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Metakirchheimerite

Formula:
Co(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 8H
 
2
O
System:TriclinicColour:pale pink
Hardness:2 - 2½


The lower hydrate of "kirchheimerite", a non-approved species which contains 12H2O per formula unit (Locock et al., 2004).

Classification of Metakirchheimerite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/E.02-50
Nickel-Strunz 10th (pending) edition ID:8.EB.10

8 : PHOSPHATES, ARSENATES, VANADATES
E : Uranyl phosphates and arsenates
B : UO2:RO4 = 1:1
Dana 8th edition ID:40.2a.17.1

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
2a : AB2(XO4)2·xH2O, containing (UO2)2+
Hey's CIM Ref.:20.7.20

20 : Arsenates (also arsenates with phosphate, but without other anions)
7 : Arsenates of U
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Type Occurrence of Metakirchheimerite

Type Locality:Sophia Mine, Böckelsbach valley, Wittichen, Schenkenzell, Black Forest, Baden-Württemberg, Germany
Year of Discovery:1958

Physical Properties of Metakirchheimerite

Colour:pale pink
Streak:white
Hardness (Mohs):2 - 2½
Cleavage:Perfect

Crystallography of Metakirchheimerite

Crystal System:Triclinic
Class (H-M):1 - Pinacoidal
Space Group:P1
Cell Parameters:a = 7.1955Å, b = 9.7715Å, c = 13.2319Å
α = 75.525°, β = 84.052°, γ = 81.661°
Ratio:a:b:c = 0.736 : 1 : 1.354
Unit Cell Volume:V 889.08 ų (Calculated from Unit Cell)

Optical Data of Metakirchheimerite

Type:Uniaxial (-)
RI values: nω = 1.644 nε = 1.617
Maximum Birefringence:δ = 0.027

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Metakirchheimerite

Formula:
Co(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 8H
 
2
O
Essential elements:As, Co, H, O, U
All elements listed in formula:As, Co, H, O, U

Relationship of Metakirchheimerite to other Species

Member of Group:
Meta-autunite Group:
A(UO
 
2
)
 
2
(XO
 
4
)
 
2
·nH
 
2
O (n = 6, 7 or 8)
Related Minerals - Nickel-Strunz Grouping):

- +
8.EB.05Autunite
Ca(UO
 
2
)
 
2
(PO
 
4
)
 
2
·11H
 
2
O
8.EB.05Heinrichite
Ba(UO
 
2
)
 
2
(AsO
 
4
)
 
2
·10H
 
2
O
8.EB.05Kahlerite
Fe(UO
 
2
)
 
2
(AsO
 
4
)
 
2
·12H
 
2
O
8.EB.05Nováčekite-I
Mg(UO
 
2
)
 
2
(AsO
 
4
)
 
2
·12H
 
2
O
8.EB.05Saléeite
Mg(UO
 
2
)
 
2
(PO
 
4
)
 
2
·10H
 
2
O
8.EB.05Torbernite
Cu(UO
 
2
)
 
2
(PO
 
4
)
 
2
·12H
 
2
O
8.EB.05Uranocircite
Ba(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 10H
 
2
O
8.EB.05Uranospinite
Ca(UO
 
2
)(AsO
 
4
)
 
2
·10H
 
2
O
8.EB.05Xiangjiangite
(Fe
3+
 
,Al)(UO
 
2
)
 
4
[OH|(SO
 
4
)
 
2
|(PO
 
4
)
 
2
] · 22H
 
2
O
8.EB.05Zeunerite
Cu(UO
 
2
)
 
2
(AsO
 
4
)
 
2
·12H
 
2
O
8.EB.05UM1997-18-AsO:HNiU
Ni(UO
 
2
)
 
2
(AsO
 
4
)
 
2
·6-8H
 
2
O
8.EB.05Metarauchite
Ni(UO
 
2
)
 
2
(AsO
 
4
)
 
2
·8H
 
2
O
8.EB.10Bassetite
Fe
2+
 
(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 8H
 
2
O
8.EB.10Lehnerite
Mn
2+
 
(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 8H
 
2
O
8.EB.10Meta-autunite
Ca(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 6-8H
 
2
O
8.EB.10Metasaléeite
Mg(UO
 
2
)(PO
 
4
)
 
2
·8H
 
2
O
8.EB.10Metauranocircite
Ba(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 7H
 
2
O
8.EB.10Metauranospinite
Ca(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 8H
 
2
O
8.EB.10Metaheinrichite
Ba(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 8H
 
2
O
8.EB.10Metakahlerite
Fe
2+
 
(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 8H
 
2
O
8.EB.10Metanováčekite
Mg(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 4-8H
 
2
O
8.EB.10Metatorbernite
Cu(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 8H
 
2
O
8.EB.10Metazeunerite
Cu(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 8H
 
2
O
8.EB.10Przhevalskite
Pb
 
2
(UO
 
2
)
 
3
[(OH)
 
2
|PO
 
4
]
 
2
· 3H
 
2
O
8.EB.10Meta-lodèvite
8.EB.15Abernathyite
K
 
2
(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 6H
 
2
O
8.EB.15Chernikovite
(H
 
3
O)
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 6H
 
2
O
8.EB.15Meta-ankoleite
K
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 6H
 
2
O
8.EB.15Natrouranospinite
(Na
 
2
,Ca)(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 5H
 
2
O
8.EB.15Trögerite
(UO
 
2
)
 
3
(AsO
 
4
)
 
2
·12H
 
2
O (?)
8.EB.15Uramphite
(NH
 
4
)
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 6H
 
2
O
8.EB.15Uramarsite
(NH
 
4
,H
 
3
O)
 
2
(UO
 
2
)
 
2
[(AsO
 
4
,PO
 
4
)]
 
2
· 6H
 
2
O
8.EB.20Threadgoldite
Al(UO
 
2
)
 
2
[OH|(PO
 
4
)
 
2
] · 8H
 
2
O
8.EB.20Chistyakovaite
Al(UO
 
2
)
 
2
[(F,OH)|(AsO
 
4
)
 
2
] · 6.5H
 
2
O
8.EB.25Arsenuranospathite
HAl(UO
 
2
)
 
4
(AsO
 
4
)
 
4
·40H
 
2
O
8.EB.25Uranospathite
Al
 
1-x
[]
 
x
)[(UO
 
2
)(PO
 
4
)]
 
2
(H
 
2
O)
 
20+3x
F
 
1-3x
, (0 < x < 0.33)
8.EB.30Vochtenite
(Fe
2+
 
,Mg)Fe
3+
 
(UO
 
2
)
 
4
[OH|(PO
 
4
)
 
4
] · 12-13H
 
2
O
8.EB.35Coconinoite
Fe
3+
2
Al
 
2
(UO
 
2
)
 
2
[(OH)
 
2
|SO
 
4
|(PO
 
4
)
 
4
] · 20H
 
2
O
8.EB.40Ranunculite
HAlUO
 
2
PO
 
4
(OH)
 
3
·4H
 
2
O
8.EB.45Triangulite
Al
 
3
(UO
 
2
)
 
4
(PO
 
4
)
 
4
(OH)
 
5
·5H
 
2
O
8.EB.50Furongite
Al
 
13
(UO
 
2
)
 
7
(PO
 
4
)
 
13
(OH)
 
14
· 58H
 
2
O
8.EB.55Sabugalite
HAl(UO
 
2
)
 
4
(PO
 
4
)
 
4
·16H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
20.7.1Trögerite
(UO
 
2
)
 
3
(AsO
 
4
)
 
2
·12H
 
2
O (?)
20.7.2Natrouranospinite
(Na
 
2
,Ca)(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 5H
 
2
O
20.7.3Abernathyite
K
 
2
(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 6H
 
2
O
20.7.4Metazeunerite
Cu(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 8H
 
2
O
20.7.5Zeunerite
Cu(UO
 
2
)
 
2
(AsO
 
4
)
 
2
·12H
 
2
O
20.7.6Metanováčekite
Mg(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 4-8H
 
2
O
20.7.7Nováčekite-I
Mg(UO
 
2
)
 
2
(AsO
 
4
)
 
2
·12H
 
2
O
20.7.8Arsenuranylite
Ca(UO
 
2
)
 
4
[(OH)
 
2
|AsO
 
4
]
 
2
· 6H
 
2
O
20.7.9Metauranospinite
Ca(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 8H
 
2
O
20.7.10Uranospinite
Ca(UO
 
2
)(AsO
 
4
)
 
2
·10H
 
2
O
20.7.11Metaheinrichite
Ba(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 8H
 
2
O
20.7.12Heinrichite
Ba(UO
 
2
)
 
2
(AsO
 
4
)
 
2
·10H
 
2
O
20.7.13Metalodèvite
Zn(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 10H
 
2
O
20.7.14Arsenuranospathite
HAl(UO
 
2
)
 
4
(AsO
 
4
)
 
4
·40H
 
2
O
20.7.15Hallimondite
Pb
 
2
(UO
 
2
)[AsO
 
4
]
 
2
· nH
 
2
O, 0 ≤ n ≤ 0.5
20.7.16Hügelite
Pb
 
2
(UO
 
2
)
 
3
[O|AsO
 
4
]
 
2
· 5H
 
2
O
20.7.17Asselbornite
Pb(UO
 
2
)
 
4
(BiO)
 
3
(AsO
 
4
)
 
2
(OH)
 
7
·4H
 
2
O
20.7.18Metakahlerite
Fe
2+
 
(UO
 
2
)
 
2
[AsO
 
4
]
 
2
· 8H
 
2
O
20.7.19Kahlerite
Fe(UO
 
2
)
 
2
(AsO
 
4
)
 
2
·12H
 
2
O

Other Names for Metakirchheimerite

Other Languages:
German:Metakirchheimerit
Spanish:Metakirchheimerita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Metakirchheimerite

Reference List:Walenta, K. (1958): Die sekundaren Uranmineralien des Schwarzwaldes. Jahresheft geol. Landesant Baden-Wurttemberg, 3, 17-51 [type-description].

American Mineralogist (1959): 44: 466.

Walenta, K. (1964): Rare arsenate minerals with special consideration of occurrences in the Black Forest. Tschermaks Mineralogische und Petrographische Mitteilungen: 9, 111-174. (in German)

Locock, Andrew J.; Burns, Peter C.; Flynn, Theodore M. (2004): Divalent transition metals and magnesium in structures that contain the autunite-type sheet. Canadian Mineralogist 42, 1699-1718.

Votchen, R. & Geominne, A (1984): Synthesis, chrystallographic data, solubility, and electrokinetic properties of meta-zeunerite, meta-kirchheimerite and nickel-uranylarsenate. Physics and Chemistry of Minerals, 11, 95-100 (synthetic material).

Ondrus, Veselovsky, Gabasova, Srein (2003) Supplement to secondary and rock-forming minerals of the Jachymov ore district. Journal of the Czech Geological Society: 48, 4/4: 149-155.

Internet Links for Metakirchheimerite

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    Localities for Metakirchheimerite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Karlovy Vary Region
        • Krušné Hory Mts (Erzgebirge)
          • Ostrov
            • Jáchymov (St Joachimsthal)
    Ondrus, Veselovsky, Gabasova, Srein (2003) Supplement to secondary and rock-forming minerals of the Jachymov ore district. Journal of the Czech Geological Society: 48, 4/4: 149-155.
    France
     
    • Languedoc-Roussillon
      • Hérault
        • Lodève
    Le Règne Minéral, Hors Série IV (1998)
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Schenkenzell
          • Wittichen
            • Böckelsbach valley
    American Mineralogist (1959) 44, pp. 466; Tscherm MPM 9 (1964), 111
            • Burgfelsen
    No reference listed
            • Heubach Valley
    No reference listed
    Mineral and/or Locality
    Google
     
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