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Aspidolite

Formula:
NaMg
 
3
[(OH)
 
2
|AlSi
 
3
O
 
10
]
System:MonoclinicColour:Light brown, white, ...
Name:From the Greek "aspisidos", like a shield, alluding to the appearance of its crystals
This page provides mineralogical data about Aspidolite.

Classification of Aspidolite

IMA status:Approved 2004
Explanation of status:In 1998, the Mica Subcommittee voted to resurrect the name aspidolite (von Kobell 1869), which represented an old description of what was in more recent years referred to as sodium phlogopite (Schreyer et al. 1980).
Strunz 8th edition ID:8/H.11-70
Nickel-Strunz 10th (pending) edition ID:9.EC.20

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
Dana 7th edition ID:71.2.2.13
mindat.org URL:http://www.mindat.org/min-27494.html
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Type Occurrence of Aspidolite

Type Locality:Kasuga mine, Kasuga-mura, Gifu Prefecture, Chubu Region, Honshu Island, Japan
General Appearance of Type Material:Interleaved with phlogopite.
Place of Conservation of Type Material:Geological Museum (Geological Survey of Japan).
Geological Setting of type material:Contact aureole.
Associated Minerals at type locality:
PhlogopitePargasiteMagnesiosadanagaiteTitaniteCalcite
Marialite-Meionite SeriesApatitePyrrhotiteChalcopyrite

Physical Properties of Aspidolite

Colour:Light brown, white, greenish red
Streak:White

Crystallography of Aspidolite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m (B1 1 2/m) [C2/m] {C1 2/m 1}
Cell Parameters:a = 5.291Å, b = 9.16Å, c = 10.12Å
β = 105.1°
Ratio:a:b:c = 0.578 : 1 : 1.105
Unit Cell Volume:V 473.54 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
d-spacingIntensity
9.77(100)
4.59(25)
3.26(50)
2.61(100)
2.55(25)
2.45(20)
Comments:From type description

Chemical Properties of Aspidolite

Formula:
NaMg
 
3
[(OH)
 
2
|AlSi
 
3
O
 
10
]
Essential elements:
All elements listed in formula:Al, H, Mg, Na, O, Si

Relationship of Aspidolite to other Species

Related to:
  • Mica Group
    • Related Minerals - Nickel-Strunz Grouping):
    9.EC.05Minnesotaite
    (Fe,Mg)
     
    3
    		Si
     
    4
    		O
     
    10
    		(OH)
     
    2
    9.EC.05Talc
    Mg
     
    3
    		Si
     
    4
    		O
     
    10
    		(OH)
     
    2
    9.EC.05Willemseite
    (Ni,Mg)
     
    3
    		Si
     
    4
    		O
     
    10
    		(OH)
     
    2
    9.EC.10Ferripyrophyllite
    Fe
     
    2
    		Si
     
    4
    		O
     
    10
    		(OH)
     
    2
    9.EC.10Pyrophyllite
    Al
     
    2
    		Si
     
    4
    		O
     
    10
    		(OH)
     
    2
    9.EC.15Boromuscovite
    KAl
     
    2
    		[(OH)
     
    2
    		|BSi
     
    3
    		O
     
    10
    		]
    9.EC.15Celadonite
    K(Mg,Fe
    2+
     
    		)(Fe
    3+
     
    		,Al)[(OH)
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
    9.EC.15Chernykhite
    (Ba,Na)(V
    3+
     
    		,Al,Mg)
     
    2
    		[(OH)
     
    2
    		|(Si,Al)
     
    4
    		O
     
    10
    		]
    9.EC.15Montdorite
    (K,Na)
     
    2
    		(Fe
    2+
     
    		,Mn
    2+
     
    		,Mg)
     
    5
    		[(OH,F)
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
     
    2
    9.EC.15Muscovite
    KAl
     
    2
    		[(OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.15Nanpingite
    CsAl
     
    2
    		[(OH,F)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.15Paragonite
    NaAl
     
    2
    		[(OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.15Roscoelite
    K(V,Al)
     
    2
    		[(OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.15Tobelite
    (NH
     
    4
    		,K)Al
     
    2
    		[(OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.15Aluminoceladonite
    K(Mg,Fe
    2+
     
    		)(Al,Fe
    3+
     
    		)[(OH)
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
    9.EC.15Chromphyllite
    K(Cr,Al)
     
    2
    		[(OH,F)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.15Ferro-aluminoceladonite
    K(Fe
    2+
     
    		,Mg)(Al,Fe
    3+
     
    		)[(OH)
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
    9.EC.15Ferroceladonite
    K(Fe
    2+
     
    		,Mg)(Fe
    3+
     
    		,Al)[(OH)
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
    9.EC.15Chromceladonite
    K(Mg,Fe
    2+
     
    		)(Cr,Al)[(OH)
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
    9.EC.15Tainiolite
    KLiMg
     
    2
    		[F
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
    9.EC.15Ganterite
    (Ba,Na,K)(Al,Mg)
     
    2
    		[(OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.20Annite
    KFe
    2+
    3
    		[(OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.20Biotite
    9.EC.20Ephesite
    NaLiAl
     
    2
    		[(OH)
     
    2
    		|Al
     
    2
    		Si
     
    2
    		O
     
    10
    		]
    9.EC.20Hendricksite
    K(Zn,Mg,Mn
    2+
     
    		)
     
    3
    		[(OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.20Masutomilite
    (K,Rb)(Li,Mn
    3+
     
    		,Al)
     
    3
    		[(F,OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.20Norrishite
    KLiMn
    2+
    2
    		[(OH)
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
    9.EC.20Phlogopite
    KMg
     
    3
    		[(OH,F)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.20Polylithionite
    KLi
     
    2
    		Al[(F,OH)
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
    9.EC.20Preiswerkite
    NaMg
     
    2
    		Al[(OH)
     
    2
    		|Al
     
    2
    		Si
     
    2
    		O
     
    10
    		]
    9.EC.20Siderophyllite
    KFe
    2+
    2
    		Al[(F,OH)
     
    2
    		|Al
     
    2
    		Si
     
    2
    		O
     
    10
    		]
    9.EC.20Tetra-ferriphlogopite
    KMg
     
    3
    		[(OH,F)
     
    2
    		|(Fe
    3+
     
    		,Al)Si
     
    3
    		O
     
    10
    		]
    9.EC.20Wonesite
    (Na,K)(Mg,fe,Al)
     
    6
    		(Al,Si)
     
    8
    		O
     
    20
    		(OH,F)
     
    4
    9.EC.20Zinnwaldite
    KLiFe
    2+
     
    		Al[(F,OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.20Eastonite
    KMg
     
    2
    		Al[(OH)
     
    2
    		|Al
     
    2
    		Si
     
    2
    		O
     
    10
    		]
    9.EC.20Tetraferriannite
    KFe
    2+
    3
    		[(OH)
     
    2
    		|(Fe
    3+
     
    		,Al)Si
     
    3
    		O
     
    10
    		]
    9.EC.20Trilithionite
    K(Li,Al)
     
    3
    		[(F,OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.20Fluorannite
    KFe
    2+
    3
    		[(F,OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.20Shirokshinite
    KNaMg
     
    2
    		[F
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
    9.EC.20Shirozulite
    K(Mn
    2+
     
    		,Mg)
     
    3
    		[(OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.20Sokolovaite
    CsLi
     
    2
    		AlSi
     
    4
    		O
     
    10
    		F
     
    2
    9.EC.20Fluorophlogopite
    KMg
     
    3
    		[(F,OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.25Brammallite
    Na
     
    0.65
    		Al
     
    2.0
    		ٱAl
     
    0.65
    		Si
     
    3.35
    		O
     
    10
    		(OH)
     
    2
    9.EC.30Margarite
    CaAl
     
    2
    		[(OH)
     
    2
    		|Al
     
    2
    		Si
     
    2
    		O
     
    10
    		]
    9.EC.35Anandite
    (Ba,K)(Fe
    2+
     
    		,Mg)
     
    3
    		[(O,OH)
     
    2
    		|(Si,Al,Fe)
     
    4
    		O
     
    10
    		]
    9.EC.35Bityite
    CaLiAl
     
    2
    		[(OH)
     
    2
    		|BeAlSi
     
    2
    		O
     
    10
    		]
    9.EC.35Clintonite
    Ca(Mg,Al)
     
    3
    		[(OH)
     
    2
    		|Al
     
    3
    		SiO
     
    10
    		]
    9.EC.35Kinoshitalite
    (Ba,K)(Mg,Mn
    2+
     
    		,Al)
     
    3
    		[(OH)
     
    2
    		|Al
     
    2
    		Si
     
    2
    		O
     
    10
    		]
    9.EC.35Ferrokinoshitalite
    (Ba,K)(Fe
    2+
     
    		,Mg)
     
    3
    		[(OH,F)
     
    2
    		|Al
     
    2
    		Si
     
    2
    		O
     
    10
    		]
    9.EC.35Oxykinoshitalite
    (Ba,K)(Mg,Ti,Fe
    3+
     
    		,Fe
    2+
     
    		)
     
    3
    		[(O,OH,F)
     
    2
    		|(Si,Al)
     
    4
    		O
     
    10
    		]
    9.EC.40Beidellite
    (Na,Ca
     
    0.5
    		)
     
    0.3
    		Al
     
    2
    		(Si,Al)
     
    4
    		O
     
    10
    		(OH)
     
    2
    		·nH
     
    2
    		O
    9.EC.40Kurumsakite
    (Zn,Ni,Cu)
     
    8
    		Al
     
    8
    		V
     
    2
    		Si
     
    5
    		O
     
    35
    		·27H
     
    2
    		O (or near)
    9.EC.40Montmorillonite
    (Na,Ca)
     
    0.33
    		(Al,Mg)
     
    2
    		Si
     
    4
    		O
     
    10
    		(OH)
     
    2
    		·nH
     
    2
    		O
    9.EC.40Nontronite
    Na
     
    0.3
    		Fe
     
    2
    		(Si,Al)
     
    4
    		O
     
    10
    		(OH)
     
    2
    		·nH
     
    2
    		O
    9.EC.40Volkonskoite
    Ca
     
    0.3
    		(Cr,Mg,Fe)
     
    2
    		(Si,Al)
     
    4
    		O
     
    10
    		(OH)
     
    2
    		·4H
     
    2
    		O
    9.EC.40Yakhontovite
    (Ca,Na)
     
    0.5
    		(Cu,Fe,Mg)
     
    2
    		Si
     
    4
    		O
     
    10
    		(OH)
     
    2
    		·3H
     
    2
    		O
    9.EC.40Smectite
    9.EC.45Hectorite
    Na
     
    0.3
    		(Mg,Li)
     
    3
    		Si
     
    4
    		O
     
    10
    		(F,OH)
     
    2
    9.EC.45Saponite
    Ca
     
    0.25
    		(Mg,Fe)
     
    3
    		(Si,Al)
     
    4
    		O
     
    10
    		(OH)
     
    2
    		·nH
     
    2
    		O
    9.EC.45Sauconite
    Na
     
    0.3
    		Zn
     
    3
    		(Si,Al)
     
    4
    		O
     
    10
    		(OH)
     
    2
    		·4H
     
    2
    		O
    9.EC.45Spadaite
    MgSiO
     
    2
    		(OH)
     
    2
    		·H
     
    2
    		O
    9.EC.45Stevensite
    (Ca,Na)
     
    x
    		Mg
     
    3
    		Si
     
    4
    		O
     
    10
    		(OH)
     
    2
    9.EC.45Swinefordite
    Li(Al,Li,Mg)
     
    4
    		(Si,Al)
     
    8
    		O
     
    20
    		,(OH,F)
     
    4
    		·xH
     
    2
    		O
    9.EC.45Zincsilite
    Zn
     
    3
    		Si
     
    4
    		O
     
    10
    		(OH)
     
    2
    		·4H
     
    2
    		O
    9.EC.45Ferrosaponite
    Ca
     
    0.3
    		(Fe
    2+
     
    		,Mg,Fe
    3+
     
    		)
     
    3
    		(Si,Al)
     
    4
    		O
     
    10
    		(OH)
     
    2
    		·4H
     
    2
    		O
    9.EC.50Vermiculite
    (Mg,Fe,Al)
     
    3
    		(Al,Si)
     
    4
    		O
     
    10
    		(OH)
     
    2
    		·4H
     
    2
    		O
    9.EC.55Baileychlore
    (Zn,Fe,Al,Mg)
     
    6
    		(Si,Al)
     
    4
    		O
     
    10
    		(OH)
     
    8
    9.EC.55Chamosite
    (Fe
    2+
     
    		,Mg)
     
    5
    		Al[(OH)
     
    8
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.55Clinochlore
    (Mg,Fe
    2+
     
    		)
     
    5
    		Al[(OH)
     
    8
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.55Cookeite
    LiAl
     
    4
    		(Si
     
    3
    		Al)O
     
    10
    		(OH)
     
    8
    9.EC.55Franklinfurnaceite
    Ca
     
    2
    		FeMn
     
    3
    		MnZn
     
    2
    		Si
     
    2
    		O
     
    10
    		(OH)
     
    8
    9.EC.55Gonyerite
    (Mn,Mg)
     
    5
    		Fe(Si
     
    3
    		Fe)O
     
    10
    		(OH)
     
    8
    9.EC.55Nimite
    (Ni,Mg,Al)
     
    6
    		(Si,Al)
     
    4
    		O
     
    10
    		(OH)
     
    8
    9.EC.55Orthochamosite
    (Fe,Mg,Fe)
     
    5
    		Al(Si
     
    3
    		Al)O
     
    10
    		(OH,O)
     
    8
    9.EC.55Pennantite
    (Mn
     
    5
    		Al)(Si
     
    3
    		Al)O
     
    10
    		(OH)
     
    8
    9.EC.55Sudoite
    (Mg,Fe
    2+
     
    		)
     
    2
    		Al
     
    3
    		[(OH)
     
    8
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.55Donbassite
    Al
     
    2
    		[Al
     
    2.33
    		][Si
     
    3
    		AlO
     
    10
    		](OH)
     
    8
    9.EC.55Glagolevite
    Na(Mg,Al)
     
    6
    		[(OH,O)
     
    8
    		|AlSi
     
    3
    		O
     
    10
    		]
    9.EC.55Borocookeite
    Li
     
    1+3x
    		Al
     
    4-x
    		[(BSi
     
    3
    		)O
     
    10
    		](OH)
     
    8
    		 [0.00 <= x <=0.33]
    9.EC.60Aliettite
    Ca
     
    0.2
    		Mg
     
    6
    		(Si,Al)
     
    8
    		O
     
    20
    		(OH)
     
    4
    		·4H
     
    2
    		O
    9.EC.60Corrensite
    (Mg,Fe)
     
    9
    		(Si,Al)
     
    8
    		O
     
    20
    		(OH)
     
    10
    		·nH
     
    2
    		O
    9.EC.60Dozyite
    Mg
     
    7
    		Al
     
    2
    		[(OH)
     
    12
    		|Al
     
    2
    		Si
     
    4
    		O
     
    15
    		]
    9.EC.60Hydrobiotite
    9.EC.60Karpinskite
    (Ni,Mg)
     
    2
    		Si
     
    2
    		O
     
    5
    		(OH)
     
    2
    9.EC.60Kulkeite
    Mg
     
    8
    		Al(AlSi
     
    7
    		)O
     
    20
    		(OH)
     
    10
    9.EC.60Lunijianlaite
    Li
     
    0.7
    		Al
     
    6.2
    		(Si
     
    7
    		AlO
     
    20
    		)(OH,O)
     
    10
    9.EC.60Rectorite
    (Na,Ca)Al
     
    4
    		(Si,Al)
     
    8
    		O
     
    20
    		(OH)
     
    4
    		·2H
     
    2
    		O
    9.EC.60Saliotite
    Li
     
    0.5
    		Na
     
    0.5
    		Al
     
    3
    		Si
     
    3
    		AlO
     
    10
    		(OH)
     
    5
    9.EC.60Tosudite
    9.EC.60Brinrobertsite
    Na
     
    0.3
    		Al
     
    4
    		[(OH)
     
    2
    		|Si
     
    4
    		O
     
    10
    		]
     
    2
    		 · 3.5 H
     
    2
    		O
    9.EC.65Macaulayite
    (Fe,Al)
     
    24
    		Si
     
    4
    		O
     
    43
    		(OH)
     
    2
    9.EC.70Burckhardtite
    Pb
     
    2
    		(Fe,Mn)AlTeO
     
    2
    		Si
     
    3
    		O
     
    10
    		(OH)
     
    2
    		·H
     
    2
    		O
    9.EC.75Ferrisurite
    (Pb,Ca)
     
    2-3
    		(CO
     
    3
    		)
     
    1.5-2
    		(OH,F)
     
    0.5-1
    		[(Fe,Al)
     
    2
    		Si
     
    4
    		O
     
    10
    		(OH)
     
    2
    		]·nH
     
    2
    		O
    9.EC.75Surite
    Pb(Pb,Ca)(CO
     
    3
    		)
     
    2
    		(Al,Fe,Mg)
     
    2
    		(Si,Al)
     
    4
    		O
     
    10
    		(OH)
     
    2
    9.EC.75Niksergievite
    (Ba,Ca)
     
    2
    		(Al,Si)
     
    7
    		O
     
    10
    		(CO
     
    3
    		)(OH)
     
    6
    		·nH
     
    2
    		O
    9.EC.80Kegelite
    Pb
     
    12
    		(Zn,Fe)
     
    2
    		Al
     
    4
    		(SO
     
    4
    		)
     
    4
    		Si
     
    11
    		O
     
    38
    		 or near
    Related Minerals - Dana Grouping):
    71.2.2.1Muscovite
    KAl
     
    2
    		[(OH)
     
    2
    		|AlSi
     
    3
    		O
     
    10
    		]
    71.2.2.2Illite
    K
     
    0.65
    		A
     
    2.0
    		 [][Al
     
    0.65
    		Si,
     
    3.35
    		O
     
    10
    		](OH)
     
    2
    71.2.2.5Glauconite
    K
     
    0.08
    		R
    1
    1.33
    		 R
    2
    0.67
    		 [][Al
     
    0.13
    		Si
     
    3.87
    		O
     
    10
    		](OH)
     
    2

    Other Names for Aspidolite

    Synonyms:
    IMA2004-049Na-PhlogopiteNa PhlogopiteSodium Phlogopite
    German names:
    AspidolithNa PhlogopitNatriumphlogopit
    Japanese names:
    ソーダ金雲母

    Other Information

    Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

    References for Aspidolite

    Reference List:von Kobell, F. (1869): Sitzungsber. königl. bayer. Akad. Wiss. I, 364-366.

    Schreyer (1980): Contrib. Mineral. Petrol. 74, 223-233.

    Hintze, C. (1897): Handbuch der Mineralogie.

    Canadian Mineralogist: 36: 905-912.

    Kogure, T., Banno, Y., Miyawaki, R. (2004): "Interlayer structure in aspidolite, the Na-analogue of phlogopite", European Journal of Mineralogy: 16, 891-898.

    Banno, Y., R. Miyawaki, T. Kogure, S. Matsubara, T. Kamiya & S. Yamada, Mineralogical Magazine, 69(6), 1047–1057 (2005).

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    Localities for Aspidolite

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    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Algeria
     
    • Aïn Defla Province
      • Tell Atlas
        • Ksar el Boukhari
          • Derrag
    		Contrib. Mineral. Petrol. 74, 223-233
    • Tamanghasset Province
      • Ahaggar Mts (Hoggar Mts)
        • Laouni
    		C. Lemanski, Jr. (re-entry lost Mindat data).
    Austria
     
    • Tyrol
      • North Tyrol
    		von Kobell, F. (1869): Sitzungsber. königl. bayer. Akad. Wiss, (I), 364-366.; Can Min 36 (1998), 905
    Chile
     
    • Antofagasta Region
      • El Loa Province
        • San Pedro volcano
    		C. Lemanski, Jr. (re-entry of lost Mindat data).
    China
     
    • Xinjiang (Xinjiang-Uygur) Autonomous Region
      • Yili Hasake (Ili Kazakh) Autonomous Prefecture
        • Tacheng (Tarbaghatay) Prefecture
          • Junggar basin
    		C. Lemanski, Jr. (re-entry lost Mindat data).
    Japan
     
    • Honshu Island
      • Chubu Region
        • Gifu Prefecture
          • Kasuga-mura
    		IMA Website
    New Zealand
     
    • South Island
      • Southland
    		C. Lemanski, Jr. (re-entry of lost Mindat data).
    Russia
     
    • Mekensk
      • Grosnaja
    Mineral and/or Locality
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