilldellite-Mn
    Ca
     
    2
    		Mn
    2+
    3
    		[(OH)
     
    2
    		|AsO
     
    4
    		]
     
    2
    		 · 9H
     
    2
    		O
    20.8.17Berzeliite
    NaCa
     
    2
    		(Mg,Mn
    2+
     
    		)
     
    2
    		[AsO
     
    4
    		]
     
    3
    20.8.19Magnesiochlorophoenicite
    (Mg,Mn)
     
    3
    		Zn
     
    2
    		(AsO
     
    4
    		)(OH,O)
     
    6
    20.8.20Villyaellenite
    (Mn,Ca,Zn)
     
    5
    		(AsO
     
    4
    		)
     
    2
    		[AsO
     
    3
    		(OH)]
     
    2
    		·4H
     
    2
    		O
    20.8.21Hematolite
    (Mn,Mg,Al)
     
    15
    		(AsO
     
    3
    		)(AsO
     
    4
    		)
     
    2
    		(OH)
     
    23
    20.8.22Grischunite
    NaCa
     
    2
    		Mn
    2+
    5
    		Fe
    3+
     
    		[AsO
     
    4
    		]
     
    6
    		 · 2H
     
    2
    		O
    Related Minerals - Dana Grouping):
    38.2.1.1Berzeliite
    NaCa
     
    2
    		(Mg,Mn
    2+
     
    		)
     
    2
    		[AsO
     
    4
    		]
     
    3
    38.2.1.3Palenzonaite
    (Ca,Na)
     
    3
    		CaMn
    2+
    2
    		[VO
     
    4
    		]
     
    3
    38.2.1.4Schäferite
    Ca
     
    2
    		NaMg
     
    2
    		[VO
     
    4
    		]
     
    3

    Other Names for Manganberzeliite

    Synonyms:
    ManganoberzeliiteMn-BerzeliitePyrrharsenite
    German names:
    ManganberzeliitManganoberzeliit
    Spanish names:
    ManganberzeliitaManganoberzeliita
    Varieties:
    PyrrhoarseniteSilicomanganberzeliite

    Other Information

    Other Information:Readily soluble in HNO3 or HCl.
    Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

    References for Manganberzeliite

    Reference List:Igelström (1886) Bulletin de la Société française de Minéralogie: 9: 218 (as Pyrrho-arsenite).

    Högbom (1887) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 9: 397.

    Igelström (1893) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 15: 471 (as Chlorarsenian ?).

    Igelström (1894) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 23: 592 (as Manganberzeliit).

    Mauzelius analysis in: Sjögren (1895) Bull. Geol. Inst. Upsala: 2: 92.

    Goldschmidt, V. (1913) Atlas der Krystallformen. 9 volumes, atlas, and text: vol. 1: 191.

    Doelter, C. (1914) Handbuch der Mineral-chemie (in 4 volumes divided into parts): 3 [1]: 635, 639.

    Hintze, Carl (1922) Handbuch der Mineralogie. Berlin and Leipzig. 6 volumes: 1 [4A]: 214.

    Landergren (1930) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 52: 123.

    Bubeck, W. and Machatschki, F. (1935): The crystal structure of berzeliite. Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 90: 44-50.

    Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 681-683.

    Blix, R. and Wickman, F. E. (1960): The mineral berzeliite. Arkiv Mineral. Geol. 2, 417-424.

    Ito, J. (1968): Synthesis of the berzeliite (Ca2NaMg2As3O12)-manganese berzeliite (Ca2NaMn2As3O12) series (arsenate garnet). American Mineralogist: 53: 316-319.

    Hawthorne, F. C. (1976). Refinement of the crystal structure of berzeliite. Acta Cryst., B32, 1581-1583.

    Anthony, J.W., Bideaux, R.A., Bladh, K.W., and Nichols, M.C. (2000) Handbook of Mineralogy, Volume IV. Arsenates, Phosphates, Vanadates. Mineral Data Publishing, Tucson, AZ, 680pp.: 65.

    Zeitschrift für Kristallographie: 90: 44-50 (berzeliite).

    Internet Links for Manganberzeliite

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  • Look for Manganberzeliite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Manganberzeliite in the Natural History Museum (London) online catalogue
  • Manganberzeliite details from Handbook of Mineralogy (PDF)
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    Localities for Manganberzeliite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Italy
     
    • Aosta Valley
      • Nus
        • Saint-Barthélemy
    		• Barresi, A.A., Kolitsch, U., Ciriotti, M.E., Ambrino, P., Bracco, R., Bonacina, E. (2005): La miniera di manganese di Varenche (Aosta, Italia nord-occidentale): ardennite, arseniopleite, manganberzeliite, pirofanite, sarkinite, thortveitite, nuovo As-Sc-analogo della metavariscite e altre specie. Micro (località), 2/2005, 81-122.
    • Liguria
      • Genova Province
        • Ne
          • Graveglia Valley
    		Redazionale (2005): Sistematica ligure: resoconto 2005. Notiziario di Mineralogia del Ferrania Club, 19 , 3-5.
            • Reppia
    		Bracco, R. & Ciriotti, M.E. (2003): Todorokite e Manganberzeliite dalla Liguria. Micro (UK report), 2003, 3-6
    • Lombardy
      • Sondrio Province
        • Malenco Valley
    Japan
     
    • Honshu Island
      • Tohoku Region
        • Fukushima Prefecture
          • Iwaki
    		Matsubara, S. (1975): Manganberzeliite from Gozaisho mine, Fukushima Prefecture, Japan. Kobutsugaku Zasshi 12, 238-52. (in Japanese); Matsubara, S., Miyawaki, R., Kato, A., Matsuyama, F., Mouri, T. and Suzuki, Y. (2001): Arseniopleite from the Gozaisho mine, Fukushima Prefecture, Japan. Bull. Natn. Sci. Mus., Tokyo, Ser. C, 27, 51-62.
    Namibia
     
    • Otjozondjupa Region
      • Grootfontein District
        • Kombat
    		Mineralogical Record: 22: 421.
    Sweden
     
    • Värmland
      • Filipstad
    		American Mineralogist, 53, pp. 316 (1968); Nysten, P., Holtstam, D. and Jonsson, E. (1999) The Långban minerals. In Långban - The mines,their minerals, geology and explorers (D. Holtstam and J. Langhof, eds.), Swedish Museum of Natural History and Raster Förlag, Stockholm & Chr. Weise Verlag, Munich, pp. 89-183.
        • Nordmark
    		GFF 123, 29
    • Västmanland
      • Hällefors
        • Grythyttan
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 683.
    Switzerland
     
    • Grischun (Grisons; Graubünden)
      • Albula Valley
        • Oberhalbstein (Surses; Sursass)
          • Tinizong (Tinzen)
    USA
     
    • New Jersey
      • Sussex Co.
        • Franklin Mining District
          • Franklin
    		Frondel, C. & Ito, J.: American Mineralogist (1963): 48: 663-664; Dunn, Pete J. (1995): Franklin and Sterling Hill New Jersey: the world’s most magnificent mineral deposits, part 5: 673.
    Venezuela
     
    • Miranda
    Mineral and/or Locality
    Google
     
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