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Metakirchheimerite

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Big Photo

Svornost Mine (Einigkeit Mine), Jáchymov (St Joachimsthal), Jáchymov (St Joachimsthal) District, Krušné Hory Mts (Erzgebirge), Karlovy Vary Region, Bohemia (Böhmen; Boehmen), Czech Republic
© Knut Eldjarn

Show Metakirchheimerite Photos (2)



Formula:
Co(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
System:TriclinicColour:pale pink
Hardness:2 - 2½
Member of:Meta-autunite Group
Name:For Professor Franz Waldemar Kirchheimer (1911–1984), former Director of the Geological Survey of Baden-Württemberg, Germany, geologist, palaeontologist and mining historian, for his contribution on uranium deposits in Baden-Württemberg.


Meta-autunite Group.

The lower hydrate of "kirchheimerite", a non-approved species which contains 12 water molecules per formula unit (Walenta, 1964; Locock et al., 2004).

Classification of Metakirchheimerite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/E.02-50
Nickel-Strunz 10th (pending) edition ID:8.EB.10

8 : PHOSPHATES, ARSENATES, VANADATES
E : Uranyl phosphates and arsenates
B : UO2:RO4 = 1:1
Dana 8th edition ID:40.2a.17.1

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
2a : AB2(XO4)2·xH2O, containing (UO2)2+
Hey's CIM Ref.:20.7.20

20 : Arsenates (also arsenates with phosphate, but without other anions)
7 : Arsenates of U
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Type Occurrence of Metakirchheimerite

Type Locality:Sophia Mine, Böckelsbach valley, Wittichen, Schenkenzell, Black Forest, Baden-Württemberg, Germany
Year of Discovery:1958

Physical Properties of Metakirchheimerite

Colour:pale pink
Streak:white
Hardness (Mohs):2 - 2½
Cleavage:Perfect

Crystallography of Metakirchheimerite

Crystal System:Triclinic
Class (H-M):1 - Pinacoidal
Space Group:P1
Cell Parameters:a = 7.1955Å, b = 9.7715Å, c = 13.2319Å
α = 75.525°, β = 84.052°, γ = 81.661°
Ratio:a:b:c = 0.736 : 1 : 1.354
Unit Cell Volume:V 889.08 ų (Calculated from Unit Cell)

Optical Data of Metakirchheimerite

Type:Uniaxial (-)
RI values: nω = 1.644 nε = 1.617
Maximum Birefringence:δ = 0.027

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Metakirchheimerite

Formula:
Co(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
Essential elements:As, Co, H, O, U
All elements listed in formula:As, Co, H, O, U

Relationship of Metakirchheimerite to other Species

Member of:Meta-autunite Group
Other Members of Group:

- +
Abernathyite
K
 
2
(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 6H
 
2
O
Bassetite
Fe
2+
 
(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 8H
 
2
O
Chernikovite
(H
 
3
O)
 
2
(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 6H
 
2
O
Lehnerite
Mn
2+
 
(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 8H
 
2
O
Meta-ankoleite
K
 
2
(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 6H
 
2
O
Meta-autunite
Ca(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 6-8H
 
2
O
Metaheinrichite
Ba(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
Metakahlerite
Fe
2+
 
(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
Metalodèvite
Zn(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 10H
 
2
O
Metanováčekite
Mg(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 4-8H
 
2
O
Metatorbernite
Cu(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 8H
 
2
O
Metauranocircite
Ba(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 7H
 
2
O
Metauranospinite
Ca(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
Metazeunerite
Cu(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
Natrouranospinite
(Na
 
2
,Ca)(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 5H
 
2
O
Uramarsite
(NH
 
4
,H
 
3
O)
 
2
(UO
 
2
)
 
2
(AsO
 
4
,PO
 
4
)
 
2
 · 6H
 
2
O
Uramphite
(NH
 
4
)
 
2
(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 6H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
8.EB.05Autunite
Ca(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 11H
 
2
O
8.EB.05Heinrichite
Ba(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 10H
 
2
O
8.EB.05Kahlerite
Fe(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 12H
 
2
O
8.EB.05Nováčekite-I
Mg(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 12H
 
2
O
8.EB.05Saléeite
Mg(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 10H
 
2
O
8.EB.05Torbernite
Cu(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 12H
 
2
O
8.EB.05Uranocircite
Ba(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 10H
 
2
O
8.EB.05Uranospinite
Ca(UO
 
2
)(AsO
 
4
)
 
2
 · 10H
 
2
O
8.EB.05Xiangjiangite
(Fe
3+
 
,Al)(UO
 
2
)
 
4
(PO
 
4
)
 
2
(SO
 
4
)
 
2
(OH) · 22H
 
2
O
8.EB.05Zeunerite
Cu(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 12H
 
2
O
8.EB.05Metarauchite
Ni(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
8.EB.05Rauchite
Ni(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 10H
 
2
O
8.EB.10Bassetite
Fe
2+
 
(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 8H
 
2
O
8.EB.10Lehnerite
Mn
2+
 
(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 8H
 
2
O
8.EB.10Meta-autunite
Ca(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 6-8H
 
2
O
8.EB.10Metasaléeite
Mg(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 8H
 
2
O
8.EB.10Metauranocircite
Ba(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 7H
 
2
O
8.EB.10Metauranospinite
Ca(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
8.EB.10Metaheinrichite
Ba(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
8.EB.10Metakahlerite
Fe
2+
 
(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
8.EB.10Metanováčekite
Mg(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 4-8H
 
2
O
8.EB.10Metatorbernite
Cu(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 8H
 
2
O
8.EB.10Metazeunerite
Cu(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
8.EB.10Przhevalskite
Pb
 
2
(UO
 
2
)
 
3
(PO
 
4
)
 
2
(OH)
 
4
 · 3H
 
2
O
8.EB.10Meta-lodèvite
8.EB.15Abernathyite
K
 
2
(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 6H
 
2
O
8.EB.15Chernikovite
(H
 
3
O)
 
2
(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 6H
 
2
O
8.EB.15Meta-ankoleite
K
 
2
(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 6H
 
2
O
8.EB.15Natrouranospinite
(Na
 
2
,Ca)(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 5H
 
2
O
8.EB.15Trögerite
(UO
 
2
)
 
3
(AsO
 
4
)
 
2
 · 12H
 
2
O (?)
8.EB.15Uramphite
(NH
 
4
)
 
2
(UO
 
2
)
 
2
(PO
 
4
)
 
2
 · 6H
 
2
O
8.EB.15Uramarsite
(NH
 
4
,H
 
3
O)
 
2
(UO
 
2
)
 
2
(AsO
 
4
,PO
 
4
)
 
2
 · 6H
 
2
O
8.EB.20Threadgoldite
Al(UO
 
2
)
 
2
(PO
 
4
)
 
2
(OH) · 8H
 
2
O
8.EB.20Chistyakovaite
Al(UO
 
2
)
 
2
(AsO
 
4
)
 
2
(F,OH) · 6.5H
 
2
O
8.EB.25Arsenuranospathite
HAl(UO
 
2
)
 
4
(AsO
 
4
)
 
4
 · 40H
 
2
O
8.EB.25Uranospathite
(Al,☐)(UO
 
2
)
 
2
(PO
 
4
)
 
2
F · 20(H
 
2
O,F)
8.EB.30Vochtenite
(Fe
2+
 
,Mg)Fe
3+
 
(UO
 
2
)
 
4
(PO
 
4
)
 
4
(OH) · 12-13H
 
2
O
8.EB.35Coconinoite
Fe
3+
2
Al
 
2
(UO
 
2
)
 
2
(PO
 
4
)
 
4
(SO
 
4
)(OH)
 
2
 · 20H
 
2
O
8.EB.40Ranunculite
HAl(UO
 
2
)(PO
 
4
)(OH)
 
3
 · 4H
 
2
O
8.EB.45Triangulite
Al
 
3
(UO
 
2
)
 
4
(PO
 
4
)
 
4
(OH)
 
5
 · 5H
 
2
O
8.EB.50Furongite
Al
 
13
(UO
 
2
)
 
7
(PO
 
4
)
 
13
(OH)
 
14
 · 58H
 
2
O
8.EB.55Sabugalite
HAl(UO
 
2
)
 
4
(PO
 
4
)
 
4
 · 16H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
20.7.1Trögerite
(UO
 
2
)
 
3
(AsO
 
4
)
 
2
 · 12H
 
2
O (?)
20.7.2Natrouranospinite
(Na
 
2
,Ca)(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 5H
 
2
O
20.7.3Abernathyite
K
 
2
(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 6H
 
2
O
20.7.4Metazeunerite
Cu(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
20.7.5Zeunerite
Cu(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 12H
 
2
O
20.7.6Metanováčekite
Mg(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 4-8H
 
2
O
20.7.7Nováčekite-I
Mg(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 12H
 
2
O
20.7.8Arsenuranylite
Ca(UO
 
2
)
 
4
(AsO
 
4
)
 
2
(OH)
 
4
 · 6H
 
2
O
20.7.9Metauranospinite
Ca(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
20.7.10Uranospinite
Ca(UO
 
2
)(AsO
 
4
)
 
2
 · 10H
 
2
O
20.7.11Metaheinrichite
Ba(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
20.7.12Heinrichite
Ba(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 10H
 
2
O
20.7.13Metalodèvite
Zn(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 10H
 
2
O
20.7.14Arsenuranospathite
HAl(UO
 
2
)
 
4
(AsO
 
4
)
 
4
 · 40H
 
2
O
20.7.15Hallimondite
Pb
 
2
(UO
 
2
)(AsO
 
4
)
 
2
 · nH
 
2
O, 0 ≤ n ≤ 0.5
20.7.16Hügelite
Pb
 
2
(UO
 
2
)
 
3
(AsO
 
4
)
 
2
O
 
2
 · 5H
 
2
O
20.7.17Asselbornite
Pb(BiO)
 
3
(UO
 
2
)
 
4
(AsO
 
4
)
 
2
(OH)
 
7
·4H
 
2
O
20.7.18Metakahlerite
Fe
2+
 
(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 8H
 
2
O
20.7.19Kahlerite
Fe(UO
 
2
)
 
2
(AsO
 
4
)
 
2
 · 12H
 
2
O

Other Names for Metakirchheimerite

Other Languages:
German:Metakirchheimerit
Spanish:Metakirchheimerita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Metakirchheimerite

Reference List:

- +
Walenta, K. (1958): Die sekundaren Uranmineralien des Schwarzwaldes. Jahresheft geol. Landesant Baden-Wurttemberg, 3, 17-51 [type-description].

American Mineralogist (1959): 44: 466.

Walenta, K. (1964): Rare arsenate minerals with special consideration of occurrences in the Black Forest. Tschermaks Mineralogische und Petrographische Mitteilungen: 9, 111-174. (in German)

Locock, Andrew J.; Burns, Peter C.; Flynn, Theodore M. (2004): Divalent transition metals and magnesium in structures that contain the autunite-type sheet. Canadian Mineralogist 42, 1699-1718.

Votchen, R. & Geominne, A (1984): Synthesis, chrystallographic data, solubility, and electrokinetic properties of meta-zeunerite, meta-kirchheimerite and nickel-uranylarsenate. Physics and Chemistry of Minerals, 11, 95-100 (synthetic material).

Ondrus, Veselovsky, Gabasova, Srein (2003) Supplement to secondary and rock-forming minerals of the Jachymov ore district. Journal of the Czech Geological Society: 48, 4/4: 149-155.

Plášil, J., Čejka, J., Sejkora, J., Hloušek, J., Goliáš, V. (2009): New data for metakirchheimerite from Jáchymov (St. Joachimsthal), Czech Republic. Journal of Geosciences, 54, 373-384

Internet Links for Metakirchheimerite

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    • Localities for Metakirchheimerite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Karlovy Vary Region
        • Krušné Hory Mts (Erzgebirge)
          • Jáchymov (St Joachimsthal) District
            • Jáchymov (St Joachimsthal)
    		Ondrus, Veselovsky, Gabasova, Srein (2003) Supplement to secondary and rock-forming minerals of the Jachymov ore district. Journal of the Czech Geological Society: 48, 4/4: 149-155; Tvrdý, J. & Plášil, J. (2010): Jáchymov - Reiche Erzlagerstätte und Radonbad im böhmischen Westerzgebirge. Aufschluss 61, 277-292.
    Plášil, J., Čejka, J., Sejkora, J., Hloušek, J., Goliáš, V. (2009): New data for metakirchheimerite from Jáchymov (St. Joachimsthal), Czech Republic. Journal of Geosciences, 54, 373-384.
    France
     
    • Languedoc-Roussillon
      • Hérault
        • Lodève
    		Le Règne Minéral, Hors Série IV (1998)
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Schenkenzell
          • Wittichen
    		Markl, G. & Slotta, C. (2011): Die Uranmineralien des Lagerstättenreviers Wittichen im mittleren Schwarzwald. Lapis 36 (3), 25-37; 54 (in German).
            • Böckelsbach valley
    		American Mineralogist (1959) 44, pp. 466; Tscherm MPM 9 (1964), 111
            • Burgfelsen
    		No reference listed
            • Heubach Valley
    		No reference listed
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