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Fluorvesuvianite

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Formula:
Ca
 
19
(Al,Mg,Fe
2+
 
)
 
13
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
O(F,OH)
 
9
Note that the T-positions (compare group formula) are unoccupied. The vacancies have been omitted from the formula.
System:TetragonalColour:colourless to white
Hardness:6
Member of:Vesuvianite Group
Name:For its relation to vesuvianite and the fluoride dominance over hydroxide in its chemical composition.


Fluorine analogue of Vesuvianite.

Classification of Fluorvesuvianite

IMA status:Approved 2000
Strunz 8th edition ID:8/C.26-05
Nickel-Strunz 10th (pending) edition ID:9.BG.35

9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
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Type Occurrence of Fluorvesuvianite

Type Locality:Lupikko Mine, Pitkyaranta (Pitkäranta) District, Ladoga Region, Karelia Republic, Northern Region, Russia
General Appearance of Type Material:fibrous crystals to 1.5 cm
Geological Setting of type material:calcite filled vugs of a diopside-magnetite skarn
Associated Minerals at type locality:
VesuvianiteSphaleriteClinochloreCalcite

Physical Properties of Fluorvesuvianite

Lustre:Vitreous, Silky
Diaphaneity (Transparency):Transparent
Colour:colourless to white
Streak:white
Hardness (Mohs):6
Tenacity:Brittle
Cleavage:None Observed
Density (measured):3.43 g/cm3

Crystallography of Fluorvesuvianite

Crystal System:Tetragonal
Class (H-M):4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Cell Parameters:a = 15.51Å, c = 11.77Å
Ratio:a:c = 1 : 0.759
Unit Cell Volume:V 2,831.39 ų (Calculated from Unit Cell)
Morphology:{100}, {110}, elongated along [001]
X-Ray Powder Diffraction:
d-spacingIntensity
2.74 (90)
2.59 (50)
2.45 (100)

Chemical Properties of Fluorvesuvianite

Formula:
Ca
 
19
(Al,Mg,Fe
2+
 
)
 
13
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
O(F,OH)
 
9


Note that the T-positions (compare group formula) are unoccupied. The vacancies have been omitted from the formula.
Essential elements:Al, Ca, F, O, Si
All elements listed in formula:Al, Ca, F, Fe, H, Mg, O, Si

Relationship of Fluorvesuvianite to other Species

Member of:Vesuvianite Group
Other Members of Group:

- +
Manganvesuvianite
Ca
 
19
Mn
3+
 
(Al,Mn
3+
 
,Fe
3+
 
)
 
10
(Mg,Mn
2+
 
)
 
2
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
O(OH)
 
9
Vesuvianite
(Ca,Na,☐)
 
19
(Al,Mg,Fe
3+
 
)
 
13
(☐,B,Al,Fe
3+
 
)
 
5
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
(OH,F,O)
 
10
Wiluite
Ca
 
19
(Al,Mg)
 
13
(B,☐,Al)
 
5
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
(O,OH)
 
10
Related Minerals - Nickel-Strunz Grouping):

- +
9.BG.Ferriallanite-(La)
{CaLa}{Fe
3+
 
AlFe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bAllanite-(Ce)
{CaCe}{Al
 
2
Fe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bAllanite-(La)
{CaLa}{Al
 
2
Fe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bAllanite-(Y)
{CaY}{Al
 
2
Fe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05aClinozoisite
{Ca
 
2
}{Al
 
3
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bDissakisite-(Ce)
{CaCe}{Al
 
2
Mg}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Dollaseite-(Ce)
{CaCe}{MgAlMg}(Si
 
2
O
 
7
)(SiO
 
4
)(OH)F
9.BG.05aEpidote
{Ca
 
2
}{Al
 
2
Fe
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Epidote-(Pb)
{CaPb}{Al
 
2
Fe
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Khristovite-(Ce)
{CaCe}{MgAlMn
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)(OH)F
9.BG.05Mukhinite
{Ca
 
2
}{Al
 
2
V
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Piemontite
{Ca
 
2
}{Al
 
2
Mn
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Piemontite-(Sr)
{CaSr}{Al
 
2
Mn
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bManganiandrosite-(La)
{LaMn
2+
 
}{Mn
3+
 
AlMn
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Tawmawite
{Ca
 
2
}{(Al,Fe
3+
 
,Cr)
 
3
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Manganipiemontite-(Sr)
{CaSr}{Mn
3+
 
AlMn
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Ferriallanite-(Ce)
{CaCe}{Fe
3+
 
AlFe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Clinozoisite-(Sr)
{CaSr}{Al
 
3
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Manganiandrosite-(Ce)
{(Mn
2+
 
,Ca)(Ce,REE)}{Mn
3+
 
AlMn
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Dissakisite-(La)
{CaLa}{Al
 
2
Mg}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Vanadoandrosite-(Ce)
{Mn
2+
 
Ce}{V
3+
 
AlMn
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Uedaite-(Ce)
{Mn
2+
 
Ce}{Al
 
2
Fe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Epidote-(Sr)
{CaSr}{Al
 
2
Fe
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bÅskagenite-(Nd)
{Mn
2+
 
Nd}{Al
 
2
Fe
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O
 
2
9.BG.10Zoisite
{Ca
 
2
}{Al
 
3
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.15Macfallite
Ca
 
2
(Mn
3+
 
,Al)
 
3
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
3
9.BG.15Sursassite
Mn
2+
2
Al
 
3
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
3
9.BG.20Julgoldite-(Fe2+)
Ca
 
2
(Fe
2+
 
,Mg)(Fe
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
· H
 
2
O
9.BG.20Okhotskite
Ca
 
2
(Mn
2+
 
,Mg)(Mn
3+
 
,Al,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
· H
 
2
O
9.BG.20Pumpellyite-(Fe2+)
Ca
 
2
Fe
2+
 
Al
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
· H
 
2
O
9.BG.20Pumpellyite-(Fe3+)
Ca
 
2
(Fe
3+
 
,Mg,Fe
2+
 
)(Al,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
· H
 
2
O
9.BG.20Pumpellyite-(Mg)
Ca
 
2
MgAl
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
· H
 
2
O
9.BG.20Pumpellyite-(Mn2+)
Ca
 
2
(Mn
2+
 
,Mg)(Al,Mn
3+
 
,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
· H
 
2
O
9.BG.20Shuiskite
Ca
 
2
(Mg,Al)(Cr,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
· 2H
 
2
O
9.BG.20Julgoldite-(Fe3+)
Ca
 
2
(Fe
3+
 
,Mg)(Fe
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
· H
 
2
O
9.BG.20Pumpellyite-(Al)
Ca
 
2
(Al,Fe
2+
 
,Mg)Al
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
· H
 
2
O
9.BG.20Poppiite
Ca
 
2
(V
3+
 
,Fe
3+
 
,Mg)(V
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
· H
 
2
O
9.BG.20Julgoldite-(Mg)
Ca
 
2
(Mg,Fe
2+
 
)(Fe
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
· H
 
2
O
9.BG.25Ganomalite
Pb
 
9
Ca
 
5
Mn(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)O
9.BG.30Rustumite
Ca
 
10
(Si
 
2
O
 
7
)
 
2
(SiO
 
4
)(OH)
 
2
Cl
 
2
9.BG.35Vesuvianite
(Ca,Na,☐)
 
19
(Al,Mg,Fe
3+
 
)
 
13
(☐,B,Al,Fe
3+
 
)
 
5
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
(OH,F,O)
 
10
9.BG.35Wiluite
Ca
 
19
(Al,Mg)
 
13
(B,☐,Al)
 
5
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
(O,OH)
 
10
9.BG.35Manganvesuvianite
Ca
 
19
Mn
3+
 
(Al,Mn
3+
 
,Fe
3+
 
)
 
10
(Mg,Mn
2+
 
)
 
2
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
O(OH)
 
9
9.BG.40Vyuntspakhkite-(Y)
(Y,Yb)
 
4
Al
 
2.5-1.5
(Si,Al)
 
1.5-2.5
(SiO
 
4
)
 
4
O(OH)
 
7
9.BG.45Dellaite
Ca
 
6
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
9.BG.50Gatelite-(Ce)
CaCe
 
3
Al
 
2
(Al,Mg)(Mg,Fe
2+
 
,Al)(Si
 
2
O
 
7
)(SiO
 
4
)
 
3
(O,F)(OH,O)
 
2
9.BG.55Västmanlandite-(Ce)
Ca(Ce,La)
 
3
Al
 
2
Mg
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)
 
3
(OH)
 
2
F

Other Names for Fluorvesuvianite

Other Languages:
German:Fluorvesuvian
Russian:Фторвезувиан

Other Information

Fluorescence in UV light:none
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Fluorvesuvianite

Reference List:

- +
Britvin, S.N., Antonov, A.A., Krivovichev, S.V., Armbruster, T., Burns, P.C., and Chukanov, N.V. (2003) Fluorvesuvianite, Ca19(Al,Mg,Fe 2+)13[SiO4]10[Si2O7]4O(F,OH)9, a new mineral species from Pitkäranta, Karelia, Russia: Description and crystal structure. Canadian Mineralogist: 41: 1371-1380.

Lapis (2004): 29(3):40.

Internet Links for Fluorvesuvianite

Search Engines:
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  • Raman and XRD data at RRUFF project
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  • Localities for Fluorvesuvianite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Northern Region
      • Karelia Republic
        • Ladoga Region
          • Pitkyaranta (Pitkäranta) District
    S. N. Britvin et al.: Can. Mineral. 41:1371-1380 (2003)
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