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Macedonite

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Big Photo

Långban, Filipstad, Värmland, Sweden
© Kjell Gatedal

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Formula:
PbTiO
 
3
System:TetragonalColour:Black with weak brownish ...
Lustre:VitreousHardness:5½ - 6
Member of:Perovskite Group
Name:After the type locality at Crni Kamen, Macedonia.


A rare accessory mineral in microcline-quartz syenite pegmatite veins and as inclusions in oxide phases in a metamorphosed Fe-Mn ore body.

Classification of Macedonite

IMA status:Approved
Strunz 8th edition ID:4/C.10-80
Nickel-Strunz 10th (pending) edition ID:4.CC.35

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations
Dana 8th edition ID:4.3.6.1

4 : SIMPLE OXIDES
3 : A2X3
Hey's CIM Ref.:7.11.26

7 : Oxides and Hydroxides
11 : Oxides of Sn and Pb
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Type Occurrence of Macedonite

Type Locality:Crni Kamen, Prilep, Republic of Macedonia
General Appearance of Type Material:tiny crystals to irtregular grains
Place of Conservation of Type Material:Institute for Nuclear Raw Materials, Belgrade Serbia. U.S. National Museum of Natural History, Washington, D.C., USA: #122391.
Year of Discovery:1971
Geological Setting of type material:microcline-quartz syenite pegmatite veins cutting pyroxene amphibole schist.
Associated Minerals at type locality:
ZirconRutileQuartzMicroclineArfvedsonite
Aegirine

Physical Properties of Macedonite

Lustre:Vitreous
Diaphaneity (Transparency):Opaque
Colour:Black with weak brownish tint; brownish yellow with greenish tint in thin section
Hardness (Mohs):5½ - 6
Tenacity:Very brittle
Density (measured):7.82 g/cm3
Density (calculated):8.09 g/cm3

Crystallography of Macedonite

Crystal System:Tetragonal
Class (H-M):4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Space Group:P4/nmm {P4/n 21/m 2/m}
Cell Parameters:a = 3.90(1) Å, c = 4.18(2) Å
Ratio:a:c = 1 : 1.072
Unit Cell Volume:V 63.58 ų (Calculated from Unit Cell)
Z:1
Morphology:Crystals equant to prismatic, exhibiting {100}, {001}, {110}, {101}, and {111}; irregular grains.

Optical Data of Macedonite

Type:Uniaxial
Anisotropism:Very weak.
Colour in reflected light:Gray-white
Internal Reflections:Yellow-brown to dark brownish green
Comments:Sensibly isotropic

Chemical Properties of Macedonite

Formula:
PbTiO
 
3
Essential elements:O, Pb, Ti
All elements listed in formula:O, Pb, Ti

Relationship of Macedonite to other Species

Member of:Perovskite Group
Other Members of Group:

- +
Barioperovskite
BaTiO
 
3
Isolueshite
(Na,La,Ca)(Nb,Ti)O
 
3
Lakargiite
Ca(Zr,Sn,Ti)O
 
3
Loparite-(Ce)
(Na,Ce,Ca,Sr,Th)(Ti,Nb,Fe)O
 
3
Lueshite
NaNbO
 
3
Megawite
CaSnO
 
3
Perovskite
CaTiO
 
3
Tausonite
SrTiO
 
3
Related Minerals - Nickel-Strunz Grouping):

- +
4.CC.05Chrombismite
Bi
 
16
CrO
 
27
4.CC.10Freudenbergite
Na
 
2
(Ti,Fe)
 
8
O
 
16
4.CC.15Grossite
CaAl
 
4
O
 
7
4.CC.20Mayenite
Ca
 
12
Al
 
14
O
 
33
4.CC.25Yafsoanite
Ca
 
3
Zn
 
3
(TeO
 
6
)
 
2
4.CC.30Latrappite
(Ca,Na)(Nb,Ti,Fe)O
 
3
4.CC.30Lueshite
NaNbO
 
3
4.CC.30Natroniobite
NaNbO
 
3
4.CC.30Perovskite
CaTiO
 
3
4.CC.30Barioperovskite
BaTiO
 
3
4.CC.30Lakargiite
Ca(Zr,Sn,Ti)O
 
3
4.CC.30Megawite
CaSnO
 
3
4.CC.35Loparite-(Ce)
(Na,Ce,Ca,Sr,Th)(Ti,Nb,Fe)O
 
3
4.CC.35Tausonite
SrTiO
 
3
4.CC.35Isolueshite
(Na,La,Ca)(Nb,Ti)O
 
3
4.CC.40Crichtonite
(Sr,La,Ce,Y)(Ti,Fe
3+
 
,Mn)
 
21
O
 
38
4.CC.40Davidite-(Ce)
(Ce,La)(Y,U,Fe)(Ti,Fe)
 
20
(O,OH)
 
38
4.CC.40Davidite-(La)
(La,Ce)(Y,U,Fe)(Ti,Fe)
 
20
(O,OH)
 
38
4.CC.40Davidite-(Y)
(Y,La,Ce,Na,Ca,Pb)(Y,Fe
2+
 
,◻)(Fe
2+
 
,Mn
2+
 
)
 
2
(Ti,Fe
3+
 
,Nb,Zr)
 
18
O
 
38
 (hypothetical)
4.CC.40Landauite
NaMnZn
 
2
(Ti,Fe)
 
6
Ti
 
12
O
 
38
4.CC.40Lindsleyite
(Ba,Sr)(Ti,Zr,Fe,Cr)
 
21
O
 
38
4.CC.40Loveringite
(Ca,Ce)(Ti,Fe,Cr,Mg)
 
21
O
 
38
4.CC.40Mathiasite
K(Ti,Cr,Fe,Mg,Zr)
 
21
O
 
38
4.CC.40Senaite
Pb(Ti,Fe,Mn)
 
21
O
 
38
4.CC.40Dessauite-(Y)
(Sr,Pb)(Y,U)(Ti,Fe
3+
 
)
 
20
O
 
38
4.CC.40Cleusonite
(Pb,Sr)(U
4+
 
,U
6+
 
)(Fe
2+
 
,Zn)
 
2
(Ti,Fe
2+
 
,Fe
3+
 
)
 
18
(O,OH)
 
38
4.CC.40Gramaccioliite-(Y)
(Pb,Sr)(Y,Mn)Fe
3+
2
(Ti,Fe
3+
 
)
 
18
O
 
38
4.CC.45Diaoyudaoite
NaAl
 
11
O
 
17
4.CC.45Hawthorneite
Ba(MgTi
 
3
Cr
 
4
Fe
 
4
)O
 
19
4.CC.45Hibonite
(Ca,Ce)Al
 
12
O
 
19
4.CC.45Lindqvistite
Pb
 
2
(Mg,Fe)Fe
 
16
O
 
27
4.CC.45Magnetoplumbite
(Pb,Mn)(Fe,Mn)
 
12
O
 
19
4.CC.45Plumboferrite
Pb
 
2
Fe
3+
11-x
Mn
2+
x
O
 
19-2x
, x = 1/3
4.CC.45Yimengite
K(Cr,Ti,Fe,Mg)
 
12
O
 
19
4.CC.45Haggertyite
Ba[Fe
2+
6
Ti
 
5
Mg]O
 
19
4.CC.45Nežilovite
PbZn
 
2
(Mn
4+
 
,Ti
4+
 
)
 
2
Fe
3+
8
O
 
19
4.CC.45Batiferrite
Ba[Ti
 
2
Fe
3+
8
Fe
2+
2
]O
 
19
4.CC.45IMA2009-027
(Fe,Mg)Al
 
12
O
 
19
4.CC.45Barioferrite
BaFe
3+
12
O
 
19
4.CC.50Jeppeite
(K,Ba)
 
2
(Ti,Fe)
 
6
O
 
13
4.CC.55Zenzénite
Pb
 
3
(Fe,Mn)
 
4
Mn
 
3
O
 
13
4.CC.60Mengxianminite
(Ca,Na)
 
3
(Fe,Mn)
 
2
Mg
 
2
(Sn,Zn)
 
5
Al
 
8
O
 
29
Related Minerals - Hey's Index Grouping:

- +
7.11.1Romarchite
SnO
7.11.2Cassiterite
SnO
 
2
7.11.4Schoenfliesite
Mg[Sn(OH)
 
6
]
7.11.5Burtite
Ca[Sn(OH)
 
6
]
7.11.6Vismirnovite
Zn[Sn(OH)
 
6
]
7.11.7Wickmanite
Mn
2+
 
[Sn(OH)
 
6
]
7.11.8Tetrawickmanite
Mn
2+
 
[Sn
4+
 
(OH)
 
6
]
7.11.9Jeanbandyite
(Fe
2+
 
,Mn
2+
 
)[Sn
4+
 
(OH)
 
6
]
7.11.10Natanite
Fe
2+
 
[Sn(OH)
 
6
]
7.11.11Mushistonite
(Cu,Zn,Fe
2+
 
)[Sn(OH)
 
6
]
7.11.12Ferronigerite-2N1S
Sn(Fe,Mg)Al
 
6
O
 
11
(OH)
7.11.13Magnesionigerite
7.11.14Argutite
GeO
 
2
7.11.15Brunogeierite
Fe
2+
2
Ge
4+
 
O
 
4
7.11.16Stottite
Fe
2+
 
[Ge
4+
 
(OH)
 
6
]
7.11.17Carboirite
FeAl
 
2
(GeO
 
4
)O(OH)
 
2
7.11.18Otjisumeite
PbGe
 
4
O
 
9
7.11.19Bartelkeite
PbFe
2+
 
Ge
 
3
O
 
8
7.11.20Massicot
PbO
7.11.21Litharge
PbO
7.11.22Minium
Pb
 
3
O
 
4
7.11.23Plattnerite
PbO
 
2
7.11.24Scrutinyite
alpha-PbO
 
2
7.11.25Murdochite
PbCu
 
6
O
 
8-x
(Cl,Br)
 
2x
 where x<=0.5
7.11.27Cesàrolite
PbH
 
2
Mn
 
3
O
 
8
7.11.28Coronadite
Pb(Mn
4+
 
,Mn
3+
 
)
 
8
O
 
16
7.11.29Quenselite
PbMnO
 
2
(OH)
7.11.30Plumboferrite
Pb
 
2
Fe
3+
11-x
Mn
2+
x
O
 
19-2x
, x = 1/3
7.11.31Magnetoplumbite
(Pb,Mn)(Fe,Mn)
 
12
O
 
19
7.11.32Senaite
Pb(Ti,Fe,Mn)
 
21
O
 
38

Other Names for Macedonite

Synonyms:
IMA1970-010
Other Languages:
German:Macedonit
Russian:Македонит
Spanish:Macedonita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Macedonite

Reference List:

- +
Radusinović, D. and C. Markov (1971) Macedonite - lead titanate: a new mineral. American Mineralogist (1971): 56: 387-394.

Burke, E.A.J. and C. Kieft (1971) Second occurrence of makedonite [macedonite], PbTiO3, Langban, Sweden. Lithos, 4, 101– 04.

Solid State Communications: 54: 721-723.

Internet Links for Macedonite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Macedonite details from Handbook of Mineralogy (PDF)
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    • Localities for Macedonite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Republic of Macedonia
     
    • Prilep
    		Radusinovi´c, D. and C. Markov (1971) Macedonite - lead titanate: a new mineral. American Mineralogist (1971): 56: 387-394; Nickel & Nichols, 1991 - "Mineral Reference Manual", p123.
    Spain
     
    • Andalusia
      • Almería
        • Cuevas del Almanzora (Cuevas de Vera)
          • Sierra Almagrera
            • Las Herrerías
    		Calvo, M. Minerales y minas de España
    Sweden
     
    • Värmland
      • Filipstad
    		Burke, E.A.J. and C. Kieft (1971) Second occurrence of makedonite [macedonite], PbTiO3, Langban, Sweden. Lithos, 4, 101– 04; Nysten, P., Holtstam, D. and Jonsson, E. (1999) The Långban minerals. In Långban - The mines,their minerals, geology and explorers (D. Holtstam and J. Langhof, eds.), Swedish Museum of Natural History and Raster Förlag, Stockholm & Chr. Weise Verlag, Munich, pp. 89-183. ; Kjell Gatedal
        • Nordmark (Nordmarksberg)
    		MinMag 49, 579; Kjell Gatedal
        • Persberg district
          • Pajsberg
    		Kjell Gatedal photo, polished section
    UK
     
    • England
      • Somerset
        • Cranmore
    		Turner, R.W. and Rumsey, M.S. (2010): Mineral Relationships in the Mendip Hills. Journal of the Russell Society, vol 13, pp 3-46.
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