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Metahohmannite

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Queténa Mine, Toki Cu deposit, Chuquicamata District, Calama, El Loa Province, Antofagasta Region, Chile
© 2008, JGW

Formula:
Fe
3+
2
[O|(SO
 
4
)
 
2
] · 4H
 
2
O
Colour:Orange


Pulverulent masses formed by the partial dehydration of hohmannite.

Classification of Metahohmannite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:6/D.01-35
Nickel-Strunz 10th (pending) edition ID:7.DB.30

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
B : With only medium-sized cations; insular octahedra and finite units
Dana 8th edition ID:31.9.5.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
9 : (AB)(XO4)Zq·xH2O
Hey's CIM Ref.:25.10.13

25 : Sulphates
10 : Sulphates of Fe alone
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Type Occurrence of Metahohmannite

Type Locality:Chuquicamata Mine, Chuquicamata District, Calama, El Loa Province, Antofagasta Region, Chile
Year of Discovery:1938

Physical Properties of Metahohmannite

Colour:Orange

Crystallography of Metahohmannite

Morphology:Pulverulent masses.

Optical Data of Metahohmannite

Type:Biaxial (+)
RI values: nα = 1.709 nβ = 1.718 nγ = 1.734
2V:Measured: 70° , Calculated: 76°
Maximum Birefringence:δ = 0.025

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:r > v weak
Pleochroism:Visible
Comments:X = Light yellow
Y = Reddish yellow
Z = Reddish brown

Chemical Properties of Metahohmannite

Formula:
Fe
3+
2
[O|(SO
 
4
)
 
2
] · 4H
 
2
O
Essential elements:Fe, H, O, S
All elements listed in formula:Fe, H, O, S

Relationship of Metahohmannite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
7.DB.05Aubertite
CuAl[Cl|(SO
 
4
)
 
2
] · 14H
 
2
O
7.DB.05Magnesioaubertite
(Mg,Cu)Al[Cl|(SO
 
4
)
 
2
] · 14H
 
2
O
7.DB.05Svyazhinite
(Mg,Mn
2+
 
,Ca)(Al,Fe
3+
 
)[F|(SO
 
4
)
 
2
] · 14H
 
2
O
7.DB.10Khademite
Al[F|SO
 
4
] · 5H
 
2
O
7.DB.10Rostite
Al[OH|SO
 
4
] · 5H
 
2
O
7.DB.15Jurbanite
Al[OH|SO
 
4
] · 5H
 
2
O
7.DB.20Minasragrite
(V
4+
 
O)[SO
 
4
] · 5H
 
2
O
7.DB.20Orthominasragrite
(V
4+
 
O)[SO
 
4
] · 5H
 
2
O
7.DB.20Anorthominasragrite
(V
4+
 
O)[SO
 
4
] · 5H
 
2
O
7.DB.25Bobjonesite
(V
4+
 
O)[SO
 
4
] · 3H
 
2
O
7.DB.30Amarantite
Fe
3+
2
[O|(SO
 
4
)
 
2
] · 7H
 
2
O
7.DB.30Hohmannite
Fe
3+
2
[O|(SO
 
4
)
 
2
] · 8H
 
2
O
7.DB.35Aluminocopiapite
Al
 
2/3
Fe
3+
4
[OH|(SO
 
4
)
 
3
]
 
2
 · 20H
 
2
O
7.DB.35Calciocopiapite
CaFe
 
4
(SO
 
4
)
 
6
(OH)
 
2
·10H
 
2
O
7.DB.35Copiapite
Fe
2+
 
Fe
3+
4
[OH|(SO
 
4
)
 
3
]
 
2
 · 20H
 
2
O
7.DB.35Cuprocopiapite
CuFe
 
4
(SO
 
4
)
 
6
(OH)
 
2
·20H
 
2
O
7.DB.35Ferricopiapite
Fe
 
5
(SO
 
4
)
 
6
O(OH)·20H
 
2
O
7.DB.35Magnesiocopiapite
MgFe
3+
4
[OH|(SO
 
4
)
 
3
]
 
2
 · 20H
 
2
O
7.DB.35Zincocopiapite
ZnFe
3+
4
[OH|(SO
 
4
)
 
3
]
 
2
 · 18H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
25.10.1Szomolnokite
FeSO
 
4
·H
 
2
O
25.10.2Rozenite
FeSO
 
4
·4H
 
2
O
25.10.3Siderotil
FeSO
 
4
·5H
 
2
O
25.10.4Ferrohexahydrite
FeSO
 
4
·6H
 
2
O
25.10.5Melanterite
FeSO
 
4
·7H
 
2
O
25.10.6Rhomboclase
(H
 
5
O
 
2
)Fe
3+
 
(SO
 
4
)
 
2
·2H
 
2
O
25.10.7Lausenite
Fe
 
2
(SO
 
4
)
 
3
·6H
 
2
O
25.10.8Kornelite
Fe
 
2
(SO
 
4
)
 
3
·7H
 
2
O
25.10.9Coquimbite
Fe
 
2
(SO
 
4
)
 
3
·9H
 
2
O
25.10.10Paracoquimbite
Fe
 
2
(SO
 
4
)
 
3
·9H
 
2
O
25.10.11Quenstedtite
Fe
 
2
(SO
 
4
)
 
3
·10H
 
2
O
25.10.12Ferricopiapite
Fe
 
5
(SO
 
4
)
 
6
O(OH)·20H
 
2
O
25.10.14Hohmannite
Fe
3+
2
[O|(SO
 
4
)
 
2
] · 8H
 
2
O
25.10.15Butlerite
Fe
3+
 
[OH|SO
 
4
] · 2H
 
2
O
25.10.16Parabutlerite
Fe
3+
 
[OH|SO
 
4
] · 2H
 
2
O
25.10.17Amarantite
Fe
3+
2
[O|(SO
 
4
)
 
2
] · 7H
 
2
O
25.10.18Fibroferrite
Fe
3+
 
[OH|SO
 
4
] · 5H
 
2
O
25.10.19Hydroniumjarosite
(H
 
3
O)Fe
3+
3
(SO
 
4
)
 
2
(OH)
 
6
25.10.20Römerite
Fe
2+
 
Fe
3+
2
(SO
 
4
)
 
4
·14H
 
2
O
25.10.21Bílinite
Fe
2+
 
Fe
3+
2
(SO
 
4
)
 
4
·22H
 
2
O
25.10.22Copiapite
Fe
2+
 
Fe
3+
4
[OH|(SO
 
4
)
 
3
]
 
2
 · 20H
 
2
O

Other Names for Metahohmannite

Other Languages:
German:Metahohmannit
Russian:Метагогманит
Spanish:Metahohmannita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Metahohmannite

Reference List:Mackintosh (1889) American Journal of Science: 38: 243 (material may not be identical to metahohmannite).

Bandy (1928) American Mineralogist: 23: 748.

Ungemach (1935) Bulletin de la Société française de Minéralogie: 58: 97.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 608.

Scordari, Fernando, Gennaro Ventruti, and Alessandro F. Gualtieri (2004), The structure of metahohmannite, Fe23+[O(SO4)2].4H2O, by in situ synchrotron, American Mineralogist: 89: 365-370.

Internet Links for Metahohmannite

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  • Raman and XRD data at RRUFF project
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  • Metahohmannite details from Handbook of Mineralogy (PDF)
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    Localities for Metahohmannite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • South Australia
      • Olary Province
        • Mingary
          • Pine Creek - Mutooroo area
    Chile
     
    • Antofagasta Region
      • El Loa Province
        • Calama
          • Cerritos Bayos
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 608.
          • Chuquicamata District
    		American Mineralogist (1938): 23: 748; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 608.
            • Toki Cu deposit
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 608.
    • Tarapacá Region
      • Iquique Province
        • Pampa del Tamarugal
    		Peter G. Seroka collection
    USA
     
    • Nebraska
      • Jefferson Co.
        • Fairbury
    		Chemical Geology Volume 215, Issues 1-4, 15 February 2005, Pages 433-452
    Mineral and/or Locality
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