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Masuyite

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Shinkolobwe Mine (Kasolo Mine), Shinkolobwe, Central area, Katanga Copper Crescent, Katanga (Shaba), Democratic Republic of Congo (Zaïre)
© Richard De Nul

Show Masuyite Photos (5)
Formula:
Pb(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 3H
 
2
O
System:Orthorhombic


Might actually represent two different species (cf. Deliens & Piret, 1996).
The crystal structure of masuyite with the formula Pb[(UO2)3O3(OH)2](H2O)3 was determined by Burns & Hanchar (1999).

Classification of Masuyite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:4/H.03-50
Nickel-Strunz 10th (pending) edition ID:4.GB.35

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
G : Uranyl Hydroxides
B : With additional cations (K, Ca, Ba, Pb, etc.); with mainly UO2(O,OH)5 pentagonal polyhedra
Dana 8th edition ID:5.2.2.1

5 : OXIDES CONTAINING URANIUM OR THORIUM
2 : AXO3·xH2O
Hey's CIM Ref.:7.16.27

7 : Oxides and Hydroxides
16 : Oxides of U
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Type Occurrence of Masuyite

Type Locality:Shinkolobwe Mine (Kasolo Mine), Shinkolobwe, Central area, Katanga Copper Crescent, Katanga (Shaba), Democratic Republic of Congo (Zaïre)
Year of Discovery:1947

Crystallography of Masuyite

Crystal System:Orthorhombic
Cell Parameters:a = 13.98Å, b = 12.11Å, c = 14.2Å
Ratio:a:b:c = 1.154 : 1 : 1.173
Unit Cell Volume:V 2,404.03 ų (Calculated from Unit Cell)

Optical Data of Masuyite

Type:Biaxial (-)
RI values: nα = 1.785 nβ = 1.895 nγ = 1.915
2V:Measured: 50° , Calculated: 44°
Maximum Birefringence:δ = 0.130

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:extreme

Chemical Properties of Masuyite

Formula:
Pb(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 3H
 
2
O
Essential elements:H, O, Pb, U
All elements listed in formula:H, O, Pb, U

Relationship of Masuyite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
4.GB.05Agrinierite
K
 
2
(Ca,Sr)(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 5H
 
2
O
4.GB.05Compreignacite
K
 
2
(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 7H
 
2
O
4.GB.05Rameauite
K
 
2
Ca(UO
 
2
)
 
6
(OH)
 
16
 · H
 
2
O
4.GB.10Becquerelite
Ca(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 8H
 
2
O
4.GB.10Billietite
Ba(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 4-8H
 
2
O
4.GB.10Protasite
Ba(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 3H
 
2
O
4.GB.15Richetite
PbU
 
4
O
 
13
·4H
 
2
O
4.GB.20Bauranoite
Ba(UO
 
2
)
 
2
(OH)
 
6
 · 1-2H
 
2
O
4.GB.20Calciouranoite
(Ca,Ba,Pb)U
 
2
O
 
7
·5H
 
2
O
4.GB.20Metacalciouranoite
(Ca,Ba,Pb,K
 
2
)U
 
2
O
 
7
·2H
 
2
O
4.GB.25Fourmarierite
PbU
 
4
O
 
13
·4H
 
2
O
4.GB.30Wölsendorfite
(Pb,Ca)U
 
2
O
 
7
·2H
 
2
O
4.GB.40Metavandendriesscheite
PbU
 
7
O
 
22
·nH
 
2
O n < 12
4.GB.40Vandendriesscheite
PbU
 
7
O
 
22
·12H
 
2
O
4.GB.45Vandenbrandeite
Cu(UO
 
2
)(OH)
 
4
4.GB.50Sayrite
Pb
 
2
(UO
 
2
)
 
5
O
 
6
(OH)
 
2
·4H
 
2
O
4.GB.55Curite
Pb
 
3+x
(H
 
2
O)
 
2
[(UO
 
2
)
 
4
O
 
4+x
(OH)
 
3-x
]
 
2
4.GB.60Iriginite
UO
 
2
Mo
 
2
O
 
7
·3H
 
2
O
4.GB.65Uranosphaerite
Bi(UO
 
2
)O
 
2
(OH)
4.GB.70Holfertite
Ca
 
x
U
6+
2-x
Ti(O
 
8-x
OH
 
4x
) · 3H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
7.16.1Uraninite
UO
 
2
7.16.2Schoepite
(UO
 
2
)
 
8
O
 
2
(OH)
 
12
 · 12H
 
2
O
7.16.3Paraschoepite
UO
 
3
 · 2H
 
2
O
7.16.4Metaschoepite
UO
 
3
 · 1-2H
 
2
O
7.16.5Metastudtite
UO
 
4
 · 2H
 
2
O
7.16.6Studtite
[(UO
 
2
)(O
 
2
)(H
 
2
O)
 
2
]·H
 
2
O
7.16.7Ianthinite
U
4+
 
(UO
 
2
)
 
5
O
 
7
 · 10H
 
2
O
7.16.8Compreignacite
K
 
2
(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 7H
 
2
O
7.16.9Vandenbrandeite
Cu(UO
 
2
)(OH)
 
4
7.16.10Roubaultite
Cu
 
2
(UO
 
2
)
 
3
(OH)
 
10
 · 5H
 
2
O
7.16.11Becquerelite
Ca(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 8H
 
2
O
7.16.12Rameauite
K
 
2
Ca(UO
 
2
)
 
6
(OH)
 
16
 · H
 
2
O
7.16.13Agrinierite
K
 
2
(Ca,Sr)(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 5H
 
2
O
7.16.14Protasite
Ba(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 3H
 
2
O
7.16.15Billietite
Ba(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 4-8H
 
2
O
7.16.16Bauranoite
Ba(UO
 
2
)
 
2
(OH)
 
6
 · 1-2H
 
2
O
7.16.17Metacalciouranoite
(Ca,Ba,Pb,K
 
2
)U
 
2
O
 
7
·2H
 
2
O
7.16.18Calciouranoite
(Ca,Ba,Pb)U
 
2
O
 
7
·5H
 
2
O
7.16.19Orthobrannerite
U
4+
 
U
6+
 
Ti
 
4
O
 
12
(OH)
 
2
7.16.20Thorutite
(Th,U,Ca)Ti
 
2
(O,OH)
 
6
7.16.21Davidite-(La)
(La,Ce)(Y,U,Fe)(Ti,Fe)
 
20
(O,OH)
 
38
7.16.22Davidite-(Ce)
(Ce,La)(Y,U,Fe)(Ti,Fe)
 
20
(O,OH)
 
38
7.16.23Brannerite
(U
4+
 
,Ca)(Ti,Fe
3+
 
)
 
2
O
 
6
7.16.24Fourmarierite
PbU
 
4
O
 
13
·4H
 
2
O
7.16.25Richetite
PbU
 
4
O
 
13
·4H
 
2
O
7.16.26Curite
Pb
 
3+x
(H
 
2
O)
 
2
[(UO
 
2
)
 
4
O
 
4+x
(OH)
 
3-x
]
 
2
7.16.28Vandendriesscheite
PbU
 
7
O
 
22
·12H
 
2
O
7.16.29Metavandendriesscheite
PbU
 
7
O
 
22
·nH
 
2
O n < 12
7.16.30Sayrite
Pb
 
2
(UO
 
2
)
 
5
O
 
6
(OH)
 
2
·4H
 
2
O
7.16.31Wölsendorfite
(Pb,Ca)U
 
2
O
 
7
·2H
 
2
O
7.16.32Clarkeite
(Na,Ca,Pb)
 
2
U
 
2
(O,OH)
 
7
7.16.33Uranosphaerite
Bi(UO
 
2
)O
 
2
(OH)

Other Names for Masuyite

Other Languages:
German:Masuyit
Russian:Масюйит
Spanish:Masuyita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Masuyite

Reference List:American Mineralogist (1948): 33: 384.

Michel Deliens and Paul Piret (1996): Les masuyites de Shinkolobwe constituent un groupe formé par deux variétés distinctes par leur composition chimique et leurs propriétés radiocristallographiques. Bulletin de l'Institut Royal des Sciences Naturelles de Belgique, 66, 187-192 (In French).

Burns, P.C. and Hanchar, J.M. (1999) The structure of masuyite, Pb[(UO2)3O3(OH)2](H2O)3, and its relationship to protasite. Canadian Mineralogist: 37: 1483-1491.

Burns, P.C. (2005) U 6+ minerals and inorganic compounds: insights into an expanded structural hierarchy of crystal structures. Canadian Mineralogist: 43: 1839-1894.

Internet Links for Masuyite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Masuyite in the Natural History Museum (London) online catalogue
  • Masuyite details from Handbook of Mineralogy (PDF)
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    Localities for Masuyite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • Northern Territory
      • South Alligator Valley Mineral Field
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Central Bohemia Region
    		Pauliš P., Kopecký S., Černý P. 2007: Uranové minerály České Republiky a jejich naleziště. 1. část. (Kutna Hora, issue 1)
      • Karlovy Vary Region
        • Krušné Hory Mts (Erzgebirge)
          • Ostrov
    		Lapis 2002(7/8), 63-65
      • Liberec Region
        • Harrachov (Harrachsdorf)
    		Pauliš P., Kopecký S., Černý P. 2007: Uranové minerály České Republiky a jejich naleziště. 1. část. (Kutna Hora, issue 1)
    • Moravia (Mähren; Maehren)
      • Olomouc Region
        • Javorník
          • Horní Hostice
    		Pauliš, P., Novák, F., Ševců, J.: Sekundární minerály z uranového ložiska Jelení vrch u Horních Hoštic v Rychlebských horách. Acta Musei Moraviae, Scientiae geologicae, 2004, roč. 89, s. 121 - 138.
    Democratic Republic of Congo (Zaïre)
     
    • Katanga (Shaba)
      • Katanga Copper Crescent
        • Central area
          • Shinkolobwe
    		[AmMin 85:1565]
        • Western area
          • Kolwezi
            • Kamoto
    No reference listed
    France
     
    • Auvergne
      • Puy-de-Dôme
        • Puy-Guillaume
          • Lachaux
    		P.-C. Guiollard (2002), L'uranium du Morvan et du Forez, Ed. P.-C. Guiollard, Fichous(64), 95 pp.
    • Languedoc-Roussillon
      • Hérault
        • Lodève
    		Le Règne Minéral, Hors Série IV (1998)
    [Le Cahier des Micromonteurs, 1998, 2, p.13-26]
    [Le Règne Minéral 1997, 13, p.5-18]
    India
     
    • Rajasthan (Rajputana)
      • Ajmer Division
        • Bhilwara District
    		Current Science, 92, 5, 592-4, 2007
    Italy
     
    • Trentino-Alto Adige
      • Trento Province
        • Condino
    		Campostrini, I., Demartin, F., & Gramaccioli, C. M. (2006). Rio Giulis. Minerali secondari del giacimento uranifero presso Condino, Trento. Rivista Mineralogica Italiana, 30(3), 152-165.
        • Daone
          • Limes
    		Campostrini, I., Demartin, F., Gramaccioli, C.M. (2005): Val Daone. Minerali secondari del giacimento uranifero presso Limes, Daone (TN). Rivista Mineralogica Italiana, 4/2005, 228-240.
    Switzerland
     
    • Wallis (Valais)
      • Le Trient Valley
        • Les Marécottes
    		Stalder, H. A., Wagner, A., Graeser, S. und Stuker, P. (1998): Mineralienlexikon der Schweiz. Wepf Verlag, Basel, 579 pp.
    Stalder, H. A., Wagner, A., Graeser, S. and Stuker, P. (1998): "Mineralienlexikon der Schweiz", Wepf (Basel), p. 269.
    Zambia
     
    • North-Western Province
      • Solwezi
    		American Mineralogist: 59: 1139
    Mineral and/or Locality
    Google
     
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    Copyright © Jolyon Ralph and Ida Chau 1993-2009. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 8th Oct 2009 09:27:47