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Mantienneite

Formula:
KMg
 
2
Al
 
2
Ti[(OH)
 
3
|(PO
 
4
)
 
4
] · 15H
 
2
O
System:OrthorhombicHardness:3


A vacancy-dominant end-member (possible new mineral) is discussed by Sejkora et al. (2006), based on analytical data of Fransolet et al. (1984).

Compare also benyacarite and paulkerrite.

Classification of Mantienneite

IMA status:Approved
Strunz 8th edition ID:7/D.33-10
Nickel-Strunz 10th (pending) edition ID:8.DH.35

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
Dana 8th edition ID:42.11.21.2

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
Hey's CIM Ref.:19.8.23

19 : Phosphates
8 : Phosphates of Al and other metals
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Type Occurrence of Mantienneite

Type Locality:Anloua, Adamaoua plateau, Cameroon
Year of Discovery:1984

Physical Properties of Mantienneite

Hardness (Mohs):3

Crystallography of Mantienneite

Crystal System:Orthorhombic
Cell Parameters:a = 10.4Å, b = 20.33Å, c = 12.31Å
Ratio:a:b:c = 0.512 : 1 : 0.606
Unit Cell Volume:V 2,602.73 ų (Calculated from Unit Cell)

Optical Data of Mantienneite

Type:Biaxial (-)
RI values: nα = 1.564 nγ = 1.598
2V:Measured: 50° to 60°
Maximum Birefringence:δ = 0.034

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r > v strong

Chemical Properties of Mantienneite

Formula:
KMg
 
2
Al
 
2
Ti[(OH)
 
3
|(PO
 
4
)
 
4
] · 15H
 
2
O
Essential elements:Al, H, K, Mg, O, P, Ti
All elements listed in formula:Al, H, K, Mg, O, P, Ti

Relationship of Mantienneite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
8.DH.05Minyulite
KAl
 
2
[(OH,F)|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.10Leucophosphite
KFe
3+
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.10Spheniscidite
(NH
 
4
,K)(Fe
3+
 
,Al)
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.10Tinsleyite
KAl
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.15Jahnsite-(CaMnFe)
CaMn
2+
 
Fe
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(CaMnMg)
CaMn
2+
 
(Mg,Fe
2+
 
)
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(CaMnMn)
CaMn
2+
 
Mn
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Keckite
(Ca,Mg)(Mn
2+
 
,Zn)
 
2
Fe
3+
3
(PO
 
4
)
 
4
(OH)
 
3
 · 2H
 
2
O
8.DH.15Rittmannite
(Mn
2+
 
,Ca)Mn
2+
 
(Fe
2+
 
,Mn
2+
 
,Mg)
 
2
(Al,Fe
3+
 
)
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Whiteite-(CaFeMg)
Ca(Fe
2+
 
,Mn
2+
 
)Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Whiteite-(CaMnMg)
CaMn
2+
 
Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Whiteite-(MnFeMg)
(Mn
2+
 
,Ca)(Fe
2+
 
,Mn
2+
 
)Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(MnMnMn)
Mn
2+
 
Mn
2+
 
Mn
2+
2
Fe
3+
2
(PO
 
4
)
 
4
](OH)
 
2
 · 8H
 
2
O
8.DH.15Kaluginite
(Mn
2+
 
,Ca)MgFe
3+
 
[OH|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.15Jahnsite-(CaFeFe)
CaFeFe
 
2
Fe
 
2
(PO
 
4
)
 
4
(OH)
 
2
·8H
 
2
O
8.DH.15Jahnsite-(NaFeMg)
NaFe
3+
 
Mg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(NaMnMg)
NaMnMg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(CaMgMg)
CaMgMg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.20Manganosegelerite
(Mn
2+
 
,Ca)(Mn
2+
 
,Fe
2+
 
,Mg)Fe
3+
 
(PO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DH.20Overite
CaMgAl[OH|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.20Segelerite
Ca
 
2
 Mg
 
2
 Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.20Wilhelmvierlingite
CaMnFe
3+
 
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.20Juonniite
CaMgSc(PO
 
4
)
 
2
(OH)·4H
 
2
O
8.DH.25Calcioferrite
Ca
 
2
Fe
3+
2
[OH|(PO
 
4
)
 
3
] · 7H
 
2
O
8.DH.25Kingsmountite
Ca
 
4
(Fe
2+
 
,Mn
2+
 
)Al
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
8.DH.25Montgomeryite
Ca
 
4
MgAl
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
8.DH.25Zodacite
Ca
 
4
Mn
2+
 
Fe
3+
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
8.DH.30Arseniosiderite
Ca
 
2
Fe
3+
3
[O
 
2
|(AsO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Kolfanite
Ca
 
2
Fe
3+
2
[O
 
2
|(AsO
 
4
)
 
3
] · 2H
 
2
O
8.DH.30Mitridatite
Ca
 
2
Fe
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Pararobertsite
Ca
 
2
Mn
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Robertsite
Ca
 
3
Mn
3+
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 3H
 
2
O
8.DH.30Sailaufite
Ca
 
2
Mn
3+
3
[O|CO
 
3
|(AsO
 
4
)
 
2
] · 3H
 
2
O
8.DH.35Paulkerrite
K(Mg,Mn
2+
 
)
 
2
(Fe
3+
 
,Al,Ti,Mg)
 
2
Ti(PO
 
4
)
 
4
(OH)
 
3
 · 15H
 
2
O
8.DH.35Benyacarite
(H
 
2
O,K)
 
2
(Mn
2+
 
,Fe
2+
 
)
 
2
(Fe
3+
 
,Ti)
 
2
Ti[(O,F)
 
2
|(PO
 
4
)
 
4
] · 14H
 
2
O
8.DH.40Xanthoxenite
Ca
 
4
Fe
3+
2
[OH|(PO
 
4
)
 
2
]
 
2
 · 3H
 
2
O
8.DH.45Mahnertite
NaCu
 
3
(AsO
 
4
)
 
2
Cl · 5H
 
2
O
8.DH.50Andyrobertsite
KCdCu
 
5
[H
 
2
AsO4|(AsO
 
4
)
 
4
] · 2H
 
2
O
8.DH.50Calcioandyrobertsite
KCaCu
 
5
[H
 
2
AsO
 
4
|(AsO
 
4
)
 
4
] · 2H
 
2
O
8.DH.55Englishite
K
 
3
Na
 
2
Ca
 
10
Al
 
15
[OH|(PO
 
4
)
 
3
]
 
7
 · 26H
 
2
O
8.DH.60Bouazzerite
Bi
 
6
(Mg,Co)
 
11
Fe
3+
14
(AsO
 
4
)
 
18
O
 
12
(OH)
 
4
(H
 
2
O)
 
86
Related Minerals - Hey's Index Grouping:

- +
19.8.1Montebrasite
LiAl[(OH,F)|PO
 
4
]
19.8.2Brazilianite
NaAl
 
3
[(OH)
 
2
|PO
 
4
]
 
2
19.8.3Wardite
NaAl
 
3
[(OH)
 
2
|PO
 
4
]
 
2
 · 2H
 
2
O
19.8.4Tancoite
LiNa
 
2
Al[OH|HPO
 
4
|PO
 
4
]
19.8.5Bertossaite
(Li,Na)
 
2
(Ca,Fe
2+
 
,Mn
2+
 
)Al
 
4
[(OH,F)|PO
 
4
]
 
4
19.8.6Tinsleyite
KAl
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
19.8.7Taranakite
(K,NH
 
4
)Al
 
3
(PO
 
4
)
 
3
OH·9H
 
2
O
19.8.8Francoanellite
K
 
3
Al
 
5
[(HPO
 
4
)
 
3
|PO
 
4
]
 
2
 · 12H
 
2
O
19.8.9Gordonite
MgAl
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
19.8.10Aldermanite
Mg
 
5
Al
 
12
[(OH)
 
11
|(PO
 
4
)
 
4
]
 
2
 · 32H
 
2
O
19.8.11Overite
CaMgAl[OH|(PO
 
4
)
 
2
] · 4H
 
2
O
19.8.12Montgomeryite
Ca
 
4
MgAl
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
19.8.14Foggite
CaAl[(OH)
 
2
|PO
 
4
] · H
 
2
O
19.8.15Gatumbaite
CaAl
 
2
[OH|PO
 
4
]
 
2
 · H
 
2
O
19.8.16Crandallite
CaAl
 
3
[(OH)
 
5
|(PO
 
4
)
 
2
] · H
 
2
O
19.8.17Matulaite
CaAl
 
18
[(OH)
 
5
|(PO
 
4
)
 
3
]
 
4
 · 28H
 
2
O
19.8.19Lehiite
19.8.20Millisite
(Na,K)CaAl
 
6
[(OH)
 
9
|(PO
 
4
)
 
4
] · 3H
 
2
O
19.8.21Englishite
K
 
3
Na
 
2
Ca
 
10
Al
 
15
[OH|(PO
 
4
)
 
3
]
 
7
 · 26H
 
2
O
19.8.22Kleemanite
ZnAl
 
2
[OH|PO
 
4
]
 
2
 · 3H
 
2
O
19.8.24Paulkerrite
K(Mg,Mn
2+
 
)
 
2
(Fe
3+
 
,Al,Ti,Mg)
 
2
Ti(PO
 
4
)
 
4
(OH)
 
3
 · 15H
 
2
O

Other Names for Mantienneite

Synonyms:
IMA1983-048
Other Languages:
German:Mantienneit
Russian:Мантьеннеит
Spanish:Mantienneita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Mantienneite

Reference List:Bulletin de la Société française de Minéralogie et de Cristallographie (1984): 107: 737-744.

American Mineralogist (1985): 70: 1330.

Canadian Mineralogist (1997): 35: 707-712.

Sejkora, J., Škoda, R., Ondruš, P., Beran, P. & Susser, C. (2006): Mineralogy of phosphate accumulations in the Huber stock, Krásno ore district, Slavkovský les area, Czech Republic. Journal of the Czech Geological Society 51, 103-147.

Articles/Blogs about Mantienneite

Internet Links for Mantienneite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Mantienneite in the Natural History Museum (London) online catalogue
  • Mantienneite details from Handbook of Mineralogy (PDF)
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    Localities for Mantienneite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Cameroon
     
    • Adamaoua plateau
    		FRANSOLET, A.-M., OUSTRIERE, P., FONTAN, F. & PILLARD, F. (1984) La mantiennéite, une nouvelle espèce minérale du gisement de vivianite d'Anloua, Cameroun. Bulletin de Minéralogie 107, 737-744.
    Germany
     
    • Bavaria
      • Upper Palatinate
        • Oberpfälzer Wald
          • Vohenstrauß
            • Waidhaus
    		Wittern: "Mineralfundorte in Deutschland", 2001
    Slovakia
     
    • Banská Bystrica Region
      • Cérová Mts
    		Vavrová J., Biroň A., Galko I. 2006: Mantienneite - a new phosphate mineral from alginite deposit (Pinciná, Slovakia). Mineralogia Polonica, vol. 28, 232-234
    Mineral and/or Locality
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