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Fluoropargasite

Formula:
[Na][Ca
 
2
][Mg
 
4
Al][(F,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
System:MonoclinicColour:Black
Hardness:6
Name:Named in allusion to its composition, with fluorine dominant over hydroxyl ions, and its relationship to Pargasite.


Amphibole Group. Calcic Clino-Amphibole Subgroup.

Classification of Fluoropargasite

IMA status:Approved 2003
Strunz 8th edition ID:8/F.10-112
Nickel-Strunz 10th (pending) edition ID:9.DE.15

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles
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Type Occurrence of Fluoropargasite

Type Locality:Edenville, Town of Warwick, Orange Co., New York, USA
Geological Setting of type material:Marble
Associated Minerals at type locality:
TitanitePhlogopiteCalciteActinolite

Physical Properties of Fluoropargasite

Lustre:Vitreous
Diaphaneity (Transparency):Translucent on thin edges
Colour:Black
Streak:Grey to greenish grey
Hardness (Mohs):6
Tenacity:Brittle
Cleavage:Perfect
on {110}
Fracture:Conchoidal
Density (measured):3.18 g/cm3
Density (calculated):3.19 g/cm3

Crystallography of Fluoropargasite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m (B1 1 2/m) [C2/m] {C1 2/m 1}
Cell Parameters:a = 9.8771Å, b = 18.041Å, c = 5.3092Å
β = 105.133°
Ratio:a:b:c = 0.547 : 1 : 0.294
Unit Cell Volume:V 913.25 ų
Z:2
X-Ray Powder Diffraction:
d-spacingIntensity
8.44 (100)
3.13 (80)
3.28 (41)
2.345 (41)
2.810 (32)
Comments:Format: d/Å I/% (hkl), from type description

Optical Data of Fluoropargasite

Type:Biaxial (+)
RI values: nα = 1.632 - 1.636 nβ = 1.640 - 1.644 nγ = 1.652 - 1.656
2V:Measured: 68° , Calculated: 79°
Maximum Birefringence:δ = 0.020

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r > v
Pleochroism:Weak
Comments:X - Colourless to light brown
Y - Light brown
Z - brown

Chemical Properties of Fluoropargasite

Formula:
[Na][Ca
 
2
][Mg
 
4
Al][(F,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
Essential elements:
All elements listed in formula:Al, Ca, F, H, Mg, Na, O, Si
Analyical Data:Individual contents determined by EPMA,
Emprical formula based on 24 anions, with (OH + F + Cl) = 2 apfu
SiO2 (43.30)
MgO (14.44)
FeO (9.73)
CaO (12.29)
Al2O3 (12.11)
Na2O (2.88)
TiO2 (0.90)
MnO (0.08)
K2O (0.91)
V2O3 (0.18)
Cr2O3 (0.01)
F (2.71)
Cl (0.12)

O = (F + Cl) = -1.17
H2O (0.71) (stoichiometry)

sum 99.20 wt%
Empirical Formula:
(Na
 
0.75
K
 
0.17
)Σ0.92 (Ca
 
1.94
Na
 
0.06
)Σ2.00(Mg
 
3.18
Fe
2+
1.18
Al
 
0.50
Ti
 
0.10
Fe
3+
0.02
V
 
0.02
Mn
 
0.01
)Σ5.00(Si
 
6.39
Al
 
1.61
)Σ8.00O
 
22
[F
 
1.26
(OH)
 
0.71
Cl
 
0.03
]Σ2.00

Relationship of Fluoropargasite to other Species

Related Minerals - Nickel-Strunz Grouping):
9.DE.XIMA2007-053
KCa
 
2
(Fe
2+
4
Al)Si
 
6
Al
 
2
O
 
22
(OH)
 
2
9.DE.05Cummingtonite
[ ][Mg
 
2
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Grunerite
[ ][Fe
2+
2
][Fe
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Manganocummingtonite
[ ][Mn
2+
2
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Manganogrunerite
[ ][Mn
2+
2
][Fe
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.05Permanganogrunerite
[ ][Mn
2+
2
][Mn
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Actinolite
☐Ca
 
2
(Mg,Fe
2+
 
)
 
5
(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Alumino-ferro-hornblende
Ca
 
2
Fe
 
4
Al
 
2
Si
 
7
O
 
22
(OH)
 
2
9.DE.10Alumino-magnesio-hornblende
Ca
 
2
Mg
 
4
Al
 
2
Si
 
7
O
 
22
(OH)
 
2
9.DE.10Aluminotschermakite
☐[Ca
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Ferritschermakite
☐[Ca
 
2
][Mg
 
3
Fe
3+
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Ferro-Actinolite
☐[Ca
 
2
][(Fe
2+
 
,Mg)
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Ferrohornblende
☐[Ca
 
2
][Fe
2+
4
Al][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.10Ferrotschermakite
☐[Ca
 
2
][Fe
2+
3
Fe
3+
 
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Joesmithite
[(Ca,Pb)][(Ca,Pb)
 
2
][(Mg,Fe
2+
 
)
 
5
][(OH)
 
2
|BeSi
 
7
O
 
22
]
9.DE.10Magnesiohornblende
☐[Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.10Tremolite
☐[Ca
 
2
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Tschermakite
☐[Ca
 
2
][Mg
 
3
Fe
3+
 
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.10Ferri-Ferrotschermakite
9.DE.10Alumino-Ferrotschermakite
9.DE.10Cannilloite
[Ca][Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.10Fluor-cannilloite
[Ca][Ca
 
2
][Mg
 
4
Al][(F,OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.10Parvo-manganotremolite
☐[CaMn
2+
 
][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.10Fluorotremolite
☐[Ca
 
2
][Mg
 
5
][F
 
2
|Si
 
8
O
 
22
]
9.DE.15Edenite
Na[Ca
 
2
][Mg
 
5
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Ferro-edenite
[Na][Ca
 
2
][Fe
2+
5
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Ferrokaersutite
[Na][Ca
 
2
][Fe
2+
4
Ti][O|OH|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Ferropargasite
[Na][Ca
 
2
][Fe
2+
4
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Hastingsite
[Na][Ca
 
2
][Fe
2+
4
Fe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Kaersutite
[Na][Ca
 
2
][Mg
 
4
Ti][O|OH|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Magnesiohastingsite
Na[Ca
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Magnesiosadanagaite
[Na][Ca
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Pargasite
[Na][Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Sadanagaite
[Na][Ca
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Fluoro-edenite
Na[Ca
 
2
][Mg
 
5
][(F,OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Potassic-Ferrisadanagaite
[K][Ca
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Potassic-Magnesiosadanagaite
[K][Ca
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Potassicpargasite
[K][Ca
 
2
][Mg
 
4
Al][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Potassicsadanagaite
[K][Ca
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
3
Si
 
5
O
 
22
]
9.DE.15Fluoro-magnesiohastingsite
[Na][Ca
 
2
][Mg
 
4
Fe
3+
 
][F
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Fluoro-potassichastingsite
[K][Ca
 
2
][Fe
2+
4
Fe
3+
 
][(F,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Chloro-potassichastingsite
[K][Ca
 
2
][Fe
2+
4
Fe
3+
 
][(Cl,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Parvo-mangano-edenite
Na[CaMn
2+
 
][Mg
 
5
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Chloro-potassicpargasite
[K][Ca
 
2
][Mg
 
4
Al][(Cl,OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.15Chloro-potassic-ferro-edenite
[K][Ca
 
2
][Fe
2+
5
][(Cl,OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.15Potassic-magnesiohastingsite
[K][Ca
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Aluminobarroisite
☐[CaNa][Mg
 
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Aluminokatophorite
9.DE.20Aluminotaramite
Na[CaNa][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Barroisite
☐[CaNa][Mg
 
3
AlFe
3+
 
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferri-ferrobarroisite
☐[CaNa][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Alumino-ferrowinchite
9.DE.20Ferri-ferrowinchite
☐[CaNa][Fe
2+
4
(Fe
3+
 
,Al)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Ferribarroisite
☐[CaNa][Mg
 
3
Fe
3+
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferritaramite
Na[CaNa][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Ferrikatophorite
Na[CaNa][Fe
2+
4
(Fe
3+
 
,Al)][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Alumino-ferrobarroisite
☐[CaNa][Fe
2+
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferrobarroisite
☐[CaNa][Fe
2+
3
AlFe
3+
 
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferrorichterite
Na[CaNa][Fe
2+
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Ferrowinchite
☐[CaNa][Fe
2+
4
(Al,Fe
3+
 
)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Katophorite
Na[CaNa][Fe
2+
4
(Al,Fe
3+
 
)][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Ferri-magnesiotaramite
Na[CaNa][Mg
 
3
Fe
3+
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Magnesiotaramite
Na[CaNa][Mg
 
3
AlFe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Richterite
Na[CaNa][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Taramite
Na[CaNa][Fe
2+
3
AlFe
3+
 
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Winchite
☐[CaNa][Mg
 
4
(Al,Fe
3+
 
)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Alumino-Magnesiotaramite
Na[CaNa][Mg
 
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20Fluororichterite
Na[CaNa][Mg
 
5
][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Magnesiokatophorite
Na[CaNa][Mg
 
4
(Al,Fe
3+
 
)][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.20Fluoro-potassicrichterite
K[CaNa][Mg
 
5
][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Potassicrichterite
K[CaNa][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Parvowinchite
☐[Mn
2+
 
Na][Mg
 
4
(Al,Fe
3+
 
)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Ferriwinchite
☐[CaNa][Mg
 
4
(Fe
3+
 
,Al)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.20Fluoro-alumino-magnesiotaramite
Na[CaNa][Mg
 
3
Al
 
2
][F
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.20IMA2007-015
K[CaNa][Fe
2+
3
Al
 
2
][(OH)
 
2
|Al
 
2
Si
 
6
O
 
22
]
9.DE.25Arfvedsonite
[Na][Na
 
2
][Fe
2+
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Eckermannite
[Na][Na
 
2
][(Mg,Fe
2+
 
)
 
4
Al][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferro-eckermannite
[Na][Na
 
2
][(Fe
2+
 
,Mg)
 
4
Al][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Clinoferroholmquistite
[ ][Li
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferroglaucophane
[ ][Na
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Glaucophane
[ ][Na
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Kornite
[(Na,K)][Na
 
2
][Mg
 
2
Mn
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Kôzulite
[Na][Na
 
2
][Mn
2+
4
(Fe
3+
 
,Al)][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Leakeite
[Na][Na
 
2
][Mg
 
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Magnesioriebeckite
[ ][Na
 
2
][Mg
 
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Magnesio-arfvedsonite
[Na][Na
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Nybøite
[Na][Na
 
2
][Mg
 
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.25Riebeckite
[ ][Na
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ungarettiite
[Na][Na
 
2
][Mn
2+
2
Mn
3+
3
][O
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferric-ferronyboite
9.DE.25Ferri-clinoferroholmquistite
[ ][Li
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferric-nyboite
9.DE.25Ferroleakeite
[Na][Na
 
2
][Fe
2+
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Ferronyböite
[Na][Na
 
2
][Fe
2+
3
Al
 
2
][(OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.25Fluoro-ferroleakeite
[Na][Na
 
2
][Fe
2+
2
Fe
3+
2
Li][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Sodic-ferri-clinoferroholmquistite
[(☐,Na)][(Li,☐)
 
2
][Fe
2+
3
Fe
3+
2
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Fluoro-magnesio-arfvedsonite
[Na][Na
 
2
][Mg
 
4
Fe
3+
 
][(F,OH)
 
2
|[Si
 
8
O
 
22
]
9.DE.25Sodic-ferripedrizite
[Na][Li
 
2
][Mg
 
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Potassicleakeite
[K][Na
 
2
][Mg
 
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Fluoronybøite
[Na][Na
 
2
][Mg
 
3
Al
 
2
][(F,OH)
 
2
|AlSi
 
7
O
 
22
]
9.DE.25Ferriwhittakerite
Na(Na
 
1.0-1.5
Li
 
0.5-1.0
)
 
2
(Fe
3+
2
Mg
 
2
Li)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferri-ottoliniite
[](Na
 
1
Li
 
1
)(Fe
3+
2
Mg
 
3
)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Dellaventuraite
NaNa
 
2
(MgMn
3+
2
LiTi
4+
 
)Si
 
8
O
 
22
O
 
2
9.DE.25Fluoro-sodicpedrizite
[Na][Li
 
2
][Mg
 
2
Al
 
2
Li][(F,OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Potassicarfvedsonite
[(K,Na)][Na
 
2
][Fe
2+
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Obertiite
[Na][Na
 
2
][Mg
 
3
(Ti,Fe
3+
 
,Mn
3+
 
)
 
2
][O
 
2
|Si
 
8
O
 
22
]
9.DE.25Fluoro-potassic-magnesio-arfvedsonite
[(K,Na)][Na
 
2
][Mg
 
4
Fe
3+
 
][(F,OH)
 
2
|[Si
 
8
O
 
22
]
9.DE.25Sodic-ferri-ferropedrizite
[Na][Li
 
2
][Fe
2+
2
Fe
3+
2
Li][(OH)
 
2
|Si
 
8
O
 
22
]
9.DE.25Potassic-magnesio-arfvedsonite
[K][Na
 
2
][Mg
 
4
Fe
3+
 
][(OH)
 
2
|Si
 
8
O
 
22
]

Other Names for Fluoropargasite

Synonyms:
IMA2003-050
German names:
Fluorpargasit
Russian names:
Фторпаргасит

Other Information

Fluorescence in UV light:None
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Fluoropargasite

Reference List:Oberti, R., Sardone, N., Hawthorne, F.C., Raudsepp, M., and urnock, A.C. (1995c) Synthesis and crystal-structure refinement of synthetic fluor-pargasite. Canadian Mineralogist: 33: 25-31.

Kahl W.-A., Maresch W.V., Welch M.D. (2003): Enthalpy of formation of pargasite by high-temperature solution calorimetry and heat capacity of pargasite and fluoropargasite by differential scanning calorimetry. European Journal of Mineralogy, 15, 617-628.

Lupulescu, M.V., Rakovan, J., Robinson, G.W., Hughes, J.M. (2005): Fluoropargasite, a new member of the Group 2, calcic amphiboles, from Edenville, Orange County, New York. Canadian Mineralogist, 43, 1423-1428.

Hawthorne, Frank C., and Roberta Oberti (2006), On the classification of amphiboles: Canadian Mineralogist:
44(1): 1-21.

Internet Links for Fluoropargasite

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  • Raman and XRD data at RRUFF project
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  • Search for Fluoropargasite in the Natural History Museum (London) online catalogue
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    Localities for Fluoropargasite

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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    USA
     
    • New York
      • Orange Co.
        • Monroe Township
    		M. V. Lupulescu et al.: Can. Min. 43:1423-1428 (2005)
        • Town of Warwick
    		M. V. Lupulescu et al.: Can. Min. 43:1423-1428 (2005)
    George Robinson & Steven Chamberlain (2007) Gazetteer of major New York State mineral localities. Rocks & Minerals, 82, #6, 472-483.
      • St Lawrence Co.
    		M. V. Lupulescu et al.: Can. Min. 43:1423-1428 (2005)
    Mineral and/or Locality
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