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Poppiite

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Val Graveglia (Gambatesa) Mine, Reppia, Graveglia Valley, Ne, Genova Province, Liguria, Italy
© G. Armellino

Formula:
Ca
 
2
(V
3+
 
,Fe
3+
 
,Mg)(V
3+
 
,Al)
 
2
[(OH,O)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
System:MonoclinicColour:Greenish brown
Name:In memory of Luciano Poppi, Professor of Mineralogy, Modena and Reggio Emilia University, and all his generous and fruitful efforts devoted to mineral science.


Pumpellyite group

Classification of Poppiite

IMA status:Approved 2005
Strunz 8th edition ID:8/C.24-75
Nickel-Strunz 10th (pending) edition ID:9.BG.20

9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
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Type Occurrence of Poppiite

Type Locality:Val Graveglia (Gambatesa) Mine, Reppia, Graveglia Valley, Ne, Genova Province, Liguria, Italy
General Appearance of Type Material:minute prismatic crystals up to 0.6 mm
Place of Conservation of Type Material:Museo Mineralogico e Geologico Estene, GEMMA 1786 at the Modena and Reggio Emilia University, Italy.
Geological Setting of type material:Manganese deposit
Associated Minerals at type locality:
RoscoeliteAxinite-(Mn)GoldmaniteGanophylliteCalcite

Physical Properties of Poppiite

Colour:Greenish brown
Density (measured):3.36 g/cm3
Density (calculated):3.44 g/cm3

Crystallography of Poppiite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m (B1 1 2/m) [C2/m] {C1 2/m 1}
Cell Parameters:a = 19.2889Å, b = 6.0444Å, c = 8.8783Å
β = 97.328°
Ratio:a:b:c = 3.191 : 1 : 1.469
Unit Cell Volume:V 1026.66 ų
Morphology:Minute (0.1 to 0.6 mm) prismatic crystals.
X-Ray Powder Diffraction:
d-spacingIntensity
2.930 (100)
3.817 (70)
2.548 (65)
2.551 (62)
1.612 (57)
Comments:Format: d/Å (I/%) (hkl)

Optical Data of Poppiite

Type:Biaxial (-)
RI values: nα = 1.768 nβ = 1.804 nγ = 1.810
2V:Calculated: 44°
Maximum Birefringence:δ = 0.042

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Pleochroism:Visible
Comments:α = light yellowish brown
ß = deep greenish brown
γ = brown to reddish brown

Chemical Properties of Poppiite

Formula:
Ca
 
2
(V
3+
 
,Fe
3+
 
,Mg)(V
3+
 
,Al)
 
2
[(OH,O)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
Essential elements:
All elements listed in formula:Al, Ca, Fe, H, Mg, O, Si, V

Relationship of Poppiite to other Species

Related Minerals - Nickel-Strunz Grouping):
9.BG.05Allanite-(Ce)
{CaCe}{Al
 
2
Fe
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Allanite-(La)
{CaLa}{Al
 
2
Fe
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Allanite-(Y)
{CaY}{Al
 
2
Fe
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Clinozoisite
{Ca
 
2
}{Al
 
3
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Dissakisite-(Ce)
{CaCe}{Al
 
2
Mg}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Dollaseite-(Ce)
{CaCe}{MgAlMg}[F|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Epidote
{Ca
 
2
}{Al
 
2
Fe
3+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Epidote-(Pb)
{CaPb}{Al
 
3
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Khristovite-(Ce)
{CaCe}{MgAlMn
2+
 
}[F|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Mukhinite
{Ca
 
2
}{Al
 
2
V
3+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Piemontite
{Ca
 
2
}{Al
 
2
Mn
3+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Piemontite-(Sr)
{CaSr}{Al
 
2
Mn
3+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Manganiandrosite-(La)
{LaMn
2+
 
}{Mn
3+
 
AlMn
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Tawmawite
Ca
 
2
(Al,Fe
3+
 
,Cr)
 
3
[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Manganipiemontite-(Sr)
{CaSr}{Mn
3+
 
AlMn
3+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Ferriallanite-(Ce)
{CaCe}{Fe
3+
 
AlFe
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Clinozoisite-(Sr)
CaSrAl
 
3
(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Ferriepidote
9.BG.05Manganiandrosite-(Ce)
(Mn
2+
 
,Ca)(Ce,REE)AlMn
3+
 
Mn
2+
 
(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Dissakisite-(La)
{CaLa}{Al
 
2
Mg}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Vanadoandrosite-(Ce)
{Mn
2+
 
Ce}{V
3+
 
AlMn
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05Androsite-(La)
9.BG.05Uedaite-(Ce)
{Mn
2+
 
Ce}{Al
 
2
Fe
2+
 
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.05IMA2006-055
CaSrAl
 
2
Fe
3+
 
(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.10Zoisite
{Ca
 
2
}{Al
 
3
}[O|OH|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.15Macfallite
Ca
 
2
(Mn
3+
 
,Al)
 
3
[(OH)
 
3
|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.15Sursassite
Mn
 
2
Al
 
3
[(OH)
 
3
|SiO
 
4
|Si
 
2
O
 
7
]
9.BG.20Julgoldite-(Fe2+)
Ca
 
2
(Fe
2+
 
,Mg)(Fe
3+
 
,Al)
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Okhotskite
Ca
 
8
(Mn,Mg)
 
4
(Mn,Al,Fe)
 
8
Si
 
12
O
 
56-n
(OH)
 
n
9.BG.20Pumpellyite-(Fe2+)
Ca
 
2
Fe
2+
 
Al
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Pumpellyite-(Fe3+)
Ca
 
2
(Fe
3+
 
,Mg,Fe
2+
 
)(Al,Fe
3+
 
)
 
2
[(OH,O)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Pumpellyite-(Mg)
Ca
 
2
MgAl
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Pumpellyite-(Mn2+)
Ca
 
2
(Mn
2+
 
,Mg)(Al,Mn
3+
 
,Fe
3+
 
)
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Shuiskite
Ca
 
2
(Mg,Al)(Cr,Al)
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · 2H
 
2
O
9.BG.20Julgoldite-(Fe3+)
Ca
 
2
(Fe
3+
 
,Mg)(Fe
3+
 
,Al)
 
2
[(OH,O)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Pumpellyite-(Al)
Ca
 
2
(Al,Fe
2+
 
,Mg)Al
 
2
[(OH,O)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.20Julgoldite-(Mg)
Ca
 
2
(Mg,Fe
2+
 
)(Fe
3+
 
,Al)
 
2
[(OH)
 
2
|SiO
 
4
|Si
 
2
O
 
7
] · H
 
2
O
9.BG.25Ganomalite
Pb
 
9
Ca
 
5
Mn[O|SiO
 
4
|(Si
 
2
O
 
7
)
 
4
]
9.BG.30Rustumite
Ca
 
10
(Si
 
2
O
 
7
)
 
2
(SiO
 
4
)Cl
 
2
(OH)
 
2
9.BG.35Vesuvianite
Ca
 
10
(Mg,Fe)
 
2
Al
 
4
Si
 
9
O
 
34
(OH)
 
4
9.BG.35Wiluite
Ca
 
19
(Al,Mg,Fe,Ti)
 
13
(B,Al,[ ])
 
5
Si
 
18
O
 
68
(O,OH)
 
10
9.BG.35Manganvesuvianite
Ca
 
19
Mn(Al,Mn,Fe)
 
19
(Mg,Mn)
 
2
Si
 
18
O
 
69
(OH)
 
9
9.BG.35Fluorvesuvianite
Ca
 
19
(Al,Mg,Fe
2+
 
)
 
13
[(F,OH,O)
 
10
|(SiO
 
4
)
 
10
|(Si
 
2
O
 
7
)
 
4
]
9.BG.40Vyuntspakhkite-(Y)
Y
 
4
Al
 
3
Si
 
5
O
 
18
(OH)
 
5
9.BG.45Dellaite
Ca
 
6
Si
 
3
O
 
11
(OH)
 
2
9.BG.50Gatelite-(Ce)
CaCe
 
3
Al
 
2
(Al,Mg)(Mg,Fe
2+
 
,Al)[(O,F)|(OH,O)
 
2
|(SiO
 
4
)
 
3
|Si
 
2
O
 
7
]
9.BG.55Västmanlandite-(Ce)
Ca(Ce,La)
 
3
Al
 
2
Mg
 
2
 [F|(OH)
 
2
|(SiO
 
4
)
 
3
|Si
 
2
O
 
7
]

Other Names for Poppiite

Synonyms:
IMA2005-018

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Poppiite

Reference List:Brigatti, M.F., Caprilli, E., Marchesini, M. (2006): "Poppiite, the V3+ end member of the pumpellyite group: Description and crystal structure", American Mineralogist 91, 584-588

Caprilli, E. (2004): "Miche e cloriti: implicazioni cristallochimiche", PhD thesis, University of Modena and Reggio Emilia, 205 pp

Caprilli, E. (2005): "Micas and chlorites: crystal chemical implications", Plinius 31, 65-70

Internet Links for Poppiite

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    Localities for Poppiite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Italy
     
    • Liguria
      • Genova Province
        • Ne
          • Graveglia Valley
            • Reppia
    		Brigatti, M.F., Caprilli, E., Marchesini, M. (2006): "Poppiite, the V3+ end member of the pumpellyite group: Description and crystal structure", American Mineralogist 91, 584-588.
    Mineral and/or Locality
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