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Poppiite

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Valgraveglia Mine (Gambatesa Mine), Reppia, Graveglia Valley, Ne, Genova Province, Liguria, Italy
© G. Armellino




Formula:
Ca
 
2
(V
3+
 
,Fe
3+
 
,Mg)(V
3+
 
,Al)
 
2
[(OH,O)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
System:MonoclinicColour:Greenish brown
Name:In memory of Luciano Poppi, Professor of Mineralogy, Modena and Reggio Emilia University, and all his generous and fruitful efforts devoted to mineral science.


Pumpellyite Group.

Classification of Poppiite

IMA status:Approved 2005
Strunz 8th edition ID:8/C.24-75
Nickel-Strunz 10th (pending) edition ID:9.BG.20

9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
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Type Occurrence of Poppiite

Type Locality:Valgraveglia Mine (Gambatesa Mine), Reppia, Graveglia Valley, Ne, Genova Province, Liguria, Italy
General Appearance of Type Material:minute prismatic crystals up to 0.6 mm
Place of Conservation of Type Material:Museo Mineralogico e Geologico Estene, GEMMA 1786 at the Modena and Reggio Emilia University, Italy.
Geological Setting of type material:Manganese deposit
Associated Minerals at type locality:
RoscoeliteGoldmaniteGanophylliteCalciteAxinite-(Mn)

Physical Properties of Poppiite

Colour:Greenish brown
Density (measured):3.36 g/cm3
Density (calculated):3.44 g/cm3

Crystallography of Poppiite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m {B1 1 2/m} {C2/m} {C1 2/m 1}
Cell Parameters:a = 19.2889Å, b = 6.0444Å, c = 8.8783Å
β = 97.328°
Ratio:a:b:c = 3.191 : 1 : 1.469
Unit Cell Volume:V 1026.66 ų
Morphology:Minute (0.1 to 0.6 mm) prismatic crystals.
X-Ray Powder Diffraction:
d-spacingIntensity
2.930 (100)
3.817 (70)
2.548 (65)
2.551 (62)
1.612 (57)
2.367 (51)
Comments:Format: d/Å (I/%) (hkl)

Optical Data of Poppiite

Type:Biaxial (-)
RI values: nα = 1.768 nβ = 1.804 nγ = 1.810
2V:Calculated: 44°
Maximum Birefringence:δ = 0.042

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Pleochroism:Visible
Comments:α = light yellowish brown
ß = deep greenish brown
γ = brown to reddish brown

Chemical Properties of Poppiite

Formula:
Ca
 
2
(V
3+
 
,Fe
3+
 
,Mg)(V
3+
 
,Al)
 
2
[(OH,O)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
All elements listed in formula:Al, Ca, Fe, H, Mg, O, Si, V

Relationship of Poppiite to other Species

Member of Group:
Pumpellyite Group:
Related Minerals - Nickel-Strunz Grouping):

- +
9.BG.05bAllanite-(Ce)
{CaCe}{Al
 
2
Fe
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05bAllanite-(La)
{CaLa}{Al
 
2
Fe
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05bAllanite-(Y)
{CaY}{Al
 
2
Fe
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05aClinozoisite
{Ca
 
2
}{Al
 
3
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05bDissakisite-(Ce)
{CaCe}{Al
 
2
Mg}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Dollaseite-(Ce)
{CaCe}{MgAlMg}[F|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05aEpidote
{Ca
 
2
}{Al
 
2
Fe
3+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Epidote-(Pb)
CaPbFe
3+
 
Al
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Khristovite-(Ce)
{CaCe}{MgAlMn
2+
 
}[F|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Mukhinite
{Ca
 
2
}{Al
 
2
V
3+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Piemontite
{Ca
 
2
}{Al
 
2
Mn
3+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Piemontite-(Sr)
{CaSr}{Al
 
2
Mn
3+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05bManganiandrosite-(La)
{LaMn
2+
 
}{Mn
3+
 
AlMn
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Tawmawite
Ca
 
2
(Al,Fe
3+
 
,Cr)
 
3
[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Manganipiemontite-(Sr)
{CaSr}{Mn
3+
 
AlMn
3+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Ferriallanite-(Ce)
{CaCe}{Fe
3+
 
AlFe
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Clinozoisite-(Sr)
CaSrAl
 
3
(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Ferriepidote
9.BG.05Manganiandrosite-(Ce)
(Mn
2+
 
,Ca)(Ce,REE)Mn
3+
 
AlMn
2+
 
(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Dissakisite-(La)
{CaLa}{Al
 
2
Mg}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Vanadoandrosite-(Ce)
{Mn
2+
 
Ce}{V
3+
 
AlMn
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Androsite-(La)
9.BG.05Uedaite-(Ce)
Mn
2+
 
CeAl
 
2
Fe
2+
 
[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Epidote-(Sr)
CaSrAl
 
2
Fe
3+
 
(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bIMA2009-073
Mn
2+
 
NdAlAlFe
3+
 
(Si
 
2
O
 
7
)(SiO
 
4
)O
 
2
9.BG.10Zoisite
{Ca
 
2
}{Al
 
3
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.15Macfallite
Ca
 
2
(Mn
3+
 
,Al)
 
3
[(OH)
 
3
|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.15Sursassite
Mn
 
2
Al
 
3
[(OH)
 
3
|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.20Julgoldite-(Fe2+)
Ca
 
2
(Fe
2+
 
,Mg)(Fe
3+
 
,Al)
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Okhotskite
Ca
 
8
(Mn
2+
 
,Mg)
 
4
(Mn
3+
 
,Al,Fe)
 
8
Si
 
12
O
 
56-n
(OH)
 
n
9.BG.20Pumpellyite-(Fe2+)
Ca
 
2
Fe
2+
 
Al
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Pumpellyite-(Fe3+)
Ca
 
2
(Fe
3+
 
,Mg,Fe
2+
 
)(Al,Fe
3+
 
)
 
2
[(OH,O)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Pumpellyite-(Mg)
Ca
 
2
MgAl
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Pumpellyite-(Mn2+)
Ca
 
2
(Mn
2+
 
,Mg)(Al,Mn
3+
 
,Fe
3+
 
)
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Shuiskite
Ca
 
2
(Mg,Al)(Cr,Al)
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · 2H
 
2
O
9.BG.20Julgoldite-(Fe3+)
Ca
 
2
(Fe
3+
 
,Mg)(Fe
3+
 
,Al)
 
2
[(OH,O)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Pumpellyite-(Al)
Ca
 
2
(Al,Fe
2+
 
,Mg)Al
 
2
[(OH,O)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Julgoldite-(Mg)
Ca
 
2
(Mg,Fe
2+
 
)(Fe
3+
 
,Al)
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.25Ganomalite
Pb
 
9
Ca
 
5
Mn[O|SiO
 
4
|(Si
 
2
O
 
7
)
 
4
]
9.BG.30Rustumite
Ca
 
10
(Si
 
2
O
 
7
)
 
2
(SiO
 
4
)Cl
 
2
(OH)
 
2
9.BG.35Vesuvianite
Ca
 
10
(Mg,Fe)
 
2
Al
 
4
Si
 
9
O
 
34
(OH)
 
4
9.BG.35Wiluite
Ca
 
19
(Al,Mg,Fe,Ti)
 
13
(B,Al,[ ])
 
5
Si
 
18
O
 
68
(O,OH)
 
10
9.BG.35Manganvesuvianite
Ca
 
19
Mn(Al,Mn,Fe)
 
19
(Mg,Mn)
 
2
Si
 
18
O
 
69
(OH)
 
9
9.BG.35Fluorvesuvianite
Ca
 
19
(Al,Mg,Fe
2+
 
)
 
13
[(F,OH,O)
 
10
|(SiO
 
4
)
 
10
|(Si
 
2
O
 
7
)
 
4
]
9.BG.40Vyuntspakhkite-(Y)
Y
 
4
Al
 
3
Si
 
5
O
 
18
(OH)
 
5
9.BG.45Dellaite
Ca
 
6
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
9.BG.50Gatelite-(Ce)
CaCe
 
3
Al
 
2
(Al,Mg)(Mg,Fe
2+
 
,Al)[(O,F)|(OH,O)
 
2
|(SiO
 
4
)
 
3
|Si
 
2
O
 
7
]
9.BG.55Västmanlandite-(Ce)
Ca(Ce,La)
 
3
Al
 
2
Mg
 
2
 [F|(OH)
 
2
|(SiO
 
4
)
 
3
|Si
 
2
O
 
7
]

Other Names for Poppiite

Synonyms:
IMA2005-018
Other Languages:

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Poppiite

Reference List:Brigatti, M.F., Caprilli, E., Marchesini, M. (2006): "Poppiite, the V3+ end member of the pumpellyite group: Description and crystal structure", American Mineralogist 91, 584-588

Caprilli, E. (2004): "Miche e cloriti: implicazioni cristallochimiche", PhD thesis, University of Modena and Reggio Emilia, 205 pp

Caprilli, E. (2005): "Micas and chlorites: crystal chemical implications", Plinius 31, 65-70

Internet Links for Poppiite

Search Engines:
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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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    Localities for Poppiite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Italy
     
    • Liguria
      • Genova Province
        • Ne
          • Graveglia Valley
            • Reppia
    		Brigatti, M.F., Caprilli, E., Marchesini, M. (2006): "Poppiite, the V3+ end member of the pumpellyite group: Description and crystal structure", American Mineralogist 91, 584-588.
    Mineral and/or Locality
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    Copyright © Jolyon Ralph and Ida Chau 1993-2010. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 19th Aug 2010 21:44:12