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Marinellite

Formula:
(Na,K)
 
42
Ca
 
6
[Cl
 
2
|(SO
 
4
)
 
8
|(Al
 
6
Si
 
6
O
 
24
)
 
6
] · 3 H
 
2
O
System:TrigonalColour:colourless
Hardness:
Name:After Professor Giorgio Marinelli (1922-1993), University of Pisa, Italy


Cancrinite Group.

Classification of Marinellite

IMA status:Approved 2002
Strunz 8th edition ID:8/J.09-95
Nickel-Strunz 10th (pending) edition ID:9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
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Type Occurrence of Marinellite

Type Locality:Sacrofano, Campagnano di Roma, Rome Province, Latium, Italy

Physical Properties of Marinellite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent
Colour:colourless
Streak:white
Hardness (Mohs):
Hardness Data:Measured
Cleavage:Poor/Indistinct
on {001}
Fracture:Conchoidal
Density (measured):2.405 g/cm3
Density (calculated):2.4 g/cm3

Crystallography of Marinellite

Crystal System:Trigonal
Class (H-M):3m - Ditrigonal Pyramidal
Space Group:P3 1c
Cell Parameters:a = 12.88Å, c = 31.761Å
Ratio:a:c = 1 : 2.466
Unit Cell Volume:V 4563.1 ų
Z:1
X-Ray Powder Diffraction:
d-spacingIntensity
3.725 (100)
3.513 (80)
4.20 (42)
3.089 (40)
2.150 (40)

Optical Data of Marinellite

Type:Uniaxial (+)
RI values: nω = 1.495 nε = 1.497
Maximum Birefringence:δ = 0.002

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Marinellite

Formula:
(Na,K)
 
42
Ca
 
6
[Cl
 
2
|(SO
 
4
)
 
8
|(Al
 
6
Si
 
6
O
 
24
)
 
6
] · 3 H
 
2
O
Essential elements:
All elements listed in formula:Al, Ca, Cl, H, K, Na, O, S, Si
Analyical Data:electron microprobe analysis, H2O calculated by difference.
K2O (7.94)
Na2O (14.95)
CaO (5.14)
Al2O3 (27.80)
SiO2 (32.73)
SO3 (9.84)
Cl (0.87)
H2O (0.93)

sum 100.20 wt %, less O = Cl 0.20
(total 100.00 wt %)

Empirical Formula:
(Na
 
31.86
K
 
11.13
Ca
 
6.06
)
 
=49.05
(Si
 
35.98
Al
 
36.02
)
 
=72
O
 
144.60
(SO
 
4
)
 
8.12
Cl
 
1.62
· 3.441H
 
2
O

Relationship of Marinellite to other Species

Related to:
  • Cancrinite Group
  • Related Minerals - Nickel-Strunz Grouping):
    9.FB.05Afghanite
    (Na,Ca,K)
     
    8
    [(Cl
     
    2
    ,SO
     
    4
    ,CO
     
    3
    )
     
    3
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ] · 0.5H
     
    2
    O
    9.FB.05Bystrite
    (Na,K)
     
    7
    Ca[(S
     
    3
    )
     
    1.5
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ] · H
     
    2
    O
    9.FB.05Cancrinite
    Na
     
    6
    Ca
     
    2
    [(CO
     
    3
    )
     
    2
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ] · 2H
     
    2
    O
    9.FB.05Cancrisilite
    Na
     
    7
    [CO
     
    3
    |Al
     
    5
    Si
     
    7
    O
     
    24
    ] · 3H
     
    2
    O
    9.FB.05Davyne
    (Na,K)
     
    6
    Ca
     
    2
    [(Cl
     
    2
    ,SO
     
    4
    )
     
    2
    |Al
     
    6
    Si
     
    6
    SO
     
    24
    ]
    9.FB.05Franzinite
    (Na,K)
     
    6
    Ca
     
    2
    [(SO
     
    4
    )
     
    2
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ] · 0.5H
     
    2
    O
    9.FB.05Giuseppettite
    (Na,K,Ca)
     
    7-8
    [(SO
     
    4
    ,Cl)
     
    1-2
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ]
    9.FB.05Hydroxycancrinite
    Na
     
    8
    [(OH)
     
    2
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ] · 2H
     
    2
    O
    9.FB.05Liottite
    (Na,K)
     
    16
    Ca
     
    8
    [Cl
     
    4
    |(SO
     
    4
    )
     
    5
    |(Al
     
    6
    Si
     
    6
    O
     
    24
    )
     
    3
    ]
    9.FB.05Microsommite
    Na
     
    4
    K
     
    2
    Ca
     
    2
    [Cl
     
    2
    |SO
     
    4
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ]
    9.FB.05Pitiglianoite
    Na
     
    6
    K
     
    2
    [SO
     
    4
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ] · 2H
     
    2
    O
    9.FB.05Quadridavyne
    (Na,K)
     
    6
    Ca
     
    2
    [Cl
     
    4
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ]
    9.FB.05Sacrofanite
    (Na,Ca,K)
     
    9
    [{(OH)
     
    2
    ,SO
     
    4
    ,CO
     
    3
    ,Cl
     
    2
    }
     
    3
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ] · 0.5H
     
    2
    O
    9.FB.05Tounkite
    (Na,Ca,K)
     
    8
    [Cl|(SO
     
    4
    )
     
    2
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ] · H
     
    2
    O
    9.FB.05Vishnevite
    (Na,K)
     
    8
    [(SO
     
    4
    ,CO
     
    3
    )|Al
     
    6
    Si
     
    6
    O
     
    24
    ] · 2H
     
    2
    O
    9.FB.05Farneseite
    (Na,Ca,K)
     
    56
    [(SO
     
    4
    )
     
    12
    |Al
     
    42
    Si
     
    42
    O
     
    168
    ] · 6H
     
    2
    O
    9.FB.05Alloriite
    (Na,Ca,K)
     
    26
    Ca
     
    4
    [Cl
     
    6
    |(SO
     
    4
    )
     
    6
    |(Al
     
    6
    Si
     
    6
    O
     
    24
    )
     
    4
    ]
    9.FB.05IMA2008-006
    [Na
     
    82.5
    Ca
     
    33
    K
     
    16.5
    ]
     
    132
    (Si
     
    99
    Al
     
    99
    O
     
    396
    )(SO
     
    4
    )
     
    33
    ·4H
     
    2
    O
    9.FB.10Bicchulite
    Ca
     
    2
    [(OH)
     
    2
    |Al
     
    2
    SiO
     
    6
    ]
    9.FB.10Danalite
    Fe
    2+
    4
    Be
     
    3
    [S|(SiO
     
    4
    )
     
    3
    ]
    9.FB.10Genthelvite
    Zn
     
    4
    Be
     
    3
    [S|(SiO
     
    4
    )
     
    3
    ]
    9.FB.10Haüyne
    (Na,Ca)
     
    4-8
    [Al
     
    6
    Si
     
    6
    (O,S)
     
    24
    ](SO
     
    4
    ,Cl)
     
    1-2
    9.FB.10Helvite
    Mn
    2+
    4
    Be
     
    3
    [S|(SiO
     
    4
    )
     
    3
    ]
    9.FB.10Kamaishilite
    Ca
     
    2
    [(OH)
     
    2
    |Al
     
    2
    SiO
     
    6
    ]
    9.FB.10Lazurite
    (Na,Ca)
     
    8
    [(S,SO
     
    4
    ,Cl
     
    2
    )|Al
     
    6
    Si
     
    6
    O
     
    24
    ]
    9.FB.10Nosean
    Na
     
    8
    [SO
     
    4
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ]
    9.FB.10Sodalite
    Na
     
    8
    [Cl
     
    2
    |Al
     
    6
    Si
     
    6
    O
     
    24
    ]
    9.FB.10Tsaregorodtsevite
    N(CH
     
    3
    )
     
    4
    [AlSi
     
    5
    O
     
    12
    ]
    9.FB.10Tugtupite
    Na
     
    4
    [Cl|BeAlSi
     
    4
    O
     
    12
    ]
    9.FB.10Helvine
    9.FB.15Marialite
    Na
     
    4
    [Cl|(AlSi
     
    3
    O
     
    8
    )
     
    3
    ]
    9.FB.15Meionite
    Ca
     
    4
    [CO
     
    3
    |(Al
     
    2
    Si
     
    2
    O
     
    8
    )
     
    3
    ]
    9.FB.15Silvialite
    (Ca,Na)
     
    4
    [(SO
     
    4
    ,CO
     
    3
    )|(Al
     
    2
    Si
     
    2
    O
     
    8
    )
     
    3
    ]

    Other Names for Marinellite

    Synonyms:
    IMA2002-021
    Russian names:
    Маринеллит

    Other Information

    Fluorescence in UV light:none
    Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

    References for Marinellite

    Reference List:Bonaccorsi, E. & P. Orlandi (2003): Marinellite, a new feldspathoid of the cancrinite-sodalite group.- European Journal of Mineralogy (2003): 15: 1019-1027.

    Internet Links for Marinellite

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  • External Links:
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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Marinellite in the Natural History Museum (London) online catalogue
  • Mineral Dealers:
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  • Rare and Unusual minerals at Mineralogical Research Company
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    Localities for Marinellite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Italy
     
    • Latium
      • Rome Province
        • Campagnano di Roma
    E. Bonaccorsi & P. Orlandi (2003): Marinellite, e new feldspathoid of the cancrinite-sodalite group.- Eur. Journ. Mineral. 15, 1019-1027
    F. Bellatreccia, G. Della Ventura, R. Pucci and L. Mattei, Università Roma Tre
    Mineral and/or Locality
    Google
     
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