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Ferriwhittakerite

Formula:
Na(Na
 
1.0-1.5
Li
 
0.5-1.0
)
 
2
(Fe
3+
2
Mg
 
2
Li)Si
 
8
O
 
22
(OH)
 
2
System:MonoclinicColour:Bluish black
This page provides mineralogical data about Ferriwhittakerite.

Classification of Ferriwhittakerite

IMA status:Approved 2001
Nickel-Strunz 10th (pending) edition ID:9.DE.15

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles
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Physical Properties of Ferriwhittakerite

Lustre:Vitreous
Diaphaneity (Transparency):Translucent
Colour:Bluish black

Crystallography of Ferriwhittakerite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m {B1 1 2/m} {C2/m} {C1 2/m 1}
Cell Parameters:a = 9.712Å, b = 17.851Å, c = 5.297Å
β = 103.63°
Ratio:a:b:c = 0.544 : 1 : 0.297
Unit Cell Volume:V 892.47 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
d-spacingIntensity
3.392(33)
3.098(37)
2.701(100)
2.576(14)
2.524(100)
2.157(20)
1.646(20)
Comments:From Type Description.

Chemical Properties of Ferriwhittakerite

Formula:
Na(Na
 
1.0-1.5
Li
 
0.5-1.0
)
 
2
(Fe
3+
2
Mg
 
2
Li)Si
 
8
O
 
22
(OH)
 
2
All elements listed in formula:Fe, H, Li, Mg, Na, O, Si

Relationship of Ferriwhittakerite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
9.DE.05Anthophyllite
☐[Mg
 
2
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Cummingtonite
[ ][Mg
 
2
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Clinoferroholmquistite
[ ][Li
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Grunerite
[ ][Fe
2+
2
][Fe
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Manganocummingtonite
[ ][Mn
2+
2
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Manganogrunerite
[ ][Mn
2+
2
][Fe
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Permanganogrunerite
[ ][Mn
2+
2
][Mn
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Fluoro-sodic-ferropedrizite
NaLi
 
2
(Fe
 
2
Al
 
2
Li)(Si
 
6
Al
 
2
)O
 
22
F
 
2
9.DE.10Actinolite
☐Ca
 
2
(Mg,Fe
2+
 
)
 
5
(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Alumino-ferro-hornblende
Ca
 
2
Fe
 
4
Al
 
2
Si
 
7
O
 
22
(OH)
 
2
9.DE.10Alumino-magnesio-hornblende
Ca
 
2
Mg
 
4
Al
 
2
Si
 
7
O
 
22
(OH)
 
2
9.DE.10Aluminotschermakite
☐[Ca
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Ferritschermakite
☐[Ca
 
2
][Mg
 
3
Fe
3+
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Ferro-Actinolite
☐[Ca
 
2
][(Fe
2+
 
,Mg)
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Ferrohornblende
☐[Ca
 
2
][Fe
2+
4
Al][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.10Ferrotschermakite
☐[Ca
 
2
][Fe
2+
3
Fe
3+
 
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Joesmithite
PbCa
 
2
Mg
 
3
Fe
3+
2
[Si
 
6
Be
 
2
O
 
22
](OH)
 
2
9.DE.10Magnesiohornblende
☐[Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.10Tremolite
☐[Ca
 
2
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Tschermakite
☐[Ca
 
2
][Mg
 
3
Fe
3+
 
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Ferri-Ferrotschermakite
9.DE.10Alumino-Ferrotschermakite
9.DE.10Cannilloite
[Ca][Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.10Fluor-cannilloite
[Ca][Ca
 
2
][Mg
 
4
Al][(F,OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.10Parvo-manganotremolite
☐[CaMn
2+
 
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Fluorotremolite
☐[Ca
 
2
][Mg
 
5
][F
 
2
|Si
 
8
O
 
22
]
9.DE.15Edenite
Na[Ca
 
2
][Mg
 
5
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Ferro-edenite
[Na][Ca
 
2
][Fe
2+
5
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Ferrokaersutite
[Na][Ca
 
2
][Fe
2+
4
Ti][O|OH|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Ferropargasite
[Na][Ca
 
2
][Fe
2+
4
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Hastingsite
[Na][Ca
 
2
][Fe
2+
4
Fe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Kaersutite
[Na][Ca
 
2
][Mg
 
4
Ti][O|OH|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Magnesiohastingsite
Na[Ca
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Magnesiosadanagaite
[Na][Ca
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Pargasite
[Na][Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Sadanagaite
[Na][Ca
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Fluoro-edenite
Na[Ca
 
2
][Mg
 
5
][(F,OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Potassic-Ferrisadanagaite
[K][Ca
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Potassic-Magnesiosadanagaite
[K][Ca
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Potassicpargasite
[K][Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Potassicsadanagaite
[K][Ca
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Fluoro-magnesiohastingsite
[Na][Ca
 
2
][Mg
 
4
Fe
3+
 
][F
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Ferri-ottoliniite
[](Na
 
1
Li
 
1
)(Fe
3+
2
Mg
 
3
)Si
 
8
O
 
22
(OH)
 
2
9.DE.15Fluoro-potassichastingsite
[K][Ca
 
2
][Fe
2+
4
Fe
3+
 
][(F,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Chloro-potassichastingsite
[K][Ca
 
2
][Fe
2+
4
Fe
3+
 
][(Cl,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Fluoropargasite
[Na][Ca
 
2
][Mg
 
4
Al][(F,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Parvo-mangano-edenite
Na[CaMn
2+
 
][Mg
 
5
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Chloro-potassicpargasite
[K][Ca
 
2
][Mg
 
4
Al][(Cl,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Chloro-potassic-ferro-edenite
[K][Ca
 
2
][Fe
2+
5
][(Cl,OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Potassic-magnesiohastingsite
[K][Ca
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Potassic-ferropargasite
KCa
 
2
(Fe
2+
4
Al)Si
 
6
Al
 
2
O
 
22
(OH)
 
2
9.DE.20Aluminobarroisite
☐[CaNa][Mg
 
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Aluminokatophorite
9.DE.20Aluminotaramite
Na[CaNa][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Barroisite
☐[CaNa][Mg
 
3
AlFe
3+
 
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferri-ferrobarroisite
☐[CaNa][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferri-ferrowinchite
☐[CaNa][Fe
2+
4
(Fe
3+
 
,Al)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Ferribarroisite
☐[CaNa][Mg
 
3
Fe
3+
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferritaramite
Na[CaNa][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Ferrikatophorite
Na[CaNa][Fe
2+
4
(Fe
3+
 
,Al)][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Alumino-ferrobarroisite
☐[CaNa][Fe
2+
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferrobarroisite
☐[CaNa][Fe
2+
3
AlFe
3+
 
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferrorichterite
Na[CaNa][Fe
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Ferrowinchite
☐[CaNa][Fe
2+
4
(Al,Fe
3+
 
)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Katophorite
Na[CaNa][Fe
2+
4
(Al,Fe
3+
 
)][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferri-magnesiotaramite
Na[CaNa][Mg
 
3
Fe
3+
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Magnesiotaramite
Na[CaNa][Mg
 
3
AlFe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Richterite
Na[CaNa][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Taramite
Na[CaNa][Fe
2+
3
AlFe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Winchite
☐[CaNa][Mg
 
4
(Al,Fe
3+
 
)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Alumino-Magnesiotaramite
Na[CaNa][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Fluororichterite
Na[CaNa][Mg
 
5
][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Magnesiokatophorite
Na[CaNa][Mg
 
4
(Al,Fe
3+
 
)][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Fluoro-potassicrichterite
K[CaNa][Mg
 
5
][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Potassicrichterite
K[CaNa][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Parvowinchite
☐[Mn
2+
 
Na][Mg
 
4
(Al,Fe
3+
 
)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Ferriwinchite
☐[CaNa][Mg
 
4
(Fe
3+
 
,Al)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Fluoro-alumino-magnesiotaramite
Na[CaNa][Mg
 
3
Al
 
2
][F
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20IMA2007-015
K[CaNa][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.25Arfvedsonite
[Na][Na
 
2
][Fe
2+
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Eckermannite
[Na][Na
 
2
][(Mg,Fe
2+
 
)
 
4
Al][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferro-eckermannite
[Na][Na
 
2
][(Fe
2+
 
,Mg)
 
4
Al][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferroglaucophane
[ ][Na
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Glaucophane
[ ][Na
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Kornite
[(Na,K)][Na
 
2
][Mg
 
2
Mn
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Kôzulite
[Na][Na
 
2
][Mn
2+
4
(Fe
3+
 
,Al)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Leakeite
[Na][Na
 
2
][Mg
 
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Magnesioriebeckite
[ ][Na
 
2
][Mg
 
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Magnesio-arfvedsonite
[Na][Na
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Nybøite
[Na][Na
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.25Riebeckite
[ ][Na
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ungarettiite
[Na][Na
 
2
][Mn
2+
2
Mn
3+
3
][O
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferric-ferronybøite
[Na][Na
 
2
][(Fe
2+
 
,Mg)
 
3
Fe
3+
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.25Ferri-clinoferroholmquistite
[ ][Li
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferric-nyboite
9.DE.25Ferroleakeite
[Na][Na
 
2
][Fe
2+
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferronyböite
[Na][Na
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.25Fluoro-ferroleakeite
[Na][Na
 
2
][Fe
2+
2
Fe
3+
2
Li][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Sodic-ferri-clinoferroholmquistite
[(☐,Na)][(Li,☐)
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Fluoro-magnesio-arfvedsonite
[Na][Na
 
2
][Mg
 
4
Fe
3+
 
][(F,OH)
 
2
|[Si
 
8
O
 
22
]
9.DE.25Sodic-ferripedrizite
[Na][Li
 
2
][Mg
 
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Potassicleakeite
[K][Na
 
2
][Mg
 
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Fluoronybøite
[Na][Na
 
2
][Mg
 
3
Al
 
2
][(F,OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.25Dellaventuraite
NaNa
 
2
(MgMn
3+
2
LiTi
4+
 
)Si
 
8
O
 
22
O
 
2
9.DE.25Fluoro-sodicpedrizite
[Na][Li
 
2
][Mg
 
2
Al
 
2
Li][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Potassicarfvedsonite
[(K,Na)][Na
 
2
][Fe
2+
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Obertiite
[Na][Na
 
2
][Mg
 
3
(Ti,Fe
3+
 
,Mn
3+
 
)
 
2
][O
 
2
|Si
 
8
O
 
22
]
9.DE.25Fluoro-potassic-magnesio-arfvedsonite
[(K,Na)][Na
 
2
][Mg
 
4
Fe
3+
 
][(F,OH)
 
2
|[Si
 
8
O
 
22
]
9.DE.25Sodic-ferri-ferropedrizite
[Na][Li
 
2
][Fe
2+
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Potassic-magnesio-arfvedsonite
[K][Na
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Sodicpedrizite
NaLi
 
2
(LiMg
 
2
Fe
3+
 
Al)(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Sodic-ferropedrizite
NaLi
 
2
(LiFe
2+
2
Al)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Pedrizite
Li
 
2
(Li,Mg,Fe
2+
 
Al)
 
5
Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferropedrizite
NaLi
 
2
[Fe
2+
2
Fe
3+
 
AlLi)Si
 
8
O
 
22
(OH)
 
2
9.DE.25IMA2009-012
NaNa
 
2
(Mg
 
2
Al
 
2
Li)(Si
 
8
O
 
22
)F
 
2
9.DE.25IMA2009-034
NaNa
 
2
(Fe
2+
3
Fe
3+
 
Ti)Si
 
8
O
 
22
O
 
2

Other Names for Ferriwhittakerite

Synonyms:
IMA2001-069
Other Languages:
Russian:Ферривиттакерит

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ferriwhittakerite

Reference List:Oberti, R., F. Cámara, & J.M. Caballero (2004), Ferri-ottoliniite and ferriwhittakerite, two new end-members of the new Group 5 for monoclinic amphiboles: American Mineralogist: 88: 888-893.

Internet Links for Ferriwhittakerite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Ferriwhittakerite in the Natural History Museum (London) online catalogue
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    Localities for Ferriwhittakerite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Spain
     
    • Madrid
      • Sierra de Guadarrama
        • Eastern Pedriza Massif
    		CanMin 41:1355-1362 (2003)
    Mineral and/or Locality
    Google
     
    www.mindat.org Web
    Copyright © Jolyon Ralph and Ida Chau 1993-2009. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 15th Nov 2009 10:56:52