Maricopaite
A valid IMA mineral species
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About Maricopaite
Formula:
Pb7Ca2(Si,Al)48O100 · 32H2O
Colour:
White, colorless
Lustre:
Vitreous, Silky
Hardness:
1 - 1½
Specific Gravity:
2.94
Crystal System:
Orthorhombic
Member of:
Name:
Named after Maricopa County, Arizona, USA, which includes the type locality.
Chemically similar to wickenburgite and 'UM1985-25-SiO:AlCaMgPb'.
The only currently known natural zeolite representative with lead as an essential cation.
The only currently known natural zeolite representative with lead as an essential cation.
Unique Identifiers
Mindat ID:
2577
Long-form identifier:
mindat:1:1:2577:1
GUID
(UUID V4):
(UUID V4):
88ad807c-f303-4628-89d8-1728ceef993d
IMA Classification of Maricopaite
Approved
IMA Formula:
Ca2Pb7(Si36Al12)O99 · n(H2O,OH)
First published:
1988
Classification of Maricopaite
9.GD.35
9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
D : Chains of 6-membered rings – tabular zeolites
9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
D : Chains of 6-membered rings – tabular zeolites
77.1.6.3
77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
16.14.15
16 : Silicates Containing Aluminum and other Metals
14 : Aluminosilicates of Ti, Zr, Sn and Pb
16 : Silicates Containing Aluminum and other Metals
14 : Aluminosilicates of Ti, Zr, Sn and Pb
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Mrp | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Maricopaite
Vitreous, Silky
Transparency:
Transparent, Translucent
Colour:
White, colorless
Streak:
White
Hardness:
1 - 1½ on Mohs scale
Tenacity:
Very brittle
Cleavage:
Imperfect/Fair
{010} imperfect.
{010} imperfect.
Density:
2.94 g/cm3 (Measured) 2.90 g/cm3 (Calculated)
Comment:
Measured with heavy liquids.
Optical Data of Maricopaite
Type:
Biaxial (-)
RI values:
nα = 1.563(3) nβ = 1.582(3) nγ = 1.592
2V:
Measured: 70° (10), Calculated: 70°
Max Birefringence:
δ = 0.029
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r > v strong
Optical Extinction:
X = a; Y = c; Z = b.
Comments:
γ calculated.
Chemistry of Maricopaite
Mindat Formula:
Pb7Ca2(Si,Al)48O100 · 32H2O
Crystallography of Maricopaite
Crystal System:
Orthorhombic
Cell Parameters:
a = 19.434(2) Å, b = 19.702(2) Å, c = 7.538(1) Å
Ratio:
a:b:c = 0.986 : 1 : 0.383
Unit Cell V:
2,886.21 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Thin bundles of crystals elongated along [001]; in radial sprays, to 1 mm.
Comment:
Point Group: 2/m 2/m 2/m; mm2; or 222:; Space Group: Cmmm; Cm2m; Cmm2; or C222
Crystal Structure
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2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0001636 | Maricopaite | Rouse R C, Peacor D R (1994) Maricopaite, an unusual lead calcium zeolite with an interrupted mordenite-like framework and intrachannel Pb4 tetrahedral clusters American Mineralogist 79 175-184 | 1994 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
13.7 Å | (100) |
3.216 Å | (50) |
9.86 Å | (40) |
3.357 Å | (40) |
2.978 Å | (40) |
2.845 Å | (40) |
4.35 Å | (30) |
Comments:
Moon Anchor Mine, Arizona, USA. The data are from the type description.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-𝑇 alteration and/or metamorphism | |
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits | |
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] |
Type Occurrence of Maricopaite
General Appearance of Type Material:
Sprays of translucent white, acicular crystals. Thin bundles of extremely elongate acicular crystals, frequently as mats with admixed mimetite. Radial sprays up to 1.0 mm in diameter.
Place of Conservation of Type Material:
National Museum of Natural History (Smithsonian Institution), Washington, D.C., USA, numbers NMNH 163248 and 163247.
Geological Setting of Type Material:
Au-Pb-Ag mineralization in a vein deposit with pod-like ore bodies. Host rock is gneiss and schist. The type material came from the hanging wall of the vein which consists of calcite-fluorite gangue with many square voids thought to be from former galena.
Associated Minerals at Type Locality:
Reference:
Peacor, D.R., Dunn, P.J., Simmons, W.B., Wicks, F.J., Raudsepp, M. (1988) Maricopaite, a new hydrated Ca-Pb, zeolite-like silicate from Arizona. The Canadian Mineralogist: 26: 309-313.
Other Language Names for Maricopaite
Relationship of Maricopaite to other Species
Member of:
Other Members of this group:
Alflarsenite | NaCa2Be3Si4O13(OH) · 2H2O | Mon. 2 : P21 |
Amicite | K2Na2Al4Si4O16 · 5H2O | Mon. 2 |
Ammonioleucite | (NH4)(AlSi2O6) | Tet. 4/m : I41/a |
Analcime | Na(AlSi2O6) · H2O | Tric. 1 : P1 |
Bellbergite | (K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2O | Hex. |
Bikitaite | LiAlSi2O6 · H2O | Tric. 1 : P1 |
Boggsite | Ca8Na3(Si,Al)96O192 · 70H2O | Orth. mmm (2/m 2/m 2/m) : Imma |
Brewsterite Subgroup | Zeolite Group. | |
Chabazite-Levyne Subgroup | M[Al2Si4O12] · 6H2O | |
Chiavennite | CaMnBe2Si5O13(OH)2 · 2H2O | Mon. 2/m : P21/b |
Clinoptilolite Subgroup | M3-6(Si30Al6)O72 · 20H2O | |
Cowlesite | CaAl2Si3O10 · 6H2O | Orth. mmm (2/m 2/m 2/m) |
Dachiardite Subgroup | Zeolite Group. | |
Direnzoite | NaK6MgCa2(Al13Si47O120) · 36H2O | Orth. mmm (2/m 2/m 2/m) : Pmmn |
Edingtonite | Ba[Al2Si3O10] · 4H2O | Orth. 2 2 2 : P21 21 21 |
Epistilbite | CaAl2Si6O16 · 5H2O | Mon. |
Erionite Subgroup | M2[Al4Si14O36] · 15H2O | |
Faujasite Subgroup | M3.5[Al7Si17O48] · 32H2O | |
Ferrierite Subgroup | Zeolite Group. | |
Ferrochiavennite | Ca1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2O | Mon. 2/m : P21/b |
Flörkeite | (K3Ca2Na)[Al8Si8O32] · 12H2O | Tric. 1 : P1 |
Garronite Subgroup | ||
Gaultite | Na4Zn2Si7O18 · 5H2O | Orth. mm2 : Fdd2 |
Gismondine Subgroup | Zeolite Group. | |
Gmelinite Subgroup | In 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K. | |
Gobbinsite | Na5(Si11Al5)O32 · 11H2O | Orth. mmm (2/m 2/m 2/m) : Pnma |
Goosecreekite | Ca[Al2Si6O16] · 5H2O | Mon. 2 : P21 |
Gottardiite | Na3Mg3Ca5Al19Si117O272 · 93H2O | Orth. mmm (2/m 2/m 2/m) : Cmca |
Heulandite Subgroup | (Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O | |
Hsianghualite | Ca3Li2(Be3Si3O12)F2 | Iso. 4 3 2 : I41 3 2 |
Kirchhoffite | Cs(BSi2O6) | Tet. 4/mmm (4/m 2/m 2/m) : I41/acd |
Laumontite | CaAl2Si4O12 · 4H2O | Mon. 2/m : B2/m |
Loomisite | Ba[Be2P2O8] · H2O | Mon. m |
Lovdarite | K2Na6Be4Si14O36 · 9H2O | Orth. mm2 |
Martinandresite | Ba2(Al4Si12O32) · 10H2O | Orth. mmm (2/m 2/m 2/m) : Pmmn |
Mazzite Subgroup | Zeolite Group. | |
Merlinoite | (K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O | Orth. mmm (2/m 2/m 2/m) : Immm |
Montesommaite | (K,Na)9Al9Si23O64 · 10H2O | Orth. mm2 : Fdd2 |
Mordenite | (Na2,Ca,K2)4(Al8Si40)O96 · 28H2O | Orth. |
Mutinaite | Na3Ca4Si85Al11O192 · 60H2O | Orth. mmm (2/m 2/m 2/m) : Pnma |
Nabesite | Na2BeSi4O10 · 4H2O | Orth. 2 2 2 : P21 21 21 |
Natrolite Subgroup | A subgroup of the Zeolite Group. | |
Offretite | KCaMg(Si13Al5)O36 · 15H2O | Hex. 6 m2 : P6m2 |
Pahasapaite | Li8(Ca,Li,K)10.5Be24(PO4)24 · 38H2O | Iso. 2 3 : I2 3 |
Parthéite | Ca2(Si4Al4) O15 (OH)2 · 4H2O | Mon. 2/m : B2/b |
Paulingite Subgroup | Paulingite was originally described in 1960. | |
Perlialite | K9Na(Ca,Sr)[Al2Si4O12]6 · 15H2O | Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm |
Phillipsite Subgroup | Zeolite Group. | |
Pollucite | (Cs,Na)2(Al2Si4O12) · 2H2O | Iso. m3m (4/m 3 2/m) : Ia3d |
Roggianite | Ca2Be(OH)2Al2Si4O13 · 2.5H2O | Tet. 4/mmm (4/m 2/m 2/m) : I4/mcm |
Stilbite Subgroup | M6-7[Al8-9Si27-28O72] · nH2O | |
Terranovaite | (Na,Ca)8(Si68Al12)O160 · 29H2O | Orth. |
Thomsonite Subgroup | The large majority of "thomsonite" is thomsonite-Ca. | |
Tschernichite | (Ca,Na2)[Al2Si4O12] · 4-8H2O | Tet. 4/mmm (4/m 2/m 2/m) : P4/mmm |
Tschörtnerite | Ca4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2O | Iso. m3m (4/m 3 2/m) : Fm3m |
UM1996-38-SiO:AlCaHNa | Na-Ca-Al-Si-O-H | |
UM1999-33-SiO:AlHKNa | K7Na5Al12Si20O64 · 24H2O | |
UM2002-40-SiO:AlCaHKMgNa | (Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2O | Tet. 4 2 2 : P41 2 2 |
Unnamed (Ca analogue of Merlinoite) | (Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ? | |
Wairakite | Ca(Al2Si4O12) · 2H2O | Mon. 2/m : B2/m |
Weinebeneite | CaBe3(PO4)2(OH)2 · 4H2O | Mon. m : Bb |
Wenkite | (Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2O | Hex. 6 m2 : P62m |
Willhendersonite | KCa[Al3Si3O12] · 5H2O | Tric. 1 : P1 |
Yugawaralite | CaAl2Si6O16 · 4H2O | Mon. m : Pb |
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
9.GD.05 | Gmelinite-Ca | Ca2(Si8Al4O24] · 11H2O |
9.GD.05 | Gmelinite-K | K4(Si8Al4O24) · 11H2O |
9.GD.05 | Gmelinite-Na | Na4(Si8Al4O24] · 11H2O |
9.GD.10 | Willhendersonite | KCa[Al3Si3O12] · 5H2O |
9.GD.10 | Chabazite-Ca | (Ca,K2,Na2)2[Al2Si4O12]2 · 12H2O |
9.GD.10 | Chabazite-K | (K2,Ca,Na2,Sr,Mg)2[Al2Si4O12]2 · 12H2O |
9.GD.10 | Chabazite-Na | (Na2,K2,Ca,Sr,Mg)2[Al2Si4O12]2 · 12H2O |
9.GD.10 | Chabazite-Sr | Sr2[Al2Si4O12]2 · 12H2O |
9.GD.10 | Chabazite-Mg | (Mg0.7K0.5Ca0.5Na0.1)[Al3Si9O24] · 10H2O |
9.GD.15 | Lévyne-Ca | (Ca,Na2,K2)[Al2Si4O12] · 6H2O |
9.GD.15 | Lévyne-Na | (Na2,Ca,K2)[Al2Si4O12] · 6H2O |
9.GD.20 | Bellbergite | (K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2O |
9.GD.20 | Erionite-Ca | (Ca,K2,Na2)2[Al4Si14O36] · 15H2O |
9.GD.20 | Erionite-K | (K2,Ca,Na2)2[Al4Si14O36] · 15H2O |
9.GD.20 | Erionite-Na | (Na2,K2,Ca)2[Al4Si14O36] · 15H2O |
9.GD.25 | Offretite | KCaMg(Si13Al5)O36 · 15H2O |
9.GD.25 | Wenkite | (Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2O |
9.GD.30 | Faujasite-Ca | (Ca,Na2,Mg)3.5[Al7Si17O48] · 32H2O |
9.GD.30 | Faujasite-Mg | (Mg,Na2,Ca)3.5[Al7Si17O48] · 32H2O |
9.GD.30 | Faujasite-Na | (Na2,Ca,Mg)3.5[Al7Si17O48] · 32H2O |
9.GD.35 | Mordenite | (Na2,Ca,K2)4(Al8Si40)O96 · 28H2O |
9.GD.40 | Dachiardite-K | K4(Si20Al4O48) · 13H2O |
9.GD.40 | Dachiardite-Ca | (Ca,Na2,K2)5Al10Si38O96 · 25H2O |
9.GD.40 | Dachiardite-Na | (Na2,Ca,K2)5Al10Si38O96 · 25H2O |
9.GD.45 | Epistilbite | CaAl2Si6O16 · 5H2O |
9.GD.50 | Ferrierite-K | (K,Na)5(Si31Al5)O72 · 18H2O |
9.GD.50 | Ferrierite-Mg | [Mg2(K,Na)2Ca0.5](Si29Al7)O72 · 18H2O |
9.GD.50 | Ferrierite-Na | (Na,K)5(Si31Al5)O72 · 18H2O |
9.GD.50 | Ferrierite-NH4 | (NH4,Mg0.5)5(Al5Si31O72) · 22H2O |
9.GD.55 | Bikitaite | LiAlSi2O6 · H2O |
Fluorescence of Maricopaite
None observed.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Maricopaite
mindat.org URL:
https://www.mindat.org/min-2577.html
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References for Maricopaite
Reference List:
Rouse, Roland C., Peacor, Donald R. (1994) Maricopaite, an unusual lead calcium zeolite with an interrupted mordenite-like framework and intrachannel Pb4, tetrahedral clusters. American Mineralogist, 79 (1-2) 175-184
Coombs, Douglas S., Alberti, Alberto, Armbruster, Thomas, Artioli, Gilberto, Colella, Carmine, Galli, Ermanno, Grice, Joel D., Liebau, Friedrich, Mandarino, Joseph A., Minato, Hideo, Nickel, Ernest H., Passaglia, Elio, Peacor, Donald R., Quartieri, Simona, Rinaldi, Romano, Ross, Malcolm I., Sheppard, Richard A., Tillmanns, Ekkehart, Vezzalini, Giovanna (1997) Recommended nomenclature for zeolite minerals; report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. The Canadian Mineralogist, 35 (6) 1571-1606
Localities for Maricopaite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
USA (TL) | |
| Peacor et al. (1988) +1 other reference |
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Moon Anchor Mine, Hummingbird Springs, Osborn Mining District, Maricopa County, Arizona, USA